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N-Butyl Nitrate

    • Product Name N-Butyl Nitrate
    • Alias n-Butyl nitrate
    • Einecs 209-602-6
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    410231

    Chemical Name N-Butyl Nitrate
    Molecular Formula C4H9NO3
    Molar Mass 119.12 g/mol
    Cas Number 928-45-0
    Appearance Colorless liquid
    Boiling Point 108°C (226°F)
    Density 0.991 g/cm3 at 20°C
    Flash Point 6°C (43°F)
    Solubility In Water Slightly soluble
    Odor Sweet, fruity
    Refractive Index 1.414 at 20°C
    Vapor Pressure 24 mmHg at 25°C

    As an accredited N-Butyl Nitrate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing N-Butyl Nitrate is packaged in a 500 mL amber glass bottle with a secure screw cap and safety hazard labeling.
    Shipping N-Butyl Nitrate is shipped as a hazardous material due to its flammability and explosive potential. It must be packaged in approved, tightly sealed containers, kept away from heat, ignition sources, and incompatible substances. Transportation follows regulations for hazardous chemicals, with appropriate labeling, documentation, and handling by trained personnel to ensure safety.
    Storage N-Butyl Nitrate should be stored in a cool, dry, and well-ventilated area away from heat, sparks, open flames, and sources of ignition. It must be kept in tightly sealed containers compatible with nitrates and separated from strong acids, bases, oxidizers, and reducing agents. Proper labeling and explosion-proof electrical equipment are necessary due to its flammability and potential for explosive decomposition.
    Application of N-Butyl Nitrate

    Applications of N-Butyl Nitrate in Industrial Manufacturing

    As a direct manufacturer of high-purity N-Butyl Nitrate, we support leading global industries with consistent, specification-driven material for precise downstream applications. Our technical expertise ensures that all end uses comply with market access requirements, safety regulations, and bespoke production demands in their respective sectors.

    1. Energy Sector: Propellant and Explosives Formulations

    N-Butyl Nitrate plays a pivotal role as an energetic plasticizer and fuel component in the synthesis of double-base propellant systems, smokeless powders, and explosive compositions. Its high oxygen content and volatility enhance the energetic yield, critical for defense and civilian blasting applications. Manufacturers require meticulously controlled nitrate additions for safe processing and reliable performance during the extrusion, molding, and stabilization stages of energetic material production.

    Industry compliance standards

    • United Nations Recommendations on the Transport of Dangerous Goods (UN Model Regulations)
    • Council Directive 93/15/EEC on Civil Explosives (EU)
    • US Department of Defense MIL-STD-286
    • REACH Regulation (EC) No 1907/2006 (Annex XVII restrictions for energetic materials)

    Typical usage ratio

    • Ranges from 5% to 25% by weight in composite propellant and blasting gelatin formulations; process engineers adjust the ratio based on target burn rates, temperature sensitivities, and desired stability.

    Downstream process integration

    • Incorporated during the blending phase alongside nitrocellulose, nitroglycerin, and stabilizers, followed by wet granulation and vacuum drying. Typically mixed in controlled environments with designated static discharge prevention protocols.

    Final product types

    • Industrial detonators
    • Mining explosives (emulsion and gelatinous types)
    • Propellant grains for ammunition
    • Specialized rocket and missile solid fuel cartridges

    2. Chemical Synthesis: Intermediate for Pharmaceutical Manufacturing

    Within active pharmaceutical ingredient (API) and specialty chemical synthesis, N-Butyl Nitrate serves as a selective nitrating agent for introducing nitro functionalities to complex molecules. Its controlled reactivity supports downstream steps in the preparation of vasodilators and diagnostic intermediates. Manufacturers apply detailed process validation to manage purity, minimize by-products, and ensure batch consistency in accordance with pharmaceutical cGMP frameworks.

    Industry compliance standards

    • International Council for Harmonisation (ICH Q7: Good Manufacturing Practice for APIs)
    • US Pharmacopeia (USP) general chapters on chemical purity
    • EU GMP Directives (EudraLex Volume 4)
    • Chinese Pharmacopoeia (ChP) for precursor chemicals

    Typical usage ratio

    • Typically 0.5–5 molar equivalents relative to target substrate; chemists fine-tune based on the specific nitration reaction’s selectivity and scale.

