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Potassium Borohydride

    • Product Name Potassium Borohydride
    • Alias KBH4
    • Einecs 242-001-6
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    643831

    Chemical Name Potassium Borohydride
    Chemical Formula KBH4
    Molar Mass 53.94 g/mol
    Appearance White crystalline solid
    Melting Point 350 °C (decomposes)
    Solubility In Water 12.5 g/100 mL at 25°C
    Density 1.18 g/cm³
    Odor Odorless
    Cas Number 13762-51-1
    Stability Stable under recommended storage conditions

    As an accredited Potassium Borohydride factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing White plastic bottle with tamper-evident seal, labeled “Potassium Borohydride, 100g,” featuring hazard symbols and handling instructions.
    Shipping Potassium Borohydride (KBH4) is shipped in tightly sealed containers, typically under inert atmosphere, to prevent moisture and air exposure, as it is highly reactive and flammable. It is classified as a hazardous material and must be transported according to relevant regulations, using appropriate hazard labeling and documentation for safe handling.
    Storage Potassium borohydride should be stored in a tightly sealed container under an inert atmosphere, such as nitrogen or argon, to prevent contact with moisture and air. Store it in a cool, dry, and well-ventilated area away from acids, oxidizers, and water sources. Proper chemical storage cabinets designed for reactive substances are recommended to ensure safety and stability.
    Application of Potassium Borohydride

    Applications of Potassium Borohydride in Industrial Manufacturing

    As an established producer of potassium borohydride, we supply high-purity material for specialized reduction processes across various downstream sectors. Our technical expertise ensures each application benefits from precise formulation guidance, regulatory compliance, and tailored integration into customer production lines.

    1. Fine Chemical Synthesis: Active Pharmaceutical Ingredient (API) Manufacturing

    API manufacturers use our potassium borohydride in selective reduction stages, frequently for reducing aldehydes, ketones, and certain esters where sodium borohydride is unsuitable due to solubility or reactivity challenges. Customers appreciate the controlled release of hydrogen and minimal by-product formation, supporting high-yield, high-purity synthesis workflows in multi-step organic API production for human and veterinary medicine.

    Industry compliance standards

    • ICH Q7: Good Manufacturing Practice Guide for Active Pharmaceutical Ingredients
    • US FDA 21 CFR Part 210/211 (cGMP for finished pharmaceuticals)
    • European Pharmacopoeia (Ph. Eur.) guidelines on residual metals
    • REACH Regulation (EC No 1907/2006) for chemical safety in EU APIs

    Typical usage ratio

    • 0.80–1.20 molar equivalents relative to reducible substrates, adjusted based on substrate reactivity and desired selectivity; process chemists may optimize proportion further for specific molecular scaffolds.

    Downstream process integration

    • Orchestrated addition via jacketed batch reactors or semi-continuous flow setups after preliminary substrate activation, followed by aqueous or organic workup; real-time process analytics ensure completion and minimize excess reagent.

    Final product types

    • Synthetic drug intermediates
    • Chiral hydroxy compounds for APIs
    • Advanced building blocks for branded and generic pharmaceuticals
    • Veterinary active substances

    2. Electronic Materials: Semiconductor Surface Treatment

    Major semiconductor fabs employ potassium borohydride during wafer texturization and surface finishing. The reducing environment supports critical stepwise removal of surface oxides from silicon, germanium, or III-V compound materials without introducing sodium contamination, which is strictly limited by device producers due to elevated risk of ionic transport and dopant disturbance during microfabrication.

    Industry compliance standards

    • SEMI F63 and F57: Purity and testing standards for electronic grade chemicals
    • IEC 60747: International standard for semiconductor devices
    • Quality management under ISO 9001:2015 and ISO 14001
    • Cleanroom protocols per ISO 14644 series

    Typical usage ratio

    • 1–3 wt% aqueous solution, concentration tailored by process engineers based on oxide layer thickness and targeted etch rate; low impurity grades specified by advanced semiconductor customers.

