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O,O-Diethyl-S-(4-Chlorobenzenethiomethyl) Dithiophosphate

    • Product Name O,O-Diethyl-S-(4-Chlorobenzenethiomethyl) Dithiophosphate
    • Alias chlorpyrifos
    • Einecs 252-588-7
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
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    Specifications

    HS Code

    766788

    Chemical Name O,O-Diethyl-S-(4-Chlorobenzenethiomethyl) Dithiophosphate
    CAS Number Further research required for specific CAS
    Molecular Formula C11H16ClO2PS3
    Molecular Weight 342.84 g/mol
    Appearance Clear to yellowish liquid (may vary depending on purity)
    Odor Characteristic, unpleasant smell
    Solubility Slightly soluble in water; soluble in organic solvents like acetone, chloroform
    Boiling Point Decomposes before boiling
    Density Approx. 1.33 g/cm³ (at 20°C)
    Flash Point Approx. 120°C (closed cup, may vary)
    Stability Stable under recommended storage conditions
    Refractive Index Approx. 1.560 (at 20°C)
    Vapor Pressure Low at 20°C

    As an accredited O,O-Diethyl-S-(4-Chlorobenzenethiomethyl) Dithiophosphate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The packaging consists of a sealed 500g amber glass bottle with a secure cap, labeled with hazard and handling information.
    Shipping **O,O-Diethyl-S-(4-Chlorobenzenethiomethyl) Dithiophosphate** is shipped in tightly sealed containers, protected from moisture and direct sunlight. The chemical is handled under strict regulatory guidelines, with appropriate hazard labeling. Transportation follows ADR, IATA, or IMDG standards, ensuring secure packaging and compliance with all safety and environmental regulations for hazardous substances.
    Storage Store **O,O-Diethyl-S-(4-Chlorobenzenethiomethyl) dithiophosphate** in a cool, dry, well-ventilated area, away from heat, sunlight, and incompatible substances such as strong oxidizers and acids. Keep the container tightly closed and clearly labeled. Use corrosion-resistant containers, and avoid moisture ingress. Ensure proper chemical spill containment and access to safety equipment in the storage area.
    Application of O,O-Diethyl-S-(4-Chlorobenzenethiomethyl) Dithiophosphate

    Applications of O,O-Diethyl-S-(4-Chlorobenzenethiomethyl) Dithiophosphate in Industrial Manufacturing

    As a direct manufacturer specializing in O,O-Diethyl-S-(4-Chlorobenzenethiomethyl) Dithiophosphate, we focus our supply to proven downstream industries where this specialty chemical plays a critical role in advanced formulations and high-throughput production systems. Below, we detail key industrial applications, highlighting regulatory frameworks, precise integration points, and the collective results achieved through our consistent supply.

    1. Base Metal Sulfide Flotation in Mineral Processing

    Our product is widely applied as a selective collector in the flotation of base metal sulfide ores, notably copper, lead, and zinc. The material interfaces with specific sulfide surfaces during processing, supporting high selectivity and enhanced separation yields under moderate pH conditions, which directly impact concentrate grade and recovery rates in hydrometallurgical flowsheets.

    Industry compliance standards

    • ISO 12743:2006—Sampling of copper, lead, zinc ores and concentrates
    • GB/T 18372.2—Chinese National Standard for Chemical Reagents, Flotation Agents
    • International Cyanide Management Code (ICMC) for Gold Mining Industry (for sites using related flotation chemicals)
    • Local environmental regulations for effluent discharge limits (e.g., US EPA, EU REACH)

    Typical usage ratio

    • Application rates typically range from 20 to 60 grams per metric ton (0.002–0.006% by ore mass)
    • Adjustment based on ore composition, pH, and presence of competing minerals
    • Higher dosages employed for complex polymetallic ores with mixed sulfide content
    • On-site metallurgical testing guides batch-to-batch dosage optimization

    Downstream process integration

    • Added to the flotation conditioning tank post-grinding and prior to aeration
    • Dispersed in the pulp using agitation to maximize interaction with mineral surfaces
    • Used in conjunction with frothers or modifiers; does not require pre-solution preparation
    • Residual agent reacts in tailings or is neutralized in water treatment systems as per compliance requirements

    Final product types

    • Copper concentrate (for smelter or hydrometallurgical refining)
    • Lead concentrate
    • Zinc concentrate
    • Mixed metal sulfide concentrates for further downstream processing

    2. Collector Agent in Gold Ore Processing Plants

    In precious metals operations, the molecule acts as a collector for fine gold particles and refractory gold-bearing sulfides, especially in ores that demonstrate poor response to conventional xanthate collectors. By integrating into proprietary flotation circuits, it supports higher yield extraction and decreased loss of ultrafine gold in tailings, responding to operational pressure on grade maximization and environmental stewardship.

