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Tetrachlorophthalic Anhydride

    • Product Name Tetrachlorophthalic Anhydride
    • Alias TCPA
    • Einecs 221-107-1
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    620064

    Cas Number 117-08-8
    Molecular Formula C8Cl4O3
    Molecular Weight 319.90 g/mol
    Physical Appearance White to off-white crystalline powder
    Melting Point 248-250°C
    Boiling Point 430°C (decomposes)
    Density 2.15 g/cm³
    Solubility In Water Insoluble
    Solubility In Organic Solvents Soluble in acetone, benzene, chloroform
    Odor Pungent
    Stability Stable under recommended storage conditions
    Reactivity Reacts with strong oxidizing agents
    Ec Number 204-181-3
    Un Number 2812

    As an accredited Tetrachlorophthalic Anhydride factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Tetrachlorophthalic Anhydride is packaged in a 500g sealed amber glass bottle with tamper-evident cap and hazard labeling.
    Shipping Tetrachlorophthalic Anhydride is shipped in tightly sealed containers, typically as a solid or powder, protected from moisture and incompatible materials. During transport, it must be labeled as a hazardous material, handled according to relevant regulations (such as UN 3077), and kept away from foodstuffs and oxidizing agents to ensure safety.
    Storage Tetrachlorophthalic anhydride should be stored in a cool, dry, and well-ventilated area, away from moisture and incompatible substances such as strong bases and oxidizers. Store in tightly sealed containers made of corrosion-resistant material. Keep away from heat, sparks, and open flames. Use secondary containment to prevent spills, and clearly label the storage area with appropriate hazard warnings.
    Application of Tetrachlorophthalic Anhydride

    Applications of Tetrachlorophthalic Anhydride in Industrial Manufacturing

    Tetrachlorophthalic anhydride enables specialized chemical synthesis in advanced polymers, coatings, electrical insulation, agrochemical intermediates, and flame-retardant systems. Our production supports global manufacturers adhering to strict quality, safety, and regulatory requirements.

    1. Flame Retardant Additive Manufacture

    Industrial resin compounders introduce tetrachlorophthalic anhydride as a chlorinated aromatic modifier in the synthesis of halogenated flame-retardant resins. The material performs vital chlorination during resin polymerization, ensuring enhanced char formation and smoke suppression according to stringent safety regulations in electronics housing, wire insulation, and automotive components. Controlled use supports regulatory compliance regarding halogen content and VOC emission while enabling high-performance end-product certification for electrical and building sectors.

    Industry compliance standards

    • UL 94 Flammability Standards
    • RoHS Directive (2011/65/EU)
    • REACH Regulation (EC) No 1907/2006
    • IEC 60695-11-10 Fire Hazard Testing

    Typical usage ratio

    • 5–20% by weight in unsaturated polyester and epoxy matrices, adjusted based on required UL 94 rating, part geometry, and matrix compatibility.

    Downstream process integration

    • Melt phase incorporation into pre-polymer blend during initial compound mixing.
    • Solution blending with base resins for prepreg manufacturing and molding compounds.
    • Direct halogenation reactions in resin synthesis workflows.

    Final product types

    • Flame-retardant composite panels
    • Encapsulation resins for electronics
    • Thermoset casings and circuit board laminates
    • Automotive under-hood parts

    2. Specialty Polyester Resin Production

    Tetrachlorophthalic anhydride enters the polyester resin industry as a co-monomer to impart controlled hydrolytic resistance and high thermal performance in specialty unsaturated polyester resins. Resin formulators utilize the anhydride for cross-linking to meet advanced chemical resistance and mechanical strength demanded in chemical storage vessels, underground pipes, and corrosion-resistant laminates.

    Industry compliance standards

    • ASTM D7576 Standard Specification for Thermosetting Polyester Resin Systems
    • DIN EN ISO 846:2019 (Microbial Resistance)
    • ISO 9001:2015 Quality Management

    Typical usage ratio

    • 5–18% by molar content in polyester backbone; specific ratios set according to viscosity requirements and cross-linking density for corrosion class rating.

