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Propyleneimine

    • Product Name Propyleneimine
    • Alias 2-Methylaziridine
    • Einecs 204-808-2
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    243558

    ChemicalName Propyleneimine
    CASNumber 75-55-8
    MolecularFormula C3H7N
    MolecularWeight 57.09 g/mol
    Appearance Colorless liquid
    Odor Ammonia-like
    MeltingPoint -67 °C
    BoilingPoint 67-68 °C
    Density 0.827 g/cm³ at 20 °C
    SolubilityInWater Miscible
    FlashPoint -18 °C (closed cup)
    VaporPressure 99 mmHg at 25 °C
    RefractiveIndex 1.405 at 20 °C
    AutoignitionTemperature 416 °C
    UNNumber 1921

    As an accredited Propyleneimine factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Propyleneimine is packaged in a 1-liter amber glass bottle, sealed with a Teflon-lined cap, labeled with hazard and safety information.
    Shipping Propyleneimine must be shipped as a hazardous material in compliance with international regulations (UN 1921, Class 3, Flammable Liquids, Subsidiary risk: Toxic). It should be packed in tightly sealed, corrosion-resistant containers, clearly labeled, and kept away from heat, sparks, and incompatible substances. Proper protective measures and documentation are required during transport.
    Storage Propyleneimine should be stored in a tightly closed, corrosion-resistant container in a cool, dry, and well-ventilated area, away from heat, sparks, open flames, and incompatible substances such as acids and oxidizers. The storage area should be equipped with spill containment and have proper signage. Access should be restricted to trained personnel, and containers must be clearly labeled.
    Application of Propyleneimine

    Applications of Propyleneimine in Industrial Manufacturing

    Propyleneimine serves as a reactive amine intermediate in several high-value chemical manufacturing sectors. Below, we detail its industrial use across various compliant and validated downstream applications, highlighting specific process integration, industry quality standards, formulation ranges, and the resulting advanced products.

    1. Cationic Polyacrylamide Production for Water Treatment

    Industrial manufacturers use propyleneimine to introduce cationic groups during the functionalization of polyacrylamide polymers. The raw material engages in post-polymerization modification, increasing the charge density essential for municipal and industrial wastewater flocculants. Its molecular reactivity supports chain branching control, enhancing performance in solid-liquid separation processes under diverse pH and ionic conditions.

    Industry compliance standards

    • NSF/ANSI Standard 60 (for drinking water treatment chemicals)
    • EN 1408:2008 (Chemicals used for treatment of water intended for human consumption)
    • ISO 9001 certified manufacturing processes
    • Chinese GB 28854-2012 for polyacrylamide flocculant quality management

    Typical usage ratio

    • 0.5%–2.5% by mass relative to acrylamide units, adjusted to polymer charge target and viscosity index

    Downstream process integration

    • Added to aqueous acrylamide polymer during post-polymerization amination stage using controlled pH and temperature (45–60°C) for optimal grafting

    Final product types

    • High charge density cationic PAM powders
    • Liquid coagulant concentrates
    • Custom flocculant blends for oilfield and paper industries
    • Filter aid formulations for municipal water plants

    2. Epoxy Resin Curing Agents

    Epoxy systems in electrical, automotive, and construction coatings require amine-initiated curing mechanisms. Propyleneimine acts as a chain extender and crosslinker in advanced amine adduct formulations, providing fast cure rates and excellent chemical resistance at room and elevated temperatures. Manufacturers benefit from the controlled reactivity and minimal color introduction, supporting consistent end-product performance in demanding environments.

    Industry compliance standards

    • REACH Annex XVII (Substances of Very High Concern management)
    • UL 94, IEC 60216 (electrical insulation safety and heat resistance for cured resins)
    • AAMI TIR17:2017 (coatings for medical device housings)
    • RoHS Directive 2011/65/EU compliance for electronic encapsulation

    Typical usage ratio

    • 3%–8% by total resin weight, depending on base epoxy structure, filler content, and end-use requirements

    Downstream process integration

    • Introduced in amine hardener blends prior to mixing with the base resin; batchwise addition under inert atmosphere to limit premature reaction

    Final product types

    • Fast-cure electrical potting resins
    • Anti-corrosive floor and tank linings
    • Automotive adhesive systems
    • Composite tooling and mold release coatings

    3. Synthesis of Wet-Strength Agents for Paper Industry

    Paper mills utilize propyleneimine in the synthesis of polyamide-epichlorohydrin (PAE) resins, essential for imparting permanent wet strength to tissue, packaging, and specialty papers. The chemical reacts with polyamidoamines to increase molecular branching and cross-linking. This process optimizes performance in sanitary grades and food packaging, while ensuring paper recyclability through controlled dosage and residual monomer management.