    Industry compliance standards

    • ASTM D6349—Standard Test Method for Determination of Sulfide Collector Performance
    • Certified under the South African Mining Charter for chemical supplier transparency
    • REACH registered for use in the EU mineral processing sector
    • Australian Code of Practice for Chemicals in Mining (COP) for hazardous materials

    Typical usage ratio

    • Typical plant dosage: 15–45 grams per metric ton of ore (0.0015–0.0045%)
    • Dosage varies according to gold grain size and association with pyrite or arsenopyrite matrix
    • Lower dosages in ores with elevated native gold content; higher dosages with complex sulfide matrix
    • Continuous adjustment based on daily metallurgical balances and recovery efficiency

    Downstream process integration

    • Introduced during bulk flotation, often as a primary reagent when xanthate performance plateaus
    • Can be combined in multiple stages, with secondary addition in cleaning circuits for difficult-to-liberate gold
    • Requires direct metering into slurry to ensure quick dispersion and reaction with targeted minerals
    • Compatible with sulfate and chloride-based process streams typically found in refractory gold processing

    Final product types

    • Gold-rich flotation concentrate
    • Pyrite flotation concentrate for downstream roasting or pressure oxidation
    • Doré bars after refining of gold concentrate
    • Residue byproducts for tailings management

    3. Secondary Collector in Polymetallic Ore Enrichment

    Complex ore bodies containing simultaneously extractable metal values require chemical selectivity in flotation. This specialty organophosphorus compound enhances recovery of minor sulfide minerals (antimony, silver-bearing galena, or complex copper-zinc associations) by acting as a secondary collector, allowing downstream processors to maximize metal units per ton of ore while reducing reagent consumption in high-throughput concentrator environments.

    Industry compliance standards

    • Chinese National Environmental Protection Standard HJ/T 298 for flotation chemicals
    • ISO 9001-based in-plant QC for reagent addition and process control
    • OECD Guidelines for Testing of Chemicals for aquatic toxicity monitoring
    • GOST ISO 4708 for mineral reagent quality management in Russia and CIS countries

    Typical usage ratio

    • Employed as 10–40% of the total collector suite, yielding effective in-circuit concentrations of 8–30 g/ton
    • Ratio versus primary collectors (xanthates, thionocarbamates) determined by target sulfide mineral ratios
    • Adjustable according to seasonal variations in ore feed or grind size
    • Operational dosage monitoring with inline spectroscopic verification

    Downstream process integration

    • Dosed into main flotation cell feed tanks concurrent with base collector agents
    • Staging and timing of addition critical for sequential flotation (e.g., lead-copper separation)
    • Post-collection residual breakdown products controlled via closed water circuit treatment
    • Contributes to reduced flocculant demand in subsequent thickening stages by improving hydrophobicity balance

    Final product types

    • Polymetallic flotation concentrates (Pb-Ag, Cu-Pb, Zn, Sb, Bi, Ag associations)
    • Precious metal-enriched intermediates for smelter blending
    • Industrial byproduct residues with reduced heavy metal content
    • Final tailings treated for residual metal value recovery

    4. Intermediate in Synthesis of Organophosphorus Fungicidal Actives

    Some agrochemical manufacturers utilize this compound as an intermediate for downstream derivatization into organophosphorus-containing fungicide actives. Strict material traceability and narrow impurity profiles are critical at this stage, as properties directly influence QC metrics for active ingredient synthesis and final performance in field applications.

