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Vanadium Oxytrichloride

    • Product Name Vanadium Oxytrichloride
    • Alias Vanadium chloride oxide
    • Einecs 218-354-5
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    156847

    Chemical Name Vanadium Oxytrichloride
    Chemical Formula VOCl3
    Molar Mass 173.30 g/mol
    Appearance Yellow to red fuming liquid
    Odor Pungent, irritating
    Melting Point -23 °C
    Boiling Point 126.7 °C
    Density 1.82 g/cm³ (at 20 °C)
    Solubility In Water Reacts violently
    Vapor Pressure 65 mmHg (at 25 °C)
    Cas Number 1332-51-2
    Flash Point Non-flammable, but forms corrosive fumes
    Refractive Index 1.566 (at 25 °C)
    Color Yellowish

    As an accredited Vanadium Oxytrichloride factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Vanadium Oxytrichloride, 500 mL, is supplied in a sealed amber glass bottle with hazard labeling, inside a protective cardboard box.
    Shipping Vanadium Oxytrichloride is shipped in tightly sealed, corrosion-resistant containers under dry, cool, and well-ventilated conditions. It is classified as a hazardous material (UN 2864) and must be labeled accordingly. Transport requires compliance with local and international regulations to ensure safety due to its toxic, corrosive, and moisture-sensitive nature.
    Storage Vanadium oxytrichloride should be stored in a cool, dry, and well-ventilated area, away from moisture and incompatible substances such as water, alcohols, and bases. Use tightly sealed, corrosion-resistant containers, preferably glass or certain plastics. Protect from light and humidity, as it reacts violently with water, releasing toxic fumes. Clearly label storage containers and keep away from ignition sources.
    Application of Vanadium Oxytrichloride

    Applications of Vanadium Oxytrichloride in Industrial Manufacturing

    Vanadium Oxytrichloride serves as a critical intermediate and process aid across several advanced materials industries. As direct manufacturer, we supply this raw material for strictly regulated, value-added downstream uses. All application routes are based on established industrial operation and regulatory requirements.

    1. Titanium Alloy Additive in Specialty Metals

    Vanadium Oxytrichloride is introduced in controlled amounts to the melting process of specialty titanium alloys, enhancing mechanical properties such as strength and corrosion resistance required in aerospace, medical, and industrial equipment. The additive reacts in the melt to foster homogenous alloying and refine grain structure per precision metal standards, ensuring consistent batch-to-batch properties demanded in highly regulated markets.

    Industry compliance standards

    • ASTM B348 (Titanium and Titanium Alloy Bars and Billets)
    • AMS 4928 (Titanium Alloy Bars, Wire, Forgings for Aerospace)
    • ISO 9001:2015 (Quality Management for Production)
    • EN 9100 (Aerospace Quality Systems)

    Typical usage ratio

    • 0.1%–2.5% by weight of vanadium content in the final alloy; precise amount determined through ladle chemistry correction and alloy design specifications.

    Downstream process integration

    • Added to titanium scrap or sponge during induction or vacuum arc remelting. The chemical is introduced under inert or vacuum atmospheres for full integration into molten titanium prior to casting or forming.

    Final product types

    • Titanium-vanadium alloy plates, rods, forgings for medical implants, jet engine components, and critical structural aerospace parts.

    2. Catalyst Precursor in Ethylene Polymerization

    This compound functions as an active vanadium source for immobilized catalysts utilized in low-pressure ethylene polymerization reactors. It is reacted with magnesium-based supports in dedicated catalyst synthesis lines, ensuring tight control over vanadium oxidation state and dispersion. The resulting catalysts directly dictate polymer molecular weight distribution and mechanical performance, pivotal for industrial film and molding-grade polyethylenes.

    Industry compliance standards

    • ISO 9001:2015 (Quality Management for Catalyst Manufacturing)
    • EC 1935/2004 (Materials and Articles Intended to Come into Contact with Food – for polymer producers)
    • ASTM D2027 (Polyethylene Materials Standards)
    • REACH Regulation (EU chemicals use restriction and documentation)

    Typical usage ratio

    • 0.05–0.3 mmol vanadium per gram of catalyst support, adjusted for desired activity and polymer grade requirements.

    Downstream process integration

    • Dosed in controlled atmosphere gloveboxes or continuous stirred tank reactors during catalyst synthesis, followed by washing and activation prior to reactor loading.

    Final product types

    • High-molecular-weight polyethylene films, blow-molded containers, injection-molded automotive parts and food packaging resins.

