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Sodium Arsenite Aqueous Solution

    • Product Name Sodium Arsenite Aqueous Solution
    • Alias Sodium Arsenite Solution
    • Einecs 247-852-1
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
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    Specifications

    HS Code

    740235

    Product Name Sodium Arsenite Aqueous Solution
    Chemical Formula NaAsO2
    Cas Number 7784-46-5
    Appearance Colorless to slightly yellow liquid
    Molecular Weight 129.91 g/mol
    Concentration Variable; typically 1-10% NaAsO2 in water
    Solubility Completely soluble in water
    Ph Approximately 10-11 (alkaline)
    Odor Odorless or faint, characteristic
    Toxicity Highly toxic; harmful if swallowed, inhaled, or absorbed through skin
    Boiling Point Similar to water (about 100°C, but may vary with concentration)
    Density Dependent on concentration; approx. 1.05-1.15 g/cm³ for typical solutions
    Storage Temperature Room temperature; store in tightly closed container
    Hazard Statements Toxic if swallowed, causes damage to organs, suspected of causing cancer
    Un Number UN 1971

    As an accredited Sodium Arsenite Aqueous Solution factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Amber glass bottle containing 500 mL sodium arsenite aqueous solution, securely sealed, labeled with hazard symbols, concentration, and safety instructions.
    Shipping Sodium Arsenite Aqueous Solution is shipped as a hazardous material in tightly sealed, corrosion-resistant containers. The packaging must comply with regulations for toxic substances (UN 1977, Class 6.1). It requires clear hazard labeling, secure containment to prevent leaks, and transport documentation. Handling should prioritize safety, including use of proper personal protective equipment.
    Storage Sodium Arsenite Aqueous Solution should be stored in tightly closed, labeled containers made of compatible materials. Keep the storage area cool, dry, well-ventilated, and away from incompatible substances such as strong acids and oxidizers. Store away from heat, direct sunlight, and ignition sources. Ensure access is restricted to trained personnel and maintain appropriate spill containment and safety equipment nearby.
    Application of Sodium Arsenite Aqueous Solution

    Applications of Sodium Arsenite Aqueous Solution in Industrial Manufacturing

    Sodium arsenite aqueous solution supports specialized industrial operations that require precise control of chemical reactions, preservation processes, and metallurgical treatments. As a direct manufacturer, we see significant demand from sectors where strict regulatory standards and bespoke production parameters are essential to ensuring safety, process reliability, and finished goods performance.

    1. Wood Preservation for Utility Poles and Railway Sleepers

    Major wood treatment facilities apply sodium arsenite in pressure impregnation chambers to extend the durability and decay resistance of wooden utility poles and railway ties. The solution acts by inhibiting fungal and insect activity inside the timber’s capillaries. Operators prepare dipping or vacuum-pressure bath fluids with specific concentration limits to ensure both deep penetration and compliance with safety requirements for environmental and occupational exposure.

    Industry compliance standards

    • AWPA P5: Standard for Waterborne Preservatives
    • US EPA Reregistration Eligibility Decision for Inorganic Arsenicals
    • OSHA HAZCOM for worker protection
    • EU Biocidal Products Regulation (BPR) No. 528/2012*

    Typical usage ratio

    • 0.5%–2.5% (w/v) sodium arsenite in treatment bath, tailored to wood species and exposure class. Final concentration confirmed by retort colorimetric or titrimetric assay.

    Downstream process integration

    • Sodium arsenite diluted and mixed before direct injection or immersion in high-pressure autoclaves after pre-drying phase.

    Final product types

    • Pressure-treated utility poles
    • Railway sleepers
    • Timber for marine and ground contact use

    2. Glass Manufacturing Additive

    Specialty and technical glass producers add sodium arsenite to molten glass batches during mixing to enhance fining and to minimize the formation of color imperfections caused by ferric iron trace contamination. The addition timing and blending protocol directly affect both glass clarity and chemical durability, which is critical for laboratory and optical glassware.

    Industry compliance standards

    • DIN EN 572: Basic soda-lime-silica glass composition guidelines
    • ISO 4802: Laboratory glassware material selection
    • RoHS Directive 2011/65/EU (trace element limits)
    • REACH SVHC reporting for arsenic compounds

    Typical usage ratio

    • 0.01%–0.1% (by batch weight); dosing dependent on raw batch iron content and final clarity specification. Regular adjustment based on incoming silica and recycled cullet purity.