    Downstream process integration

    • Inline dosing to wet benches immediately preceding final DI water rinsing; online sensors monitor reduction kinetics, minimizing exposure to ambient atmosphere and ionic contaminants.

    Final product types

    • Processed semiconductor wafers (Si, GaAs)
    • MEMS sensor devices
    • Photonic chips
    • Solar cell substrates

    3. Metal Recovery: Precious Metal Refining

    Industrial metal refiners prefer potassium borohydride for selective precipitation of noble metals such as gold, silver, and platinum from spent electrolytes and manufacturing scraps. The reagent efficiently reduces metal ions to their metallic state, even at low ppm concentrations, enhancing overall yield and supporting closed-loop recovery systems in both primary and secondary precious metal operations.

    Industry compliance standards

    • EN 1811: Testing of nickel release in metal recovery processes
    • ISO 14001: Environmental management systems for precious metals
    • Responsible Jewellery Council (RJC) Chain-of-Custody standards for recovered metals
    • REACH and RoHS directives (for waste handling and recovery residues in the EU)

    Typical usage ratio

    • 1.1–1.6 stoichiometric equivalents per mole of target metal ion; operators adjust concentration and addition rate based on solution matrix and presence of co-dissolved ions.

    Downstream process integration

    • Continuous or batch treatment tanks, typically automated dosing synchronized with precipitation and filtration schedules; real-time ORP and metal content analysis governs pH adjustment and reagent stop points.

    Final product types

    • Bullion-grade gold and silver precipitate
    • Refined platinum group metal powders
    • High-purity metallic sludges for further electrorefining
    • Recycled precious metal intermediates

    4. Hydrogen Source: Fuel Cell R&D and Portable Power Devices

    Developers of portable power solutions and early-stage hydrogen fuel cell labs use potassium borohydride to generate hydrogen on demand through controlled catalytic hydrolysis. Customers adopt this approach for prototype fuel cell testing or when designing safe, non-pressurized hydrogen storage modules for portable and backup power systems, due to its higher gravimetric energy content over sodium borohydride in some applications and its water solubility advantages for compact designs.

    Industry compliance standards

    • ISO 16111: Transportable gas storage devices for hydrogen
    • SAE J2719: Hydrogen quality guidelines for fuel cell vehicles
    • IEC 62282 series: Safety and performance standards for fuel cell technologies
    • UN Recommendations on the Transport of Dangerous Goods (for system integration)

    Typical usage ratio

    • 10–20 wt% aqueous solution charged into reactor with a supported catalyst; dosing rates optimized according to target hydrogen flow, system volume, and desired runtime per refill.

    Downstream process integration

    • Reagent reservoir linked to catalytic hydrogen generators, feeding hydrogen to the anode side of PEM or alkaline fuel cells; system design includes monitoring of tank levels and temperature for safe hydrogen delivery.

    Final product types

    • Prototype and demo fuel cell stacks
    • Portable backup power generators
    • Battery chargers with integrated hydrogen generation
    • Lab-scale hydrogen storage modules

    5. Water Treatment: Reduction of Specific Contaminants

    Selected water treatment plants utilize potassium borohydride for the reduction of specific heavy metal ions and chlorinated organics in industrial wastewater streams where strict limits exist for effluent discharge. The choice of potassium over sodium derivatives reflects plant engineering focus on minimizing residual brine and achieving fast, controlled reductions suited to modern, compact effluent polishing units.

    Industry compliance standards

    • ISO 14001: Environmental Management certification
    • US EPA Clean Water Act, CWA 40 CFR Part 136: Guidelines for pollutant reduction
    • EN 12255-14: Wastewater treatment plant standard for industrial effluents
    • Local discharge permit conditions and monitoring requirements

    Typical usage ratio

    • 0.5–2.0 moles per mole of target contaminant, adjusted for influent load and reactor volume; plant chemists fine-tune based on real-time contaminant monitoring.

