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Selenium Tetrachloride

    • Product Name Selenium Tetrachloride
    • Alias selenium(IV) chloride
    • Einecs 233-958-8
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    920400

    Name Selenium Tetrachloride
    Chemical Formula SeCl4
    Molar Mass 220.77 g/mol
    Appearance colorless to pale yellow solid
    Melting Point 192 °C (378 °F)
    Boiling Point 346 °C (655 °F)
    Density 2.678 g/cm³
    Solubility In Water reacts
    Odor sharp, irritating
    Cas Number 10026-03-6
    Hazard Class Corrosive
    Structure tetrahedral molecular geometry
    Stability decomposes in water
    Vapor Pressure 1 mmHg at 85 °C
    Color colorless to pale yellow

    As an accredited Selenium Tetrachloride factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A sealed, amber glass bottle containing 250 grams of Selenium Tetrachloride, clearly labeled with hazard symbols and handling precautions.
    Shipping Selenium Tetrachloride should be shipped in tightly sealed, corrosion-resistant containers, protected from moisture and physical damage. Label as a hazardous material and comply with all relevant transport regulations. Transport in a cool, dry, and well-ventilated environment, away from incompatible substances such as water, reducing agents, and combustibles.
    Storage Selenium tetrachloride should be stored in a cool, dry, well-ventilated area away from moisture, heat, and incompatible substances such as strong bases and water. Keep the container tightly closed and protected from light. Use corrosion-resistant containers, preferably made of glass or certain plastics. Store separately from food and combustible materials, and ensure access to spill containment equipment.
    Application of Selenium Tetrachloride

    Applications of Selenium Tetrachloride in Industrial Manufacturing

    Selenium tetrachloride plays a key role across multiple high-value industrial processes, enabling precision synthesis, advanced material modification, and fine chemical transformations. As a specialized producer, we supply consistently pure grades for varied downstream requirements in metallurgy, electronics, glass coloration, organoselenium synthesis, and analytical chemistry sectors. Our technical team ensures strict production and QC, supporting global manufacturing standards at scale.

    1. High Purity Selenium Precursor for Semiconductor Doping

    Selenium tetrachloride delivers controlled selenium input in vapor phase doping of high-purity silicon and compound semiconductor materials. Specialty electronics foundries require precisely dosed selenium sources to modify electrical properties in chips, solar cell substrates, and discrete optoelectronic parts. Material must meet stringent purity, trace metals, and controlled hydrolysis profile specifications. Operations depend on stable delivery systems and automated ratio control for reproducible device yield and performance.

    Industry compliance standards

    • JEDEC J-STD-033 Handling, Packing, Shipping
    • SEMI F57-0314 semiconductor materials purity
    • QS-9000: Quality Systems Standard
    • IEC 60749 for microelectronic device processing

    Typical usage ratio

    • 0.01–0.1% by mass in vapor phase doping chambers, adjusted per substrate thickness and required dopant concentration

    Downstream process integration

    • Low-pressure chemical vapor deposition (LPCVD) entry via controlled injection vaporizer
    • Direct blend with inert carrier gases (e.g., argon) prior to reaction chamber
    • Inline trace metal filtration for sub-ppb impurity control

    Final product types

    • Monocrystalline silicon solar wafers
    • Compound semiconductors (InGaSe, GaAsSe, etc.)
    • Power rectifiers and photodetectors
    • Light-sensing and imaging array chips

    2. Glass Red Colorant and Decolorizer for Specialty Glass Manufacturing

    Industrial glass producers use selenium tetrachloride as an input in furnace melts to achieve controlled red or pink coloration, or to decolorize iron-tinted glass. The material oxidizes upon glass fusion to selenium dioxide, which influences light absorption in the visible spectrum. Applications span architectural glass, automotive glass, decorative products, and specialty optical filters. Operators must handle with precision dosing to avoid cracking and maintain color homogeneity; automated feeders and real-time colorimetry support process repeatability.

    Industry compliance standards

    • EN 572-2:2012 Flat Glass Chemical Composition
    • ISO 9053-2 Gob Forming Controls
    • ASTM C162-05 Color Glass Definitions
    • RoHS Directive (for colored glass in EEE)

    Typical usage ratio

    • 0.001–0.015% elemental selenium content per glass batch, adjusted for desired hue and batch composition

    Downstream process integration

    • Direct pre-batch dosing to glass furnace charge prior to melting
    • Continuous feed maintained via consistency controller tied to spectrophotometric feedback

    Final product types

    • Architectural red glass panes
    • Automotive pink/neutral glass
    • Specialty glass beads for reflectivity
    • Vitreous coatings for luxury tableware

    3. Chemical Intermediate for Organoselenium Compound Synthesis

    Producers of high-value organoselenium fine chemicals use selenium tetrachloride as a direct chlorinating agent for phenols, anilines, and aromatics. Typical use includes the batchwise chlorination of carbon frameworks for pharmaceuticals, agricultural actives, specialty catalysts, and chemical R&D. Reaction yields, selectivity, and purity must meet downstream customer or pharmacopeial demands, requiring precise ratio calculation and controlled addition under anhydrous conditions. In-house analytical pipelines confirm residuals and support process validation.

