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HS Code |
237614 |
| Chemical Name | 1,2,3,6-Tetrahydro-4-Methylphthalic Anhydride |
| Cas Number | 27658-13-3 |
| Molecular Formula | C9H10O3 |
| Molecular Weight | 166.18 g/mol |
| Appearance | White to off-white solid |
| Melting Point | 82-86°C |
| Boiling Point | 285°C (estimated) |
| Solubility | Slightly soluble in water, soluble in organic solvents |
| Density | 1.22 g/cm³ (approximate) |
| Flash Point | 140°C (closed cup, approx.) |
| Synonyms | 4-Methyl-1,2,3,6-tetrahydrophthalic anhydride |
| Structure Type | Cyclic anhydride |
| Odor | Characteristic |
| Stability | Stable under normal conditions |
As an accredited 1,2,3,6-Tetrahydro-4-Methylphthalic Anhydride factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | The packaging contains 500 grams of 1,2,3,6-Tetrahydro-4-Methylphthalic Anhydride, sealed in a white, airtight, labeled HDPE bottle. |
| Shipping | 1,2,3,6-Tetrahydro-4-Methylphthalic Anhydride should be shipped in tightly sealed containers, protected from moisture and direct sunlight. Transport in accordance with local, state, and international regulations for chemicals. Use proper labeling and documentation, and avoid contact with incompatible substances. Handle with gloves and eye protection to ensure safe delivery. |
| Storage | 1,2,3,6-Tetrahydro-4-Methylphthalic Anhydride should be stored in a cool, dry, and well-ventilated area, away from moisture, heat, and incompatible substances such as strong bases, oxidizers, and water. Keep the container tightly closed and properly labeled. Use chemical-resistant containers and avoid exposure to air, as the compound is sensitive to hydrolysis and may react with water or humid conditions. |
Applications of 1,2,3,6-Tetrahydro-4-Methylphthalic Anhydride in Industrial ManufacturingAs an established manufacturer, we support advanced industries with high-purity 1,2,3,6-tetrahydro-4-methylphthalic anhydride, a specialty anhydride applied in several mature high-value downstream sectors. Below we detail real-world application scenarios, providing industry standards, formulation guidance, process details, and end-use product types for each. 1. Curing Agent for Epoxy Resin Composites in Electronic EncapsulationOur material serves as a critical curing agent in the production of epoxy composites utilized in electronic component encapsulation, providing enhanced thermal stability and electrical insulation required for integrated circuits, power modules, and electronic control devices. Customers rely on this anhydride to achieve precise curing cycles and consistent dielectric properties. Industry compliance standards
Typical usage ratio
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2. Intermediate for Unsaturated Polyester Resin (UPR) Synthesis in Automotive ComponentsWithin the UPR sector, 1,2,3,6-tetrahydro-4-methylphthalic anhydride acts as a key intermediate delivering controlled reactivity, which leads to resins with improved chemical resistance and mechanical profiles suited for automotive under-the-hood and exterior composite applications. Manufacturers value its contribution to dimensional stability under heat and vibration. Industry compliance standards
Typical usage ratio
Downstream process integration
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3. Modifier for Alkyd Resin Formulations in Anticorrosion CoatingsIn the coatings industry, formulators introduce this anhydride as a modifier in alkyd resin synthesis, imparting outstanding hardness and solvent resistance, which are essential for demanding marine and industrial anticorrosion coatings. Its use enables formulated coatings to withstand harsh chemical exposure and prolonged moisture contact. Industry compliance standards
Typical usage ratio
Downstream process integration
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4. Raw Material for Polyimide Film Manufacture in High-Temperature Applications1,2,3,6-tetrahydro-4-methylphthalic anhydride is used as a dianhydride component in the synthesis of specialty polyimide films, which provide dielectric strength and dimensional stability in environments with sustained exposure to 200°C or more. Manufacturers employ this structure to tune film flexibility and low outgassing for components in aerospace and microelectronics production. Industry compliance standards
Typical usage ratio
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5. Crosslinking Agent in Powder Coatings for Electrical AppliancesPowder coating manufacturers apply this anhydride as a crosslinking curative to achieve high-gloss, impact-resistant surfaces with controlled cure kinetics for electrical appliance housings and metal fixtures. It ensures regulation-compliant surface chemistry, mechanical durability, and color retention through repeated cleaning cycles. Industry compliance standards
Typical usage ratio
Downstream process integration
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1,2,3,6-Tetrahydro-4-Methylphthalic Anhydride, often recognized across the industry as MeTHPA, stands as a signature product in our lineup. Decades of operation in bulk anhydride production give our team a grounded view of its daily role in real-world processes—from curing agents in epoxy systems to specialized intermediates in advanced polymers. The name might sound academic, but in our facility, it’s a substance we’ve worked with in large reactors, monitored in real time on the factory floor, and tested batch after batch for consistent quality.