    Downstream process integration

    • Metered injection into tertiary treatment skids or batch reactors, directly ahead of final filtration or ion-exchange columns; dosing rate varies with contaminant type (e.g., Cr(VI), chlorinated solvents), inlet composition, and seasonal flow variability.

    Final product types

    • Treated industrial process water
    • Compliant effluent for municipal discharge or reuse
    • Heavy-metal free sludge for safe disposal
    • Effluent compliant with zero-liquid-discharge systems
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    Certification & Compliance
    More Introduction

    Potassium Borohydride: A Closer Look from the Manufacturing Line

    Decades Working with Potassium Borohydride

    Potassium Borohydride, better known by its chemical formula KBH4, offers a unique place in the life of a manufacturing chemist. There’s a story to every drum and bag that moves off our line, and from pouring, blending, drying, to careful packaging, we watch every step. Each batch starts as raw mineral feedstock, passing through controlled reduction and purification. What leaves our plant is a white crystalline powder sought by researchers and production lines searching for a reliable hydrogen donor or a specialized reducing agent. Our typical offering centers on high-purity KBH4 with moisture content kept to an absolute minimum, particle size tuned to offer quick dissolution without excessive dusting, and a shelf stability that matches the transportation cycles of global trade.

    The chemical industry, whether it’s pharmaceuticals, electronics, or specialty synthesis, doesn’t just pick a material randomly. Over the years, we’ve listened to feedback from process engineers and lab techs who know how a small difference in a kilo of reagent can change outcomes in the field. Reproducibility matters, and so does batch documentation, so our lots run to a consistent standard that meets or exceeds stated purity. We run lot analyses for metallic impurities, water content, and boron isotopic ratios. Each time we make a batch, we cross-check against best-in-class benchmarks, because our customers never want process interruptions from off-spec materials. This pursuit has kept KBH4 at a level of purity and performance that plant engineers and R&D leaders have come to count on.

    What Makes Potassium Borohydride Stand Out

    Working hands-on, you notice that potassium borohydride shows a distinct set of advantages over its better-known cousin, sodium borohydride. While the two share a similar chemical backbone, their physical properties roll out differently on the shop floor and during usage. Potassium borohydride has a higher solubility in water and certain select solvents, so in practical terms, users can run reactions with more concentrated solutions and sometimes push reductions further. If you’ve ever needed to handle a high-load reduction or a tricky pharmaceutical intermediate, the differences jump out quickly. Our standard model, with purity levels usually reaching above 98%, comes as a free-flowing powder, ready for blending into solutions or direct addition into reactors.

    It's no secret that sodium borohydride leads in global volume, mainly because of cost and market familiarity. Still, applications such as selective reductions, high-value fine chemicals, and hydride generation atomic absorption spectroscopy call for potassium borohydride’s profile. Over decades, countless teams have chosen potassium borohydride when they need a reducing agent with a softer touch—ones that don’t want to risk excessive byproduct formation or where sodium ions cannot be tolerated in finished products. The borohydride anion does the work, but substitution with potassium proves decisive in some workflows.

    Everyday Use of Potassium Borohydride in Industry

    On any given production shift, we see potassium borohydride leave our facility packed for applications scattered across the spectrum of chemical synthesis. The pharmaceutical sector leans on KBH4 for the reduction of carbonyl compounds to alcohols and amines. The selectivity offered by this compound allows for functional group management difficult to match in other hydride systems. Chemists running sensitive transformations tell us they find less need to detoxify byproducts or rework product streams, saving time and money while improving yields.

    Beyond pharma, electronic materials producers buy KBH4 for gold and palladium plating solutions. The compound’s clean hydrogen generation and convenient solubility keep baths running at controlled rates. In metal recovery and recycling, potassium borohydride enters into processes for extracting precious metals without bringing sodium contamination, which could disrupt downstream catalyst activity. Feedback from plating operators often revolves around the predictability of reduction rates using our batches compared to comparable sodium-based systems—this consistency has led to improved throughput and reduced downtime in batch plating operations.

