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Potassium Dichromate

    • Product Name Potassium Dichromate
    • Alias Dichromic acid dipotassium salt
    • Einecs 231-906-6
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    105477

    Chemicalname Potassium Dichromate
    Chemicalformula K2Cr2O7
    Molarmass 294.18 g/mol
    Appearance Orange-red crystalline solid
    Meltingpoint 398 °C (decomposes)
    Solubilityinwater 12.5 g/100 mL at 20 °C
    Density 2.676 g/cm³
    Casnumber 7778-50-9
    Odor Odorless
    Ph 4.0 (50 g/L in water at 20 °C)
    Boilingpoint Decomposes before boiling
    Hazardclass Oxidizing, Carcinogenic, Toxic
    Color Orange-red
    Storageconditions Store in a cool, dry, well-ventilated area away from combustible substances

    As an accredited Potassium Dichromate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A sealed, amber glass bottle containing 500g of Potassium Dichromate, labeled with hazard symbols and chemical details for laboratory use.
    Shipping Potassium Dichromate is shipped in tightly sealed, corrosion-resistant containers made of materials like glass or HDPE. It must be labeled as a toxic and oxidizing agent, and kept away from incompatible substances. Transport requires compliance with hazardous material regulations, ensuring protection from moisture, heat, and physical damage during transit.
    Storage Potassium dichromate should be stored in a cool, dry, well-ventilated area away from incompatible materials such as acids, organic substances, and reducing agents. Store in tightly sealed, corrosion-resistant containers clearly labeled as toxic and oxidizing. Avoid exposure to moisture and direct sunlight. Access should be restricted to trained personnel, and appropriate chemical safety procedures must be followed at all times.
    Application of Potassium Dichromate

    Applications of Potassium Dichromate in Industrial Manufacturing

    Potassium dichromate is an inorganic chemical widely used in several downstream sectors for its strong oxidizing properties and unique chemical reactivity. As a primary manufacturer, we supply this material to industries with stringent production and regulatory requirements. Below are key industrial application scenarios, each with corresponding compliance, technical, and process details.

    1. Chrome Plating for Metal Finishing

    In the surface finishing sector, metalworking facilities rely on potassium dichromate primarily for chrome plating processes. The compound acts as an oxidizing agent and catalyst in the chromic acid electroplating bath, enabling a uniform, corrosion-resistant, and decorative metallic layer. Exact dosage and bath control strongly influence coating thickness, hardness, and adhesion. Strict environmental and operator safety controls are enforced due to the compound’s toxicity and waste treatment load.

    Industry compliance standards

    • REACH Regulation (EC) No 1907/2006
    • OSHA 29 CFR 1910.1026 Hexavalent Chromium Standard
    • RoHS Directive 2011/65/EU (applicable for residue and effluent limits)
    • ISO 1456:2017 Metallic coatings—Electroplated coatings of nickel plus chromium and of copper plus nickel plus chromium

    Typical usage ratio

    • 0.3 – 1.5 g/L in chromic acid bath, adjusted depending on tank geometry, metal substrate, and target plating thickness

    Downstream process integration

    • Bath make-up: Addition during tank preparation after dilution of chromic acid
    • Periodic replenishment: Supplemented during production runs to maintain redox potential
    • Bath monitoring: QC sampling for potassium dichromate and contaminant control
    • Final rinse: Post-plating neutralization and hexavalent chromium removal

    Final product types

    • Automotive trim parts
    • Sanitary fittings
    • Architectural hardware
    • Consumer electronics casings

    2. Manufacture of Inorganic Pigments

    Producers of inorganic color pigments use potassium dichromate in controlled reactions to synthesize chrome yellow (lead chromate) and chrome orange, valued for their vividness, weather resistance, and light stability. Strict process management is required to ensure complete reaction, prevent residual hexavalent chromium in finished pigment, and achieve regulation-compliant product for downstream coating, ink, and plastics compounding use. Legacy applications in pigments remain regulated or banned in certain jurisdictions, emphasizing the importance of end-market compliance.