    Downstream process integration

    • Feeding as aqueous solution with batch raw materials into the melting furnace at temperatures above 1400°C, followed by careful homogenization.

    Final product types

    • Laboratory glassware (flasks, beakers, columns)
    • Technical optical glass (prisms, lenses)
    • High-clarity container glass

    3. Metallurgical Processing for Non-Ferrous Metals

    Refiners in copper and lead metallurgy use sodium arsenite for selective precipitation and wastewater purification processes. Its main role is to control dissolved heavy metals by forming less soluble complexes, thereby aiding recovery and minimizing effluent toxicity. Operators must adhere to strict guidelines to avoid carryover into final metal products while ensuring regulatory discharge parameters.

    Industry compliance standards

    • ASTM E754: Precipitation practices in non-ferrous refining
    • ISO 14001:2015 Environmental Management Systems
    • Local Water Pollution Control Permits (e.g. US EPA NPDES, EU Urban Wastewater Directive 91/271/EEC)
    • Occupational exposure limits: ACGIH TLV/OSHA PEL for arsenic

    Typical usage ratio

    • Dosage varies—typically 0.1–2.0 g/L depending on effluent contaminant load. Routine lab titration determines minimum effective dose per batch.

    Downstream process integration

    • Injected into stirred tank reactors post-leach or as a pre-polishing step before filtration and metals precipitation train; coordinated with pH adjustment protocols and downstream ion removal units.

    Final product types

    • Electrolytic copper
    • Refined lead bullion
    • Compliant industrial effluent streams

    4. Pesticide Intermediate Synthesis

    Large-volume agrochemical manufacturers use sodium arsenite as a chemical precursor to synthesize arsenic-based herbicides and rodenticides. The solution enters multi-step organic synthesis streams where control of molarity and reaction pH governs product purity and intermediate stability. Quality assurance typically involves in-process titration to ensure transition to the next synthetic stage without excess residual arsenite.

    Industry compliance standards

    • FAO/WHO Guidelines on Pesticide Specifications
    • ISO 9001:2015 for process management
    • CFR Title 40—EPA Pesticide Registration Regulation
    • U.S. Toxic Substances Control Act (TSCA)

    Typical usage ratio

    • Reactor charge 1–5% (w/v); precise molarity set per final product route sheet, reviewed per batch on in-plant HPLC analysis.

    Downstream process integration

    • Metered addition to jacketed batch reactors during aqueous synthesis stage. Strict in-process monitoring before downstream neutralization or conversion.

    Final product types

    • Organic arsenical herbicide concentrates
    • Rodenticide actives containing arsenic
    • Arsenic intermediate compounds for agrochemical blends

    5. Analytical Reagent Preparation

    Producers of analytical laboratory reagents utilize sodium arsenite in solution for redox titrations and as a reducing agent in trace analyses. The controlled purity and defined molarity enable consistent production of certified reference materials and environment-testing kits. Processing standards require rigorous validation of solution concentration prior to bottling and distribution.

    Industry compliance standards

    • ISO 17034:2016 for reference material producers
    • ASTM D1193: Water quality standards for reagent preparation
    • ISO/IEC 17025: Testing and calibration laboratory standards
    • GHS chemical labelling for transport and storage

    Typical usage ratio

    • Standardized solution strength: 0.05 N to 0.2 N, adjusted per target determination method as documented in respective analytical protocols.

    Downstream process integration

    • Final dilution and volumetric bottling with QA/QC certification and lot traceability integrated at the reagent packing line.

    Final product types

    • Sodium arsenite analytical standards
    • Certified redox titration solutions
    • Trace arsenic testing kits
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    Certification & Compliance
    More Introduction

    Sodium Arsenite Aqueous Solution: Practical Insights from the Manufacturer

    Our Perspective as the Producer

    Decades spent handling and developing sodium arsenite aqueous solution have shaped the way we see its role in industry and research. This product is familiar territory inside our plant. Each batch follows a hands-on process where precision and environmental responsibility set the pace. Customers often ask about the differences between our sodium arsenite solution and similar materials on the market, and we approach these questions frankly. The process starts from carefully sourced raw arsenic trioxide, which passes through strict checks to avoid impurities that could later affect both performance and safety. Over the years, this attention to consistency has kept us aligned with the requirements of chemists, manufacturing engineers, and laboratory professionals who rely on each shipment for repeatable results.