    Industry compliance standards

    • BfR Recommendation XXXVI (paper and board for food contact)
    • FDA 21 CFR 176.170/180 (paper additives for direct food contact)
    • ISO 187 (paper conditioning and testing)
    • IEC 62321 (heavy metals testing on food contact materials)

    Typical usage ratio

    • 1.5%–4% of total polyamide weight in resin synthesis, depending on target wet-strength and finished paper basis weight; dosage reduced for food-contact grades

    Downstream process integration

    • Added during polyamide condensation reaction, prior to reaction with epichlorohydrin; strict monitoring of free monomer for regulatory compliance

    Final product types

    • Facial tissue and paper towel grades
    • Wet-strength food packaging board
    • Industrial filter media papers
    • Paper currency stock

    4. Polyurethane Catalyst Preparation

    Propyleneimine is involved in manufacturing specific tertiary amine catalysts for polyurethane foam and elastomer production, affecting cell structure, suppression of side reactions, and physical property development. Process engineers enable tailored gel times and mechanical properties for downstream flexible and rigid foam systems, benefiting automotive interiors, insulation, and appliance applications.

    Industry compliance standards

    • ISO 12414 (flexible polyurethane foam for automotive applications)
    • GMP EU Regulation 2023/2006 for catalyst manufacturing (for food-related foams)
    • UL 94 and DIN 4102 flammability classification for building materials
    • ASTM D3574 (flexible cellular materials—slab/cut foam)

    Typical usage ratio

    • 0.1%–0.5% by combined polyol and isocyanate weight; ratio adjusted based on final foam density, reactivity, and processing speed requirements

    Downstream process integration

    • Converted to tertiary amine catalyst intermediates and introduced during polyol blending before mixing with isocyanate; process temp 20–35°C to control catalyst reactivity

    Final product types

    • Automotive comfort and crash pad foams
    • Refrigerator insulation foam panels
    • Spray urethane for pipe insulation
    • Molded appliance elastomers

    5. Production of Chelating Agents for Industrial Cleaning

    Manufacturers utilize propyleneimine for synthesizing polyamine chelating agents. The material’s primary and secondary amine groups allow chelate formation with calcium, magnesium, iron, and heavy metal ions. Finished chelants are widely employed in boiler water treatment, descaling, and as high-performance scale inhibitors in oilfield and industrial circulation systems, where robust and targeted sequestration is essential for equipment longevity and process protection.

    Industry compliance standards

    • EN ISO 9001 for production traceability
    • ASTM D1126 (standard test method for hardness in water using chelating agent titration)
    • Directive 98/83/EC (water intended for human consumption—industrial clean-in-place systems)
    • RoHS compliance for components in food and pharma process equipment cleaning

    Typical usage ratio

    • 5%–20% active chelant in industrial cleaning formulations; ratio depends on water hardness, metal ion burden, and process system type

    Downstream process integration

    • Used in reaction with chloroacetic acid and/or alkylene oxides during chelant synthesis; added to end formulation during blending of finished water treatment chemicals

    Final product types

    • Multipurpose boiler descalers
    • High-concentration water treatment chelants
    • Reverse osmosis antiscalant preparations
    • Closed loop system metal protectants

    6. Polyetheramine Manufacture for Additive and Surfactant Industries

    Propyleneimine serves as a nucleophilic initiator in polyether synthesis, producing polyetheramines with tailored molecular weight and end-group functionality for use as dispersants, fuel additives, and surfactant intermediates. Its integration allows precise control of chain architecture, supporting advanced additive packages for automotive, marine, and cleaning sectors, while ensuring batch-to-batch consistency required by major industry customers.

