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1,1'-Dimethylferrocene

    • Product Name 1,1'-Dimethylferrocene
    • Alias Bis(methylcyclopentadienyl)iron
    • Einecs 245-621-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    792607

    Chemical Name 1,1'-Dimethylferrocene
    Molecular Formula C12H14Fe
    Molar Mass 218.08 g/mol
    Cas Number 1273-89-8
    Appearance Orange crystalline solid
    Melting Point 108-110 °C
    Density 1.33 g/cm³
    Solubility In Water Insoluble
    Solubility In Organic Solvents Soluble in ether, benzene, chloroform
    Structure Sandwich compound with two methyl-substituted cyclopentadienyl rings
    Odor Aromatic
    Flash Point 96 °C (closed cup)
    Storage Conditions Store in a cool, dry place, protected from air and moisture

    As an accredited 1,1'-Dimethylferrocene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 1,1'-Dimethylferrocene is packaged in a 25-gram amber glass bottle, securely sealed, with a hazard label and product details.
    Shipping 1,1'-Dimethylferrocene should be shipped in tightly sealed containers to prevent leaks and contamination. Store and transport it in a cool, dry place away from sources of ignition or strong oxidizers. Comply with local, national, and international regulations for transporting organic chemicals. Use appropriate hazard labeling and documentation during shipping.
    Storage 1,1'-Dimethylferrocene should be stored in a cool, dry, and well-ventilated area, away from sources of ignition and incompatible materials such as strong oxidizing agents. Keep the container tightly closed and protected from moisture. Store in a designated flammable chemicals cabinet. Proper labeling and secondary containment are recommended to prevent spills and ensure safe handling.
    Application of 1,1'-Dimethylferrocene

    Applications of 1,1'-Dimethylferrocene in Industrial Manufacturing

    As a direct manufacturer of 1,1'-Dimethylferrocene, we supply this specialty organometallic compound to high-value industries worldwide. Its stable redox properties, thermal behavior, and reactivity profile support advanced downstream synthesis and performance enhancement across several focused industrial sectors. Below, we detail real-use scenarios, compliance frameworks, recommended formulation ratios, industrial process roles, and finished product outcomes drawn from actual manufacturing practice.

    1. Catalysts for High-Temperature Olefin Polymerization

    Polyolefin producers incorporate this ferrocene derivative as a ligand component in metallocene-based catalyst systems, targeting precision control of polymer chain architecture and molecular weight distribution during high-temperature olefin polymerization. Integration enhances catalyst stability and tuning options for specific polymer characteristics in continuous production lines.

    Industry compliance standards

    • ISO 9001:2015 Quality Management for chemical and polymer manufacturing
    • REACH Regulation (EC) No 1907/2006 for chemical safety in the EU
    • US EPA TSCA listing for organometallic intermediates
    • Chinese GB/T 12670 for industrial catalyst components

    Typical usage ratio

    • 0.01–0.05 mol% relative to the Zr/Ti center in the metallocene complex; actual loading may increase for specialty copolymers or as dictated by process throughput and desired polymer microstructure specifications.

    Downstream process integration

    • Introduced during in-situ catalyst complexation prior to reactor charging; maintains stability in fluidized bed, loop reactor, and slurry phase operation; downstream separation and residual analysis managed as part of final polymer QC.

    Final product types

    • High density polyethylene (HDPE) with tailored branching
    • Isotactic polypropylene with narrow MWD
    • Specialty random copolymers for packaging fi­lms
    • Polyolefin elastomers with engineered elasticity

    2. Mediators in Non-Aqueous Redox Flow Battery Electrolytes

    Researchers and commercial scale-up entities in energy storage deploy this dimethyl-substituted ferrocene as an electron transfer mediator in the organic phase of redox flow batteries. Its well-defined redox potential and resistance to over-oxidation or degradation offer high cycle lifetimes in these advanced electrochemical systems.

    Industry compliance standards

    • IEC 62932-2-1:2022 for flow battery safety and design
    • EU RoHS 2011/65/EU for battery materials
    • ISO 14001:2015 for environmental management in battery production
    • UL 9540A for battery system fire safety testing (relevant during battery module qualification)

    Typical usage ratio

    • 0.2–1.0 M in non-aqueous catholyte; selection guided by target open-circuit voltage, electrolyte viscosity, and operational temperature of the specific cell stack, with final concentration optimized to minimize resistance and enhance coulombic efficiency.