    What Sets Our Sodium Arsenite Solution Apart

    Quality control begins with the water used as a base. We run the process on deionized water filtered daily. Controlling the source and grade of water ensures that dissolved solids never cause inaccuracies. The solution’s concentration (typically 20% or 25% sodium arsenite by weight, depending on model) stays within tight tolerances, confirmed by titrimetric analysis and cross-checked by ICP-OES for trace contamination. These numbers may sound routine to a chemist, but anyone who’s tried to repeat reactions with variable input knows precision on paper means little unless packed in every drum.

    One point people sometimes overlook is shelf stability. Poorly mixed sodium arsenite solutions precipitate over time, which can throw off applications in wood preservation or chemical analysis. We design our process so every batch leaves with homogeneity verified under extended storage conditions, at temperatures mimicking both cool warehouses and hot loading docks. We don’t just rely on automated mixers. Operators manually sample for granule size and appearance during each fill, watching for cloudiness that signals a failed batch. Years ago, manual checks caught minor changes other plants shrugged off. Later, those same changes turned out to affect preservation test panels and reaction endpoints, proving that field experience beats shortcuts.

    Knowing the Uses from the Inside Out

    Direct, first-hand experience with customers in mining, timber, and laboratories drives our understanding of end-use scenarios for sodium arsenite solution. Copper ore concentrators rely on the solution’s selective precipitation properties, using it to separate copper minerals from iron and other heavy metals. We saw firsthand the ripple effects of a single out-of-spec batch on flotation yields; operators in these environments demand quick feedback, so we set up internal benchmarks mirroring their concerns.

    Wood preservation remains one of the older, but still practiced, uses. Sodium arsenite solutions inhibit wood decay in utility poles and agricultural stakes. Over the years, we’ve worked alongside field engineers experimenting with blend ratios and application rates, and saw how a carefully balanced solution minimizes leach, improving long-term retention. Conservation studies have highlighted how variations in sodium concentration lead to different leaching profiles—experience tells us that even a 1% inconsistency can lead to early degradation or environmental problems downstream.

    Laboratory applications draw from the product’s precise reactivity. Academic research groups and industrial process labs count on tightly defined concentrations to ensure reaction reproducibility, especially in the synthesis of dyes, pharmaceuticals, or glass compositions. We developed specialized lines with lower metal ion impurities for these users after facing a series of questions from researchers frustrated by background signals in their assays. Learning from feedback, we continuously refine purification steps in the process—dealing with trace iron or lead, for example, before it becomes a published complaint.

    Safety Built into the Process

    Every chemical plant faces the responsibility of worker and environmental protection. Sodium arsenite’s reputation as a hazardous arsenic compound means we never compromise on testing and containment. Our facility’s core processes include airtight transfer, negative pressure rooms, and waste effluent management. Each shift, plant safety officers audit us for airborne arsenic. Failures or lapses are documented and the process adapts—a culture of openness has helped us avoid incidents and build trust among both employees and regulators.

    We believe that risk awareness goes hand in hand with clear product labeling and customer education. Customers often request guidance on handling spills, air exposure, and personal protective equipment. Based on actual incident data collected over several years, we developed custom training sessions and digital resources tailored for end-user environments, whether that’s an automated plant or a university teaching lab. This connection with the user community means we not only sell a chemical, we stand behind how it’s integrated safely into daily routines.

    Product Models and Their Origins

    Our lineup covers two main concentrations: Model SAQ-20 at 20% sodium arsenite and Model SAQ-25 at 25%. In both cases, the base sodium arsenite meets or surpasses analytical reagent grades by purity. Selection between models often follows the customer’s balance between storage space, process strength, and handling safety.

    Once, a mining client shifted from 20% to 25% after reevaluating storage costs versus process throughput. We worked alongside their engineering team to update dosing calculations, adjusting for the higher concentration’s effect on reaction time. In wood treatment facilities, the lower concentration model tends to fit better when environmental discharge standards or exposure risks limit the amount that can be stored or used at one time.

    Key Differences from Other Arsenic Solutions

    Customers familiar with sodium arsenate or arsenic trioxide solutions sometimes ask about switching to sodium arsenite aqueous solution. The differences are not just chemical—they show up in practical workflows and regulatory contexts. Sodium arsenite sits chemically between the trivalent arsenic (As(III)) state, with reactivity that triggers unique coordination with transition metals, compared to the pentavalent As(V) in sodium arsenate. Those differences lead to variations in solubility, transport, and the way reaction byproducts form.

