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1,3,6,8-Tetrabromo-9H-Carbazole

    • Product Name 1,3,6,8-Tetrabromo-9H-Carbazole
    • Alias NSC401322
    • Einecs 813-043-0
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
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    Specifications

    HS Code

    404593

    Productname 1,3,6,8-Tetrabromo-9H-Carbazole
    Casnumber 57102-97-1
    Molecularformula C12H4Br4N
    Molecularweight 519.79 g/mol
    Appearance Light yellow to brown powder
    Meltingpoint 305-308 °C
    Purity Typically >98%
    Solubility Insoluble in water; soluble in most organic solvents (e.g., chloroform, dichloromethane)
    Boilingpoint Decomposes before boiling
    Smiles Brc1cc2c(cc1Br)c3c(cc(Br)cc3Br)[nH]2
    Inchikey FGHVKYMGVTXWBV-UHFFFAOYSA-N
    Storageconditions Store at room temperature, protected from light and moisture
    Synonyms 1,3,6,8-Tetrabromocarbazole
    Ecnumber None assigned

    As an accredited 1,3,6,8-Tetrabromo-9H-Carbazole factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

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    Application of 1,3,6,8-Tetrabromo-9H-Carbazole

    Applications of 1,3,6,8-Tetrabromo-9H-Carbazole in Industrial Manufacturing

    As the direct manufacturer of 1,3,6,8-Tetrabromo-9H-Carbazole, we supply this specialty brominated carbazole exclusively to key downstream industries with demanding technical requirements. The following sections outline the well-established application scenarios where this material plays a critical role, with a detailed focus on industry standards, formulation ratios, process integration points, and the ultimate types of finished products created by our industrial customers.

    1. High-Performance Polymer Flame Retardant Additives

    Major polymer compounders and plastics processors incorporate our material as a non-migratory flame retardant in specialty engineering plastics. Combinations of polycarbonate, ABS, and polyamide rely on halogenated organics such as this carbazole derivative to achieve targeted UL 94 ratings, especially for E&E and transport-related components exposed to stringent flammability testing. It is built into masterbatch concentrates and directly melt-blended into base polymers during extrusion or injection molding, providing high char formation and avoiding polymer degradation under standard processing temperatures.

    Industry compliance standards

    • UL 94 (Tests for Flammability of Plastic Materials for Parts in Devices and Appliances)
    • IEC 60695 (Fire Hazard Testing for Electrical and Electronic Products)
    • RoHS Directive (2011/65/EU, limits on hazardous substances in EEE)
    • REACH Annex XVII (Restrictions of Certain Hazardous Substances)

    Typical usage ratio

    • 3–12% by total polymer mass, depending on polymer matrix, required V-0/V-1 rating, and synergists present

    Downstream process integration

    • Direct feeding during melt extrusion compounding, or as pre-dispersed granules in injection and blow molding feedstock; incorporated at the masterbatch stage for color and performance modification

    Final product types

    • Electrical housings, automotive under-hood parts, connector blocks, rail vehicle interior trims, and switchgear enclosures

    2. OLED Electroluminescent Layer Intermediates

    Several advanced optoelectronics manufacturers use our compound as a precursor molecule and synthetic intermediate in fabricating carbazole-based host materials for organic light-emitting diode (OLED) displays and lighting. Its multi-bromination enables efficient further derivatization through cross-coupling reactions, critical for achieving high-purity emissive layers with precise energy gaps. The intermediate is integrated at the fine chemical synthesis phase before device fabrication.