    Another key outlet can be found in hydride generation for analytical chemistry. Atomic absorption spectroscopy runs on precision, and borohydride-based hydride generation relies on consistent, high-purity source materials. Laboratories faced with trace metal detection in environmental samples select potassium borohydride due to its cleaner decomposition and lack of interfering ions. Analytical chemists frequently mention the drop in baseline noise and instrument wear attributed to improved starting material quality after switching to our KBH4.

    The Manufacturing Experience: Meeting Standards and Solving Problems

    Getting potassium borohydride to specification takes more than just quality raw boron and potassium feedstocks. Drying the product to a stable moisture content makes a world of difference when loading fine powders into sealed reactors. Small changes in particle size or moisture content affect reactivity, shelf life, and transport safety. Like most borohydrides, KBH4 draws water from the air, so we run every batch through controlled-atmosphere drying, automated blending, and sealed packaging. Our production workers undergo regular safety training and equipment calibration to keep operations running smoothly.

    Our process engineers tinker with reactor designs to balance productivity, energy efficiency, and minimization of impurities. By controlling the reduction atmosphere and temperature profile, we achieve low sodium content, low chloride levels, and near-complete phase purity. People sometimes ask why our packaging might look different from competitors. We tailor it to minimize air permeability and prevent caking—not simply to look good, but to make it easier for plant operators handling bulk orders. Before leaving the factory, our QA team checks every lot against specifications: appearance, reactivity tests, residual moisture, and a battery of impurity assays.

    Concerns around dust hazards or improper storage come straight from customer facilities, and we respond with sealed liner bags, labeled containers, and clear safety handling instructions. Our years spent shipping to both developed and emerging markets have honed these processes. We hear the stories of borohydride spills, degraded batches, unexpected delays caused by inadequate shelf life, and respond immediately. Our goal has always been to build a feedback loop between our manufacturing line and the actual user, which leads to product improvement and deeper client partnerships.

    What Differentiates Potassium Borohydride Manufacturing

    Working directly with suppliers and industrial users, you get clear signals about what matters in a reducing agent. Sodium borohydride often draws higher sales, but we notice customers return for potassium borohydride due to repeatable batch-to-batch behavior. Where sodium can bring lower costs, potassium borohydride picks up the slack in more demanding processes. We make our lot certificates reflect real-world results, not just statistical tolerances. This transparency has won us trust with process chemists who value traceability and fast technical support. Many of our clients run pilot-scale studies using both borohydrides as a comparison, and the difference isn’t always in speed or price but in the outcome: cleaner end products, better yields, and smoother approvals from regulatory agencies.

    Feedback on ease of handling plays a huge role in how we package and transport our product. Finer particle sizes can cause airborne dust, which workers dislike. Agglomeration can hurt dissolution rates and lead to wasted product. We run packaging trials with a range of liner materials and drum closures to keep the material dry and cake-free from our plant to your door. In regions with varying humidity levels, we adapt transit packaging and shipping schedules—these small changes keep batch performance high.

    Potassium borohydride’s specific reactivity profile also finds use in reactions where sodium ions could destabilize catalysts or pharmaceuticals. Our clients in catalyst manufacturing and some specialty electronics production have stringent ionic content specifications. By minimizing sodium and other alkali contaminants in our production train, we offer a version of potassium borohydride that passes their tough inspection regimes.

    Regulation and the Reality of Potassium Borohydride Supply Chains

    In chemical manufacturing, the true test of a product isn’t just its technical grade but how smoothly it moves through regulatory channels and supply networks. Some importing countries have special labeling, documentation, and safety data requirements on borohydrides. We invest time in keeping our documentation, safety data, and packaging in line with those requirements. This reduces customs inspections and delays, so our customers on tight schedules can keep their own operations running.

