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1,3-Dimethylimidazolium Methanesulfonate

    • Product Name 1,3-Dimethylimidazolium Methanesulfonate
    • Alias [BMIM][MeSO3]
    • Einecs 629-503-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    416551

    Chemical Name 1,3-Dimethylimidazolium Methanesulfonate
    Molecular Formula C6H12N2O3S
    Molecular Weight 192.24 g/mol
    Cas Number 152180-01-9
    Appearance Colorless to pale yellow liquid or solid
    Melting Point 38-42 °C
    Boiling Point Decomposes before boiling
    Density 1.25 g/cm3 (approx)
    Solubility In Water Miscible
    Purity Typically ≥98%
    Refractive Index n20/D 1.481 (approx)
    Storage Conditions Store at room temperature, keep tightly closed
    Ph Neutral to slightly acidic in aqueous solution
    Smiles Cn1cc[n+](c1C)C.[O-]S(=O)(=O)C
    Ec Number 687-552-2

    As an accredited 1,3-Dimethylimidazolium Methanesulfonate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 500g white HDPE bottle with a red screw cap, labeled “1,3-Dimethylimidazolium Methanesulfonate” and CAS, hazard, and batch information.
    Shipping 1,3-Dimethylimidazolium Methanesulfonate should be shipped in tightly sealed containers, protected from moisture and incompatible materials. It must be labeled clearly according to regulatory requirements. Handle with appropriate personal protective equipment. Transport under ambient conditions unless otherwise specified by the supplier’s safety data sheet. Comply with local, national, and international chemical shipping regulations.
    Storage 1,3-Dimethylimidazolium methanesulfonate should be stored in a tightly sealed container, away from moisture and incompatible materials such as strong oxidizers. Keep in a cool, dry, well-ventilated area, and protect from direct sunlight. Store at room temperature and avoid temperature extremes. Ensure proper labeling, and restrict access to trained personnel. Follow local regulations for safe chemical storage.
    Application of 1,3-Dimethylimidazolium Methanesulfonate

    Applications of 1,3-Dimethylimidazolium Methanesulfonate in Industrial Manufacturing

    1,3-Dimethylimidazolium methanesulfonate is recognized in various strategic sectors for its performance in catalysis, electrochemistry, and polymer modification. As a direct manufacturer, we supply this ionic liquid to downstream industries engaged in advanced materials processing, specialty catalysis, high-purity electrochemical applications, and sustainable process development. Below, we detail main industrial segments where our product plays a critical, well-defined role.

    1. Electroplating and Metal Surface Treatment

    Electroplating companies use this ionic liquid as an essential electrolyte component in non-aqueous and hybrid systems. The raw material provides enhanced ionic mobility, supporting uniform metal deposition and reduced defects in final coatings. Operators typically combine it with metal salts and additive formulations, optimizing bath conductivity without introducing problematic impurities seen in older systems. The compound’s low volatility and stability across a wide voltage range make it suitable for precision electrochemical control in high-value plating operations, such as those for electronic contacts and connector terminals.

    Industry compliance standards

    • RoHS Directive 2011/65/EU
    • REACH Regulation (EC) No 1907/2006
    • IEC 62321 for hazardous substances in electronics
    • ISO 9001:2015-certified quality management

    Typical usage ratio

    • 5–30% by volume in electrolyte baths; range adjusted per metal system and target deposition rate

    Downstream process integration

    • Mix into electroplating baths prior to metal salt additions
    • Used in closed systems to minimize evaporation and ensure consistent ion conductivity
    • Process typically maintained between 25–50°C for optimal viscosity control

    Final product types

    • Gold- and silver-plated connectors
    • Copper tracks for printed circuit boards
    • Corrosion-resistant automotive fasteners
    • Decorative plated jewelry components

    2. Biomass Processing and Cellulosic Dissolution

    Producers in bio-refining and advanced materials sectors employ this material as a cellulose solvent or co-solvent. Its ionic structure enables direct dissolution of lignocellulose without pre-derivatization, streamlining conversion steps for biofuel, biopolymer, or specialty cellulose ether production. Process engineers leverage the raw material’s strong hydrogen bond disrupting capability which assists in breaking biomass recalcitrance, enabling enzymatic or catalytic access in further processing stages. Systems using this approach can reduce both solvent recycling demand and process temperatures compared to legacy solvents such as DMAc or NMMO.