    Industry compliance standards

    • OECD Guidelines for Testing of Chemicals (environmental impact)
    • Directive 2004/42/EC (volatile organic compound limits for additives)
    • ISO 9001 for batch release and traceability
    • SAE J183 for engine cleanliness requirements

    Typical usage ratio

    • 0.5%–3% initiator (propyleneimine) based on total monomer charge; stoichiometry optimized for target amine number and product viscosity

    Downstream process integration

    • Charged at initiator stage of polyether polyol production (KOH-catalyzed) under inert gas protection; downstream conversion to end-use polyetheramines with MW control

    Final product types

    • Engine detergent additive concentrates
    • Marine fuel system cleaners
    • Anionic/cationic surfactant intermediates
    • Corrosion inhibitor formulations
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    Certification & Compliance
    More Introduction

    Propyleneimine: A Closer Look from the Manufacturer’s Perspective

    Understanding Propyleneimine and Our Commitment to Quality

    Propyleneimine stands out in the specialty chemicals market due to its unique molecular structure and the reactive aziridine ring it contains. Chemical makers like us focus on this compound for its versatility in industry. Our production stands on decades of hands-on experience with aziridine chemistries, drawing from both established know-how and ongoing research. Each lot starts with carefully sourced raw materials, selected through rigorous quality control systems that reach far beyond minimum compliance. The result is a chemical that consistently meets stability and purity thresholds, which customers have come to expect over years of working with us directly.

    Our Manufacturing Experience Sets the Standard

    A chemical like Propyleneimine must offer more than a single-use solution. Over the years, as manufacturing processes evolve and applications expand, we make it part of our job to keep pace with new needs. We maintain strict process control, avoiding cross-contamination and ensuring batch-to-batch consistency. From reactor settings to packaging, every stage has seen iterative improvements. Each adjustment has its reasons, learned through long nights troubleshooting real-world plant issues—never just reading from a playbook.

    Operators, engineers, and lab teams participate in continuous feedback meetings. These gatherings often lead to small but hard-earned changes in temperature controls, pressure monitoring, and purification steps. The goal always remains the same: keep the product robust and reliable while increasing efficiency and worker safety.

    Specifications: Clarity, Not Just Numbers

    It’s easy to list specification numbers, but for us, the story is deeper. Propyleneimine leaves our facility with high-grade purity, typically at or above industry benchmarks for aziridine compounds, and free from water and unwanted byproducts detected through gas chromatography and NMR analysis. The color, clarity, and odor get checked by skilled workers who recognize the difference between a minor impurity and a major deviation. Typical specifications include a minimum assay of 99.5% by mass, negligible water content, and absence of amines above detection limits.

    Our shipments move only after meeting in-house and sometimes customer-specific requirements. Some customers want larger sample retains for in-process validation; others request tailored packaging to minimize exposure in transit. We support these variations out of respect for their own process control challenges, and we use their feedback to fine-tune our production protocols.

    Real Uses: Value Beyond the Lab Bench

    Propyleneimine plays a direct role in the manufacturing of epoxy curing agents, surface coating modifiers, ion-exchange resins, and other specialized polymer systems. Its high reactivity makes it a preferred alkylating agent in organic synthesis, plus it acts as a monomer for making specialty polyamines. We’ve seen customers use it in compact settings like pilot reactors for scaleup experiments and in sprawling, continuous-flow systems for bulk resin production. In each area of use, our involvement doesn’t stop with delivery—we regularly help troubleshoot scale-up issues and share what works based on years spent tracking customer outcomes.

    Epoxy systems especially benefit from Propyleneimine. By controlling the balance of ring-opening and cross-linking reactions, formulators get better control over mechanical strength, flexibility, and chemical resistance. Our technical advice, based on practical batch data, helps them avoid common pitfalls like runaway exotherms or gelation delays. Over time, we’ve documented these performance differences, and they show up in cured resin clarity and resistance to yellowing in weathering tests—properties that come directly from raw material quality.

    Why Purity and Handling Matter in Real Life

    Factories that use Propyleneimine soon learn that a flawless batch reduces headaches—for both their plant managers and their customers downstream. A trace amount of moisture or unwanted amine can foul up entire reactor lines or leave residues in end products. Past experience has shown that monitoring and maintaining material within spec isn’t optional; it directly affects yield, mechanical properties, and workplace safety.

    We avoid repackaging from drums or totes that travel through multiple warehouses. Our logistics track each container’s exposure history, preventing contamination and environmental damage. Users can trust that a fresh shipment matches its COA because we enforce controls at our filling and loading lines, not just in the lab report. This hands-on care comes from years spent visiting customer plants, witnessing what happens if short cuts occur, and adjusting our practices accordingly.

