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Sodium Hydrosulfide

    • Product Name Sodium Hydrosulfide
    • Alias sodium-hydrosulfide
    • Einecs 232-185-6
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    923079

    Chemicalname Sodium Hydrosulfide
    Chemicalformula NaHS
    Molarmass 56.06 g/mol
    Appearance Colorless to yellow solid
    Odor Rotten egg (hydrogen sulfide-like)
    Solubilityinwater Very soluble
    Meltingpoint 350 °C (decomposes)
    Density 1.79 g/cm³
    Ph Alkaline (basic) in solution
    Casnumber 16721-80-5

    As an accredited Sodium Hydrosulfide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Sodium Hydrosulfide is packaged in a 25 kg net weight, blue HDPE drum with a tightly sealed lid and hazard labels.
    Shipping Sodium Hydrosulfide should be shipped in tightly sealed, corrosion-resistant containers, clearly labeled and compliant with hazardous materials regulations. It must be transported under cool, dry conditions, away from acids and oxidizing agents. Proper safety documentation and emergency procedures must accompany the shipment to ensure safe handling during transit.
    Storage Sodium hydrosulfide should be stored in a cool, dry, well-ventilated area away from moisture, acids, and oxidizing agents. Keep the container tightly closed and properly labeled. Use corrosion-resistant materials for storage. Protect from physical damage and sources of ignition. Store in a secure location to prevent unauthorized access and environmental contamination, and always follow applicable safety regulations and guidelines.
    Application of Sodium Hydrosulfide

    Applications of Sodium Hydrosulfide in Industrial Manufacturing

    Sodium hydrosulfide plays a critical role as a process additive and functional intermediate in several mature industrial sectors, each governed by established regulatory frameworks and process-specific requirements. Our manufacturing expertise ensures consistent product quality and traceability across all compliant applications described below.

    1. Pulp and Paper Bleaching – Kraft Process

    Sodium hydrosulfide is essential in the pulp and paper industry, primarily as a makeup chemical in the Kraft (sulfate) pulping process. It acts as a sulfur donor to maintain the desired sulfidity during white liquor preparation, directly impacting lignin removal and fiber brightness. Quality and dosing precision impact pulp yield, kappa number, and effluent characteristics, making application control vital for downstream batch consistency and environmental compliance.

    Industry compliance standards

    • ISO 9001:2015 Quality Management Systems
    • EPA Effluent Guidelines for Pulp, Paper, and Paperboard (40 CFR Part 430, US)
    • REACH Regulation (EC) No 1907/2006 for chemical inputs
    • GB/T 4619-2012 (China National Standard for Pulp and Paper Chemical Use)

    Typical usage ratio

    • 2–6 kg per ton of air-dry pulp, depending on wood species, cooking liquor composition, and mill sulfidity targets

    Downstream process integration

    • Added to white liquor tanks before impregnation and cooking stages in continuous or batch digesters
    • Serves to stabilize liquor sulfidity and promote lignin fragmentation during cooking

    Final product types

    • Bleached and unbleached Kraft pulp
    • Packaging papers and containerboard
    • Printing and writing paper grades
    • Specialty cellulose products

    2. Mining and Metallurgy – Copper Ore Flotation

    The mining sector utilizes sodium hydrosulfide primarily as a selective depressant and alkali modifier in copper ore flotation, especially in the recovery of copper from molybdenum-rich ores. It reacts with metal ions on mineral surfaces, selectively suppressing iron sulfides and enhancing copper-molybdenum separation. Reliable dosing and process sequencing are essential to maximize mineral recovery yields and reduce downstream refining losses.

    Industry compliance standards

    • ISO 14001:2015 Environmental Management Systems
    • MSHA (Mine Safety and Health Administration) Part 56 regulations (US)
    • ICMM Sustainable Development Framework
    • GB 30892-2014 (Chinese National Mining Safety Standard)

    Typical usage ratio

    • 50–400 g per metric ton of ore, optimized according to ore mineralogy, pH, and flotation cell configuration

    Downstream process integration

    • Dosed into slurry conditioning tanks ahead of selective flotation cells
    • Acts as a depressant, especially for pyrite and other iron sulfides, allowing better copper recovery

    Final product types

    • Copper concentrate
    • Molybdenum concentrate
    • By-product precious metal concentrates

    3. Leather Industry – Unhairing and Dehairing Processes

    In leather manufacturing, sodium hydrosulfide is applied during the unhairing stage to efficiently break down keratin and remove hair from hides. Controlled dosing affects hide integrity and wastewater chemical oxygen demand (COD). Strict safety and environmental standards guide use to prevent overexposure in operator environments and minimize sulfur emissions in effluent streams.