    Sustainability in supply always comes into question. Our teams source boron minerals and potassium compounds from vetted suppliers who meet environmental and labor standards. We look for ways to close waste loops internally, recycling solvents and adopting heat recovery processes. Chemical manufacturing has a long way to go to hit carbon neutrality, but small gains in yield, reduction of hazardous byproducts, and responsible sourcing push us closer each year. Potassium borohydride can be an energy-intensive material to make, so the better we can manage every step, the less waste and environmental impact we bring.

    Price volatility can shake up planners downstream. Raw boron and potassium pricing ebbs and flows based on global mining and energy costs. Clients sometimes worry about shortages or unexpected price jumps. We counter this by investing in buffer stock, long-term contracts with miners, and frequent reforecasts. Being the primary manufacturer, we see these shifts earlier than most distributors and quickly advise regular customers. This level of supply chain management helps us guarantee consistent throughput to major manufacturing centers and research labs worldwide.

    Challenges in Scaling and Innovating with Potassium Borohydride

    There’s no way around the challenges of scaling up production of challenging chemicals. If you’re running a small batch for custom synthesis, you might not run into the bottlenecks of moisture pickup or heat-sensitive decomposition. At the scale we operate, every gram lost to in-plant breakdown or poor transfer represents real cost. We run periodic plant shutdowns for cleaning and maintenance, keeping corrosion and cross-contamination at bay. Our technical team invests in new drying technology, inert gas handling, and particle size control not only to serve customers better, but to control input costs and raise safety standards for everyone involved.

    We encounter companies asking for customized potassium borohydride blends—sometimes with added flow agents, sometimes gentle granulation for automated dispensers. We balance their requests with a firm understanding of shelf life, reactivity, and transport risks. No compound exists in a vacuum, so we work with external labs, regulatory specialists, and global customers to adjust formulation while meeting both quality assurance and supply chain needs.

    Training and safety outreach continue hand-in-hand with manufacturing improvements. We’ve hosted plant tours, on-site demonstrations, and online seminars for partners nervous about handling borohydride compounds. As interest grows in “greener” chemistry and alternative reductants, we explain the real-world impacts and tradeoffs from a manufacturer’s viewpoint: what options bring similar performance, which create new challenges, and why certain end-uses still require tried and true solutions like ours. This ongoing discussion with the technical and purchasing community keeps us sharp and relevant in a competitive field.

    Looking Ahead with Potassium Borohydride

    While new green chemistry trends push hard for alternatives to legacy reagents, potassium borohydride continues to show its stubborn value in several specialized areas. Recovery of catalyst metals, selective reductions without off-flavors or unwanted ions, and applications where predictable reactivity under gentle conditions matter still drive customer demand. We work closely with researchers testing electrocatalytic and continuous-flow reductions, bringing feedback into our manufacturing roadmap. Where possible, we pilot new production technologies that reduce waste and lower energy requirements without compromising quality.

    Transparency and technical documentation lead to better outcomes every day. From batch certificates detailing actual impurity levels to prompt technical support for troubleshooting, we believe these investments shorten the gap between what a supplier can do and what a customer truly needs. No one wants guesswork during critical synthesis or scale-up, so we work for shorter lead times, more precise analytics, and smoother delivery. Regular customer audits keep us honest and push us to keep delivering beyond promises in the data sheet.

    Chemical manufacturing is a long-haul race, not a sprint. Every container of potassium borohydride that leaves our gates carries behind it dozens of production, QA, and logistics improvements made over years of listening to our industrial partners. As chemistry continues to advance, and as new sustainability and performance requirements enter the market, we remain committed to delivering the highest quality and reliability in every batch. Our direct link to end-users, and our open approach to problem-solving, keeps potassium borohydride relevant, proven, and ready for the most demanding applications.