    Downstream process integration

    • Fed into the reactor during polycondensation, providing chlorine content in the final copolymer structure.
    • Monitored addition during initiator and promoter stages to control gel time.

    Final product types

    • Glass fiber reinforced tanks and pipes
    • Chemical-resistant flooring and grating
    • Protective coatings for anti-corrosion environments
    • Marine construction profiles

    3. Electrical Insulation Material Synthesis

    Tetrachlorophthalic anhydride provides halogenation and aromatic stabilization when used in high-voltage insulating varnish and encapsulation compounds. Technical teams select precise input amounts to achieve low partial discharge and high tracking resistance necessary for manufacturing instrument transformers, circuit breakers, and insulating bushings in power transmission.

    Industry compliance standards

    • IEC 60216 Thermal Endurance Standards
    • IEC 60112 Tracking Resistance
    • EN 60243-1 Electrical Strength of Insulating Materials

    Typical usage ratio

    • 10–15% by total resin weight in anhydride curing blends for epoxy and polyester-based insulation; ratios adapted for specific voltage classes and insulation thickness.

    Downstream process integration

    • Added during the blending of liquid varnish formulations before application onto coil windings or casting molds.
    • Mixed with compatible hardeners in the prepreg stage for dry-type transformer manufacture.

    Final product types

    • High-voltage transformer coil insulation
    • Low-voltage switchgear encapsulation systems
    • Busbar insulating varnishes
    • Epoxy-bonded mica tapes

    4. Agrochemical Intermediate Synthesis

    Agrochemical manufacturers use tetrachlorophthalic anhydride as a chlorinated aromatic intermediate to create specialty pesticides and herbicides. The anhydride’s reactivity allows efficient ring formation and halogen substitution steps in the multi-stage synthesis of fungicide actives and crop protection agents. Production teams control purity, moisture, and reaction temperature to meet agricultural regulatory specifications and downstream formulating needs.

    Industry compliance standards

    • FAO/WHO Joint Meeting on Pesticide Specifications (JMPS)
    • US EPA 40 CFR Part 180 Tolerances and Exemptions for Pesticide Chemicals
    • ISO 17025:2017 Analytical Laboratory Testing

    Typical usage ratio

    • Molar ratios based on target pesticide structure; frequently 1:1.05 mol with nucleophile reactants during core substitution, ratio adjusted based on route yield and desired active isomer.

    Downstream process integration

    • Feeds the primary aromatic halogenation step during active ingredient intermediate synthesis.
    • Used as a reactant in closed reactor vessels for post-chlorination or cyclization stages.

    Final product types

    • Technical grade fungicide intermediates
    • Halogenated herbicide precursors
    • Chlorinated pesticide actives
    • Crop protection formulation bases

    5. Cross-Linker in Powder Coating Systems

    Powder coating formulators employ tetrachlorophthalic anhydride to impart chemical inertness and improve weathering performance in polyester-based powder coatings for appliances, architectural panels, and utility-grade coatings. The material acts as an anhydride cross-linker, with precise dosing to achieve target curing profiles and surface hardness, supporting compliance with international outdoor exposure and chemical resistance demands.

    Industry compliance standards

    • Qualicoat Specifications for Architectural Aluminum
    • ISO 8130 Powder Coating Test Procedures
    • ASTM D3359 Adhesion Tests

    Typical usage ratio

    • 2–10% by resin mass, tuned based on gloss retention and flexibility requirements in powder formulation.

    Downstream process integration

    • Blended at mill base stage before extrusion and micronization.
    • Cross-linker role during curing chamber exposure in end-user application.