Chemists sometimes call it methyl-endomethylene phthalic anhydride, but here we rely on its telling features. The molecule blends the reactivity found in classic phthalic anhydrides with a ring structure that opens doors to performance not easily matched by more familiar grades. Through our process, the product typically arrives at customers as a colorless or pale yellow liquid, free-flowing and low in suspended solids. Each batch runs through glass-lined reactors and controlled with automated feeds, keeping moisture and impurities at bay—a necessity, since trace water can ruin downstream reaction rates, something we’ve seen firsthand in early pilot runs.
Direct feedback from long-standing customers pushes us to refine every lot before shipment. Craftsmen in the field look for more than a spec sheet; they trust that each drum delivers reliable reactivity and purity. The low viscosity stands out in our experience. Where solid anhydrides may hold up large-scale compounding lines, MeTHPA remains liquid at room temperature, letting pumps move it with ease, avoiding clogs and wasted man-hours. While classic phthalic anhydride forms often need preheating, our MeTHPA skips that inconvenience, saving energy and letting shops scale up faster.
Colleagues involved in coil coatings, electrical encapsulants, and composite resins came to us over the years with requests to address specific bottlenecks—delays in mixing, uneven curing, thermal stability troubles in their final materials. Experience taught us that the methyl group on MeTHPA’s structure tweaks its reactivity. Instead of requiring high temperatures to kickstart ring opening, reactions proceed efficiently at a lower heat compared to simple phthalic or hexahydrophthalic anhydride grades. One project saw a customer swap out a generic blend for MeTHPA and cut their oven temperatures by twenty degrees Celsius, shaving days off their total turnaround on encapsulated modules.
The tetrahydro ring in MeTHPA’s backbone means a tighter structure and greater chemical stability under long-term heat. This benefits electrical and electronic manufacturers who need materials to resist yellowing, embrittlement, or creeping failure in transformers and PCB assemblies. We’ve tested our batches under thermal cycling, confirming less volatilization and improved insulation values compared to lower-branched anhydride species. Real-world savings materialize as reduced maintenance breaks and extended product lifespans, benefits that outclass basic alternatives.
From the shop floor, standard parameters—acidity, viscosity, color, and water content—matter most day-in and day-out. We track every lot using both automated analytics and manual titration, making sure the acid anhydride content falls within the tight ranges needed for consistent curing ratios. Some months deliver more demanding runs. The humid summer season challenges us to keep tanks bone-dry, especially for export shipments crossing long distances. Our veteran technicians react by running parallel moisture checks and tightening seal protocols on every outgoing drum.
Every production cycle builds on generations of tweaks: catalyst loading, agitation rates, condenser settings. Our line operators know cutting corners here triggers downstream headaches. Once, a minor slip in cooling rates brought up a haze in cooled products—not visible in the plant, but enough for a finicky end user to scrap a hundred thousand units. Since then, we batch-sample and retain reference bottles for months after each shipment, so quality managers can chase down any questions without delay.
We embrace transparency about the practical differences between MeTHPA and more pedestrian anhydrides. Model options from our plant typically include standard industrial grade—targeting the biggest market for resins and adhesives—and stabilized versions, crafted with inhibitors for high-value electronics and thermal applications. Purity levels sit above 99%, confirmed by both wet chemical and spectroscopic analysis.