    Industry compliance standards

    • ISO 9001:2015 for production control
    • Food Chemical Codex (where food-grade derivatives are produced)
    • EFSA food contact material migration limits (for relevant polymers)
    • Local environmental permitting on solvent use and discharge

    Typical usage ratio

    • 40–70% by weight (relative to total solvent system); ratio refined per biomass feedstock type and target degree of polymerization

    Downstream process integration

    • Acts as main solvent in the initial cellulose dissolution reactor
    • Operates at 80–120°C for efficient dissolution of raw biomass or processed pulp
    • Precipitates cellulose using antisolvents (e.g., water) after target dissolution time

    Final product types

    • Dissolving pulp for regenerated fibers (e.g., viscose, lyocell)
    • Microcrystalline cellulose for food/pharma
    • Bio-based platform chemicals
    • Cellulose derivatives for filtration or pharmaceutical excipients

    3. Homogeneous Catalytic Synthesis

    Chemical manufacturers employ this imidazolium salt as a reaction medium for homogeneous catalysis, frequently in coupling or alkylation synthesis. Its high polarity, low nucleophilicity, and capacity to dissolve transition metal complexes provide an environment that supports high catalyst turnover number and minimal deactivating side reactions. The tailored ion profile enables selective regulation of reaction kinetics, critical for processes such as carbon–carbon bond formation in pharmaceutical intermediates and specialty fine chemicals manufacturing.

    Industry compliance standards

    • GMP guidelines (EU GMP, 21 CFR Part 210/211 for pharma intermediates)
    • ISO 14001 for chemical environmental management
    • Internal HSE policies for handling reactive solvents
    • REACH registration (where volume thresholds met)

    Typical usage ratio

    • Solvent/reaction medium: 60–95% by volume of the reaction matrix, modulated for catalyst solubility or work-up

    Downstream process integration

    • Charged to batch or flow reactors before catalyst and substrate additions
    • Reaction temperature typically maintained at 50–110°C
    • Post-reaction, the ionic liquid is separated and recycled via phase separation or distillation under reduced pressure

    Final product types

    • API intermediates for small-molecule drugs
    • Specialty monomers for advanced polymerization
    • Functionalized aromatics for electronic chemicals
    • Chiral building blocks for agrochemical synthesis

    4. Electrolytes in Capacitor and Battery Systems

    Energy storage device fabricators utilize 1,3-dimethylimidazolium methanesulfonate as a non-volatile ionic medium in safer, long-life capacitor and advanced battery technologies. Compared to traditional organic electrolytes, it presents negligible vapor pressure, thermal stability beyond 150°C, and electrochemical windows well-suited to next-generation supercapacitors and lithium-free designs. The controlled anion/cation pairing allows engineers to fine-tune ion mobility, directly influencing capacitance and cycle stability in solid-state and hybrid capacitor assemblies. In pilot production, manufacturers report lower cell impedance and improved reliability in fast-charge/discharge tests.

    Industry compliance standards

    • IEC 61056 and IEC 60952 (industrial secondary batteries)
    • UN/IEC 62133 for battery safety
    • EU Battery Directive 2006/66/EC
    • ISO 14001 for environmental controls in electrolyte handling

    Typical usage ratio

    • 60–90% by volume in liquid electrolyte formulations; concentration varies based on device protocol and required conductivity

    Downstream process integration

    • Fill directly into cell or module assemblies under inert atmosphere
    • Blended with functional additives for enhanced stability or performance
    • Curing or post-assembly conditioning under controlled temperature to achieve full impregnation

    Final product types

    • Supercapacitor modules for industrial and grid applications
    • Hybrid capacitors for energy harvesting equipment
    • Prototype solid-state batteries
    • Advanced energy storage cells for R&D platforms