    Industry compliance standards

    • ISO 5394:2015 (Leather — Chemical tests — Determination of sulfide content)
    • REACH Annex XVII (Restrictions on certain hazardous substances)
    • ZDHC (Zero Discharge of Hazardous Chemicals) Wastewater Guidelines
    • OHSAS 18001/ISO 45001 on workplace chemical safety

    Typical usage ratio

    • 2–5% by weight of soaked hide, variably adjusted for animal type, desired dehairing efficiency, and hide thickness

    Downstream process integration

    • Introduced in rotating drums or paddle vats during the unhairing phase directly after soaking/liming
    • Reacted with epidermal proteins to loosen hair follicles for mechanical removal

    Final product types

    • Wet blue leather
    • Pickled hides
    • Full-grain, split, and suede finished leathers

    4. Synthetic Organic Chemicals – Sulfur Dye and Intermediate Production

    Sodium hydrosulfide functions as a key sulfurating and reducing agent during sulfur dye synthesis and in the preparation of sulfur-containing pharmaceutical and agrochemical intermediates. Precision in feed rates and redox control ensures desired yield and purity, supporting consistent coloration strength or downstream molecule reactivity. Process emission and effluent limits apply to regulate volatile sulfur species release.

    Industry compliance standards

    • GMP for Active Pharmaceutical Ingredients (ICH Q7)
    • ISO 9001:2015 for chemical synthesis
    • EU Regulation (EC) No 1223/2009 for colorant safety (Textile dyes)
    • Chinese national standard GB/T 21801 (for sulfur dyes)

    Typical usage ratio

    • 1.5–8% based on batch mass, adjusted to substrate reactivity and required sulfur incorporation degree

    Downstream process integration

    • Added to reaction vessels in sulfur dye synthesis, after initial substrate dissolution or amination
    • Facilitates reduction and sulfur bridging for indigo and other sulfurized chromophores

    Final product types

    • Sulfur black, brown, and blue dyes (e.g., CI Sulphur Black 1)
    • Sulfonated intermediate compounds
    • Certain pharmaceutical and agrochemical industrial intermediates

    5. Water Treatment – Oxygen Scavenger in Boiler Feedwater

    In industrial water treatment, sodium hydrosulfide serves as an efficient oxygen scavenger to protect boiler or processing systems from oxygen-induced corrosion. Precision metering maintains dissolved oxygen below corrosion thresholds, supporting equipment life and minimizing downtime. Monitoring and compliance with feedwater and discharge regulations ensure safe operation and environmental stewardship.

    Industry compliance standards

    • API Standard 682 (Pumps—Shaft Sealing Systems)
    • ASME Boiler and Pressure Vessel Code, Section I
    • ASTM D888-18 Standard Test Methods for Dissolved Oxygen
    • European Pressure Equipment Directive (PED) 2014/68/EU

    Typical usage ratio

    • 0.1–0.5 mg/L in boiler feedwater, titrated according to dissolved oxygen content, system volume, and process temperature

    Downstream process integration

    • Metered directly into deaerator tanks or mixed feedwater streams before entering pressure vessels
    • Rapidly reacts with residual oxygen prior to heat input

    Final product types

    • Treated boiler feedwater for power generation
    • Process steam for industrial heating
    • Industrial water systems requiring scale and corrosion control

    6. Textile and Fiber Production – Sulfur-based Dyeing

    Sodium hydrosulfide is crucial in sulfur dyeing of textiles, especially cotton and regenerated cellulose fibers. It acts both as a reducing agent and sulfur source in the vatting and dye fixing steps. The chemical’s amount, timing, and purity significantly influence shade uniformity, wash fastness, and compliance with restricted substance lists, making rigorous QC and process adjustment a must for downstream fabric quality.