    Industry compliance standards

    • IEC 62341 (OLED Display Device Safety Requirements)
    • JEITA RCR-4111A (Optoelectronic Material Purity Specifications)
    • Quality Management: ISO 9001:2015 compliance for organic electronic intermediates
    • Supply chain traceability as per IECQ QC 080000:2017 (Hazardous Substance Process Management)

    Typical usage ratio

    • Used stoichiometrically in downstream coupling at 1:1 to 1:2 molar ratios with relevant aryl/alkyl reagents, often adjusted by batch reactivity and end-purity targets

    Downstream process integration

    • Input at the early stage of host material synthesis via Suzuki–Miyaura or Buchwald–Hartwig cross-coupling; subsequent purification and finalization before thin-film deposition in OLED stack assembly

    Final product types

    • High-brightness OLED display panels, flexible OLED lighting modules, and specialty photoconductive films for advanced imaging

    3. Photoinitiator Precursors for UV-Curable Inks and Coatings

    Producers of UV-curable inkjet inks and high-speed overprint varnishes use this tetrabrominated carbazole as a core intermediate while manufacturing high-reactivity photoinitiator molecules. It serves as a critical brominated nucleus in synthesizing Type II photoinitiators specific to graphic arts and industrial coatings, enabling rapid polymerization under low-irradiance UV sources. Manufacturers introduce this raw material at the synthesis phase followed by rigorous purification for formulation compatibility.

    Industry compliance standards

    • ISO 2834-1:2021 (Print Technology—Testing of Printability, Photoinitiator Safety)
    • Swiss Ordinance SR 817.023.21 (Packaging Inks Chemical Components List)
    • EuPIA Exclusion Policy (Raw Material Compliance for Printing Inks)
    • ISO 9001:2015 GMP for Specialty Chemicals

    Typical usage ratio

    • Consumed in photoinitiator synthesis at 1:1–1.2:1 molar basis depending on product and reaction pathway; final photoinitiator content in inks typically 0.5–5% by weight

    Downstream process integration

    • Introduced during the fine chemical synthesis of photoinitiator compounds; subsequent blending with monomers and oligomers for ink and coating formulation

    Final product types

    • UV inkjet and flexo inks, digital overprint varnishes, UV-cured adhesives used in electronics and packaging

    4. Specialty Flame Retardant for Wire and Cable Insulation Compounds

    Cable insulation manufacturers select this tetrabromo carbazole for compounding with PVC and specialty elastomers to formulate halogenated flame retardant systems. It provides high thermal stability, ensuring retention of insulation properties during continuous extrusion at elevated temperatures. Compounding plants optimize loadings for cable grades requiring both low-smoke generation and strict self-extinguishing characteristics, with careful control of mechanical integrity and plasticizer compatibility.

    Industry compliance standards

    • IEC 60332 (Tests on Electric Cables Under Fire Conditions)
    • UL 1581 (Reference Standard for Electrical Wires, Cables, and Flexible Cords)
    • EN 50267-2-1 (Halogen Acid Gas Emission Specification for Cable Compounds)
    • RoHS 3 (2015/863/EU) and REACH registration for polymer additives

    Typical usage ratio

    • 2–8% by compound weight, adjusted for cable diameter, target flame rating (VW-1/FT1), and synergist package

    Downstream process integration

    • Physically mixed into cable compound at the dry blend stage or suspension polymerization, introduced prior to extrusion through crosshead or single-screw lines

    Final product types

    • Low-smoke halogenated cable jackets, appliance cords, communication wire insulation, building wire sheaths

    5. Advanced Organic Semiconductor Synthesis Intermediates

    Manufacturers of high-mobility organic semiconductors integrate this compound as a primary brominated starting material in controlled syntheses of carbazole-based π-conjugated oligomers and polymers. Its tetrabromo substitution pattern supports highly selective coupling reactions, critical to tuning charge carrier mobility and stability in molecular electronics. Its use occurs at the first or second synthetic step in multi-stage lab and kilo-scale production for solid-state devices.

