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Tert-Butyl Acrylate

    • Product Name Tert-Butyl Acrylate
    • Alias TBA
    • Einecs 215-481-4
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    842952

    CAS_Number 1663-39-4
    Molecular_Formula C7H12O2
    Molecular_Weight 128.17 g/mol
    Appearance Colorless liquid
    Boiling_Point 123-124 °C
    Density 0.885 g/cm³ at 20 °C
    Melting_Point -65 °C
    Flash_Point 18 °C (closed cup)
    Refractive_Index 1.418-1.420 at 20 °C
    Solubility_in_Water Insoluble
    Odor Pungent, ester-like
    Vapor_Pressure 8 mmHg at 20 °C

    As an accredited Tert-Butyl Acrylate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Tert-Butyl Acrylate is packaged in a 1-liter amber glass bottle with a secure cap, labeled with hazard and handling information.
    Shipping Tert-Butyl Acrylate should be shipped in tightly sealed containers, protected from heat, sparks, and direct sunlight. It must be classified and labeled as a flammable liquid and handled as per UN 2348 guidelines. During transport, ensure proper ventilation and store away from incompatible substances, such as strong oxidizers and acids.
    Storage Tert-Butyl Acrylate should be stored in a cool, dry, well-ventilated area away from heat, ignition sources, and direct sunlight. Keep the container tightly closed and protected from moisture. Store separately from oxidizers, acids, and bases. Use containers made of compatible material, ideally in a flammable liquids storage cabinet. Ensure proper labeling and access is restricted to trained personnel.
    Application of Tert-Butyl Acrylate

    Applications of Tert-Butyl Acrylate in Industrial Manufacturing

    Tert-Butyl Acrylate plays a key role as a building block in advanced polymer synthesis and specialty coatings manufacturing. Our facility supplies material used across multiple certified industrial sectors, reflecting research-led quality control and formulation experience. Below, we detail prime downstream use cases, including sector standards, dosage guidance, process workflow, and typical finished goods.

    1. Production of Pressure-Sensitive Adhesives

    The production of acrylic-based pressure-sensitive adhesives relies on precise incorporation of tert-butyl acrylate for tuning tack, peel, and aging properties of adhesive films and tapes. Formulators adjust the monomer balance to match viscosity, adhesive cohesion, and environmental resistance targets. Tert-butyl acrylate enters the copolymerization stage, influencing both polymer flexibility and resistance to plasticizers during continuous reactor operations in commercial plants. Final adhesive products address requirements for automotive assemblies, specialty labels, and electronic tapes.

    Industry compliance standards

    • ASTM D3330/D3330M (Standard for Peel Adhesion of Pressure-Sensitive Tape)
    • FDA 21 CFR 175.105 (Components of adhesives for indirect food contact)
    • EU Regulation (EC) No. 1907/2006 (REACH registration for polymeric adhesives)
    • ISO 8510-1:2006 (Adhesives—Determination of tensile lap-shear strength using rigid-to-rigid bonded assemblies)

    Typical usage ratio

    • 5–30% by weight in acrylic monomer blends, with exact percentage tailored to required adhesive balance between cohesion and peel; higher tert-butyl acrylate yields softer, more flexible adhesives.

    Downstream process integration

    • Direct monomer feeding into emulsion or solution polymerization reactors; addition timing adjusted based on molecular weight targets and co-monomer ratio.

    Final product types

    • Double-sided mounting tapes
    • Automotive foam tapes
    • Protective film adhesives for electronics
    • Removable label stock

    2. Synthesis of Specialty Acrylic Resins for Automotive Coatings

    Automotive OEM and refinish coatings require high-performance acrylic resins to impart weather resistance, chemical stability, and mechanical flexibility. Tert-butyl acrylate is selected by formulators for its high glass transition temperature and hydrophobic profile, enabling fine-tuning of resin hardness and scratch resistance during backbone synthesis. Our technical grade material supports strict batch reproducibility for downstream resin kettle polymerization, ultimately shaping coating basecoats and clearcoats engineered for exterior durability.