    Industry compliance standards

    • ISO 1248:2015 Pigments—Determination of chromate content
    • EN 71-3:2019 Safety of toys—Migration of certain elements
    • EU CLP Regulation (EC) No 1272/2008 for labeling and packaging
    • NIOSH/OSHA air monitoring for worker exposure

    Typical usage ratio

    • Varies: 1.0 – 1.4 mol potassium dichromate per 1 mol lead nitrate, or equivalent, depending on reaction stoichiometry and shade target

    Downstream process integration

    • Reactant addition: Dosed with other precursors in aqueous synthesis reactors
    • Filtration and washing: Removal of unreacted chromate and soluble byproducts
    • Calcination or drying: Particle stabilization and conversion control
    • Post-treatment: Surface modification or encapsulation to reduce leachability

    Final product types

    • Chrome yellow pigment for industrial paints
    • Color masterbatches for plastics
    • Industrial printing inks
    • Coil and container coatings

    3. Organic Fine Chemical Synthesis (Oxidation Reactions)

    Chemical manufacturers deploy potassium dichromate as a strong oxidizer in synthetic organic chemistry, especially for converting alcohols to corresponding aldehydes, ketones, or carboxylic acids. Pharmaceuticals, agrochemicals, fragrance intermediates, and fine chemicals rely on these transformations. Operational safety, byproduct management, and effluent treatment are critical due to the compound’s oxidative strength and toxicological profile.

    Industry compliance standards

    • GMP (Good Manufacturing Practice) for active pharmaceutical ingredient (API) production, per ICH Q7
    • Pharmacopoeial monographs (USP, Ph. Eur.) governing residual contaminants
    • Responsible Care and Process Safety Management (PSM) protocols
    • Local wastewater hexavalent chromium discharge limits

    Typical usage ratio

    • 0.2 – 0.8 molar equivalents per substrate, optimized by reactant type and target oxidation state

    Downstream process integration

    • Batch or semi-continuous addition in jacketed reactors
    • Quenching and separation of chromium byproducts after oxidation step
    • Post-reaction purification: Filtration or extraction to remove secondary residues
    • Spent oxidizer sent for chromium recovery or disposition

    Final product types

    • Pharmaceutical intermediates and APIs
    • Fragrance compounds (e.g., aldehydes)
    • Specialty monomers
    • Pesticide precursors

    4. Analytical Laboratory Reagents

    The compound serves as a primary reagent in both quantitative and qualitative analytical chemistry applications. Laboratories rely on its consistent oxidation potential for titrimetric analysis, especially in the measurement of iron, organic matter in wastewater, and alcohols. Batch quality and traceability are strictly managed to ensure analytical reproducibility, and packaging configurations are tailored for safe laboratory handling.

    Industry compliance standards

    • ISO 6353-1:1982 Reagents for chemical analysis—General test methods
    • ASTM D1687 for chemical analysis of water
    • Analytical-grade standards as per ACS Reagent Guidelines
    • Good Laboratory Practice (GLP)

    Typical usage ratio

    • Preparation of 0.1 N or 0.025 N standardized solutions for titration, based on target analyte and detection limit

    Downstream process integration

    • Preparation of primary standard solutions in volumetric glassware
    • Addition in redox titration methods, such as Mohr and Volhard procedures
    • Spectrophotometric calibration curves
    • Waste neutralization post-analysis

    Final product types

    • Standardized lab reagents for chemical analysis kits
    • Certified reference materials
    • Laboratory titration packs
    • Wastewater analysis chemicals

    5. Wood Preservation and Leather Tanning

    Potassium dichromate has a historical and continued, though increasingly regulated, use in wood preservation and leather tanning. In these applications, it oxidizes organic chromophores and crosslinks protein structures, helping improve dimensional stability, resistance to microbial attack, and color fastness. Ongoing regulatory scrutiny governs its permitted use, worker exposure, and waste management, and alternatives are increasingly considered in specific regions.