    Industry compliance standards

    • OEKO-TEX® Standard 100 (Textile Contact Material Safety)
    • ZDHC MRSL (Manufacturing Restricted Substances List)
    • ISO 105-C06 (Textiles – Tests for color fastness to domestic and commercial laundering)
    • Chinese GB/T 17592 for formaldehyde and S-containing compounds in textiles

    Typical usage ratio

    • 2–6 g/L in dye bath, adjusted based on fabric weight, liquor ratio, and required reduction level

    Downstream process integration

    • Introduced during dye vatting and reducing steps for sulfur dyeing of cotton or viscose
    • Enables formation of water-soluble dye intermediate and subsequent oxidation onto fiber

    Final product types

    • Sulfur-dyed cotton yarns and fabrics
    • Sulfur-dyed viscose textiles
    • Industrial workwear, denim, toweling, and upholstery fabrics
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    Certification & Compliance
    More Introduction

    Sodium Hydrosulfide: Direct from the Manufacturing Floor

    Our Role and Experience in Producing Sodium Hydrosulfide

    Every batch of sodium hydrosulfide rolling out from our plant carries with it the story of both modern chemical engineering and decades of factory wisdom. For those who haven’t walked through the steam-wrapped corridors of a sodium hydrosulfide unit, the process may seem straightforward; feedstock goes in, yellowish flakes or a clear solution comes out. Talk to an operator, though, and you’ll quickly learn there’s little room for lack of precision or cutting corners. Sodium hydrosulfide isn’t a sideline job. Our production line, running to supply industries from mining to leather tanning, demands a focus on purity, consistency, and safe handling at every turn.

    Our product finds its primary demand among copper mining operations—especially in ore flotation—where it separates copper from undesirable minerals. Our experience tells us what the miners value: a reliable grade, easy dissolution on site, and predictable reactivity with their ores. We work directly with their specifications. Feedback taught us long ago that even slight variations in iron or carbonate impurities can throw off a process. Whether producing sodium hydrosulfide flakes at 70% purity or the 45% liquid solution, our team pays constant attention to raw material quality and controlled reaction conditions. Meeting tight specs means more than passing a test; it often determines whose concentrate grades recover and whose do not.

    We’ve seen sodium hydrosulfide go into pulp and paper mills, where its reducing power in pulping and chemical recovery keeps costs down and recycling efficient. Our customers in leather rely on this compound to remove hair and open hides. Through years of visiting and listening to plant engineers, we’ve learned that one operator’s process may differ from another, so a single-model approach never works. This isn’t just about purity. Solubility, flake integrity, and solution clarity matter to the end-user in their world of pumps, reactors, and tanks. The same product, used in different applications, shows just how adaptable sodium hydrosulfide can be with the right technical support at hand.

    Comparing Our Sodium Hydrosulfide with Alternatives and Grades

    Our sodium hydrosulfide comes in several grades that reflect both the needs and realities of customer processes. For the ore flotation industry, we typically supply a 70% flake form that stores well and dissolves quickly, so plant operators get a consistent solution with minimal waste. Compared to traditional sodium sulfide, our product solves many safety concerns due to its lower tendency to release hydrogen sulfide gas under normal handling. This makes storage and transfer much simpler, especially in warm or humid climates. We also manufacture a liquid sodium hydrosulfide solution at 45%. Some customers prefer this version, since it eliminates the extra step of dissolving flakes and speeds up dosing routines. It helps with consistent application in papermaking or chemical synthesis operations.

    When talking about alternatives, many chemical users look at sodium sulfide, calcium polysulfide, or organic reducing agents. Yet each of these comes with trade-offs. Sodium hydrosulfide stands apart for several reasons. First, it delivers a higher reduction potential per unit mass, so users extract more value with less product. Second, its reaction profile generates fewer unwanted side-products in most industrial setups. Our hands-on experience with customer feedback is why we keep refining our product line. If a client sees occasional feed pump clogging or inconsistent solution color, we help look for culprits—maybe a shift in feedstock composition, maybe a small change in particle size across a large batch. Those issues don’t show up in the lab, but they matter in actual production. That’s the kind of field information we rely on to keep improving.

    Not every manufacturer approaches sodium hydrosulfide processing the same way. Some focus only on large-scale, bulk output with minimal technical backup. We see the gaps that creates. There’s no substitute for knowing which shipment works best at a copper concentrator in the high Andes, or in a northern European wastewater plant, or in a tanner’s open vats during peak season. We don’t believe in one-size-fits-all solutions. The feedback we get from these settings shapes our process design and our direct technical support. People in the field want a product that won’t create dust hazards on transfer, resists caking during longer storage, and flows easily in cold or humid stock warehouses. For us, manufacturing sodium hydrosulfide isn’t just about filling drums. It’s about making sure that product performs under real-world stresses in settings far removed from a spotless lab bench.

