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1,2,4-Benzenetricarboxylic Acid

    • Product Name 1,2,4-Benzenetricarboxylic Acid
    • Alias Trimellitic acid
    • Einecs 202-476-7
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    304764

    Chemical Name 1,2,4-Benzenetricarboxylic Acid
    Synonyms Trimellitic acid
    Molecular Formula C9H6O6
    Molecular Weight 210.14 g/mol
    Cas Number 526-39-8
    Appearance White to off-white crystalline powder
    Melting Point 165-170 °C
    Boiling Point Decomposes
    Solubility In Water Slightly soluble
    Density 1.7 g/cm³
    Pka Values 1.41, 2.84, 3.89
    Structure Benzene ring with three carboxylic acid groups at positions 1, 2, and 4
    Odor Odorless
    Ec Number 208-392-7

    As an accredited 1,2,4-Benzenetricarboxylic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 1,2,4-Benzenetricarboxylic Acid is packaged in a 100g amber glass bottle with a secure screw cap and clear labeling.
    Shipping 1,2,4-Benzenetricarboxylic Acid should be shipped in tightly sealed containers, clearly labeled, and protected from moisture and physical damage. Store and transport in a cool, dry, well-ventilated area following local, national, and international regulations for non-combustible, non-hazardous chemicals. Avoid contact with incompatible substances during transit.
    Storage 1,2,4-Benzenetricarboxylic Acid should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area, away from incompatible substances such as strong oxidizers. Avoid exposure to moisture and direct sunlight. Ensure containers are clearly labeled and kept away from heat sources. Use secondary containment to prevent spills and minimize environmental contamination.
    Application of 1,2,4-Benzenetricarboxylic Acid

    Applications of 1,2,4-Benzenetricarboxylic Acid in Industrial Manufacturing

    1,2,4-Benzenetricarboxylic Acid supports critical processing requirements in diverse specialty chemical sectors. As an original manufacturer, we serve leading global industries with this precise raw material. Below, we detail its direct industrial uses in real downstream application streams.

    1. High-Performance Polyimide Resin Synthesis

    Polyimide manufacturers use 1,2,4-Benzenetricarboxylic Acid as a key monomer to tailor thermal, electrical, and mechanical properties in advanced polymers. The acid’s unique tricarboxylic structure delivers rigidity and stability in imide backbones, supporting resin grades for flexible circuit substrates, insulation films, and aerospace composites. Process engineers closely monitor molar ratios and heat profiles to maximize degree of imidization and achieve targeted molecular weights per end-use specification.

    Industry compliance standards

    • ISO 9001:2015 (Quality Management Systems for chemical production)
    • EN 60439-1 (Electrical insulation material qualification in Europe)
    • ASTM D5213 (Standard Specification for Polyimide Resins)
    • RoHS Directive 2011/65/EU, as applicable to electronics-grade films

    Typical usage ratio

    • 10–35 mol% relative to total dianhydride content, with adjustment based on desired glass transition temperature and mechanical performance

    Downstream process integration

    • Input as a direct co-monomer in the condensation polymerization with diamines and other components, typically via thermal or chemical imidization

    Final product types

    • Flexible polyimide films
    • High-temperature polyimide coatings
    • Aerospace composite prepregs
    • Microelectronic substrate laminates

    2. Plasticizer Intermediates for Specialized Polymers

    Producers of custom plasticizers utilize 1,2,4-Benzenetricarboxylic Acid to introduce functionality in polyesters, alkyds, and specialty vinyls where standard phthalates fail to meet performance needs. Its three carboxyl groups enable multi-site esterification, resulting in plasticizers that improve flexibility, migration resistance, and heat distortion in end products. Quality control labs track residual monomer and side reactions to comply with health and durability regulations.

    Industry compliance standards

    • REACH (EC 1907/2006) Registration for industrial chemicals in the EU
    • EN 71-3 (Safety of toys – migration of hazardous elements)
    • FDA 21 CFR 177.2420 (Plastics for food-contact, USA)
    • DIN EN ISO 14001:2015 (Environmental Management in chemical synthesis)

    Typical usage ratio

    • 15–30 wt% in polyol esterification, modified by required softness and extraction resistance parameters of the target polymer

    Downstream process integration

    • Used in multi-stage esterification reactors with glycols or alcohols; followed by downstream blending into compounder extrusion lines or direct incorporation during resin production

    Final product types

    • Non-phthalate plasticizer blends for flexible PVC
    • Plasticized alkyd resin coatings
    • Polyester soft-sheet films used in electronics
    • High-clarity packaging membranes

    3. Crosslinking Agent in Powder Coating Systems

    Powder coating formulators select 1,2,4-Benzenetricarboxylic Acid to introduce controlled crosslink density in polyester and epoxy systems. The compound’s high carboxyl content provides functional anchoring for polyester matrices, which chemists leverage to boost hardness, gloss retention, and chemical resistance in architectural and automotive powders. Regulatory adherence includes VOC-free syntheses and tight traceability of multi-batch blending.