    Industry compliance standards

    • ISO/TS 80004-9:2017 (Nanotechnologies—Terminology for Organic Electronics)
    • IEC 62899 (Printed Electronics—Materials Specification)
    • Internal company QC/analytical standards for electronic purity (HPLC, MALDI-TOF QC protocols)
    • ISO 9001 certification for advanced material intermediates

    Typical usage ratio

    • Stoichiometric, typically 1:1 with coupling partners; may range from 100–250 g per kg of final product depending on reaction yield and product line

    Downstream process integration

    • Input at coupling synthesis reactors; intermediates directly isolated, purified, and routed into continuous flow or batch processing for semiconducting layer fabrication

    Final product types

    • Thin-film transistors (TFTs), organic field-effect transistor (OFET) substrates, sensor arrays, printed flexible electronics
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    More Introduction

    Introducing 1,3,6,8-Tetrabromo-9H-Carbazole: Strength, Stability, and Straightforward Application

    Understanding the Product

    1,3,6,8-Tetrabromo-9H-Carbazole stands out in the world of specialty chemicals thanks to its remarkable bromine content and the strong backbone of the carbazole core. With a molecular formula of C12H4Br4N and a molecular weight that registers well above 500 g/mol, this compound brings together a tight structure and reliable thermal stability. Its crystalline form makes it easy to handle for those used to working with technical powders, and it arrives with a level of purity that chemistry-focused teams can count on.

    The four bromine atoms attached to the carbazole core don’t just boost fire resistance—they open up a route to more advanced materials. Those who have worked in the electronics or polymer industries know how much difference a well-placed halogen can make in both function and lifespan. In my experience, specialty compounds like 1,3,6,8-Tetrabromo-9H-Carbazole enable innovation in materials by giving manufacturers flexibility and reliability under challenging conditions.

    Applications Beyond the Basics

    True value often lies in what you can do with a product, rather than merely what it’s made of. Many researchers and companies reach for 1,3,6,8-Tetrabromo-9H-Carbazole when higher flame retardance is non-negotiable. In flame retardant formulations for polymers, this compound plays an active role by providing elemental bromine in a form that resists leaching and volatilization. I’ve seen its adoption in the development of high-performance plastics for uses where safety standards leave little room for compromise—such as housing for electronics, industrial cabling, and circuit boards.

    There’s another story here beyond fire safety. Brominated carbazoles see use as intermediates in organic synthesis, often as building blocks for more specialized molecules. Researchers exploring organic semiconductors look closely at carbazole derivatives for their ability to support charge transport and stability under light and heat. Tetrabrominated versions, including this one, give chemists attachment points for further modification. These sorts of tweaks help tune color, conductivity, and compatibility with other materials—key qualities for OLEDs, photovoltaic cells, or advanced coatings.

    The Science Behind the Structure

    Bromination at the four peripheral positions of carbazole sets this compound apart from less substituted analogues. In the past, I have worked on projects where a single halogen shift could influence the solubility or the electronic structure of a polymer. Tetrabrominated carbazoles bring a unique blend of rigidity and electron-withdrawing effect. What this means in practical terms: you get better flame suppression, different reactivity in coupling reactions, and often a material that resists UV degradation.

    For chemists, each bromine takes up space but also draws electrons away from the core. This makes 1,3,6,8-Tetrabromo-9H-Carbazole more resilient under harsher processing conditions. Its crystalline nature allows for easier weighing and mixing in pilot-scale settings. Colleagues familiar with melt processing or solvent blending remark on how readily it disperses compared with chunkier or oilier alternatives.

    Why It Matters: Comparing to Other Solutions

    With every new chemical, people want to know—why choose this and not something else? The world of flame retardants and functional materials is crowded, but many older products carry liabilities. Some halogenated compounds leach from finished products over time, posing health and regulatory concerns. Others react with ingredients under heat, breaking down into problematic byproducts.

    In conversations with safety coordinators and lab managers, I hear repeated concern over persistent, bioaccumulative flame retardants—especially ones flagged in regulatory modules like REACH. Tetrabrominated carbazoles, while still halogenated, show lower mobility in many plastic matrices, reducing risk of leaching. Compared with low-molecular-weight brominated aromatics (like hexabromobenzene or tetrabromobisphenol A), this compound provides fire performance without the volatility or solubility that can enable migration out of the end material.

    Anyone tasked with staying ahead of global chemical controls knows the headaches that come with phased-out or restricted formulations. Material scientists who want to move on from legacy flame retardants often choose 1,3,6,8-Tetrabromo-9H-Carbazole for its lower migration, chemical predictability, and history of performance in demanding environments. Plenty of studies highlight that tetrabrominated carbazoles present a different toxicological and ecological profile than some competitors—an important point as more industries face scrutiny over safety and sustainability.