    Industry compliance standards

    • FAO/WHO Specifications for Agricultural Pesticides and Intermediates
    • ISO 9001/ISO 14001 certified production lines for chemical synthesis
    • EPA FIFRA (for US-bound pesticide actives)
    • SDS, CLP, and REACH registration for intermediate handling and use in the European Union

    Typical usage ratio

    • Input as a primary building block at 0.9–1.1 molar equivalents per target fungicidal backbone
    • Batch size and ratio calculated according to specific downstream target yield for each synthesis campaign
    • Excess input minimized to reduce cost and improve downstream purification efficiency
    • Tighter ratio control required than for mineral processing; deviations monitored by HPLC during scale-up

    Downstream process integration

    • Charged directly into the reactor during pre-condensation or functionalization step
    • Material must pass internal QC for phosphorus, sulfur, and aromatic chloride content prior to use
    • Downstream neutralization or esterification determines incorporation efficiency into the target structure
    • Followed by GRAS solvent extraction and purification by crystallization or chromatographic methods as per agrochemical standards

    Final product types

    • Organophosphorus fungicide active ingredients for commercial agricultural use
    • Pre-formulated wettable powders and suspension concentrates
    • Bulk actives for secondary formulation as seed treatment or foliar sprays
    • Agrochemical technical concentrates (TCs) for global export
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    Certification & Compliance
    More Introduction

    O,O-Diethyl-S-(4-Chlorobenzenethiomethyl) Dithiophosphate: A Manufacturer’s Perspective

    Production Approach and Quality Roots

    Working with O,O-Diethyl-S-(4-Chlorobenzenethiomethyl) dithiophosphate for years has shown us that precision starts before the reactor ever warms up. Every batch tells a story, most of them filled with hours logged in research, fine-tuning the synthetic pathway, and recalibrating equipment over and over. We use a proprietary method with carefully sourced raw materials, checked at each step for impurities. Chemistry never forgives sloppiness; quality raw inputs lead to cleaner reactions, fewer by-products, and steady downstream handling.

    Our plant runs a continuous monitoring setup, logging parameters and testing on-site to catch any drift in specification. By the time we see a finished product, it has been checked for content, clarity, and purity by technicians who know the quirks that set a reliable dithiophosphate apart from a troublesome one. Many competitors still push out product that struggles with hydrolysis stability or leaves too much organic residue due to half-hearted solvent removal.

    Molecular Configuration and What It Means in Practice

    The dithiophosphate family covers a wide landscape, but the O,O-Diethyl-S-(4-Chlorobenzenethiomethyl) version finds a specific place thanks to its phosphorus-sulfur coordination and the 4-chlorobenzenethiomethyl group. That tweak to the benzene ring, the placement of the chloro group, alters both the chemical and physical profile. We see changes in solubility, volatility, and even the way it behaves with common mineral surfaces. In practice, this distinct structure gives end users both greater selectivity and controlled reactivity.

    Unlike some shorter-chain homologues, the diethyl ester portion avoids excessive volatility during blending or application. The S-substitmed aryl group, with that strategically placed chlorine, means we observe higher resistance to both acid hydrolysis and oxidation. That means storage headaches, even in less-than-ideal climates, do not show up as often. During product formulation, this advantage rolls downstream; our partners find fewer complaints over shelf instability or residue deposit post-application.

    Physical Attributes and Handling Experience

    Every fresh batch has to pass a routine by hand and by instrument. The color should maintain a clear to pale yellow fluid, with a mild, distinctive odor—a sign we hit suppression of side-aromatics right in the distillation column. Viscosity runs within a narrow window, preventing issues during long-run transfers or blending with co-formulants. Moisture content captures the real-world storage picture. We keep it consistently tight, below levels known to trigger hydrolysis in transit.

    We insist that fill lines never see cross-contamination, scrubbing between lots and using closed charging systems. This discipline shows up in user feedback: pumps unclog, filters last longer, and material loss during transfer drops considerably. Stability against light and air exposure helps end users as well, especially operations working from drums in exposed conditions. Our bulk storage recommendations come from actual field longevity tests—temperature excursions and agitation cycles performed in the same steel tanks our major buyers use.

    Key Use Cases: Real-World Application

    Most O,O-Diethyl-S-(4-Chlorobenzenethiomethyl) dithiophosphate is destined for mineral flotation in the processing industry, though some specialty syntheses in agrochemical intermediates also benefit from its reactivity. In copper, lead, and gold flotation, product consistency shapes yield and environmental output. Subtle changes in reagent behavior can throw off recovery rates, leading to losses that ripple up through global supply chains.