    Final product types

    • Home appliance coatings
    • Aluminum architectural finish powders
    • Pole and fence anti-corrosion coatings
    • Metal furniture and shelving systems
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    Certification & Compliance
    More Introduction

    Tetrachlorophthalic Anhydride – Practical Insights from the Production Floor

    Introducing a Specialty Ingredient Shaped by Real-World Demands

    Crafting chemicals isn’t just about reacting substances in a vessel. Years of hands-on experience have shown us which materials deliver under pressure, and tetrachlorophthalic anhydride (TCPA) proves its worth on the floor and in finished goods alike. Few compounds respond with such consistency to the relentless requirements set by modern industry. The real value comes through in daily production runs and in how downstream operations handle the material—it’s easy to notice the difference good quality makes. TCPA, sometimes labeled by our model designation 99.5-TCPA, stands out for its purity, convenience in handling, and the stability it offers to customers who seek more than just a commodity.

    The Name Behind a Trusted Input – What Sets This Molecule Apart

    Anyone familiar with the fibreglass or plastics business learns quickly that not every anhydride brings the same reliability. Our TCPA arrives in a white to slightly off-white crystalline powder, free flowing and easy on equipment. It runs through feeders without gumming up, dissolves completely in the suggested solvents, and offers predictable reactivity batch after batch. Hard-earned feedback from hundreds of clients helped fine-tune our control over contaminants, which rarely register above spec even during peak output periods. Many operators, especially in the resin and flame retardant sectors, have told us firsthand how it prevents unexpected shutdowns and off-grade formation. This is not theoretical: robust batches mean higher yields and fewer stoppages that eat into production schedules.

    Focus on Purity – Meeting Rigid Standards Day In, Day Out

    Delivering material that’s >99.5% pure, based on rigorous in-house and independent lab tests, demands constant monitoring. Chlorine levels always matter with this compound, since manufacturers want assured fire resistance without unwanted color-forming byproducts. We use a proprietary multi-step distillation combined with controlled cooling to ensure homogeneous crystal formation and low volatiles. Every drum and lined bag passes visual inspection and is checked by FTIR and HPLC, not only to satisfy the letter of a specification sheet but to provide genuine confidence for operators upstream. Many of our long-standing plasticizer clients comment that switching to less controlled material caused spikes in out-of-tolerance readings and reprocessing. Production lines don’t tolerate chaos, and that’s where our team’s experience—we’ve run TCPA campaigns for over a decade—pays off in repeatable, trust-worthy output.

    Usage Straight from the Shop Floor

    Our customers keep coming back to TCPA for its proven role in heat- and flame-resistant resins, especially in applications where regulatory pressure never lets up. Molded parts, circuit boards, and coil coatings all need additives that won’t degrade or drift under stress. Over the years, feedback showed clear patterns: our variant of TCPA plugs directly into unsaturated polyester resin lines, acting as both a curing component and halogenated flame retardant. It’s become instrumental in fiberglass-reinforced panels that must pass the world’s toughest fire protection tests. Paint and surface coating producers benefit from TCPA just as much—the compound finds favor as a crosslinker, leading to improved chemical resistance and lasting surface properties in commercial environments.

    Every time a floor supervisor or R&D chemist shares their experience, we learn how the material fits into continuous processing, how it behaves in bulk storage, or where surprises might crop up. One particular insight comes from high-speed glass mat resin applications, where too much dust or low-melting impurities can jam dispensers. Tight sieving and screening, completed on the same line as the final packaging, eliminate foreign particles and help reactors keep moving. TCPA also eases blending since its melting point sits right where bulk feeders and preheating sections need it: not so low that it cakes in transport, not so high that it slows melting cycles or needs expensive extra heating. This real-world feedback loops directly into our production control system.

    Looking Deeper: Differences That Make a Real-World Difference

    Not all anhydrides or phthalic derivatives work the same. We field direct questions from plastics and coatings manufacturers about possible substitutions—often from teams who previously used standard phthalic anhydride or its isomers, and ran into fire safety trouble. Switching ordinary phthalic anhydride into an application where regulatory demands or interior air quality matter quickly produces non-compliance issues or performance dips. TCPA’s chlorine load enables it to yield higher limiting oxygen indices and cut down on unwanted smoke generation, a point inspectors check regularly on production lines.