    Industry compliance standards

    • OEM paint standards: GMW 14124 (General Motors Paint Performance Specification), ISO 11997-1 (Automotive coatings—Accelerated corrosion tests)
    • US EPA 40 CFR Part 59 (VOC content limits for automobile refinish coatings)
    • IEC 60296 (Electrical insulating oils for automotive applications—polymer compatibility)

    Typical usage ratio

    • 10–25% by weight in resin monomer feedstocks; precise level selected per target weatherability, flow, and leveling characteristics in finished coatings.

    Downstream process integration

    • Charged into batch or continuous polymerization lines; reacts with other acrylate and methacrylate monomers under heat and initiator activation to produce high molecular weight acrylic polymers.

    Final product types

    • Automotive OEM clearcoats
    • Metallic automotive basecoats
    • Scratch-resistant refinish topcoats
    • Plastic component primers

    3. Manufacture of UV-Curable Inks and Coatings

    Formulators of UV-curable systems employ tert-butyl acrylate as a reactive diluent and comonomer to manage viscosity while enhancing the flexibility and adhesion of cured films. Its presence in oligomer and monomer blends helps optimize cure speed, film hardness, and substrate adhesion for graphic, packaging, and optical applications. The material is metered into prepolymers prior to UV lamp initiated crosslinking, allowing for precise adjustment of cured membrane properties under high-speed curing lines.

    Industry compliance standards

    • EuPIA Guidelines for Printing Inks for Food Packaging
    • ISO 2846-1 (Graphic technology—Color and transparency of printing ink sets for four-colour process printing)
    • 41 CFR Part 109 (Occupational exposure controls for UV curing applications)

    Typical usage ratio

    • 5–20% by weight as part of monomer/oligomer blends; the concentration is modified in relation to viscosity, surface hardness, and cure rate requirements for each ink or overprint varnish system.

    Downstream process integration

    • Blended during resin and monomer mixing stage before photoinitiator addition; fully integrated prior to UV lamp curing of finished coating or ink on printing, packaging, or wood substrates.

    Final product types

    • UV inkjet printing inks
    • UV cured wood floor coatings
    • Food packaging overprint varnishes (non-direct food contact zones)
    • Optical fiber coatings

    4. Synthesis of Functional Polymers for Water Treatment Flocculants

    Specialty flocculant and coagulant manufacturers incorporate tert-butyl acrylate as a hydrophobic co-monomer to tailor polymeric chain architecture for enhanced particle capture and dewatering performance. Our product supports cationic and anionic copolymer production under controlled aqueous solution polymerization, allowing end-user adjustment of solubility and thermal stability for industrial and municipal water treatment. Downstream partners employ these polymers in processes designed for large-scale clarification and sludge treatment.

    Industry compliance standards

    • ANSI/AWWA B453 (Water-treatment chemicals—Polyacrylamide)
    • EN 1408:2013 (Chemicals used for treatment of water intended for human consumption—Polyacrylamide and copolymers)
    • Chinese Standard GB 17514 (Polyacrylamide for Urban Water Supply and Drainage Treatment)

    Typical usage ratio

    • 2–10% by weight in final copolymer composition; selected ratio addresses balance between floc growth and settling dynamics via laboratory jar tests and scaleup adjustments.

    Downstream process integration

    • Metered with acrylamide, acrylic acid or cationic monomers into solution or inverse emulsion polymerization kettles; added before initiator charging under nitrogen protection.

    Final product types

    • Industrial effluent flocculants
    • Municipal water clarification polymers
    • Sludge dewatering aids
    • Pulp and paper retention agents

    5. Production of Impact-Modified Thermoplastic Acrylics

    Engineering plastics producers choose tert-butyl acrylate to co-polymerize with methyl methacrylate or styrene in the synthesis of acrylic impact modifiers and toughening agents. The inclusion adjusts matrix flexibility, resisting brittle fracture under stress and optimizing melt flow in injection molding applications. The monomer integrates directly in suspension or bulk polymerizations, facilitating downstream blending with vinyl-based resins. Resultant materials support manufacture of long-life automotive and appliance housings, where clarity and mechanical strength are critical.