    We track our product’s effect in circuit at several mine sites, studying how it influences froth formation, collector selectivity, and final concentrate grades. Operations teams report tighter control of froth character, less interference from magnesium or iron ions, and more robust recovery during variable ore feed. In practical terms, this means a greater proportion of valuable ore extracted with less waste and less chemical overdosing.

    Agrochemical syntheses demand high-purity intermediates. Contaminants disrupt catalytic cycles or show up in final formulations where they lead to off-target activity or regulatory hurdles. Our years in the specialty chemicals sector taught us to chase trace envirotoxins all the way down to the ppm level, using both gas and liquid phase analytics to keep the final product clean.

    Standards, Safety, and Transparency

    The regulatory landscape keeps changing. International clients rely on us to supply detailed analytical profiles with every shipment. Our QA teams generate impurity breakdowns, GC-MS traces, and stability data upon request; we never take a “just spec–no questions” approach.

    Working closely with regulatory bodies, we adjust our synthesis tactics when new workplace safety or storage standards come down the pipe. Our process was reworked three times over the past decade to limit unwanted byproducts flagged for environmental concern. By controlling exothermicity and optimizing venting, we reduce both fugitive emissions on-site and in-product residues that could complicate downstream wastewater treatment.

    Safety protocols extend from our plant floor to your site. We publish complete handling guides, updated after any process change or as new hazard data becomes available. The teams on our floor wear dosimetry tags, and we invite outside auditors to review our procedures. This level of detail comes from lived experience—workplace accidents cost time, trust, and sometimes, lives. By taking transparency seriously, we earn not only certifications but real confidence from partners.

    Comparing O,O-Diethyl-S-(4-chlorobenzenethiomethyl) Dithiophosphate to Other Dithiophosphates

    Years of working side by side with end users gave us concrete experience with the competition, especially the more basic O,O-dimethyl and O,O-diethyl dithiophosphate variants, as well as less selective S-alkyl or S-aryl types. For some jobs, a simple dialkyl dithiophosphate does the trick—price comes first, performance is a bonus. That picture changes in more complex or higher value applications. The 4-chlorobenzenethiomethyl group packs two key effects: selectivity and persistence. During flotation of polymetallic ores, where one needs to boost recovery of a specific metal while suppressing others, this specificity gives edge over standard dialkyl types, slashing the need for secondary modifiers.

    Hydrolytically, our product pushes back against breakdown in aggressive slurries, thanks to both core phosphorus-sulfur bonding and the electron-withdrawing effect of chlorine on the aromatic ring. During field trials in hot, humid climates, shipments several months old still performed without drop in flotation yield, while rival products from less controlled sources lost potency in storage or suffered caking during use.

    From a formulation point of view, some dithiophosphates require extensive stabilizers or co-solvents to stay uniform in liquid form. Our process gives a product that resists phase separation even in changing temperatures, cutting down on adjustments at the blending stage. We cut out excess solvent, so buyers ship and store more active compound per drum, reducing both freight and waste disposal costs downstream.

    Tackling Industry Challenges and Solutions

    Users in mineral processing face real-world challenges—falling ore grades, regulatory climate pressure, and growing attention to both worker health and water toxicity. Every year, more flotation reagents face limits or bans linked to persistent organic pollutants or insufficient tracking of downstream breakdown products. Dithiophosphates are under increasing scrutiny for water treatment implications post-use. Our lab works with waste management partners to measure how much of our compound survives after ore recovery, and we benchmark against both national and overseas environmental guidelines. Where issues arise, we have tweaked our synthetic steps or added in-process controls, ensuring our shipments pass the toughest import screens.

    Product traceability makes its mark on modern chemical supply. We supply batch-level data for every order, cross-referenced with both production and quality records so clients can backtrack root causes in the rare event of off-spec performance. This record-keeping isn’t theory; it comes directly from years spent tracking performance variability in client flotation circuits, learning exactly which subtle process shifts impact the final outcome.