    Industry compliance standards

    • Current Good Manufacturing Practice (cGMP) 21 CFR Part 210–211 (for API intermediates)
    • REACH registration for chemical precursors
    • ISO 9001:2015 QC Management

    Typical usage ratio

    • Stoichiometric to 10% molar excess versus substrate, depending on target product and reaction optimization tests

    Downstream process integration

    • Batch addition to anhydrous reactor charge containing aromatic substrate and hydrogen chloride scavenger
    • Continuous monitoring of exotherm and selenium species conversion by inline HPLC or titrimetry

    Final product types

    • 4,4'-Diselenodiphenol and analogues
    • Selanyl aniline derivatives for crop protection actives
    • Selenadiazole pharma building blocks
    • Organoselenium catalysts used in green chemistry transformations

    4. Trace Selenium Source in Metal Refining and Alloy Formulation

    Metallurgical operations utilize selenium tetrachloride as a precise selenium supply during electrolytic refining of copper and as an additive in brass and lead-free alloy production. Selenium content affects electrical conductivity, metal ductility, and finished mechanical performance. Material must meet bulk purity and process stability criteria; on-site pre-dilution and dispersal systems are typically deployed to integrate with continuous casting or batch mixing setups. Our QC and supply chain comply fully with traceability and handling requirements for large-scale plants.

    Industry compliance standards

    • ASTM B170-13 (Copper Electrolyte Additives)
    • ISO 9001 for alloy manufacturing quality
    • OSHA 29 CFR 1910.1200 Chemical Hazard Communication
    • ISO 14001:2015 for environmental controls

    Typical usage ratio

    • 0.0005–0.1% Se content per batch, precisely adjusted for grade and performance specification

    Downstream process integration

    • Direct metered dosing to alloy bath or cathode electrolyte solution
    • Automated dilution into bulk metal, monitored by XRF or ICP elemental analysis

    Final product types

    • High-conductivity copper wire
    • Selenium-bearing brass rods
    • Free-machining low-lead alloys
    • Refined copper for electrical applications

    5. Analytical Chemistry Reagent for Selenium Determination

    Analytical laboratories and standardization institutes employ selenium tetrachloride as a calibration and sample derivatization reagent in selenium assay protocols. This use supports trace analysis in environmental, metallurgical, and food safety testing. Labs rely on high-assay, interference-free grades that permit precise preparation of standards and spike solutions, with validated purity profiles. Our batches undergo multi-stage refining and are supplied with full analytical documentation to meet institutional method requirements.

    Industry compliance standards

    • ISO 17034:2016 (Reference Material Producers)
    • AOAC Official Methods for Selenium Determination
    • EPA Method 200.3/200.8 (ICP-MS trace metals analysis)
    • Good Laboratory Practice (GLP) compliance

    Typical usage ratio

    • Microgram-to-milligram scale per standard solution or sample, matched to scope and detection limit

    Downstream process integration

    • Addition to derivatization vials for redox conversion
    • Preparation of stock calibration solutions for calibration curve generation
    • Spiking of unknowns for recovery validation

    Final product types

    • Certified reference selenium standards
    • Calibration solutions for atomic absorption/ICP-MS
    • Sample derivatives for trace selenium quantification reports
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    Certification & Compliance
    More Introduction

    Selenium Tetrachloride: High-Purity, Reliable Production from the Source

    Delivering Consistency in Selenium Tetrachloride Manufacturing

    Our experience in producing Selenium Tetrachloride stretches back decades. Inside the factory, every batch receives close attention—never left for chance. As manufacturers, we focus on the core physical and chemical traits that labs and industries count on. Selenium Tetrachloride leaves our facility as light yellow crystals, free-flowing and easily measured. Purity levels track above 99%, which reflects the investment we’ve made in our process lines and monitoring techniques. True to its formula, SeCl4, the material vaporizes sharply, and the fuming quality stands out when exposed to moist air. That visual feedback reassures chemists and researchers that they’re working with the real thing, not an impure imitation.