    Safety Aspects: What We’ve Learned Working with Sodium Hydrosulfide

    Anyone who has handled sodium hydrosulfide on a large scale knows that safety isn’t just a matter of reading a data sheet. Our operators don’t get complacent around this material—it can react with acids to release hydrogen sulfide, which brings serious hazards. We invest in containment, training, and equipment upgrades, not because it’s written in a manual, but because our long-term workers learn quickly what works and what doesn’t to prevent accidental releases. By running close monitoring of temperature, free moisture, and pressure across our lines, we reduce unwanted gas liberations by catching problems before they escalate. Our choice of packaging relies on input from clients who want drums or IBCs that handle rough transport and variable storage conditions.

    In the early days, emergency drills might have seemed like a burden, but experience showed their value. One incident with a leaky flange in the middle of winter underlined just how quickly a small drip can escalate in the presence of rain or snow. By maintaining proper ventilation, ensuring prompt detection systems, and welcoming feedback from transport partners about packaging durability, we manage risks better than a checklist ever could. Our team worked side-by-side with several large customers, trialing improvements such as corrosion-resistant linings, sealed bulk bags, or pressure-release mechanisms. Many of the changes now used across the industry first came out of those collaborative trials.

    New entrants to sodium hydrosulfide handling often underestimate the importance of clear labeling, well-planned traffic flows in the warehouse, and proper spill response equipment. Years on the floor have shown us that small investments here pay off in fewer lost batches and safer employees. Our engagement doesn’t stop once the drum leaves the plant. Technical representatives walk through customer setups, spotting issues in dosing rigs, tank agitation, or pipework. Through these hands-on visits, we learn what the textbooks never cover.

    Understanding Customer Priorities and Supporting Their Operations

    Mining firms, tan yards, and paper mills each describe a different wish list when they place their sodium hydrosulfide order. For copper mines in Chile or Kazakhstan, the main points revolve around purity and steady supply. Their costs stack up rapidly when a load gets delayed or off-spec. They call for reliability not only in the chemical itself, but in the predictability of delivery and paperwork. Our logistics network, anchored by real-world feedback from regular customers, helps us avoid surprises—not just by filling trucks on time, but by communicating if a storm is going to slow things down. We find ways to keep spare safety stock in strategic locations to bridge those inevitable hiccups.

    Leather producers focus more on easy dissolving and minimal dusting. They work in tight spaces, often surrounded by workers who rely on a clean operation. We have worked with these clients to adjust flake size and adjust packaging to minimize spillage and avoid airborne particles. These efforts didn’t come from a design manual—they came from standing in leather factories and seeing what slows down real production lines. Paper mills ask yet another set of questions, usually about smooth dosing and integration with their recovery cycles. They push us to provide consistent solution viscosity and clarity. Our R&D group works to help them avoid blockages and settling in pipelines.

    What we’ve learned is that priorities differ—what matters to a Chilean mine might only be a bonus to a European tanner. We spend as much time listening as we do refining our own process. Our technical specialists travel to see installations first-hand, from tropical docks to northern industrial parks, ensuring we understand specific site issues that affect use. If something doesn’t work, we want to know about it. No product stays static; the feedback loop between users and factory keeps us improving the manufacturing process, packaging, and aftersales support.

    Environmental Impact: Steps Forward from the Factory Floor

    Environmental conversations have only grown in volume over recent decades, and with good reason. Sodium hydrosulfide remains a compound that needs attention in handling and disposal, as it readily generates hydrogen sulfide under certain conditions. Meeting tighter environmental rules serves both our business and our community. We developed, over years of incremental upgrades, closed-loop process systems that capture byproduct gases. These systems didn’t appear overnight. There were hiccups and setbacks, and sometimes the lessons meant retrofitting lines at substantial cost. Still, the end result raised both our yield and environmental credentials—recovering more product, spewing less to the surroundings.

    Our wastewater handlers separate dissolved sulfide and organic pollutants with a tailored treatment train. The recycled streams save on water usage, while our purged sludges go through stabilized, well-documented routes to offsite treatment. In our corner of the industry, environmental diligence isn’t just following regulations, it’s expecting them to get stricter, and getting ahead before anyone is told what to do. Customers appreciate this uptick in stewardship, particularly those serving overseas markets, since more retailers and buyers check supply chain impacts. We also regularly train both our own staff and customer-side handlers on keeping loss to a minimum during dosing and transfer operations, helping everyone work safer and cleaner.