    Industry compliance standards

    • Qualicoat Qualisystems (Global architectural standards)
    • JIS K 5659 (Powder coatings, Japan)
    • FDA 21 CFR 175.300 (Resinous and polymeric coatings for food contact, as needed)
    • EU Regulation 2018/213 (Epoxy coatings in direct food contact)

    Typical usage ratio

    • 3–8 wt% in the polyester or hybrid resin formulation; levels may be elevated for high-performance exterior coatings

    Downstream process integration

    • Added during melt blending and prepolymer formation, followed by extrusion, micronization, and downstream powder application

    Final product types

    • UV- and weather-resistant exterior powder coatings
    • Automotive top coats and chassis finishes
    • Food-safe appliance coatings
    • Heavy-duty industrial pipe and equipment coatings

    4. Synthetic Building Block for Agrochemical Actives

    Researchers and technical manufacturers rely on 1,2,4-Benzenetricarboxylic Acid as a key core for synthesizing specialized heterocyclic agrochemical agents. It supports the formation of tricarboxylic-based intermediates in multi-stage active ingredient production, especially for herbicides and fungicides requiring precise substitution patterns. Synthetic chemists manage derivatization and purification steps to eliminate regulated impurities and to achieve batch homogeneity according to active registration dossiers.

    Industry compliance standards

    • FAO/WHO JMPR guidelines (Pesticide active ingredient specification)
    • OECD GLP (Good Laboratory Practice for batch records)
    • ISO 17025 (Accredited laboratory analysis)
    • REACH registration for agricultural chemicals

    Typical usage ratio

    • 10–20 mol% as the aromatic scaffold in synthetic pathways; adjustments based on ring substitution schemes required by the active molecule design

    Downstream process integration

    • Functions as a starter carboxylic acid in condensation or cyclization reactions and downstream heterocycle closure, followed by post-reaction purification and formulation

    Final product types

    • Herbicide actives for field crops
    • Fungicidal intermediates for orchard spray formulations
    • Custom agrochemical synthesis for contract manufacturing
    • Seed treatment microgranules

    5. Additive for Specialty Adhesives and Sealants

    Specialty adhesive manufacturers incorporate 1,2,4-Benzenetricarboxylic Acid to increase crosslink site density in formulations used for automotive, construction, and electronic assembly. The tricarboxylic backbone supports rapid curing and enhances physical bonding on porous and low-energy substrates. Process control emphasizes mixing uniformity and moisture regulation to achieve high peel and shear strength while meeting strict emission and migration criteria.

    Industry compliance standards

    • ISO 10993-5 (Biocompatibility for adhesives in medical device assembly)
    • ASTM D1876 (Peel resistance for adhesives)
    • UL 94 V-0 (Flame resistance for electronics assembly adhesives)
    • DIN EN 204 D4 (Wood adhesives, construction)

    Typical usage ratio

    • 2–6 wt% in multi-component systems, fine-tuned for substrate absorption, working time, and thermal cycling stability

    Downstream process integration

    • Added during main resin polymerization or as a modifier in post-formulation blending; subjected to curing under defined temperature and humidity controls

    Final product types

    • Auto body structural adhesives
    • Industrial panel and sealant compounds
    • Electronics potting and coating systems
    • Construction adhesives for building envelope applications

    6. Intermediate for Advanced Dyes and Pigments

    Dye and pigment producers incorporate 1,2,4-Benzenetricarboxylic Acid in multi-step syntheses for high-purity colorants used in industrial coatings, inkjets, and textile applications. The acid enables the formation of complex aromatic and anhydride intermediates critical for colorfastness and light stability. Chemists control sulfonation and coupling reactions precisely to ensure regulatory conformity and reproducibility in downstream dispersion processes.