    Industry compliance standards

    • ISO 8256 (Plastics—Determination of impact tensile strength)
    • UL 94 (Standard for tests for flammability of plastic materials for parts in devices and appliances)
    • ISO 9001 (Quality systems for polymer manufacturing)

    Typical usage ratio

    • 3–15% by weight, depending on toughness and flexibility requirements; composition optimized alongside rubber phase and particle size, verified by impact and elongation testing.

    Downstream process integration

    • Direct dosing with principal monomers in controlled bulk or suspension polymerization reactors; timing and temperature profiles ensure targeted molecular architecture prior to pelletization and compounding stages.

    Final product types

    • Impact-modified PMMA sheets
    • Automotive interior parts
    • Household appliance housings
    • Clear plastic construction panels
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    Certification & Compliance
    More Introduction

    Tert-Butyl Acrylate: Consistency, Performance, and Practical Value from an Experienced Manufacturer

    Reliable Supply Backed by Long-Term Production

    Tert-butyl acrylate has worked its way into a surprising number of daily-use and industrial products. Its unique combination of acryloyl and tert-butyl groups brings both the reactivity required for polymer work and the backbone that yields a more flexible finished material. In our facilities, we've spent years optimizing reaction conditions and purification to secure a product that meets tough converter standards each and every time. Technical teams often compare various acrylates—ethyl, methyl, butyl, and tert-butyl acrylate—because even small structural differences can impact final polymer properties. With tert-butyl acrylate, you achieve a balance between flexibility, weather resistance, and low glass transition temperature that stands out. That’s why our customers in adhesives, coatings, inks, and specialty polymers keep coming back for the same grade and consistency batch after batch.

    Focus on Practical Performance, Not Just Analytical Purity

    Decades in chemical manufacturing teach you that chasing high purity alone does not always guarantee a better result for downstream users. We control for specifications that actually matter in your process. Our typical tert-butyl acrylate offers assay above 99.5% by GC and keeps inhibitors at 10-15 ppm, optimal for safe storage and strong reactivity when needed. We inspect each lot for color, water, and acidity, because even minor traces of impurities impact catalyst choice and final product color. Over the years, formulators trust the repeatability—not just the data sheet numbers, but the way material behaves in the real world. Consistent batch-to-batch supply helps avoid hunting for solutions when materials perform unexpectedly.

    Acrylate Selection Guided by Real Polymer Demands

    Each acrylate monomer comes with its own set of strengths and weak points. Chemists sometimes stick to methyl acrylate or butyl acrylate, only to find that their copolymers turn brittle in the cold, or that adhesives lose their peel strength after UV exposure. Our tert-butyl acrylate brings a larger tert-butyl side group, so resulting polymers have better flexibility and hydrolytic stability compared to methyl or ethyl acrylate. Manufacturers in paints aim for alkali resistance and color stability, so they choose this product for exterior formulations. In adhesives and sealants, tert-butyl acrylate lifts peel strength and soft feel without dragging down tack. Ink formulators count on its fast curing in UV systems, which keeps lines running without delays or reprints.

    Consistent Specifications for Uninterrupted Processing

    Handling acryloyl chemicals in bulk brings specific challenges—not only in basic purity but in removing water, managing acid content, and holding down trace metals. Any shift in water or acidity collapses emulsion polymerization yields or spoils molecular weight control. We run continuous monitoring for each drum and tank shipped, and past experience has taught us that batch variability is the single biggest cause of surprises downstream.

    Our production tracks specifications such as clarity, acid value, and absence of haze, so downstream plant operators don’t chase ghost problems during a batch change. Technical teams still reach out from time to time to explore how tweaks in inhibitor or water levels could benefit their product, and we’re able to adjust according to their feedback because we run all steps in-house.

    Solid Experience with Storage and Handling Helps You Avoid Downtime

    You cannot underestimate the importance of proper storage for acrylate monomers. Too much oxygen or too little inhibitor, and you end up with polymer gel in your pipes. Several times over the years, we’ve helped customers get equipment back online after they received off-spec monomer from less experienced suppliers. We consistently ensure inhibitors levels stay within the right window to hold back runaway reactions during shipping, but low enough not to drag down reactivity during use. Field service engineers occasionally visit customer sites to verify tank conditions, blending, and transfer systems, offering small but effective tweaks that pay off in reduced downtime.