    5. Ionothermal Synthesis in Porous Material Manufacturing

    Manufacturers specializing in porous inorganic or hybrid materials adopt this ionic liquid in ionothermal synthesis processes, where the reaction medium doubles as solvent and template. Its ability to withstand high synthesis temperatures and dissolve diverse precursors promotes uniform nucleation of frameworks such as zeolitic imidazolate frameworks (ZIFs) and certain metal-organic frameworks (MOFs). The raw material controls particle morphology, pore dimensions, and crystallinity, underpinning reproducible manufacturing of high-surface-area adsorbents and selective separation media.

    Industry compliance standards

    • ISO 9001:2015 for material quality assurance
    • ASTM E1797 (adsorbent performance)
    • REACH registration for distributed volumes in the EU
    • Local regulatory controls on post-synthesis solvent recovery

    Typical usage ratio

    • 70–100% ionic liquid as sole solvent system in batch reactors; dilution with water or polar aprotic solvents as required by precursor solubility

    Downstream process integration

    • Combine with metal salts and organic ligands in sealed, high-temperature reactors
    • Post-synthesis, recover crystals by filtration and wash with compatible solvents to remove excess ionic liquid

    Final product types

    • Zeolitic imidazolate frameworks for gas storage or catalysis
    • Functional porous sorbents for water treatment
    • Polymer-inorganic composites for membrane separation
    • High-surface-area supports for heterogeneous catalysts
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    Certification & Compliance
    More Introduction

    1,3-Dimethylimidazolium Methanesulfonate: Insights From the Manufacturer

    Real Substance Shaped by Real Experience

    1,3-Dimethylimidazolium methanesulfonate stands as a pillar in our ionic liquid lineup. My team and I have spent years refining its synthesis, watching each batch reveal the fine line between reliable performance and unwanted side-products. This is not just another salt to us—it is a carefully crafted tool for chemists looking for a combination of stability, low volatility, and the kind of ionic mobility that opens doors to new processes.

    Direct From the Production Floor

    Scaling up the manufacture of 1,3-dimethylimidazolium methanesulfonate did not come easy. We have invested heavily in controlling moisture and impurity levels, bringing batch consistency as close as technical know-how and good plant hygiene can get. At full scale, each kilogram that leaves our facility has met a standard set by hands-on engineers and chemists who know what it feels like to test for chloride traces or poke at sticky residue left after an incomplete reaction. You will see the difference in its bright white powder or crystal form, clarity in the melt, and predictable solvation abilities.

    Pushing Beyond Conventional Solvents

    Those who handle traditional organic solvents, like acetonitrile or DMF, know the hazards and the ventilation headaches. Ionic liquids enter as a fresh alternative, and among them, 1,3-dimethylimidazolium methanesulfonate shines thanks to its relatively low toxicity, thermal stability, and a melting point that doesn’t limit its use to exotic labware. We’ve seen researchers shift to this compound to put an end to persistent volatility losses or to explore new electrochemical methods. No atmospheric pressure distillation needed. Minimal vapor means no fumes chasing you out of the lab or shop floor.

    A Reliable Choice for Modern Chemistry

    Many customers send us feedback about the search for a greener, safer, and often simpler medium for reactions and separations. This product’s ionic character allows it to dissolve a much wider array of compounds compared to classic molecular solvents. We frequently see it adopted in the synthesis of energetic materials, catalysis, cellulose processing, and lithium battery formulation. Its ability to sustain electrochemical activity at moderate voltages gives new life to everything from plating baths to next-generation battery cells and capacitors.

    Form and Purity: What We Deliver

    Historically, we have aimed for purity exceeding 99%, with water content measured by Karl Fischer titration at below 0.2%. Even a small moisture spike can alter reaction yields, and organic impurities cloud solutions, so each run gets tested until it tracks with known spectra. The typical appearance of our product is a crystalline white solid under standard storage. It packs densely and shows uniform grain, letting customers portion and dissolve the amounts they want without clumping. Storage in a dry, closed environment keeps the compound in peak condition for months. But we always recommend careful handling, as open exposure will eventually draw in moisture.