    Industry compliance standards

    • EN 599-1:2013 Durability of wood and wood-based products
    • Factory safety requirements per REACH and the EU Industrial Emissions Directive
    • OSHA standards for personal protective equipment (PPE) in use of hexavalent chromium
    • ISO 11640:2012 Leather—Color fastness to cycles of to-and-fro rubbing

    Typical usage ratio

    • Wood treatment: 0.5 – 2% by weight in aqueous impregnation solutions
    • Leather tanning: 1 – 5% by weight on hide substance, with process-specific adjustment

    Downstream process integration

    • Pre-soak or impregnation of wood prior to drying and finishing
    • Addition to tanning drum or pit during chrome tanning operations
    • Final rinsing and post-tanning neutralization stages
    • Spent liquor management and chrome recovery systems

    Final product types

    • Preserved utility poles and railway sleepers
    • Outdoor decking and timber building components
    • Chromium-tanned leather for shoes, belts, and upholstery
    • Industrial gloves
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    Certification & Compliance
    More Introduction

    Potassium Dichromate: Craftsmanship and Commitment

    Understanding Potassium Dichromate from a Manufacturer’s Perspective

    Potassium dichromate demands a clear-eyed approach. From the outside, it looks like just another vivid orange powder, but the process from mineral ore to the final refined salt touches almost every step of the value chain. The heart of potassium dichromate lies in its chemistry: a simple structural arrangement, large cubic crystals, and high purity made possible only by deliberate control over every reaction and separation.

    Our workbench holds the story of potassium dichromate, and it stretches deeper than packages on a shelf. We start with chromite ore, a dense mineral with few impurities. Each load must meet tight restrictions on iron and silica content, as either can complicate the extraction steps. After crushing and roasting, sodium carbonate reacts with this chromite to yield soluble sodium chromate, which is then leached out. Few people see these glowing yellow tanks in daylight, but the repeated washing and filtering sets the stage for what matters most: pure, unadulterated chrome chemistry.

    Conversion to dichromate comes next. Streams of acid bite through the sodium chromate under temperature control to force the transformation from yellow to orange crystals. We use only industrial-grade sulfuric acid—a byproduct elsewhere, but here, the catalyst of progress. Nothing about this step is forgiving. Heating rates, acid strengths, and cooling schedules must land in a tight window, or the yield falls and the resulting dichromate ends up off-spec. Supersaturated orange liquor cools in deep tanks, crystals settle, and, nurse-like, our operators watch over growth to avoid trapping mother liquor or unwanted inclusions.

    Filtration and washing call for patient hands. Errant sodium ions or unreacted acid have no place in crystals destined for precision glassmaking, pigment synthesis, or critical analytical tests. The difference between 99.7% and 99.9% purity arrives through human vigilance: pH probes, conductivity checks, a monochrome scale for color, and sometimes, simply holding a crystal up to sunlight.

    Specification and Model Choices

    Factories like ours offer potassium dichromate in granular and fine crystalline grades. Customers expect different behavior from each. Granular forms pour quickly, resist dusting, and suit batch additions in foundries and dye operations. Finer crystals dissolve with ease but can cake in humid air. Some buyers request sub-millimeter sieving for analytical use, where every gram must dissolve without residue. Others ask for food-grade packaging unwelcome to even a speck of contamination. Each lot receives its own traceability stamp, mapped straight back to its composition and processing timeline.

    Some users want only the basics: purity, moisture content, screen size, bulk density. Our technologists go beyond that checklist. Trace elements—iron, calcium, sodium, and insoluble matter—shape the downstream application. Chrome plating houses watch sodium levels. School laboratories fear even parts-per-million of unexpected metals. Our experience says the best product is the one you can count on all year, batch after batch, without excuses or seasonal variation.

    Key Uses: Why Potassium Dichromate Stands Apart

    Potassium dichromate earns its place as a staple of classic and modern chemistry. Its deep orange color signals the presence of strong oxidizing power, and nothing replaces it where that strength is required. In many countries, environmental laws restrict use, but its unique reactivity remains central to key processes.

    One main use lies in chrome plating, where potassium dichromate acts both as an oxidizer and a provider of hexavalent chromium ions. The material’s predictable solubility means line operators achieve stable bath chemistries, and their platings emerge with the expected finish—mirror-bright, corrosion-resistant, and adherent. Plating shops that source through distributors sometimes struggle with inconsistent batches. By manufacturing from scratch, we can correct for each ore shipment’s quirks, keep the sodium to a bare minimum, and ensure stable yields.