    Real-World Use Cases

    Over the last decade, applications have kept pace with advances in electronic miniaturization and material safety requirements. Wire and cable compounds loaded with this ingredient show enhanced flame test results, with less tendency to drip or produce dense, choking smoke during combustion. Manufacturing engineers notice these differences first-hand during burn tests or qualification trials, saving time and reducing rerun costs.

    In printed circuit board (PCB) manufacturing, designers know how sensitive electronics can be to impurities and additive volatility. Using a clean, stable brominated additive helps meet tight dielectric and fire safety specifications—something not always possible with legacy additives. Polymer chemists further up the chain can tweak performance profiles by choosing or blending tetrabrominated carbazoles, depending on whether they need higher oxygen index, better afterglow suppression, or more even dispersion at the micro-scale.

    Technical and Handling Notes

    Those new to organic bromides get used to a different workflow than with standard plastics or commodity additives. 1,3,6,8-Tetrabromo-9H-Carbazole comes as a pale or off-white crystalline powder, usually packaged in inert containers to prevent moisture uptake. The compound’s melting point exceeds 300°C—a detail that counts during polymer compounding, as it won’t soften or vaporize during most processing steps.

    People handling technical-grade carbazoles should always work in well-ventilated areas and keep exposure within recommended limits. I recommend engineering controls and personal protective gear—standard fare in our labs—just as a precaution, since brominated organics can irritate the eyes and skin over time. Unlike many low-weight brominated agents, tetrabrominated carbazoles do not off-gas under standard storage, making them easier to stock over longer production campaigns.

    Shelf stability is one of the underrated aspects here. A batch I worked with sat unused for over six months; its properties and reactivity held steady, without the caking or yellowing you might see in hygroscopic compounds. This reliability means fewer rejected lots and less waste, which matters in lean operations.

    Differences from Similar Compounds

    People sometimes confuse 1,3,6,8-Tetrabromo-9H-Carbazole with other substituted carbazoles or with simpler brominated aromatics. The location and number of bromines make a difference both in performance and in safety. Less substituted bromocarbazoles tend to offer milder flame retardance and have more flexibility for further chemical transformation. But with less bromine, you typically need higher loadings to achieve a given fire performance—adding weight and cost.

    Other common brominated flame retardants like decabromodiphenyl ether (DecaBDE) or tetrabromobisphenol A carry their own sets of regulatory and performance drawbacks. DecaBDE, once a workhorse in flame retardancy, has drawn bans due to persistence, toxicity, and tendency to break down into more harmful substances. In contrast, tetrabrominated carbazoles land closer to the “middle ground”—enough halogen to do the job, without venturing into high-profile regulatory risk.

    Comparing to the non-halogenated flame retardants—phosphorus or nitrogen based—reveals a different set of trade-offs. While those alternatives appeal for their benign environmental profile, they may not match the fire suppression capabilities in high-hazard applications. 1,3,6,8-Tetrabromo-9H-Carbazole carves out a space for itself among users looking for balance: not as persistent or mobile as old-generation brominated ethers, but with enough punch to keep up with tough lab and field testing.

    Looking Forward: Challenges and Solutions

    The future of brominated carbazoles will run alongside new regulations and a sharper focus on safety through the entire product lifecycle. Firms bringing technical additives to market now must think not just about function, but also end-of-life handling and worker safety. The push for circular economies and greener chemistry is real—especially in sectors under heavy regulatory spotlight.

    One challenge lies in balancing performance with migration and persistence. It takes clear-eyed research and regular collaboration with regulators to prove that advanced brominated compounds like 1,3,6,8-Tetrabromo-9H-Carbazole can fill functional roles without the problems of yesterday’s flame retardants. Safer process design can help. In one plastics facility I’ve visited, closed-loop mixing and real-time emissions tracking keep dust and fumes at bay, allaying employee concerns. Third-party certification and ongoing toxicology updates give buyers added assurance.