    Not Just Another Imidazolium Salt

    1,3-dimethylimidazolium methanesulfonate sits apart from its analogs in real-world stability and handling. Compare it to the more sensitive halide salts, like 1,3-dimethylimidazolium chloride or bromide. We have seen how the halides can introduce corrosivity and sensitivity to air or trace water, sometimes eating away at glassware or introducing unpredictable behavior in catalytic runs. The methanesulfonate counterion changes this playbook. It brings in both acidity and robustness, holding up better in acid-sensitive synthetic steps, and it often allows for simpler workup. Our customers in cellulose research, for example, point out much easier dissolution and homogeneous solution preparation than what they get with halide-based ionic liquids.

    Solving Practical Problems in Industrial and Lab Research

    Handling large volumes of corrosive solvents or hazardous electrolytes used to be a major pain point. Introducing 1,3-dimethylimidazolium methanesulfonate has brought a real improvement for both bench chemists and plant operators. Its negligible vapor pressure greatly reduces workplace exposure risk, and its thermal window allows many reactions to proceed hotter or cooler without pressure buildup or decomposition. We’ve walked through customers’ facilities and seen how waste handling simplifies, with less air purification and drainage treatment compared to traditional organic systems. This also cuts down on environmental compliance headaches, reducing both the monitoring burden and downstream costs.

    Why Direct Manufacturing Expertise Matters

    There’s theory and there’s practice. Our team lives where the two meet. Most questions we get from experienced chemists boil down to, “How does your batch compare to what I’ve used?” We encourage side-by-side trials because our processes are fine-tuned for chemical stability and low residual base. That means fewer unwanted side-reactions and higher selectivity for key syntheses. We keep analytical equipment close to our reactors—keeping quality lab and process engineers talking daily—rather than outsourcing these steps. If you’ve ever lost a week to a poor-quality batch, you know why this matters.

    Applications Proven by Practice

    Most of our 1,3-dimethylimidazolium methanesulfonate leaves the factory for use in one of a handful of demanding applications. Electrochemistry leads the field—lithium battery researchers, in particular, appreciate its thermal endurance and stable behavior under high voltages. Those working with cellulose and lignocellulosic biomass value it for its ability to break down stubborn plant matter that resists almost every other solvent. The catalysis crowd looks to it for tuning acidity and polarity, especially where transition metal complexes need gentle solvation or immobilization.

    We have seen our customers run reactions at temperatures well above those tolerated by acetonitrile, with fewer side-products and easier workup. Ion pair stability also shows gains, notably in the synthesis of specialty materials or in chemical extraction setups handling both aqueous and organic layers. Environmental labs prefer its low hazard profile since it simplifies waste stream management and final product purification.

    Weighing Choices: 1,3-Dimethylimidazolium Methanesulfonate vs. Other Ionic Liquids

    Hundreds of ionic liquids have crossed our reactors. Some offer wider liquid ranges, others promise greater solubility or reactivity. Still, 1,3-dimethylimidazolium methanesulfonate quietly wins out on practical points: pronounced resistance to hydrolysis, compatibility with diverse functional groups, and a lack of unwanted halide contamination—important for certain catalysts and sensitive organic frameworks. The methanesulfonate anion, we’ve found, handles chlorides and other reactive species more gently than its counterparts. A research group once shared their experience with a bromide batch that destroyed a high-value electrode; since switching to methanesulfonate, those failures vanished.

    Supporting Clients With Know-How Earned on Site

    Fielding technical support for our product keeps us grounded. Most phone calls or emails come from chemists chasing cleaner reactions, more stable electrolytes, or better performance from their reactors. Problems range from accidental exposure to moisture, to incompatibility with exotic metals, to persistent coloration in final solutions. In many of these cases, our solution comes from firsthand troubleshooting—adjusting drying protocols, optimizing crystallization, or using real-time NMR to rule out slow decomposition. We’ve rolled these lessons into our production processes, and in our recurring consultations.