    It’s not simply about avoiding one bad lot; keeping a continuous, predictable tert-butyl acrylate supply on site is a key driver for most of our partners in high-throughput settings. By handling logistics ourselves, we keep lead times short and help buyers plan orders with confidence.

    Direct Application Insights—From Packaging to Adhesives

    Anyone producing pressure-sensitive adhesives soon learns there is no “one size fits all” recipe. Tert-butyl acrylate finds its best fit as a co-monomer, raising flexibility without softening the finished adhesive too much. Our own formulation customers note improved resistance to water whitening and a softer peel—important qualities for label and tape markets. Film producers take advantage of the weathering stability, relying on tert-butyl acrylate’s structure to resist embrittlement or yellowing under UV. In leather coatings, end-users have documented better elongation and stretch after months of cycles, pulling stronger through flex testing.

    Large-scale coating formulators value lower volatility and minimized monomer emissions during curing, especially as regional regulations tighten limits. With tert-butyl acrylate, coatings lines report reduced operator exposure and improved line speeds as compared to more volatile monomers.

    Clear Differences from Other Acrylate Monomers

    Practical users often ask for a side-by-side comparison with familiar materials. Methyl acrylate is known for speed and reactivity, but polymers built from it tend to harden and crack over time, especially outside. Butyl acrylate improves flexibility and is widely used for general emulsion polymers, yet some copolymers with butyl acrylate become sticky in humid environments. Our tert-butyl acrylate carries a larger branched group, lowering the polymer’s glass transition temperature and providing better resistance to alkalis and ultraviolet breakdown. This gives product designers a broader latitude to meet tough outdoor and automotive requirements.

    Ethyl acrylate remains popular for some textile and fiber applications, but concerns about volatility and workplace health have shifted preferences toward less noxious options. Workers and process managers benefit from tert-butyl acrylate’s moderate vapor pressure, which reduces fume intensity and keeps control thresholds manageable during scale-up. At the polymer synthesis scale, customers tell us this product speeds up mixing and reduces side reactions, particularly in applications that require long pot life or staged additions.

    Manufacturing Know-How Shapes Every Kilogram

    It’s tempting to believe that all acrylates are made equal, but time and process exposure tell another story. Reaction temperatures, choice of starting acrylate, inhibitor addition, and purification steps all twist the outcome. We’ve refined our columns and distillation cycles to secure tight purity and to strip off low-level by-products, which could otherwise haunt polymer quality or trigger foaming and color changes later on. Each reactor trace is logged, so recurring issues can be spotted quickly and fixed, preventing the run of sub-standard product that could wreck downstream tanks.

    In earlier years, a few batches would go slightly off-color or build up acidity from uncorrected reflux rates. Cumulative troubleshooting and regular meetings with plant technicians have eliminated these events. Our QA systems now flag any off-parameter result before drums go out the door, nipping surprises before they turn catastrophic. Buyers see the end result in steady performance; operators receive a liquid that pours, mixes, and reacts just as it did last month or last year. New team members learn from documented case histories, building a memory bank that prevents repeat problems.

    Feedback from Downstream Users Points the Way Forward

    Some of the best tweaks to our manufacturing processes have come not from lab work, but from notes and concerns passed up by users at conversion plants. Repeated requests to narrow down moisture led us to invest in upgraded drying columns, chopping defect rates in downstream copolymerization runs. Doubts about color stability triggered cooperative work with several partners to optimize inhibitor type and dose. Shipping teams keep samples from every batch, so technical support always has reference points to investigate any reported issue, whether in California, Germany, or Southeast Asia.

    We collaborate closely with major users to test product performance under realistic processing conditions—not just lab-bench quick cures, but real, line-speed mixing, storage over weeks and months, and exposure to typical field environments. We post trial results to help users match performance to their goals, cutting out guesswork and wasted time spent on trial formulations with mismatched monomer.