    For laboratories, supporting workers with better training and ventilation makes a practical difference. Outreach from professional societies and industry roundtables helps everyone stay ahead of the learning curve. I see more chemists sharing practical data about how much of the compound remains bound in finished goods compared with legacy additives. These case studies build trust with customers and regulators, keeping the technology moving forward.

    Sourcing and Quality Assurance

    Reliable sourcing matters as regulations tighten. Research teams want proof that every batch meets required purity and trace metals standards. Trace brominated impurities or heavy metal residues can shut down a successful formulation effort. Over years of bench-scale and scaleup projects, I have learned that straightforward quality documentation builds long-term customer confidence.

    It always pays to request a recent certificate of analysis and, if possible, to test incoming lots using in-house NMR or HPLC gear. Many companies offer this level of rigor, reflecting how far the specialty chemical industry has come since the days of spot-checking a sample and hoping for the best. Buyers should remember that high-purity tetrabrominated carbazole keeps sensitive applications on track, whether in electronics or fire-protected construction.

    The Practical Edge: Getting the Most from 1,3,6,8-Tetrabromo-9H-Carbazole

    This compound works best for teams prepared to match their processing approach to the characteristics of a heavily halogenated aromatic. Melt-based blending produces the most even distribution in thermoplastics, though solvent-based routes also see use for coatings and specialty thin films. Paying attention to blend temperature helps keep the product stable and effective at lower loadings.

    I have seen a number of teams try to substitute one brominated compound for another, only to run into processing or performance headaches. Tetrabrominated carbazoles respond predictably in most polymer systems, but a quick preliminary dispersion or burn test saves trouble down the line. Running side-by-side comparisons yields solid data for product development meetings—and can win over skeptical colleagues not yet convinced by the published literature.

    Waste management is less complicated with this compound than with more mobile additives. Unused material can be handled in accordance with regional guidelines for brominated aromatics, while finished goods rarely require special disposal treatments unless blended with other, more hazardous ingredients. This simplicity appeals to EHS managers seeking process improvements.

    Supporting E-E-A-T: Experience, Ethics, and Trust

    I have spent years working with specialty chemicals where the stakes for safety, performance, and compliance are high. Bringing a flame retardant or advanced additive to market is not just about technical facts—it means following safe practice, keeping careful records, and communicating risks and benefits in plain language. Teams that take the time to update their knowledge, double-check their sources, and share honest results tend to thrive, even as regulations and technologies shift.

    The best suppliers of 1,3,6,8-Tetrabromo-9H-Carbazole share data from real-world applications and encourage clients to run their own tests. Companies succeed when they make transparency and collaboration part of their everyday work, rather than holding back information except where forced to divulge it. Chemists and engineers pressed for time look for track records: consistent product quality, a willingness to troubleshoot together, and up-to-date participation in industry groups or standards bodies.

    Buyers should seek products backed by robust in-house and third-party validation. The best partners don’t just ship a pallet—they walk through the product’s fit for your process, share third-party toxicology data if available, and keep communication lines open long after the first batch leaves their warehouse. In every project I’ve worked on, strong relationships between producer, researcher, and end user made the difference between a product that met its spec and one that became the backbone of a safe, high-performance product line.

    Final Thoughts

    1,3,6,8-Tetrabromo-9H-Carbazole is more than just a chemical—it’s a tool for advancing safer, more reliable materials in a world that demands both. From plastics that protect against fire to organic semiconductors used in next-generation electronics, its impact extends across industries. The balance of high performance, reliable supply, and improved safety profile ensures it remains relevant even as regulations and technologies evolve.

    Chemists, engineers, and product managers face real pressure to innovate safely. The best results come from teams willing to dig into the details—not just the chemistry, but the handling, sourcing, and compliance processes that underpin successful adoption. Through thoughtful application and open dialogue, 1,3,6,8-Tetrabromo-9H-Carbazole stands out as a trusted option, shaping the future of fire-safe, high-performance materials.