    Factories like ours need more than technical know-how; regular audits, tracked lot records, and batch sampling back up every drum. Analytical checks—like GC-MS and titration—help us validate chloride content and ensure trace impurities stay far below the strict cutoffs for electronic and reagent grade product. Our quality assurance teams have learned that even a minor contamination—traces of iron, arsenic, or water—can break a synthesis downstream. No big claims, just the quiet satisfaction of shipments passing third-party analysis on arrival.

    Selenium Tetrachloride in Modern Industry and Science

    Research labs and manufacturing crews both look for certainty. Inorganic synthesis relies on this material to introduce selenium in its +4 oxidation state without unexpected side effects. That’s why precision matters at source. Many organoselenium compounds and selenium-based catalysts have origins in reactions that use our SeCl4. This compound reacts smoothly with organic substrates and metals, so medicinal chemists and advanced material scientists both keep it in their catalogs.

    It’s not just bench work. Selenium Tetrachloride builds up as intermediates for high-value pharmaceuticals, glass colorants, and specialty polymers. The facility is built with robust chlorination reactors that let us achieve tight control over reaction rates and minimize off-spec product. Over time, we’ve adjusted line pressures, condenser temperatures, and reactant feed speeds—all to keep yields high and waste streams under control.

    On the industrial scale, teams pull from our batches to produce pure selenium by hydrolysis or use it as a donor for controlled organoselenium syntheses. Our manufacturing lines have grown along with these applications. We’ve seen demand track especially high from custom chemical synthesis companies who need bulk quantities with consistent reactivity. Some of our biggest clients feed Selenium Tetrachloride directly into continuous flow reactors, so the granular consistency and narrow melting point range give them fewer headaches in metering and safety.

    Handling, Storage, and Safety from a Producer’s Perspective

    Working hands-on with Selenium Tetrachloride for years, safety practices have grown out of real experience. In the raw, the material fumes strongly and smells sharp—something distinctive labs never forget. Each shift starts with a review of temperature and humidity controls. SeCl4 picks up water quickly from the atmosphere, so we seal our containers under dry nitrogen and finish packing inside gloveboxes or dryrooms. This focus limits the formation of corrosive byproducts like hydrogen chloride gas, both on our shop floor and after delivery.

    People who use our product in the field sometimes call asking: why skip glass and use all PTFE or stainless fittings? Pure experience—over time, our teams saw rapid breakdown of glass apparatus and rubber gaskets. Selenium Tetrachloride is aggressive toward common elastomers, so we switched to metal-lined drums and fluoropolymer gaskets. Details like this cut down on leaks and lost product. We test and replace our transfer lines routinely, and every shipment carries a certificate of analysis that confirms the product has sat at controlled humidity throughout transit.

    Incidents have taught us the value of solid routines. If the material spills, cleanup crews wear heavy chemical-resistant suits and use copious dry sand for containment. Ventilation systems in our production areas run high-volume extraction to keep breathing air safe. Our safety managers review all near-misses and share lessons learned with our clients, ensuring that everyone down the chain gets access to practical know-how.

    Comparing Selenium Tetrachloride to Other Selenium Products

    Not every selenium compound behaves the same in the plant or lab, and our teams see those differences every day. Take selenium dioxide (SeO2). It’s solid and less volatile but can’t deliver the same reactive chloride as SeCl4. For chlorination reactions, Selenium Tetrachloride provides a clean path without adding water or oxygen. In some applications—especially in electronics cleaning—its volatility and solubility in nonaqueous solvents are a necessary trait, not a drawback.

    Some industries prefer sodium selenite or selenate for nutritional or agricultural feeds. These lack the strong oxidative character and cannot serve in the same catalytic processes. Our production staff routinely answers questions about which selenium species to buy, depending on the outcome sought. Selenium Tetrachloride supplies direct selenium transfer to organic chains or metallic surfaces, which the more oxidized or reduced forms can’t accomplish.

    We’ve fielded comparison requests for years. Engineers sometimes ask if they can swap in other halogenated seleniums—like selenium dibromide or mixed halides. Results hardly ever match, because stability, shelf life, and reactivity get thrown off. Our product holds up in dry, sealed containers for storage periods of months without caking. The shift from SeO2 to SeCl4 lets advanced synthesis routes work at lower temperatures, speeding up throughput and reducing the formation of side products.

    Sustainability and Manufacturing Focus

    Years ago, selenium’s byproducts were simply a waste concern for copper and lead smelters. Now, tough regulation and growing demand for high-purity selenium materials have changed our methods. Our site recycles selenium dioxide residues whenever possible, converting them into finished SeCl4. Waste streams are analyzed onsite, with scrubbers and distillation columns running full-time to trap volatile emissions.