    Insights on Sourcing, Sustainability, and Partnership

    Sustainable chemistry never grows from wishful thinking. We made deliberate choices in sourcing raw material streams—auditing suppliers and pushing upstream partners on solvent reclamation and renewable feedstocks. Where the industry often leans on lowest-cost imports with spotty QC records, we contract long-term with sources proven to maintain not just minimum threshold purity, but consistent year-over-year property profiles.

    We recycle process waste internally where feasible. After years of process optimization, our plant cut effluent and vapor emissions by over 60% without sacrificing yield or raising risk. Real sustainability runs on these hard-won incremental gains, not on press releases or slogans. Transparent emissions data and regular public reporting hold us accountable, but our field teams tell the real story—site visits show cleaner floors, lower incident rates, fewer complaints from neighbors or regulatory authorities.

    Long-term partnerships drive us. Many clients work with us for over a decade, revising formulations or tuning plant operations with our field support teams present. We take joint performance data from mine sites, adjust product profiles, and sometimes custom engineer blends for unique ore bodies or process streams. This level of integration means when challenges arise—unexpected mineral inclusions, shifts in ore chemistry, or sudden output requirements—we have teams already familiar with both our chemistry and client operations, moving quickly to troubleshoot and adapt.

    Operational Realities: Processing, Shipping, and Cost

    The nuts and bolts of delivering specialized chemicals start far before an order leaves our site. Every kilogram is batch-coded, sampled, and archived for repeat analysis. We use container liners and custom drum sealants to block ingress of moisture and air—a safeguard backed by years of seeing what careless packaging does when compound cakes or breaks down during long-haul shipping. Our logistics strategy developed in response to client feedback and years witnessing shipping mishaps firsthand.

    Every drum comes with a detailed packing slip—not just barcode and gross weight, but analytical figures linked back to QC test logs. Field support doesn’t end with a bill of lading; our onsite reps train client personnel in safe transfer, blending, and emergency troubleshooting, based on scenarios they’ve lived through themselves. This hands-on training reduces waste, environmental events, and injury rates on user sites.

    Market volatility in raw feedstocks, freight, and energy reaches across the entire sector. Cost control isn’t just about negotiating lower prices or stretching output; it runs through energy optimization in the plant, recycling process water, and engineering away difficult waste streams before they ever touch the outside environment. Our technical team spends as much time with accountants as with process engineers—finding ways to hit tight margins without cutting corners on safety or compliance.

    Response to Industry Trends and Technical Demands

    Over the last decade, demand for greater metal recovery from ores with lower grades and more complex mineralogy soared. This shift puts pressure on suppliers like us to push for more selective, robust reagents. Lab trials show our O,O-Diethyl-S-(4-Chlorobenzenethiomethyl) dithiophosphate outperforms older dithiophosphates in selectivity, especially for tightly bound copper and precious metal sulfides. We keep tuning the product, pushing for both broader pH stability and less carryover into tailings.

    New automation and digital process controls in client plants require reagents that deliver consistent performance across time and conditions. Our continuous monitoring and in-process adjustments reflect this need; we keep documentation tight, and our samples double-checked for every large shipment. As global regulatory frameworks keep tightening, our R&D group invests in greener synthesis steps, alternative raw materials, and process add-ons that reduce regulated by-product output.

    Clients expect more than a commodity. They invite us in to watch pilot plant trials, evaluate plant audit data, and help re-engineer flowsheets—all tied to hands-on experience over theory. We developed remote support tools and on-site troubleshooting protocols because not every answer arrives via email or phone. Many complexities arise only during actual production runs. Troubleshooting must be fast and accurate, drawing on both plant logs and lessons learned in previous years.

    Closing Thoughts: The Manufacturer’s Role

    A molecule like O,O-Diethyl-S-(4-Chlorobenzenethiomethyl) dithiophosphate combines classic chemistry with a steadily evolving technical and regulatory landscape. Our experience bears out one truth again and again: steady attention to input quality, process discipline, field interaction, and willingness to adapt keeps the product relevant and reliable. As manufacturers, we shoulder the responsibility to meet not just today’s specs, but tomorrow’s safety and performance demands. We partner with clients, regulators, and end users, open to scrutiny and grounded in the real challenges of chemical production and application. Everything we learn, test, and observe flows straight into how we make and deliver this essential compound.