    Downstream process integration

    • Meticulously charged in jacketed glass-lined reactors or continuous-flow systems during the nitration of phenolic or heterocyclic intermediates, followed by quenching, aqueous workup, and multi-step purification.

    Final product types

    • Vasodilator API intermediates (e.g., nitrate esters)
    • Pharmaceutical diagnostic reagents
    • Nitrated specialty chemicals for research
    • Contrast agents for imaging studies

    3. Lubricant Additives: Antiknock and Combustion Improver Production

    Refiners and fuel additive blenders utilize N-Butyl Nitrate in the production of cetane enhancers and antiknock agents for diesel, gasoline, and aviation fuels. Its oxygen-rich structure enables more complete combustion, resulting in lower emissions and higher engine efficiency. The additive is fed into injection blending and batch mixing units under strict QA oversight to ensure that fuel blends remain within specifications imposed by regulatory authorities.

    Industry compliance standards

    • ASTM D975 (Standard Specification for Diesel Fuel Oils)
    • EN 590:2013+A1:2017 (European diesel fuel requirements)
    • US EPA Fuel Additive Registration (40 CFR Part 79)
    • SOCMA Product Stewardship standards

    Typical usage ratio

    • Dosage typically ranges from 0.1% to 2% by volume, based on base fuel properties and mandated environmental performance limits.

    Downstream process integration

    • Added to finished or blending stock fuels during secondary refining or post-desulfurization blending using inline metered dosing equipment, monitored for homogeneity and stability over long-term storage.

    Final product types

    • Commercial diesel additive packages
    • Automotive gasoline formulations
    • Aviation piston engine fuel blends
    • Marine fuel combustion improvers

    4. Analytical Applications: Laboratory Reagents and Standards

    Technical-grade N-Butyl Nitrate enables laboratories to prepare reference materials and calibration solutions used in analytical chemistry for the determination of nitroester compound behavior, trace detection in food safety, and forensic toxicology. Consistency of purity and composition is critical, as is compliance with ISO-driven laboratory management systems. Material input is fully traceable for certified analysis workflows.

    Industry compliance standards

    • ISO/IEC 17025:2017 (General requirements for testing and calibration laboratories)
    • OIML R 76 (International Recommendation for Laboratory Balance Calibration)
    • AOAC International Official Methods of Analysis
    • Good Laboratory Practice (GLP) Guidelines (OECD Series on Principles of GLP)

    Typical usage ratio

    • Aliquots of 1–1000 ppm in solvent matrices for standard preparations; dilution levels are set according to detection range and analytical protocol.

    Downstream process integration

    • Prepared onsite in dedicated chemical handling rooms, dissolved into solvent carriers for generation of calibration curves, instrument response standards, and method validation solutions.

    Final product types

    • Certified reference calibration standards
    • Instrument check samples for nitroester quantification
    • Analytical reagents for food, environmental, and forensic detection
    • Quality assurance proficiency testing kits

    5. Specialty Coatings: Additive for Pyrotechnic and Signal Compositions

    Within the specialty coatings and pyrotechnics sector, N-Butyl Nitrate is formulated as an oxidizing additive in colored flare, smoke signal, and tracer compound coatings. Its role as a fast-decomposing nitrate provides vivid luminosity, steady burn characteristics, and rapid initiation properties, tailored for controlled release devices. The integration process requires live monitoring of exothermic reactions and is subject to regulatory limits for safe handling.

    Industry compliance standards

    • EN 16263 (Pyrotechnic Articles – Safety requirements, EU)
    • US Code of Federal Regulations Title 49 (49 CFR Part 172 – Hazardous Materials regulations)
    • NFPA 1124 (Code for the Manufacture of Fireworks and Pyrotechnic Articles)
    • International Maritime Dangerous Goods (IMDG) Code for shipping finished products

    Typical usage ratio

    • Between 3% and 10% by formulation weight, dependent on color formulation, burn profile, and effect duration desired by the end user.