    Direct Support for End-Users

    New plant engineers often bring us their process questions, sometimes before they place an order. We answer based on shop-floor realities, rather than textbook abstracts. If a customer asks about storage conditions, we share results from our own long-term retention studies, detailing how Propyleneimine holds up over months under varied environments. If they need advice for safe handling, our team can draw from real incidents we’ve helped resolve, balancing the needs of operational continuity with health and safety mandates.

    Some resin formulators approach us when scaling from lab to pilot volumes. Mistakes during this step can waste time and material, and we make a point of guiding the adjustment of mix protocols, agitation rates, and venting requirements. Polymer syntheses that rely on Propyleneimine’s fast ring-opening reactions can stall out or misfire if initiator sequences or impurities interfere. Our accumulated know-how helps flag and resolve these process bottlenecks early.

    What Makes Propyleneimine Distinct from Related Products?

    The aziridine ring in Propyleneimine creates a much higher reactivity than you get with straight-chain amines or larger cyclic amines. While ethylenimine, the nearest analog, relies on a smaller ring and can act even more aggressively, Propyleneimine brings a balance of reactivity and handling safety. Its additional methyl group offers a practical advantage in polymer branching and end-group control when compared to simple ethylenimine or other multi-function alkylating agents. These differences translate into distinct performance when formulating epoxy hardeners or surface modifiers—especially where a balance of speed and selectivity is required.

    Other alkylating agents, like propylene oxide or diethylenetriamine, offer less reactivity or more side reactions. Propyleneimine’s profile means more efficient incorporation during polymerization, often achieving higher conversion and more uniform distribution throughout a polymer matrix. We’ve tested side-by-side comparisons in our labs and confirm these benefits with repeatable results, sharing insights with our customers through direct technical reports rather than generic brochures.

    Regulatory and Workplace Considerations Based on Experience

    After dealing with international shipments for over a decade, we understand that Propyleneimine falls under several controlled-use designations, covering transportation, storage, and waste. We keep compliance tight on all outgoing batches, making sure paperwork and packaging satisfy local and international standards. Our teams don’t just leave regulatory matters to a back-office clerk. Senior staff often consult directly on regional registration and labeling requirements, building a compliance track record that reduces client risk.

    In our experience, consistency in documentation prevents unnecessary delays at customs or during internal audits. Training sessions with both our team and client operators help highlight key EPA, REACH, and GHS obligations. Rather than relying solely on generic SDS, we prepare summary sheets reflecting recent regulatory updates and test results from relevant authorities. Open communication about new findings ensures responsible use and minimizes the risk of fines or incidents.

    Adapting to the Evolving Chemical Landscape

    Markets aren’t static. Over time, demand for Propyleneimine has shifted as new polymer chemistries emerge or regulations change the way industry approaches raw materials. We’ve watched resin companies alter their preferences after a single major plant incident or a tightening of exposure limits. Sometimes, our role is to help customers downsize inventory risks by moving to smaller, more frequent shipments, or to advise alterations in baseline formula to improve environmental profiles and reduce emissions.

    We experiment in our own pilot-scale reactors to verify data before offering alternatives. In the process, we sometimes discover new application spaces for Propyleneimine, especially where classic aziridines underperform or fail at certain temperatures or pH. Our research teams engage with academic and corporate partners, running lab and field trials, and feeding successful conclusions back into product and process designs, always with a focus on reliability and worker safety.

    Solving User Challenges Through Shared Experience

    Over the years, plant engineers and formulators have brought us a broad range of process challenges. Some worry about rapid ring-opening reactions leading to heat spikes, others need guidance for post-reaction work-up, and a few have worked to minimize environmental loading by seeking higher yields and cleaner conversion. Instead of a one-size-fits-all manual, we coach based on realities like summer humidity, tank linings, or scale-up limits. Sharing field-verified tricks—such as inert gas overlays or double-checking agitation speeds—has often helped customers avoid downtime.

    Access to our historical process data comes in handy for customers running risk assessments. If a plant plans a new batch size, we can often point to real trial results and explain how impurities or storage time might influence outcome. We also provide evidence-based suggestions when organizations shift from legacy alkylating agents to Propyleneimine, presenting direct benchmarks rather than abstract projections.