    Industry compliance standards

    • Oeko-Tex Standard 100 (Textile chemical safety)
    • EN 71-7 (Safety requirements for finger paints, pigment content)
    • ASTM D4302 (Standard Specification for Artists’ Oil, Resin-Oil, and Alkyd Paints)
    • GHS compliant labeling (Globally Harmonized System of Classification and Labelling of Chemicals)

    Typical usage ratio

    • 5–15 mol% as the aromatic coupling structure, adjusted by final shade strength and stability requirements in the formulated dye lot

    Downstream process integration

    • Engaged in the initial aromatic condensation step and subsequent anhydride ring-opening or sulfonation/coupling processes before final dispersion or milling

    Final product types

    • High-performance textile dyes
    • Industrial pigment concentrates for automotive coatings
    • Digital inkjet colorants
    • Plastisol pigment pastes for plastics
    Free Quote

    Competitive 1,2,4-Benzenetricarboxylic Acid prices that fit your budget—flexible terms and customized quotes for every order.

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    Certification & Compliance
    More Introduction

    1,2,4-Benzenetricarboxylic Acid: A Chemist’s Perspective

    Understanding 1,2,4-Benzenetricarboxylic Acid

    Manufacturing 1,2,4-benzenetricarboxylic acid calls for precision and a clear understanding of aromatic chemistry. Known among our team as trimellitic acid, this aromatic tricarboxylic acid stands out with its three carboxyl groups attached to the benzene ring at the 1,2, and 4 positions. We produce this product in a technical grade that satisfies demanding industrial applications, offering a white crystalline powder with reliable purity and strong consistency. Chemists in our lab rely on high-performance liquid chromatography to validate output purity for each batch. We never leave it to chance, since even minor deviations impact downstream processing and the reputation of our product among users.

    Specifications That Matter in Real Manufacturing

    Our process targets a purity level above 99 percent, using carefully sourced phthalic anhydride as the primary starting material. As a manufacturer, we pay close attention to details beyond the basic assay numbers. Moisture content, bulk density, trace metal impurities—these small factors often drive decision-making in the plants using our acid. Each batch receives a full profile, with parameters such as melting point, particle size, and water solubility measured consistently.

    Our internal melt point range sits between 165 to 168 degrees Celsius. The acid dissolves sparingly in cold water but shows increased solubility in hot water and certain organic solvents, such as acetone and dimethylformamide. For end users, this defines how the solid handles during storage, blending, and solution-phase processes. Sticking to our specifications isn’t about checking boxes; it reflects what our partners rely on for trouble-free formulation.

    Comparing 1,2,4-Benzenetricarboxylic Acid with Other Aromatic Carboxylic Acids

    In industrial practice, many products in the benzenecarboxylic acid family look similar at first glance. Isophthalic acid and phthalic acid show up frequently in comparative discussions. The difference comes down to functional group placement and the number of functional groups present. Trimellitic acid, with three carboxyls on the benzene ring, opens up reactivity not possible with mono- or dicarboxylic analogues. We see this every time we talk to technical managers working in resins, plasticizers, or new materials—certain projects simply can’t tolerate substitutes, especially where three-site branching or cross-linking drives performance.

    Our product’s three carboxyl groups allow for controlled branching during polymerization, giving materials unique thermal and chemical properties. Phthalic acid, for example, only permits two-point branching, limiting structural complexity. Isophthalic acid lines up carboxyls at the 1 and 3 positions, which changes resin properties in ways our customers profoundly feel when they run pilot batches. These subtle chemical details set trimellitic acid apart, not marketing. We listen to what production chemists encounter, precisely because we work on these issues daily too.

    Key Applications and Daily Industry Use

    Our primary volume flows to manufacturers producing plasticizers and high-performance resin systems. Trimellitic acid's role in alkyd resin production stands out because the third carboxyl group controls polymer branching. Using this acid as a monomer, producers create resins with higher thermal resistance, improved color retention, and resilience against chemical attack. Every time a customer asks about weatherability or resistance to yellowing, the answer often traces back to the impact of that third carboxyl group—and our process precision in getting it there.

    In plasticizer manufacturing, trimellitic acid supports creation of trimellitate esters. Compared to conventional phthalate plasticizers, these esters boost flexibility at low temperatures while holding onto plasticized properties even in aggressive test environments. Electrical insulation, wire coatings, high-spec film applications—these areas value the unique flexibility and migration resistance found in trimellitate esters. Our manufacturing experience confirms what customers report at scale: trimellitic esters outperform standard alternatives in real-world longevity and safety.