    Downstream process integration

    • Blended into pyrotechnic mixes in sheared mixers or rotary tumblers, introduced during binder incorporation before extrusion or pelletizing, followed by curing and moisture-controlled packaging.

    Final product types

    • Hand-held signal flares
    • Smoke generators for marine and railway use
    • Tracer round coatings for ammunition
    • Colored pyrotechnic star shells
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    Certification & Compliance
    More Introduction

    N-Butyl Nitrate: Manufacturer Insights on Production, Quality, and Practical Use

    Creating Reliable Chemical Solutions: N-Butyl Nitrate

    Decades in the manufacturing of energetic chemicals have taught us to focus on purity, consistency, and hands-on process supervision. N-Butyl Nitrate has remained a cornerstone of our specialty nitrate production line, standing out for its unique reactivity and handling characteristics. In our operation, we work directly from raw n-butanol and concentrated nitric acid, giving us direct control over the reaction conditions and purification steps. This attention to detail underpins the quality that our downstream customers rely on, particularly across laboratory synthesis projects, propellant research, and specialized fuel formulations.

    N-Butyl Nitrate appears as a clear, pale and low-viscosity liquid, with a mild, distinctive sweet odor familiar to folks handling organic nitrates in industrial settings. Our typical product specs aim for an assay over 99.5%, achieved with continuous-flow reactors and a carefully staged extraction process. The final material is filtered and dried under reduced pressure, minimizing residual moisture and potential decomposition triggers. Every batch passes rigorous GC and IR spectral checks, as nitration byproducts or unreacted alcohol undermine both safety and reproducibility for downstream applications.

    Why N-Butyl Nitrate Gets Chosen – Manufacturer’s Perspective

    Demand for N-Butyl Nitrate comes mostly from customers looking for more than just a nitro compound—many are working with experimental formulations that leave little margin for chemical inconsistencies. There’s a clear separation between N-Butyl Nitrate and classic alkyl nitrates like isoamyl or ethyl nitrate, both in handling and in end performance. The straight-chain butyl structure shifts physical properties: it offers higher boiling point, a touch more stability in storage, and lower volatility, which matters when users scale up their work or attempt to avoid evaporative losses. This small structural difference reduces the likelihood of unplanned exothermic events during routine handling.

    Commercial and laboratory users often comment on the ease of blending N-Butyl Nitrate into liquid matrices, versus cloudier or unpredictable mixing from shorter alkyl nitrates. We hear regular feedback from labs on the reproducibility of esters and custom nitrate syntheses, with N-Butyl Nitrate providing a predictable reactivity profile. Its relatively low water solubility, compared to methyl nitrate or ethyl nitrate, cuts down the risk of unwanted side reactions, especially in multi-step processes where residual water can become a nuisance.

    Performance and Precision: Meeting Tight Requirements

    Our staff on the production floor work in small teams, walking lines of glass and stainless reactors. They make real-time adjustments informed by experience—relying on color, temperature curves, and pressure readings as much as on lab analytics. N-Butyl Nitrate’s preparation doesn’t forgive shortcuts, so we keep process parameters tight. A few degrees too high on the reaction or excess retention of acid can wreck a batch, turning a clear liquid into a murky, hazardous mass unfit for customer delivery. We train each hire on the telltale signs and establish redundancy in document checks, so that only material passing our visual and instrumental benchmarks leaves the site.

    One of the biggest challenges stems from the chemical’s sensitivity to trace impurities. For example, minor amounts of butyl nitrite, a known side product, complicate downstream synthesis and can trigger regulatory headaches during storage and shipping. We draw on in-house expertise to fine-tune the distillation cuts, recycling off-fractions until the assay meets what pharmaceutical clients and R&D teams specify. Operators consult archived run data whenever fluctuations appear, a benefit of our vertically integrated approach: by running each step ourselves rather than outsourcing, we spot trends before they become quality risks.

    Handling and Safety—The Real-World Balancing Act

    Daily use of N-Butyl Nitrate brings a safety focus that’s never just a checklist. Regulars at chemical processing benches know that organic nitrates call for vigilance. Our plant design prioritizes ventilation, small-batch runs, and static controls—details that don’t show up on data sheets but make the difference in long-term, incident-free operation. Our teams cycle through regular drills: controlled leak scenarios, hot plate management, and even mock-outs of spill responses. People learn firsthand how temperature and containment factor into the stability of nitro compounds, so that muscle memory backs up written protocols.