    Some resin designers experiment with hexachloro-end derivatives, aiming to chase still higher flame retardancy, but soon encounter processing headaches. More heavily chlorinated anhydrides show greater volatility or hydrolyze in atmospheric moisture, creating handling concerns and sometimes corroding steel feed lines. By managing chlorine levels at four atoms per ring, TCPA delivers a balance of stability, runnability, and cost that matches the majority of modern use-cases—whether the line is churning out kilometers of cable sheathing or prepping panels bound for rail interiors.

    Instead of focusing on theoretical maximal fire resistance, experience has taught us the real winner is an ingredient that behaves the same every Monday morning as it does after a week-long setup. Each lot we ship builds in protection against swings in humidity and temperature. TCPA from our lines won’t cake or absorb excess water before reaching the blend—this directly preserves throughput numbers and shifts output. Months of storage in typical transit conditions don’t degrade its melting behavior or feeding characteristics.

    Front-Line Problem Solving – From Shipping Rooms to End Use

    TCPA’s physical profile helps keep material transfer and dosing predictable. Operators who once struggled with clumping or dusting in open hoppers reported clear improvements once they shifted to product out of our facilities. Each shipment features low fines, a result achieved by on-site pneumatic sifting rather than subcontracting pelletizing out to third parties. The minor cost difference pays dividends in reduced downtime. In resin kettles or conveyorized paint mixing setups, this improvement surfaces as fewer filter blockages and more stable charging times.

    Many of our clients manage tight production windows—a full day’s stoppage can erase the margin for an entire month. That creates pressure to move away from cheaper, variable quality sources. Our logistics team knows the downstream pain points well, working directly with buyers to coordinate packaging sizes that keep moving lines clean. Whether it’s lining a five-ton railcar or hand-filling 25-kilo drums, each packaging batch is barcode-logged, sifted for foreign fibers, and sealed against ambient air. This habit came about after a spate of complaints from new customers who tried generic TCPA only to find rust flakes or fused clumps in the bag. We dedicated time and resources to root these out—not because a specification called for it, but because it shaved hours off cleanup for our customers.

    Balancing Cost and Compliance – A Real Producer’s Perspective

    Staying profitable means balancing the pressure from raw chlorine and solvent prices against the non-negotiable drive for purity. Long-standing procurement managers know that cutting corners shows up quickly in resin tests: off-colors, failed ignitability, or resin fouling exact a far bigger cost than carrying a few extra grams of premium TCPA. So, even in cycles when feedstock markets spike, we hold the line on chlorination control and solvent removal steps. The incremental saving from running at lower standards simply never makes up for the downstream consequences.

    Standards and regulations are nothing abstract for anyone in our business. Across Europe, North America, and Asia-Pacific, fire safety rules stiffen every year. We see the landscape changing in real time, as new tests force resin developers to requalify additives they’ve relied on for decades. Our R&D team runs trial compounds directly with partner manufacturers to ensure our TCPA passes evolving UL, EN, and ASTM flame resistance benchmarks. On the rare occasion a batch misses a new test, we trace the cause and overhaul the synthesis or refining phase until the update sticks. This approach builds trust, as compliance isn’t about paper alone. Consistency over years, not just with flagship units but from every reactor and packaging bay, matters to engineers running twenty-four-hour shifts.

    Field Results – Data, Not Just Hype

    Instead of banking on theoretical values, we report the basics—active ingredient purity, controlled chlorine levels, and melting point—because we know these impact production uptime and final article certification. At 99.5% purity and typical melting points around 240-245°C, our TCPA batches fit right into most resin recipes without demanding expensive retooling or new safety steps. Flame retardancy remains strong, with oxygen indexes from test panels exceeding 35%, meeting or beating internationally referenced benchmarks in both construction and transit sectors.