    One challenge remains the fate of spent solutions and residues among downstream users. We support customers by sharing practical disposal and recycling practices—not just paperwork, but practical, trialed steps that fit their infrastructure. In some regions, users recover sulfur or valuable metals from spent solutions. We help these clients inspect feeds, adjust pH or temperature control, and select decontamination routes that suit the equipment at hand. Through site visits and troubleshooting calls, our technical teams have resolved issues ranging from foul odors to murky water releases, helping customers achieve both compliance and reduced waste.

    Looking at the Market: What Drives Industry Choices Today

    The global reach of sodium hydrosulfide continues to expand, with shifts in demand coming from growing mining industries, stricter water treatment standards, and spike cycles in leather and paper production. Oil and gas sectors have also shown increased interest for use in certain scavenging applications. In all these cases, manufacturers like us face the challenge of balancing cost controls with the high purity and reliability these industries demand. We’ve had to invest in both process automation and worker skill development to keep our quality rising even as price pressures mount.

    Market cycles often surprise those who look only at numbers. For us, the biggest swings often come from sudden mining expansions or contractions. We stay nimble by keeping regular dialogue with procurement teams, staying aware of new projects that could change our production mix with little notice. In lean times, customers focus even harder on efficiency. They ask not just for lower prices, but for advice on maximizing yield and minimizing wastage, wringing every drop of value from the sodium hydrosulfide they use. These requests drive us to support pilot programs, recommend dosing optimizations, and share lessons learned from other facilities—sometimes even introducing clients to each other to brainstorm.

    One notable trend is the push for higher safety standards on both manufacturing and user sides. Far more customers now demand traceable origins, batch-level quality certificates, and clear backgrounds for every shipment. This need for transparency flows both ways; we provide open access to our test data, invite customer audits, and adapt our record-keeping systems to export data in customer-required formats. Years in this business taught us that trust is earned not just by delivering product on time, but by standing behind everything in the drum. Customer feedback often drives innovation, and we respond by trialing new material handling methods, tweaking packaging, or recalibrating specifications.

    Practical Troubleshooting: Real Experience, Real Solutions

    No day in the sodium hydrosulfide business ever plays out without challenges. We’ve faced and overcome clogged transfer pipes, surprise color changes, and customer complaints about unusual smells or cakes in drums on delivery. Most of these problems trace back to a handful of root causes: small impurities in raw material, changes in drying or storage conditions, or unexpected delays in transport that expose drums to extremes. The answer rarely lies in theory; resolution comes from rolling up sleeves, checking the line, sampling through various stages, and adjusting operating practices until the problem stops recurring.

    Our direct relationships with end users—unfiltered by layers of traders or distributors—means we hear about problems first-hand. A busy copper concentrator may call about a color shift in their incoming solution. We ask for their water chemistry, pH values, temperature logs, and shipping details. Over the years, this proactive role has forged loyalty. By sharing fix tactics openly, not only with large players but with smaller outfits who may not have extensive labs, we support the whole industry. When we solve a problem in one operation—a tendency for flakes to clot together at high humidity, or for flow meters to gum up after standing idle—the lessons feed into our process. That feedback loop has shaped our current flake drying temperatures, packaging seals, and even drum labeling practices.

    Biggest lesson: theory only gets you so far. On-the-ground troubleshooting, seasoned by years of mistakes and fixes, keeps plants running. We hold regular “talk shop” meetings with operators at all levels to review what’s worked, what hasn’t, and what adjustments make the most difference. This builds practical wisdom that outlives staff turnover and market fads, keeping the sodium hydrosulfide supply chain healthier and more resilient.

    Conclusion: Why Manufacturing Still Matters

    For us, sodium hydrosulfide isn’t just a commodity or a code on a spreadsheet. Each batch begins in the balance of raw materials, proceeds through carefully managed reactions, and ends not at our dock, but in the plant of a customer who relies on stable, consistent performance every day. The product we ship today reflects lessons learned from thousands of past deliveries—adjusted for the needs of each sector, each climate, each application. From ore flotation to paper recovery, the value lies not simply in the chemistry, but in the lived experience of manufacturing, troubleshooting, and supporting the men and women who ultimately turn our chemicals into finished goods.

    Our determination to stand behind every shipment—backed by both the facts of our process and the practical wisdom gained through years on the ground—sets the true manufacturer’s path apart from middlemen and traders. As industries evolve, as regulations shift and customer expectations rise, our commitment holds steady: delivering sodium hydrosulfide that works as reliably on your line as it does in ours.