    N-Butyl Nitrate, in competent hands, rewards care and preparation with dependable results. Its storage limits mirror those of other nitrate esters—cool, dry, and secure. Still, the higher molecular weight and increased boiling point help prevent the kinds of fume build-up and vapor phase incidents seen with lighter analogues. Field experience has shown us that with proper sealed storage and routine venting schedules, product longevity outpaces that of lower alkyl nitrates, especially under warehouse conditions where perfect temperature control isn’t always practical.

    Differentiating N-Butyl Nitrate in the Lab and Plant

    Technicians and formulating chemists often compare N-Butyl Nitrate directly with its close relatives—methyl, ethyl, and amyl nitrates. The key distinguishing marks go beyond simple chemical structure. N-Butyl Nitrate’s flash point, volatility, and reaction rate set it apart, permitting safer handling during research or bulk blending. Over many years, teams at our facility have noted that the butyl group’s extra carbon atoms confer greater liquid phase stability and reduce vapor pressure under room conditions.

    End users in propellant and energetic material labs often mention batch-to-batch reliability as a major deciding factor. Lower flash point products, while once favored for specific ignition requirements, present flammability risks that modern health and safety standards seldom permit. N-Butyl Nitrate offers the energetic punch needed, but with a wider safety margin for modern, closed-process operations. New formulations for fuel additives in aerospace rely on these properties as engineers look to replace problematic nitroparaffins, benefitting from N-Butyl Nitrate’s balance of performance and storage safety.

    Feedback from Users and Adjusting to Evolving Standards

    Our technical support staff spend considerable time interacting with process engineers and lab scientists at customer sites. We value straight talk and specific complaints—issues around trace acidity, sample homogeneity, or mission-critical failures. Over the past decade, pressure from environmental and workplace safety regulators has prompted both us and our customer base to rethink solvents, additive packages, and contaminant thresholds. N-Butyl Nitrate, due to its handling advantages and demonstrable performance, continues to see recommendation from multiple sectors adapting to fresh compliance rules.

    We’ve collaborated with teams in defense research and engine development that found certain nitrate esters no longer pass updated transportation rules. Usually, our N-Butyl Nitrate met those evolving guidelines due to its moderate vapor pressure and reduced acute toxicity. By investing in packaging innovations—double-seal drums with vapor barriers—and employing real-time monitoring of shipment conditions, we keep incidents rare and supply windows tight enough to meet project schedules. On tough regulatory issues, we work with both local and international bodies to update our internal procedures rather than wait for new laws to force change.

    Waste Handling, Environmental Concerns, and Sustainable Manufacturing

    Every production lot of N-Butyl Nitrate generates acid waste and off-gas. Manufacturing teams have installed closed-loop nitric acid recovery, ensuring we reclaim as much reactant as possible. Residual acid undergoes neutralization on-site before transfer to licensed handlers. Over the years, we’ve transitioned older open-flow production to fully contained systems, reducing operator exposure and improving product consistency. The investment in improved waste neutralization has paid off in both cost savings and environmental compliance, keeping our permitted discharge levels well within accepted local limits.

    Customers with sustainability requirements find it helpful that N-Butyl Nitrate synthesis, when run in optimized batches, produces minimal run-off compared to larger-scale nitrate-based explosives manufacturing. The relatively compact batch sizes also mean lower overall emissions from each run. While no nitrate production achieves zero impact, full tracking and reporting allow us to document progress in reducing solvent use, targeting full recycling of compatible wash streams, and steadily tightening energy use per kilogram output.

    New Developments and R&D: Addressing Market Gaps

    As producers, we don’t simply react to standard orders; periodic direct engagement with end-users and R&D partners helps us anticipate shifting industry needs. In recent years, expanded research into nitrate esters for cleaner propellants and alternative fuels has highlighted N-Butyl Nitrate’s value as both a fuel additive and a controlled booster in multi-component formulations. Our technical teams run pilot-scale simulations of customer processes, benchmarking our N-Butyl Nitrate’s performance in real system blends.