    In the realm of glassmaking, customers value potassium dichromate for reasons not obvious at first glance. It imparts a distinctive green tint in glass, but more important, it controls oxidative balance during melt. Trace metallic impurities in raw sands can shift color or clarity. Potassium dichromate supplies oxidizing equivalents that buffer these fluctuations, so each batch of glass holds to its design shade and meets the clarity standards demanded by specialty bottle and optical glass buyers. Using the wrong grade leads to sudden splotches or haze, while reliable potassium dichromate keeps shipments predictable.

    Photography has long relied on dichromates for processes that link the organic and the inorganic. In screen printing and lithography, potassium dichromate reacts with organic colloids to form hard, water-insoluble images on print surfaces. Consistent crystal size ensures uniform dispersion and repeatable results. Hobbyists and industrial printers alike may not recognize the handwork that finishes each lot, but they see the difference in image sharpness and contrast. It’s easy to cut corners here; low-grade dichromate can behave erratically, causing filter blockages or uneven exposure.

    Laboratories use potassium dichromate as a titrant in redox chemistry. It holds exceptional stability compared to liquid reagents, and its strong color signals endpoints clearly. Trace iron, present in some competing products, throws off results and erodes confidence in standardization. By working directly from mined ore through final crystallization, we cut the risk of cross-contamination, ensuring calibrations and analyses stay on mark for schools, research labs, and industrial test benches.

    Other industries, including dyes and pigments, continue to draw on potassium dichromate’s legacy. The orange chromate core has inspired many vibrantly colored formulations. Textile dyers appreciate the repeatability of oxidation—no batch-to-batch shift in shade or strength. Painters and ceramicists trust its stability to develop rich earthy tones. In every case, the correct grade and a clean handling process make all the difference between an enduring color and a short-lived imitation.

    Distinctiveness: Measuring Potassium Dichromate Against Other Chromates

    Potassium dichromate stands out in a crowded family of chromate chemicals. Some buyers ask about sodium dichromate as an alternative. Both perform similar oxidizing roles, but there’s a trade-off baked into their chemistry. Sodium dichromate boasts higher solubility, but its solution chemistry can go awry in hard water or in any process needing potassium ions. Industries working with alumina ceramics, for example, prefer potassium dichromate to prevent unwanted sodium incorporation, which would weaken fired products.

    Handling characteristics also create real-world differences. Potassium dichromate’s harder, chunkier crystals produce less airborne dust—an important quality for larger-scale users who move tons each year. Less dust means lower risk during bagging and mixing, which workers appreciate for safety and comfort. Sodium dichromate, hygroscopic and stickier, can clog feeders in humid shops. Manufacturers know the value of a dry, free-flowing product that reduces waste and cleanup.

    In terms of environmental risk and reactivity, potassium dichromate does not offer meaningful safety advantages over sodium dichromate. Both require strong handling protocols. Yet, purity sets potassium dichromate apart: certain reactions in organic synthesis will not tolerate excess sodium; some specialty metals reject any deviation from the potassium base. Titanium dioxide producers, for instance, reserve potassium dichromate as a top-end raw material because their downstream catalysts become poisoned by sodium carryover.

    Ammonium dichromate sometimes enters the discussion as a niche alternative, especially for pyrotechnics and demonstration reactions. But ammonium salts release ammonia upon decomposition, which presents additional handling complications—especially indoors. Our experience says that potassium dichromate, properly managed, gives a safer and more controllable user experience. Its lower volatility and stable decomposition profile suit industrial and lab settings far better.

    Quality, Safety, and the Real Challenges

    Meeting high specification stands at the core of potassium dichromate manufacture. Sub-standard grades pop up occasionally on the market, often passed along by resellers or brokers without clear provenance. As producers, we spend a good share of time confirming that every load matches analytical promises: colorimetric titrations, spectrographic scans, and wet chemistry validation. Buyers sometimes underestimate the value of direct accountability from the manufacturer. It goes beyond trust; it’s about controlling the chemistry from ore until the moment the product leaves the loading dock.