    Comparing TCPA with other halogenated anhydrides, users mention reduced smoke output and a less acrid odor on overheating. This gets noticed in closed environments like wind turbine housings and train interiors, where occupants and inspectors care about air quality as much as structural safety. These direct correlations—the sort clients bring back to us unprompted—drive how we refine and tweak our internal procedures. If an impurity level nudges upwards in a trend report, plant operators meet face-to-face to trace the root cause before a customer ever sees a change. We don’t leave these steps to chance, because a single off-batch can derail a partner’s schedule for weeks.

    The Production Team’s View – Behind the Scenes

    Everyone on the factory floor understands how raw material idiosyncrasies affect large-scale blending and high-throughput operations. We structure shifts and line settings to respond quickly if sampling suggests a drift from established TCPA specs. Each incremental change—an improved filter, a slight tweak to condensation temperature—comes from thousands of iterations and hands-on troubleshooting, backed by data pulled from both the shop floor and downstream reports. Operators rely on access to up-to-the-minute process logs, linking what’s happening now to longer cycle trends. These lessons learned show up in low incidence rates and, more importantly, customer reorders.

    By keeping production under one roof, with synthesis, purification, and packing all monitored by our core team, traceability stays tight. Lapses in cleanroom work or lapses in drum sealing get flagged and fixed before a truck ever rolls out. Experienced hands steer the blend settings, as minor changes can cause later headaches like feeding interruptions or batch separation. This local knowledge—built over years, not months—shapes how we address packaging, storage, and even shipping routes to avoid temperature excursions that could degrade quality before material arrives.

    Ongoing Collaboration – Partnering for Long-Term Success

    No chemical, however well-made, works in a vacuum. We keep close contact with users—from quality managers at composite panel factories, to R&D teams designing new epoxy blends. Our technical specialists are stationed where they can observe, troubleshoot, and relay user feedback to the plant, closing the loop between real-world use and plant-level innovation. Many effective changes begin with a line operator or blender noticing a minor difference in melting time or dust presence. This open feedback culture explains why our current TCPA grades keep leading benchmarks for flow properties, shelf stability, and end-use compliance.

    Some users expressed a demand for custom-grind grades, targeting high-torque extruders or high-shear mixers used in specialty laminate sheets. We answered by investing in finer-mesh mills, then worked alongside mixers to ensure no dusting risk or premature clumping in humid weather. These site visits and test runs help us anticipate wider industry shifts—whether prompted by regulatory bodies or by the growing shift toward tighter emissions and lower workplace exposure. Any need for seamless documentation or faster turnaround times gets relayed directly to the logistics scheduler, ensuring users get continuous improvement and not just lip service.

    What Really Matters in Performance and Safety

    The world rarely stops for those unprepared for change—especially not in the chemicals sector. TCPA’s reputation relies just as much on what users don’t notice: steady flow rates, no unexpected shutdowns, consistent performance in every drum opened. When a line keeps moving and passes every audit, plant managers call that success. We make it our job to protect these hidden wins for every partner, not with empty guarantees or brochure claims, but by showing up in the details that matter: strict screening, full batch traceability, practical packaging, and hands-on support.

    Commitment to Future-Proofing

    We believe the responsibility for product safety and performance falls to us. The drive to beat ever-shifting standards pushes our teams to improve synthesis steps, cut waste, and test new catalysts that minimize unwanted side reactions. Every improvement becomes part of our standard routine, not just a one-off for crises. We work openly with regulatory experts, watching new fire, health, and environmental rules, and adjusting controls to stay two steps ahead—not just in the lab, but on the floor where downtime costs real money.

    Why Practical Know-How Makes a Difference

    Anyone who spends a day in a plant blending thermosets or formulating specialty coatings learns to recognize the difference between a product that’s been mass-produced to minimum specs and one refined for its real task. TCPA owes its reputation to those who work it into resins, foams, plastics, and coatings that keep buildings, vehicles, and infrastructure safe and compliant. Our investment goes into what matters most: high-active ingredient, reliable physical and chemical behavior, and a production approach that puts the needs of day-to-day users first. Each time our TCPA passes through a mixer, a curing oven, or a composite layup line without incident, it reaffirms the value of attention to detail, constant learning, and unfiltered communication between producer and customer.