Our long tenure handling conventional phthalic and hexahydrophthalic anhydrides shapes our appreciation for the tweaks MeTHPA makes possible. Phthalic anhydride, with its well-known solid flakes, chokes conveying lines and can hydrolyze fast in open reactors. Operators spend precious hours cleaning up dust or unclogging dosing valves anytime humidity creeps above baseline. MeTHPA’s clear, pourable liquid sidesteps these common delays, allowing shifts to run longer between stoppages.
Hexahydrophthalic anhydride, another peer, brings some benefits in outdoor-grade adhesives or weathering resistance. In our trials, though, MeTHPA’s methyl substitution demonstrates better compatibility with advanced epoxy systems used in next-generation composites. The reactivity profile lets formulators cut down on catalyst loading, driving cost savings at volume scale. In energy grid hardware and heavy electrical insulation, customers who switched from cheaper solid anhydrides cite fewer signs of internal solder whiskering—a small but critical boost in safety margins under stress.
Legacy anhydrides eventually fall short in emerging sectors demanding higher resilience and flexibility. Our R&D team, in tandem with production engineers, observes greater shelf life in finished resin kits, a direct result of MeTHPA’s unique stability. This characteristic not only smooths supply chain planning for our partners, but also means less waste and reduced hazardous disposal. Large-volume users—particular in electronics—consistently report a dip in rejection rates once they shift to MeTHPA.
Our knowledge grew from repetitive, hands-on production, but also from collaboration with customers in real-world processes. Epoxy resin curing agents make up the backbone of MeTHPA’s value proposition. End users in transformer potting, protective coatings for steel, and high-end flooring systems rely on its reliable ring-opening reactivity. We’ve seen composite panel producers double their throughput using fast-curing agents, moving from general-purpose hardeners to more selective anhydrides with performance genes like MeTHPA.
Electrification and smart infrastructure upgrades pushed demand for insulators able to withstand heat stress, pulsed voltages, and physical impacts. MeTHPA helps bridge that gap. Field reports after multi-year use cycles document coatings with lower thermal drift and negligible chalking. Construction crews deploying MeTHPA-based resins say they encounter less off-gassing during installation, protecting both indoor air and team health. By reducing the need for extended ventilation or reworking faulty parts, project timelines shrink and operational budgets stretch further.
With the push toward automation and precision in assembly, MeTHPA’s ease of pumping—no preheating, easy flow at room temperatures—lets robotic dosing systems operate longer with fewer jams. Small details, like running tanks equipped with sight glass level checks and in-line centrifugal filters, make a difference for operators clearing line changeovers in minutes instead of hours. Our insight tells us that in large projects—whether bridge retrofits or wind turbine blade casts—these process gains often determine profit margins.
Beyond core electrical and coating work, the molecule finds niches in manufacturing specialty adhesives for automotive assemblies and loaded composites for aerospace fixtures. Testing with local partners showed that shifting to MeTHPA reduces micro-cracking in high-stress resin parts, especially where temperature swings would otherwise drive premature failures. In some cases, using MeTHPA in closed-mold processes eliminated bubble formation, reducing overall scrap rates in carbon-fiber parts.
Any specialty chemical draws scrutiny for its handling quirks and long-term impact—MeTHPA is no different. Our plant teams quickly learned the value of rigorous hazard management. Careless exposure to ambient moisture leads to runaway hydrolysis, so we engineer closed-loop delivery systems, nitrogen blanketing, and vacuum transfer gear for both our own workers and customer installations. Each season, new plant staff learn the discipline of quick sampling and precise titration, since off-spec acidity could spell disaster for customer blending operations.
Temperature control drives much of our maintenance calendar. Warm spells risk slow polymerization or altered reactivity, which reflects in the downstream quality for adhesives and resins. To counter these risks, our facility rotates stock quickly and maintains both raw and finished goods tanks under climate control. By logging every batch from reactor to packing, we stay ahead of aging or spoilage claims—an investment that pays for itself in long-term trust with our user base.