    Sustainability and Safety Are Built-In, Not Afterthoughts

    Environmental considerations influence nearly every batch we produce. Spills, off-gassing, and worker exposure have lasting effects, and while we focus on delivering high-purity Propyleneimine, we also review each process step for potential environmental impacts. Our internal safety team runs regular drills and reviews with operators, so emergency response is always practiced, not just theoretical.

    Solvent choices, waste stream treatment, and storage design receive ongoing review. Over the last decade, we’ve upgraded containment systems twice in response to lessons learned during both simulated and real spill scenarios. We document and publish our findings to help customers improve their own site practices. Propyleneimine’s volatility and need for careful handling drive us to invest in new safety protocols—such as double-sealed containers and real-time leak detection—for every shipment. Our investments in worker health, site air monitoring, and local community outreach stem from both regulatory duty and a genuine desire to leave the industry cleaner and safer for the next generation.

    Continuous Improvement Shaped by Reality, Not Theory

    Feedback from end-users steers our improvement process. Sometimes, a resin manufacturer alerts us to minor anomalies in reactivity, which triggers a full review of our synthesis steps. See something in the field? We send our technical support directly to their site—or set up remote diagnostics—to review procedures alongside plant engineers. Shared troubleshooting can reveal root causes that never show up in standard QC metrics. These field visits turn our lab observations into real, actionable change.

    No amount of theoretical forecasting replaces direct case reports. For instance, over the past few years we saw that subtle process deviations—slightly higher residual acidity, or storage at just a few degrees warmer—could affect handling comfort and product shelf life. Rather than burying this data, we update our clients quickly, showing them what to expect and how to counter subtle but real degradation mechanisms. That kind of reactivity and responsiveness helps foster real trust, rather than just business transactions.

    Market Evolution and Propyleneimine’s Role in New Applications

    Emerging application fields shape our priorities. Biotech, electronics, and advanced composites now ask for Propyleneimine with near-zero residuals and controlled impurity profiles. To address these shifts, we invest in new purification, drying, and bottling technology, even when legacy processes look cost-effective. Early stage researchers often share new formulation ideas; we pilot their concepts to see which can scale. This keeps us ahead, supporting clients experimenting with high-performance adhesives, unique ion-exchange systems, or medical-diagnostic resins.

    Some markets, such as battery materials or precision coatings, require reimagining what purity and performance metrics to target. We respond with tailored syntheses and aggressive analytical testing regimens. By collaborating directly with customer R&D labs, we help close the innovation loop faster than indirect suppliers. Several new formulations for electronics and engineered surfaces have started based on a few grams of our Propyleneimine, scaled up successfully after direct technical engagement.

    Resilience in the Supply Chain

    External events—storms, freight disruptions, new tariffs—routinely test our ability to deliver. We counter this by maintaining critical safety stocks, prequalifying alternative suppliers for raw materials, and certifying additional packaging and transport contractors. Our teams follow each shipment and work with clients to anticipate bottlenecks, share realistic lead times, and prebook future orders to keep lines running when others face gaps.

    Lessons learned from near-miss logistics incidents now inform our risk management and customer support policies. Ongoing investments in digital tracking, contingency planning, and supplier diversification insulate our clients from common industry shocks. We let customers know early if a timeline risks adjustment, sharing backup plans—not apologies—rooted in experience managing global trade in volatile times.

    Looking Ahead: Propyleneimine as a Platform Chemical

    While Propyleneimine remains critical in established markets, we see its function broadening as more sectors seek agile, reactive intermediates. Bio-based chemistries, recyclable polymers, and new-generation adhesives stand to benefit from its unique reactivity profile. Our development program includes ongoing scale trials of new grades, tracking not just purity and stability, but downstream properties in final-use settings. We document these new application pathways and share our learnings openly, building a technical community around real evidence rather than marketing speak.

    Seasoned chemists and newcomers alike have much to gain from transparent supplier relationships. We measure our value not simply by volume shipped, but by problems solved—tracking back to what matters for manufacturers, process teams, and their end-users. In each drum of Propyleneimine that leaves our plant, there’s more than just a chemical; there’s a legacy of improvement, honest reporting, and shared know-how that makes manufacturing—as a practice—a little smoother for everyone involved.