    Investing in scrubber upgrades and leak-detection systems has paid off. Annual audits keep us sharp, and newer staff get hands-on training with environmental controls before they go near production lines. We take pride in combining efficiency with stewardship, so customers know that their feedstock comes from a facility that takes local impacts seriously. Tracking selenium from mineral source through to packaged product gives us leverage to improve recovery rates and reduce landfill burdens.

    Final packaging uses UN-rated drums and special vented seals that allow small traces of off-gassing to escape safely, keeping the product fresh while meeting transport safety requirements. We work directly with global shippers and regulators during every load-out to head off delays and address any customs queries about chemical identity or safety classification.

    Supporting R&D and Large-Scale Innovation

    Product development in our facility comes from close cooperation with clients in pharmaceuticals, specialty alloy makers, and even researchers pushing the limits of optoelectronics. Customers from academia often ask for historical baseline data, so we’ve built up a library of performance figures and impurity analyses—measured not just once, but repeatedly across multiple years.

    The need for pure, reactive selenium in next-generation devices continues to rise. Our technical staff works shoulder-to-shoulder with R&D chemists to tailor purity levels or adjust particle sizes, all within the bounds of controlled, scalable manufacturing runs. From pilot batches to full-scale production, every tweak to a process comes with real-world tradeoffs—yield loss, increased downtime for cleaning, or tweaks to heat exchange rates. We share those numbers upfront, so clients can plan confidently for their own downstream needs.

    A significant portion of our Selenium Tetrachloride output serves as the backbone for production of high-selectivity catalysts. Industrial process engineers rely on reactivity curves and shelf-life guarantees. Over the years, we’ve optimized our storage and analytics protocols to align with these strict requirements, building trust with partners who use tiny margins of error to shape entire supply chains.

    Regulatory and Quality Compliance Grounded in Daily Work

    From the earliest days, compliance has meant more than meeting paperwork obligations. Transparent records and hands-on audits keep trust with customers and regulatory bodies alike. Our compliance coordinators work with updated chemical safety standards, local environmental guidelines, and global transport rules—every shipment and process modification receives legal and safety screening in-house.

    Batch quality reports passed to customers feature not just results, but method details—lab staff document every calibration. Every deviation from specification launches a cause analysis and retraining, not simply a form letter. It’s not just about certificates; repeat customers visit our site, check our process steps, and leave with a clear understanding of how risks are addressed in a real facility.

    International customers often expect REACH, TSCA, or GHS compliance. Years of working under these frameworks have taught us to blend documentation into mainstream production, so nobody treats regulatory work as an afterthought. Whether it’s labeling, dangerous goods declaration, or analytical method development, quality and safety work together in plain view of customers and inspectors.

    Guidance for Safe Application and Disposal

    Whether it lands in a small university lab or a remote mining operation, Selenium Tetrachloride projects share a few basic safety points. In our experience, direct transfer using closed systems—rather than open scoops or gravity pours—prevents unwanted emissions and accidental exposure. Most users return feedback on our armored shipping containers, noting sturdy construction and easy access to secondary containment.

    In terms of disposal, we recommend what has worked best for our own remediation teams: dilute hydrolysis with strong ventilation, followed by neutralization and capture of volatile chloride products. Local environmental controls matter—a lesson learned from trial and error during plant shutdowns and retoolings. Feedback loops with major downstream clients help us stay up to date on new waste reduction techniques, many of which end up adopted in our own house first.

    Storage presents its own reality; humidity and heat accelerates decomposition, so we’ve taken to running pilots on insulation and secondary moisture barriers. Many customers now use remote monitors placed alongside inventory holdings and share those data streams with our quality team to troubleshoot shelf-life issues before they cause material loss.

    Conclusion: Manufacturing with Reliability, Knowledge, and Respect

    Our approach to Selenium Tetrachloride centers on practical experience—decades of hands-on production, feedback from real-world users, and continuous innovation in process controls and safety. Every drum shipped, every batch analyzed, and every procedural update comes from solving direct challenges shared with us by chemists, engineers, and safety professionals.

    We encourage collaborative engagement with clients, as no two facilities are identical. Whether the challenge is boosting throughput, minimizing emissions, or stretching shelf life, open lines of communication lead to incremental improvement. People on our team bring stories and field wisdom to every client inquiry—bridging the gap between industrial-scale production and high-precision laboratory work.

    Selenium Tetrachloride stands apart not only by its chemical characteristics but by the workmanship, transparency, and integrity we apply at every stage. Chemical manufacturing can never be entirely risk-free, but with a focus on clarity and a relentless pursuit of reliability, we make sure our product and our reputation remain strong for every client who depends on us.