    Downstream process integration

    • Dissolved into organic solvent electrolyte blend prior to module assembly; maintained under inert atmosphere during handling; monitored for redox stability during charge–discharge cycling and subjected to post-cycle recovery protocols if needed.

    Final product types

    • Grid-scale non-aqueous redox flow batteries
    • Pilot-scale stationary energy storage racks
    • Research-grade electrochemical test cells
    • Rechargeable industrial power back-up systems

    3. Additives for Heat-Resistant Conductive Polymer Formulations

    Conductive polymer compounders utilize this organometallic to enhance electronic conductivity and thermal resistance for high-performance plastics used in electronics and aerospace. Its precise addition modifies charge mobility and stabilizes conductive networks in thermoplastic and thermoset matrices under demanding heat cycles.

    Industry compliance standards

    • IEC 61249-2-21 for halogen-free base materials in printed circuit applications
    • UL 94 flammability standard for plastic materials
    • RoHS directive for restricted substances in electrical equipment
    • REACH SVHC monitoring for additive content

    Typical usage ratio

    • 0.02–0.15 wt% of total polymer blend; optimized for resin chemistry and desired bulk conductivity, with higher levels reserved for aerospace ESD-sensitive applications.

    Downstream process integration

    • Added during masterbatch compounding or directly into polymer melt; thorough mixing ensures dispersion at molecular level prior to extrusion, injection molding, or resin casting.

    Final product types

    • Anti-static electronic packaging trays
    • Heat-resistant circuit board substrates
    • Conductive sensor housings
    • Low-resistance aerospace connector insulators

    4. Precursors for Advanced Organometallic Complex Synthesis

    Sophisticated ligand synthesis operations select this dimethylferrocene as a stable and pure building block for multi-step preparation of custom metallocene compounds, required for specialty catalysis, molecular electronics, and surface modification. Its methylation pattern offers precise steric and electronic control within the final molecular architecture.

    Industry compliance standards

    • ISO 9001:2015 and ISO 17025 for laboratory synthesis and quality verification
    • REACH and TSCA inventory status for intermediate sourcing
    • Chemical purity documentation to ICH Q7 for pharmaceutical intermediates where required
    • GMP audit compliance for pharmaceutical or diagnostic intermediates

    Typical usage ratio

    • Riched used as primary ligand base on a stoichiometry of 1:1–1:3 with metal salts or halides, adjusted to match required substitution or complexation degree in practice.

    Downstream process integration

    • Forms the starting organometallic core; undergoes stepwise derivatization—alkylation, acylation, phosphinylation, or cross-coupling depending on final catalyst or material target.

    Final product types

    • Specialty metallocene compounds for research reactors
    • Chiral catalysts for fine chemical synthesis
    • Functionalized surface modification reagents
    • Prototype molecular electronics junctions

    5. Colorimetric Oxidation Markers in Analytical Chemistry

    Analytical laboratories use this ferrocene derivative as a reference oxidation marker or redox indicator in electroanalytical methods, particularly in non-aqueous voltammetry and titrimetric protocols. Its well-defined reversible redox potential enables precise calibration and reproducible quantitation in complex sample matrices.

    Industry compliance standards

    • ISO/IEC 17025:2017 for laboratory competence
    • ASTM D9127 for voltammetric analytical protocols
    • IUPAC standards for reference material preparation
    • GLP (Good Laboratory Practice) guidelines

    Typical usage ratio

    • Concentration in the 0.5–2.0 mM range, tailored to cell geometry, electrode sensitivity, and required detection resolution; levels can be fine-tuned for specific trace analysis applications.

    Downstream process integration

    • Dissolved in supporting electrolyte or titrant; introduced prior to sample measurement; analyzed by cyclic voltammetry or colorimetric endpoint detection; reference values established in each test batch as part of QC protocol.

    Final product types

    • Certified analytical calibration kits
    • Non-aqueous voltammetry chemicals
    • Custom redox analyte kits for laboratory supply firms
    • Educational laboratory analysis sets
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