    Industrial users often look for advantages in redox systems. Sodium arsenite’s reducing properties distinguish it from more oxidized arsenic compounds. In a copper flotation cell, this translates into selective reduction that targets specific mineral surfaces, rather than treating all present metals the same way. Wood preservation relies on the way As(III) forms stable bonds in treated timber, giving a difference in leach performance over time compared to As(V) solutions.

    People often assume substituting one arsenic solution for another is interchangeable, but years of trials show why this rarely works out. Once, a client running a remediation program switched to sodium arsenate, looking for similar results based on cost. After two quarters, they came back to sodium arsenite. Field reports revealed differences in the formation of secondary minerals, leading to ineffective pollutant capture. These case studies underscore why deep product knowledge, not just molecular formulas, guides proper selection.

    Handling, Storage, and Real-World Distribution

    We approach distribution with the same seriousness as manufacturing. Sodium arsenite’s storage requires vigilance against sunlight, temperature extremes, and potential leaks. Our storage tanks and shipping drums undergo periodic inspection for corrosion; several years ago, we shifted drum suppliers after discovering subtle compatibility issues—polyethylene grades matter for long-term storage and leak prevention.

    Strict labeling and chain-of-custody procedures trace every batch from plant to customer. Periodic reviews with transport partners help anticipate challenges in remote locations or with time-sensitive deliveries. Working through actual logistics problems, such as a railcar delay during winter or a dock strike, has pushed us to develop backup routes and regional stockpoints. These experiences benefit users who rely on uninterrupted supplies for continuous processes.

    Regulatory Aspects and Ongoing Compliance

    Regulation forms the background of every decision in the plant. Sodium arsenite faces strict rules under chemical registration, transportation, and environmental disposal. Our in-house compliance officers track evolving local, national, and international standards, including REACH in Europe, TSCA in the US, and local hazardous waste codes. Navigating these requirements means ongoing dialogue with inspectors. Open reporting, combined with routine external audits, has won us some breathing room in cases where other plants faced shutdowns for documentation gaps.

    Waste management makes up a substantial part of our investment. Dedicated containment and neutralization facilities cut down atmospheric emissions and prevent ground contamination. We partner with third-party labs to routinely test site runoff and solid waste. This prevents violations and reduces liability years down the line—directly informed by incidents elsewhere in the industry where neglect caused costly cleanups or reputational damage.

    Listening and Responding to User Experience

    Direct feedback drives innovation. As a chemical manufacturer, we hear daily from industrial users, researchers, and even public agencies. Not every question relates to product quality—practical challenges like package sizing, mixing instructions, or even advice on compatible plastics show up regularly. During the pandemic disruption, packaging flexibility became a top concern. We responded by diversifying unit sizes and offering returnable drum programs, trimming waste and offering a cost-effective option to those grappling with temporary storage space shortages.

    Experience also taught us how seasonal workflow changes can affect product use. In the north, freezing temperatures risk precipitation and layering within tanks, threatening solution consistency. In plant visits, we advised customers to use recirculation systems and provided tailored cold-weather technical notes based on our own winter storage tests. These efforts go beyond theory—we send field techs to troubleshoot on-site, ensuring every installation matches the product’s requirements for safe, stable use.

    Continuous Improvement and Looking Forward

    Running a chemical manufacturing operation is about more than meeting specs; it’s about adapting as conditions change and knowledge grows. Product development meetings run on real field data, not just market research. When we discovered through multiple site visits that solution pH variability impacted application efficiency, we upgraded our control systems and retrained staff to prioritize pH monitoring alongside other metrics. These responses reflect a mindset shaped by direct accountability. Plant managers walk the lines daily; knowing that the smallest overlooked variable could snowball into downstream problems keeps us sharp.

    Sodium arsenite aqueous solution remains a niche but vital material for sectors dealing with complex technical and environmental challenges. From the earliest days, we found that simply repeating old routines leads to stagnation. Adapting production to new purification technologies, revisiting safety protocols after industry incidents, and fine-tuning formulations based on honest customer feedback—each of these forms the backbone of our approach.

    Trust grows from transparency. Whether it’s opening our plant to inspections, investing in sampling equipment, or maintaining active dialogue with users, we see engagement as the key to reliability. Over time, our team’s experience, direct problem-solving, and focus on real-world data have helped us build confidence among users who prize substance over flashy marketing. Sodium arsenite solution may never become a household product, but for those who depend on it, we remain committed to making every barrel count.