Transport remains a perennial issue, especially as we serve customers in climates where temperature and humidity swing widely. We designed our drums and IBCs for double-gasket seals and add bonus foil liners for long-haul exports. Technical support rides along with every shipment in the form of real time data access and remote troubleshooting. Customers with on-site blending rooms benefit from decades of advice about piping layouts and maintenance routines—practical knowledge that only reveals itself through repeated installs and site visits.
Waste management and regulatory compliance come up frequently in customer audits. Our in-house lab benchmarks environmental exposure and drives reduction in VOC release through better process control. Used drums get cleaned and repurposed on a tracked, closed-loop basis, with every step documented for traceability. By collaborating openly with local authorities, we strengthen both our own procedures and those of downstream partners.
Whereas much of the supply chain seeks lowest-cost sources, we find the gap between cheapest price and reliable quality can have heavy costs down the line. Experience tells us that with epoxies and composite hardeners, batch variability leads to unpredictable reaction rates, jeopardizing line speed or, worse, product safety credentials. To counteract this, we maintain a tightly integrated feedback loop between our production lab and industrial customers. Troubleshooting isn’t left to remote consultants; our engineers visit facilities, diagnose mixing or flow problems, and personally help tweak dosages or sequence timing to match local climatic demands.
Process audits held together with customer teams often uncover pain points. Sometimes, a mid-summer shift operator needs help recalibrating pump timing; other occasions, a maintenance manager seeks a faster turnaround on drum swaps. Our advice on storage, drum handling, and mixing dosages draws on years working with complex bulk systems in real-world settings. The expertise we share reflects a history of hands-on troubleshooting, not just product pamphlets.
Continual improvement defines our work. Each season brings a fresh set of challenges—supply chain disruptions, regulatory revisions, customer upgrades. Improving reactor throughput, reducing manual touch points, and extending shelf stability have moved center stage. Automation now plays a bigger role, yet we retain manual sign-off and visual batch checks, since even the best inline sensors miss subtleties caught only by seasoned eyes.
Industry doesn’t stand still. New energy, consumer electronics, high-performance transport—each sector places further demands on suppliers to balance cost, quality, sustainability, and speed. MeTHPA’s design, rooted in robust synthesis and a controlled methylated backbone, keeps pace as needs shift. In developing low-VOC formulations or next-generation flame-retardant composites, our technical team collaborates with partner labs and university researchers. Recent projects explored using MeTHPA in lower-density foam encapsulants for battery modules, aiming for higher shock absorption with less cross-linker demand.
We watch industry trends closely. Both end-users and regulators ask for lower hazard footprints, better lifecycle transparency, and tools for circular manufacturing. Our shift toward sealed, fully traceable packaging and integration with digital plant management systems reflects these priorities. Each improvement comes out of years of working with operators, maintenance staff, and product managers to close the loop between laboratory excellence and on-the-ground performance.
Sharing our findings and methods with likeminded manufacturers reinforces the push for quality and safe industry growth. Our accounts with continuous improvement include testing new anti-corrosive liners for containers, piloting recycled solvent capture, and training customers in preventative maintenance. The aim is not just more sales but a tighter, more robust value chain.
Long-standing customer partnerships shape our direction. We don’t just ship product; we cultivate relationships that cross years, site visits, and problem-solving sessions. We document practical fixes developed in the field and return those insights to our production and R&D teams, refining future batches in response. Many of our most effective process changes began as simple requests from plant supervisors or line engineers working under tight deadlines—evidence that real improvement starts not in the lab, but on the job.
Over time, the real area where MeTHPA sets itself apart isn’t in pictures or formulas, but in daily reliability, ease of handling, and resilience in varied industrial settings. It brings us pride to see products built on MeTHPA delivering better insulation to power grids, extending the lifespan of heavy equipment, and supporting the evolution of infrastructure everywhere it’s applied. Every improvement traces back to real-world manufacturing experience, honest feedback loops, and a shared commitment to moving the industry forward together.