    3. Chemical Reagent for Organic Synthesis and Fine Chemicals

    In fine and specialty chemicals manufacturing, the material acts as a powerful chlorinating reagent and oxidation catalyst in continuous or batch reaction systems. It enables selective introduction of chloride functional groups and oxygenation in pharmaceutical intermediates or agrochemical actives. Downstream processors employ rigorous handling and reactor condition control to target specific transformation pathways, optimizing product purity and yield in compliance-sensitive sectors.

    Industry compliance standards

    • GMP (Good Manufacturing Practice for APIs and intermediates – ICH Q7)
    • ISO 14001 (Environmental Management)
    • REACH Regulation (EU chemical documentation and handling protocols)
    • Process-specific validated methods for residual vanadium and by-product tracking

    Typical usage ratio

    • Stoichiometric to 1.2 molecule equivalents relative to substrate; fine-tuned per reaction route and reactor volume.

    Downstream process integration

    • Charged into jacketed glass-lined batch reactors or flow systems under strict anhydrous control at designated process steps, often followed by in-situ quenching and phase extraction.

    Final product types

    • Halogenated intermediates for pharmaceuticals, crop protection actives, specialty monomers, advanced organic dyes and pigments.

    4. Ceramic Pigment Production for High-Temperature Enamels

    Vanadium Oxytrichloride is used as a source of vanadium ions in the manufacturing of ceramic pigments, especially for yellow and green hues in high-temperature fired enamels. The material is metered into mill batches with metal oxides and fluxes. Calcination under prescribed kiln cycles ensures pigment phase development and color fastness meeting industrial ceramic quality demands, as specified for technical and decorative ceramics markets.

    Industry compliance standards

    • EN 12875-4 (Dishwasher Resistance of Ceramic Decorations)
    • ASTM C21 (Ceramic Whitewares and Porcelain Enamel Standards)
    • ISO 6486 (Lead and Cadmium Release in Ceramic Ware)
    • ISO 9001:2015 (Quality Management for Pigment Manufacturing)

    Typical usage ratio

    • 0.5%–4% by weight calculated as V2O5 equivalent in the pigment batch; the level is selected for color intensity and firing temperature range.

    Downstream process integration

    • Dispersed with host oxides in wet ball mills, followed by spray drying and solid phase calcination between 800–1200°C within multi-zone rotary or tunnel kilns.

    Final product types

    • Yellow and green ceramic pigments for porcelain enamel coatings, decorative tiles, sanitary ware glazes, and technical ceramics.

    5. Battery Electrolyte Modification for Vanadium Redox Flow Cells

    This compound is leveraged as a vanadium source for preparing high-purity electrolytes used in industrial-scale redox flow batteries. Operators convert the chlorinated material to dissolved vanadyl and vanadate species under controlled hydrolysis and purification regimes, meeting strict impurity limits demanded by large-format stationary energy storage manufacturers. The vanadium concentration and oxidation state distribution are engineered to sustain charge-discharge efficiency and long service life in grid applications.

    Industry compliance standards

    • IEC 62932 (Grid-Integrated Flow Battery Systems)
    • UL 1973 (Safety Standards for Battery Systems)
    • ISO 9001:2015 (Quality Management for Battery Component Preparation)
    • RoHS 2 (Restriction of Hazardous Substances in Electrical and Electronic Equipment)

    Typical usage ratio

    • Converted to 1.6–2.0 mol/L vanadium concentration in electrolyte (total vanadium); feedstock quantity based on full cell capacity design.

    Downstream process integration

    • Hydrolyzed and filtered to precipitate vanadium oxide hydrate, dissolved in sulfuric acid blending systems, with pH and valence precisely managed for battery charge/discharge performance.

    Final product types

    • Electrolytes for grid-scale vanadium redox flow batteries, deployed in renewable energy integration, peak-shaving, and backup power solutions.
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    Certification & Compliance
    More Introduction

    Vanadium Oxytrichloride: Proven Quality, Reliable Performance

    What We Produce and Why It Matters

    Every drum and cylinder leaving our facility with the label Vanadium Oxytrichloride (VOCl3) carries years of chemical experience and attention to detail, not just a batch number. We develop each lot from high-purity raw vanadium sourced from strictly verified suppliers. In the manufacturing process, our team relies on well-established chlorination routes to achieve extremely low impurity levels, especially with regards to moisture content, as even trace water can compromise the results our customers depend on. Our standard grade contains a minimum vanadium (V) content exceeding 99%, with chlorides and oxides tightly controlled through every production stage.

    Across the whole production line, our engineers monitor temperature and pressure at each reactor node. In practice, this isn’t just a step in a flowchart; proper monitoring helps avoid byproducts that plague less sophisticated operations: things like vanadium tetrachloride or hydrolyzed vanadium impurities. Many in the chemical market deal with inconsistent supply and poor shipment protocols, watching their VOCl3 degrade during transport. We don’t tolerate this. Finished product gets nitrogen-blanketed and filled in corrosion-resistant steel cylinders, with batch analysis performed again after packaging—every time.