    Another important use involves curing agents for epoxy systems. The acid’s structure allows cross-linking with epoxies in a way that raises performance standards for flooring, paints, and structural composites. Chemists using our acid achieve tight cross-link densities, leading to better chemical resistance and long-term stability in harsh industrial settings. End users working in asphalts, powder coatings, and specialty adhesives turn to trimellitic acid for these resin systems, always demanding the same reliable quality, batch after batch.

    We also see a growing need for trimellitic acid in pigment and dye intermediates. Its structure lets pigment chemists prepare advanced chromophores with high light- and weather-fastness, which translates directly into longer lasting color and clarity. These properties mean paint and ink manufacturers trust our process and specifications when moving new products from the lab into full-scale production, since off-spec acid leads to immediate yield and quality losses.

    Production Experience: Real Lessons and Technical Challenges

    Manufacturing trimellitic acid challenges us daily at multiple points. Sourcing clean phthalic anhydride remains essential—impurities in raw material magnify after oxidation and purification. Our oxidation system uses carefully chosen catalysts for a clean conversion. Reactor control becomes critical; small swings in temperature or oxygen feed impact conversion rates and by-product formation. Yield losses, resin yellowing, insoluble fragments—each stems from deviation in molecular structure or process discipline.

    The purification steps after oxidation matter even more. We go beyond simple recrystallization. Our team strips out sulfur, iron, and organic residues using a combination of filtration, washing, and monitored drying cycles. Failing to hit purity targets, even by a small margin, shows up in downstream polymer properties. Customers know immediately through differences in melt flow or color. We see years of documentation and process records reflecting a simple truth: careful manufacturing delivers more than just meeting listed specs. Customers build production schedules and formulations around the certainty that every lot will show the same chemical fingerprint as the last.

    Spills, dusting, and storage losses affect real operations. Trimellitic acid’s fine powder tends to drift; our facility upgraded handling equipment and improved containment after seeing small batch losses at the blending stage. Such hands-on learning shapes how our teams pack, store, and ship every order. End users benefit because they see less bridging, more consistent dispersal into solvents, and more reliable bulk transfers.

    Environmental controls at the plant play a daily role. Cutting edge emission scrubbing and wastewater treatment align with global standards. Our experience shows that staying ahead in environmental stewardship supports both regulatory compliance and long-term customer trust. We never view these measures as overhead—reliable supply depends as much on responsible operation as on technical performance.

    Troubleshooting and Field Support: Sharing What Works

    Many of our industry partners rely on our support team to resolve on-site challenges. Typical problems include incomplete dissolution, gel formation in reactors, or unexpected color shift in resins. Our process engineers often step in to review solvent selection, mixing speeds, or batch loading sequences. For example, using water-saturated trimellitic acid in high-temperature resin kettles can produce foaming and uneven color if not dried properly—we’ve seen this in practice and communicate proactive drying protocols with every shipment.

    Incorrect sequence during resin cook-ups can trigger premature gelation, often traced to high acid loading or acid added before full polyol incorporation. In these cases, our team walks through the batch sheet with plant chemists, sometimes recommending slower addition rates or process parameter tweaks. This hands-on, technical dialogue comes from real production experience—solutions don’t come from templates, but from seeing and solving operational snags side-by-side with customers.

    Downstream users often encounter dosing differences when switching from isophthalic or phthalic acid to trimellitic acid. The increased carboxyl count shifts molecular weight and mixing viscosity. Formulators look to us to confirm new ratios, but our advice goes beyond calculations—many times, we visit customer sites to run pilot blends and confirm handling procedures under actual production conditions, learning as much as teaching.

    As industries push for more sustainable chemistry, some partners ask about recycling waste streams back into new resin batches. Our R&D team studies trimellitic recovery in spent catalyst beds, developing protocols to reclaim and purify the acid without sacrificing downstream polymer consistency. Success in this area depends on unsung details like residual salt removal and thermal stability; every process tweak receives full pilot testing before recommendation.

    Quality Assurance and Why It Matters Downstream

    Much of our reputation rides on quality assurance. Our in-house labs run advanced purity screens—HPLC, FTIR, thermal analysis. Reporting doesn’t mean much if the tests don’t cover operational risks. We select analytical protocols not because they’re popular, but because they catch those impurities and batch variations that actually shift product in practice. For example, tiny shifts in particle size may not show up on routine inspection, yet influence ease of mixing into solvent or polymer melts.