    Behind Every Gram: The Manufacturing Story

    Strict control means more than notes in a logbook. Each raw material—usually starting with imidazole, methylating agents, and purified methanesulfonic acid—undergoes quality testing before it sees our reactors. My team takes pride in keeping cross-contamination at bay, keeping batch traceability tight, and documenting the quirks that pop up in daily work. For example, we learned the hard way that a small uptick in starting water content can cause excessive foaming downstream, or that slight over-methylation leads to troublesome byproducts. The workbench shapes better process control than any instrument alone can.

    Responding to Market Needs

    Over time, demand has shifted from academic research to large-scale industrial use. We have responded by offering bulk packaging and logistics support, because even top-quality product fails if it arrives clumpy or degraded. We routinely advise on storage—cool, dry, and tightly sealed, preferably with inert gas whenever long-term stowage is planned. Onsite handling, from powder transfer to dissolution, needs practical attention. We notice most customer losses trace back to sloppy sealing or air exposure, so we build safeguards into every shipment.

    Ready for the Lab or the Plant

    Small R&D teams pick up our 1,3-dimethylimidazolium methanesulfonate for synthesis runs, sometimes as little as a gram or two. They usually look for sample clarity, predictable melting point and low odour. Larger industrial users request hundreds of kilograms, focusing on batch reproducibility, reliable supply, and responsive technical support. Each group brings its own language—synthetic chemists probe for spectral clarity, electrochemists for charge transfer rates, process engineers for long-term storage and compatibility. We have met these customers in everything from brick-walled university labs to high-volume pilot plants, learning each niche and adjusting our approach on the ground.

    Emphasizing Environmental and Safety Benefits

    In an era shaped by tighter safety and environmental regulation, choosing 1,3-dimethylimidazolium methanesulfonate means fewer compliance hurdles. With virtually no vapor or flammability risk, and no VOC emissions, our product fits well into safety-conscious operations. Waste disposal typically moves more smoothly than with halogenated or aromatic solvents; even municipal and facility waste handlers prefer the straightforward hazard classifications. In our years tracking solvent incidents, very few involve properly handled ionic liquids—meaning workplace risk really does go down.

    Many of our production improvements stem from customer feedback—concerns over glove compatibility, spill cleanup, and even labeling clarity. We respond by updating our standard procedures, investing in better packaging, and keeping lines open for suggestions or warnings from actual users.

    Continuous Improvement, Grounded in Practice

    Manufacturing is never static. Every year brings insight from unexpected failures, lab mishaps, and evolving end applications. We revisit our protocols for drying, crystallization, and packaging to incorporate both new analytical data and anecdotal evidence gathered from those working with our product on the front lines. Each tweak gets tested, logged, and—if worthwhile—folded back into the workflow. This cycle has trimmed product lead times, improved handling, and delivered a steadier product than early runs could manage.

    Challenges Still on Our Mind

    No chemical, no matter how well managed, exists without issues. The biggest challenge our team faces lies in moisture control. Ionic liquids, especially those with strong hydrogen bonding abilities like this one, tend to absorb water from the air. Even with sealed drums and dry rooms, the risk never fully leaves, so we keep working on better seals and desiccant combinations. Meanwhile, increasing regulation on upstream reagents prompts us to keep raw material sources qualified and contingency planning in place. Finally, with rising customer expectations for transparency, our own documentation and real-world support must remain as clear and useful as the chemistry itself.

    Partnering With Us Means More Than Just Supply

    Supplying 1,3-dimethylimidazolium methanesulfonate is, for us, about stewardship. Yes, we make the compound at scale and keep it flowing to labs and factories. But what we truly enjoy is seeing how chemists and engineers push the limits of their work with a stable, reliable, and safe ionic liquid at hand. Each technical call, each order, each test run forms a piece of a larger puzzle—a chemistry resource shaped by those who actually use it. Providing answers shaped by hands-on experience, we see our role as more partner than mere supplier, and that difference drives our approach, every day, every batch.