    Key Applications: More Than a Raw Material

    Specialty organic chemists and polymer synthesis researchers have long appreciated high-purity vanadium oxytrichloride. In our direct supply relationships, the most frequent feedback revolves around its use as an effective catalyst precursor in the production of ethylene-propylene-diene monomer (EPDM) rubber. With premium VOCl3, the polymer backbone forms reliably, free of chain-scission problems caused by trace metal contaminants.

    Our VOCl3 offers more than a catalyst function. The chemical shows high selectivity in acylation and halogen exchange reactions. Researchers using our product see cleaner downstream separations and fewer troublesome byproducts, especially when undertaking reactions sensitive to halide composition. Pharmaceuticals and agrochemicals researchers also turn to us for material that performs with predictability and full lot traceability, knowing batch-to-batch consistency matters as much as initial purity.

    Specification and Handling: Safety Backed by Experience

    Each batch earns a certificate of analysis reporting vanadium (V) content, chloride ion concentration, residual moisture, and volatile impurities below detection thresholds. Our typical VOCl3 is a pale yellow-to-orange liquid at ambient temperature, boiling at approximately 127°C. The density averages around 1.91 g/cm3 at room temperature, a direct measure of purity and composition stability. We work with users around the world who require their drums and cylinders delivered on time, with no surprise weight loss or changes in chemical profile midway through transit.

    Collectors and process operators buy directly from us, not from intermediaries, because our packaging and shipping protocols actually take real-life storage conditions into account. The product reacts readily with water, releasing hydrogen chloride and forming vanadium pentoxide. We have trained our logistics teams not just in compliance but in hands-on drum maintenance, leak-checking, and safe transfer into lined tanks.

    Standards We Rely On

    Industry standards offer some basic guides, but real-world manufacturing draws lines beyond those recommendations. We exceed typical standards for inorganic contaminants—especially sodium, magnesium, calcium, and transition metals—because we’ve seen how even a few extra ppm can affect catalyst behavior. For use in high-performance EPDM production, our long-term partners tell us even the smallest spike in sodium can disrupt their polymerization processes. For that reason, we developed stepwise purification protocols, including multistage distillation and continuous moisture monitoring, as standard operation.

    Our vanadium oxytrichloride is primarily marketed at a commercial specification suitable for polymer and pharmaceutical R&D, process development, and full-scale manufacturing. Seasonal variations—ambient temperature, humidity during transfer, or even mechanical impact during delivery—have all been factored into our tank design decisions. Each drum is equipped with tamper-evident closures, safety labeling in multiple languages, and detailed batch data. Decades of continual feedback refine every layer of our quality assurance.

    Differences from Other Products

    Not all vanadium products perform the same tasks. In the chemical space, the most common confusion comes from lumping together vanadium oxytrichloride (VOCl3), vanadium pentoxide (V2O5), and vanadium tetrachloride (VCl4). Each compound has unique properties. Our VOCl3 carries three chlorides, and that specific composition determines its volatility, hydrolysis reaction, and catalytic activities. For high-temperature, gas-phase catalyst applications, some customers use vanadium pentoxide, as it offers greater thermal stability but does not deliver the same reactivity in organic synthesis or halogen exchange. VOCl3 brings a balance: a liquid at ambient temperatures, easily dosed, compatible with gas-phase introduction, and markedly less hazardous than pure VCl4, which fumes aggressively even at modest temperatures.

    Working directly with vanadium pentachloride (VCl5) or tetrachloride means fighting constant degradation and instability. Our direct experience showed VOCl3 remains less sensitive during normal shipping provided the drum seal remains intact and the filling is under inert gas. This reliability sets VOCl3 apart not just on paper but in labs where process interruptions drive up costs and scrap rates.

    Integrating VOCl3 in the Supply Chain

    Reliable vanadium oxytrichloride supply begins with transparent sourcing, not just process control within the factory walls. A handful of vanadium producers feed the global chemical industry, and in our early years, raw material inconsistencies led to variable yields and subpar color in the finished product. Years of partnership building with primary vanadium miners allowed our team to lock in long-term supply contracts, backed by on-site audits.

    We grip the full logistics chain, handling hazardous material certification, climate-controlled warehousing, and timely customs paperwork. By focusing on direct shipments rather than multi-leg transport through traders, we reduce product exposure and damage rates. Saving days at the port makes a noticeable difference in how the product arrives at a remote consumer’s facility. Our staff coordinate transfers from reactor to drum to transport container without equipment downtime or unnecessary handovers. We have learned that consistency breeds trust, and long-term VOCl3 buyers routinely cite our logistical stability as a reason for their multi-year contracts.