    Potassium dichromate brings inherent risk. Regulatory frameworks in most jurisdictions demand full documentation of process handling, waste recovery, and worker exposure. Legacy plants from an earlier era sometimes lag in these areas, but modernization brings hope. Sealed transfer lines, vapor extraction points at mixing stations, personal protective equipment routines—these investments reduce risk. Our team trains for every step, from mixing vats to packaging lines, aware that diligence shapes both safety and downstream application quality.

    Some industries look for alternatives due to growing health and environmental reassessment of hexavalent chromium chemistry. Waste streams from plating or glassmaking must meet strict discharge limits. The technology exists for near-total recovery of spent dichromate, and we engineered our operations for closed-loop water cycles and multi-stage waste chrome reclamation. These systems don’t come cheaply, but the alternative—uncontrolled release, regulatory fines, community pushback—hurts more in the long run. We see a future where potassium dichromate and sustainability meet as partners, not adversaries.

    Another challenge comes from misunderstanding the difference between a reagent-grade potassium dichromate and a lower industrial grade. Many small-scale buyers, attracted by discount offers, unknowingly risk process or analysis failures by skipping the assurances of a full certificate of analysis or traceable batch handling. Any detected impurity in final product, be it from glass production, plating, or laboratory determination, reflects back to shortcomings in upstream sourcing. That’s why our documentation travels with every shipment, summarizing not just what’s inside but also how it got made.

    Solutions and Commitments

    Maintaining high quality, safety, and reliable supply boils down to deliberate choices. We monitor technological changes in manufacturing for ways to keep processes safer and cleaner, even if upgrades challenge old habits. Digital controls now automate more of the temperature and pH regulation once managed by manual checks. This shift frees up staff to concentrate on sampling and quality inspection, rather than endless adjustment of turbines and stirrers.

    Ensuring consistent purity hinges on the chemistry you apply as much as the attention you pay during each step. By keeping all processing in-house, from ore calcining to final washing, every lot stays under our direct scrutiny. This vertical integration trims risk. We’re not dependent on outside parties or intermediaries whose own controls might slacken. Our technicians communicate directly with end-users—glass chemists, plating house engineers, academic instructors—sharing experience that helps better match product choice to process need.

    On the safety front, our investment in environmental monitoring systems extends into both workplace air and neighboring communities. Inline sensors, semi-automated personal protective equipment tracking, and full disclosure with safety regulators all play a role in keeping operations in line with 21st-century expectations. Old myths about the inevitability of emission or runoff don’t bear out if the whole organization buys into the goal of zero visible release.

    Collaboration across the industry matters too. Many of the largest refiners, including ourselves, participate in international safety forums and standards-setting panels. Sharing near-miss reports and mitigation ideas works better than keeping knowledge locked behind corporate curtains. Sometimes these exchanges spark genuine improvements—not because they tick a regulatory box, but because worker safety and planet health must anchor day-to-day reality.

    Potassium Dichromate and Tomorrow

    Potassium dichromate’s place in modern science and industry remains vital, though its future will evolve. Some applications may eventually transfer to less hazardous chemistries, but many industrial processes still rely on its unique characteristics. From inside our plant walls, the challenge does not rest in just making a pure, reliable, cost-competitive product, but in making one that fits into a cleaner, safer, and more transparent world economy.

    Every decision, from raw ore purchase to the final sample analysis, is linked to our reputation and the confidence customers place in our product. Knowledge moves quickest on the factory floor—not from manuals, but from operators passing down what works, what fails, and why a well-made potassium dichromate crystal remains the standard against which others are measured. With processes kept under one roof, and a clear line of communication stretching from our plant chemists to the factory technicians and laboratory analysts who use our work, the future of potassium dichromate, and those who rely on it daily, looks shaped by both tradition and progress.

    Potassium dichromate reminds us daily that critical materials come with critical responsibilities—to plant workers, end users, and the communities around every manufacturing site. The best product is one that reflects not just a mastery of chemistry, but a commitment to people and safeguards for tomorrow.