    Batch records retain every piece of process, test, and packaging data. Over years, we’ve learned that one-off deviations, even minor, trigger downstream performance issues for our largest customers. We treat each production run with the same rigor—our brand depends not on marketing but on customers experiencing zero surprises. Sharing test results in detail became an open policy; many partners now use our data directly for their own batch releases, reducing duplicate work and uncertainty.

    Supply Chain, Logistics, and Safety Insights from Experience

    Shipping trimellitic acid brings operational complexity, especially in humid climates. Moisture pickup during long ocean transport changes flow and can spark clumping, leading to poor handling and costly downtime. Our packaging isn’t just an afterthought—it stems from years of tracking loss rates, caking incidents, and partner feedback on real plant flow. Thick-sealed, multilayer polyethylene bags, drum liners, and controlled warehousing keep acid clean and free-flowing across distances.

    Safety training forms a core part of our dispatch operation. Trimellitic acid dust poses respiratory hazards at higher concentrations—operators need well-maintained extraction and dust suppression systems. Our facility builds these features into both blending and loading stations, reflecting our direct concern for worker safety. We frequently update partner firms on safe handling, storage, spill response, and first aid measures. By sharing our methods, risks drop across the entire supply chain, not just at our site.

    Regulatory compliance, transport documentation, and traceability all matter—no shipment leaves without full chain-of-custody. Our experience says that paperwork failures cost more in recall, disruption, or loss of trust than any savings from rushed dispatch. Overseas shipments face additional regulatory review; we manufacture to recognized international standards, reducing customs holdups and supply interruptions for our industry partners.

    Market Trends and the Role of Trimellitic Acid in New Technology

    Demand for specialty trimellitate esters in phthalate-free plasticizers keeps rising due to regulatory shifts globally. We now see more inquiries from insulation and automotive sector leaders needing both flexibility and fire retardance, functions trimellitic acid enables with its trifunctional chemistry. At the same time, environmentally friendly resin systems call for better weathering and color stability—again, properties linked to both trimellitic’s structure and our tight process control.

    Innovation in powder coatings, adhesives, and optical-grade plastics leads formulators back to trimellitic derivatives. Rigid coatings for electronics resist delamination and yellowing under UV, attributes stemming from tight aromatic cross-linking offered by our acid. Research teams ask for custom particle sizes and handling properties, and we respond by adjusting process parameters to produce batches with tailored flow or dissolution rates.

    From our vantage point, the evolution of recycling and materials circularity shapes future priorities. Customers ask for guidance in minimizing trimellitic acid waste streams and re-integrating recovered acid in new batch cycles. We run pilot demonstrations on resin degradation pathways, solvent recovery, and acid reclamation—sharing results with industry partners encourages wider adoption and supports sustainability targets across sectors.

    Challenges and Ongoing Improvements

    Manufacturing trimellitic acid at scale always introduces new obstacles, whether from raw material supply volatility, energy price shocks, or evolving emissions regulations. We address these challenges by building redundancy into sourcing, maintaining robust internal audits, and investing in both operator training and process upgrades. Small, continuous improvements—such as better catalyst systems, more selective filtration, or tighter environmental controls—add up to better consistency and customer outcomes over time.

    We never stop learning. Every failed batch, every shipping delay, every partner complaint highlights something we can do better. This journey defines our core approach to chemical manufacturing: solve today’s issues, plan for tomorrow’s processes, and share lessons openly with downstream users. Trimellitic acid production reflects not a fixed formula, but a constant cycle of improvement rooted in daily operational realities.

    The Difference Manufacturer Experience Makes

    The impact of consistent, pure trimellitic acid becomes clear in finished goods’ performance and business reliability for our partners. End users depend on us not for generic commodity supply, but for a technical product that arrives right every time—free from contaminants, ready to solve demanding challenges in resins, films, adhesives, coatings, and beyond. As manufacturers, we put everything we have into maintaining that quality and supporting our customers’ end-to-end operational success.

    For technical teams and production managers, our direct knowledge and willingness to collaborate on process troubleshooting and optimization create lasting partnerships. We face the same variables, troubleshoot similar problems, and chase the same outcomes: clean, predictable chemistry that delivers tangible results in the field. This sets us apart—real manufacturing expertise, transparent technical support, and constant improvement underpin both product and partnership. In a world of shifting needs and rising expectations, that difference keeps our product running strong at the core of next-generation manufacturing.