    In Practice: Solving Real-world Challenges

    Many chemists who transition to vanadium oxytrichloride have stories about clogged transfer lines or sticky residues in their batch reactors, usually from lower-grade supply or mishandled containers. We designed our drum venting and dispensing adapters specifically to eliminate air ingress during transfer. Operating experience showed that standard valves often failed to seal out humidity over repeated use, leading to discoloration or reduced shelf life. Now, every piece of shipping equipment gets inspected and replaced following a rigid schedule. This routine cuts down on risks faced by our end users and reduces the time they spend on troubleshooting.

    In our manufacturing quarters, quality control teams run parallel checks for batch verification. We avoided paper-only tracking systems after witnessing the problems of delayed cross-checks or missing serial numbers. With digital logging and continuous sensor feeds, each batch’s handling history stays accessible from raw input to filled drum. If a customer ever encounters an off-spec lot, root cause analysis can begin within hours, not days. These process improvements never happen by accident; they grow out of uncomfortable lessons drawn from early mistakes.

    Addressing Safety and Environmental Concerns

    Handling VOCl3 safely takes respect for its reactivity, as anyone who’s glimpsed a fuming drum in humid air could attest. Our protocols move beyond what regulators require, encompassing regular employee training and ongoing ventilation upgrades in fill rooms. Every staff member learns about rapid response measures in case of accidental hydrolysis or leak situations, with regular mock drills. Container drainage and residue elimination require multi-stage neutralization, not just bulk rinsing, as runoff vanadium compounds threaten groundwater quality. All post-use drums return to our facility for reclamation or high-temperature cleaning, preventing slow buildup of vanadium residues in the environment.

    Over the last decade, environmental regulations around halogenated metal compounds grew stricter. We work directly with local and national environmental inspectors, sharing real emissions data and storage practices, instead of waiting for surprise audits. Many smaller manufacturers attempt to save costs by loosening these standards, but this only backfires through lost customer contracts and hazardous waste penalties. Our best partnerships emerged from clear demonstration of these values rather than sales pitches.

    Product Ownership Throughout Its Lifecycle

    Logging the lifecycle of each VOCl3 lot takes diligence, not just regulatory compliance. From procurement of vanadium ore through every transformation step to drum sealing and after-use reclamation, traceable batch data follows along. We embraced this full-records mindset after fielding years of questions from technically demanding buyers who wanted more than a simple certificate of analysis. Having test results and material flows archived allows for near-instant tracing in response to regulatory checks or customer process reviews.

    Our shop floor system assigns each container an RFID chip linked to the master batch record, which logs maintenance, cleaning, and every transfer event. These tools proved their worth recently during a sudden review by a downstream polymer producer, tracing a packaging anomaly back to a specific drum in minutes. In markets as meticulous as Japanese electronics and American elastomer production, that capability cements the value of a disciplined approach.

    Continuous Improvement Driven by Customer Feedback

    Technical teams at customer sites who use our VOCl3 play a direct role in how we refine our process. Regular feedback sessions highlight new problems or evolving requirements, pushing us to improve reproducibility and reduce potential contaminants. As new applications for vanadium oxytrichloride emerge—such as in organic synthesis routes not envisioned by regulators two decades ago—we adapt our cleaning and analysis methods to catch trace contaminants early.

    In some years, buyers requested smaller package sizes to suit pilot plants or research labs, raising new challenges for minimizing headspace gas and evaporation loss. We introduced mini-cylinder packages with advanced pressure control, maintaining the same safety margin as bulk shipments. We also upgraded our in-lab analytical capabilities to answer detailed questions about trace elements even when certification wasn’t required, just because experienced chemists know unforeseen reactivity can upend a process overnight.

    Meeting the Future with Accountability

    Vanadium oxytrichloride will continue to play an outsized role in key industrial chemical syntheses, especially for high-end elastomers, new pharmachemical intermediates, and potentially for innovative lithium-vanadium battery designs undergoing research testing. Our commitment as a manufacturer remains shaped by the real-world demands of these markets—reliability, traceability, and practical logistics—not just by technical literature definitions.

    Ultimately, what sets our vanadium oxytrichloride apart comes down to a deeper technical understanding at every stage of the supply chain, open communication with every user, and readiness to follow up long after the initial sale. We keep learning from our industry peers and customers because real expertise grows out of years of hands-on problem-solving, not just careful process diagrams or technical brochures. Every batch we ship represents that experience—delivering the performance customers expect, the safety our teams demand, and the stewardship regulations require.