    Feedback from project teams experimenting with composite explosives or dual-phase propellants has been instrumental in shaping our purification and packaging choices. We’ve tailored drying and filtration steps so that residual acidity stays below limits required for specialized applications. Our rigid analytical controls stem from years troubleshooting subtle issues—decomposition at higher storage temperatures, crystallization inside transfer lines, unwanted coloration, or gradual vapor leaks. When these challenges appear in a research lab, a single failed experiment can cost weeks or months; for us, preventing such outcomes is a matter of reputation.

    Practical Considerations for Purchasing and Transport

    Buyers—not middlemen—identify the pain points in sourcing N-Butyl Nitrate: secure packaging, reliable ship dates, and full traceability from origin. Production lines remain subject to seasonal variations in raw material supply, but in-house stockpiling and flexible batch runs give us enough leeway to weather the usual bottlenecks. For time-critical projects, we work directly with shipping agents experienced in handling regulated energetic materials, tracking each consignment end-to-end regardless of destination.

    Our in-house documentation—COA, detailed batch analytics, storage recommendations—follows the shipment, and technical staff stand ready to answer follow-up questions, from intended use in synthesis to troubleshooting storage. Users appreciate that orders come from the actual facility crafting each liter, not repackaged or delayed through trading networks. When batch variability arises—slightly wider boiling range, marginal discoloration under certain lights, minor shifts in viscosity—we speak plainly about the reasons and work with buyers to sort out how such variations may affect planned use.

    The Role of Experience in Manufacturing N-Butyl Nitrate

    Years of operation have shown us that expertise in handling raw feedstocks, understanding seasonal differences in acid strength, and knowing how various impurities sneak in can’t be replaced by automated systems alone. Operators pass on the subtle tricks: which glassware to avoid, how to cut off distillation at the sweet spot, and when a shift in odor hints at decomposition risk. These lessons come from real incidents and the iterative troubleshooting that goes into every specification update.

    Customers trust producers who put knowledge into practice, adapting to challenges such as odd requests—smaller batch splits, extra certifications, or tight analytic tolerances. Our staff reviews each query with the understanding that practical experience beats theory, especially with a compound whose properties change quickly under imperfect conditions. In training programs, we run sample failures on purpose, letting every member see how even clean-looking product might fail later if respect for the process lapses.

    Supporting Innovation While Maintaining Reliability

    Markets for nitrate esters like N-Butyl Nitrate are shaped by new project demands as well as mature applications. We work with advanced research teams in energetic materials, seeking to extend the use of N-Butyl Nitrate into areas once occupied by less stable or more toxic compounds. The manufacturer’s unique role involves translating specification sheets into actionable, repeatable processes; it’s not enough to claim purity—every user wants confidence their results will stack up across repeat batches. Practical differences from products like amyl nitrate or methyl nitrate lie in the details: lower vapor emissions, manageable flash points, and less aggressive odor.

    Some clients use N-Butyl Nitrate for pilot-level research, where scaled-up hazards or regulatory constraints rule out other choices. Its liquid state at room temperature, plus compatibility with a wider range of nonpolar solvents, makes it a flexible option for experimental propellants and specialty fuels. In every scenario, direct feedback informs our next round of process improvements—whether that means shifting to higher-purity acid sources or tweaking process flows to address emerging customer challenges.

    Conclusion: Built on Experience, Delivered with Assurance

    Producing N-Butyl Nitrate at industrial scale demands patience, vigilance, and a constant willingness to adapt. Our people, processes, and equipment are tuned to the real requirements researchers and specialty manufacturers face every day—reliability, safety, and transparency above all. Whether a laboratory needs a few liters for a custom synthesis or a defense project requires consistent, high-assay lots for long-term work, we engage with every customer as a direct partner in problem-solving.

    The story of N-Butyl Nitrate is one of collaboration between hands-on chemical producers and innovators at the frontlines of science and industry. Every step, from raw butanol to tightly-sealed product drum, reflects contributions from operators, analysts, and technical specialists who know their work matters down to the last detail.