    Safety and Environmental Practices Based on Real-World Risks

    Safety practices around acrylates stretch far beyond MSDS statements. In full-scale manufacturing, the difference between a minor incident and a full plant shutdown often comes down to details. We regularly review our inhibitor dosing and storage routines to prevent unwanted runaway reactions that can form insoluble gel plugs. Process engineers in our plants take part in training that highlights what to watch for—temperature spikes, unexpected color, or viscosity changes, all early signs of runaway polymerization.

    Environmental compliance has moved front and center in the last decade, bringing with it higher scrutiny on emissions, spill protection, and waste management. We modified tank farms and loading bays to handle all acrylate waste in closed loops, capturing vapors and recycling process water. Users benefit from this experience when guidance is requested during audits or as part of their own push toward greener processes. Waste profiles for tert-butyl acrylate often earn better marks in local permits because the product’s lower volatility and efficient process containment cut down off-site risks.

    Continuous Investment in Process Innovation

    Innovation often comes in slow, careful steps rather than through major “breakthroughs.” Over the years, our teams have experimented with new polymerization catalysts, alternative inhibitors, and process controls to both sharpen product performance and save energy. Efforts to reduce reaction time without sacrificing purity led to continuous-flow setups, which allowed us to ramp up capacity during rising market needs without extending shift hours or raising defect rates.

    We trial advanced monitoring for trace metals and oxidizers, catching low-level contamination that traditional sampling may miss. These investments help keep our product ahead of shifting regulatory and end-use requirements. It’s not just a showpiece for auditors—every incremental change is judged on whether it improves reliability for people depending on uninterrupted, quality supply.

    Global Trends and Tert-Butyl Acrylate Demand

    Demand for acrylate products, especially tert-butyl acrylate, has surged as manufacturers move toward specialty resins and performance adhesives tuned for both durability and environmental compatibility. We see increased need in emerging markets for high-quality monomer in automotive clear coats, medical-grade films, and waterborne adhesives. Design engineers and formulation specialists crave both higher-functioning and safer end products, which drives us to further tighten product controls and provide detailed product support beyond simple spec sheets.

    Industry shifts can cause supply risks—feedstock price swings, stricter transport controls on acrylates, or abrupt regulatory changes. Some regions have slapped lower thresholds for residual monomers or banned certain stabilizers altogether. These region-specific changes force us to maintain flexible production routes and stay proactive in testing for local compliance.

    Why Real Manufacturing Matters for Buyers

    As direct producers, we’ve seen how relying on pure traders or resellers can leave users exposed to price swings, unknown handling steps, and off-spec material that can’t be traced back to its real origin in the event of failure. Real plant visibility gives us control to adjust and resolve issues rapidly—no finger-pointing between layers of middlemen. Buyers who care about predictable delivery, technical troubleshooting, or prompt invoice settlement benefit from talking directly with the source.

    New users, especially those switching from traditional butyl or methyl acrylate, get technical onboarding and guidance from our team—direct from the chemists and engineers managing bulk reactors day by day. In practice, this hands-on knowledge is more valuable than a perfect spec sheet, especially for plant managers troubleshooting unplanned downtime or facing a reformulation challenge. Our logistics service, with batch tracking to the tank and drum, cuts out the mystery in tracing, so any process glitch is addressed from source to shipment.

    Building Lasting Relationships Through Trust and Performance

    Most of our long-term tert-butyl acrylate customers began with a few containers, testing small lots in isolated runs before betting larger production lines on our material. Our team remembers these pilots and trial runs, keeping records and learning what each production line needs. The basis for these partnerships is not the lowest price per ton, but the tangible difference made by predictable, honest, and direct communication. Open reporting about any deviation, batch notification, and flexibility in packaging all come baked into our regular service. Repeatable experience—not just claims—has built our presence among innovative manufacturers big and small.

    Our direct engagement brings lessons, case histories, and a focus on shared results. Seeing end-users achieve better product life, reduce scrap, and pass audits without a panic call remains the best proof that manufacturing experience shapes a better product. With tert-butyl acrylate, the difference begins in the reactor, but it delivers clear, daily impact across product lines wherever performance, durability, and process efficiency matter.