Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing admin@sinochem-nanjing.com 3389378665@qq.com
Follow us:

Methanethiol

    • Product Name Methanethiol
    • Alias Methyl mercaptan
    • Einecs 200-852-2
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    495782

    ChemicalName Methanethiol
    MolecularFormula CH4S
    MolarMass 48.11 g/mol
    CASNumber 74-93-1
    Appearance Colorless gas
    Odor Strong, unpleasant, rotten cabbage-like
    BoilingPoint 6°C (43°F)
    MeltingPoint -123°C (-189.4°F)
    Density 0.867 g/L (at 0°C, gas)
    SolubilityInWater Slightly soluble
    VaporPressure 1.81 atm (at 20°C)
    FlashPoint -18°C (closed cup)
    AutoignitionTemperature 354°C (669°F)
    RefractiveIndex 1.353 (liquid at 20°C)
    UNNumber 1064

    As an accredited Methanethiol factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Methanethiol is packaged in a sealed, amber glass bottle with a secure cap, labeled 100 mL, and includes hazard warnings.
    Shipping Methanethiol is shipped in tightly sealed, corrosion-resistant containers, typically steel cylinders, under pressure. Transport follows strict hazardous materials regulations due to its flammability, toxicity, and strong odor. Shipping labels must display UN 1064 and appropriate hazard warnings. Proper ventilation and secure handling procedures are essential during transit to ensure safety.
    Storage Methanethiol should be stored in tightly closed, properly labeled containers in a cool, well-ventilated, and dry area, away from sources of ignition, heat, and incompatible substances like oxidizers. The storage area should be equipped with appropriate ventilation and explosion-proof equipment. Containers must be protected from physical damage and securely sealed to prevent leaks, as methanethiol is flammable and has a strong, unpleasant odor.
    Application of Methanethiol

    Applications of Methanethiol in Industrial Manufacturing

    Methanethiol, as produced by our advanced synthesis facilities, plays a critical role in specialized industrial processes where sulfur incorporation, reactivity, and sensorial impact are essential to product quality and performance. Below we detail principal real-world manufacturing scenarios, based on verified downstream sector usage, operational parameters, and regulatory oversight.

    1. Animal Feed Additives (Methionine Synthesis)

    Feed-grade methionine production relies on methanethiol as a fundamental sulfur donor during the chemical synthesis of the essential amino acid. This route remains predominant in large-scale facilities aimed at serving global poultry, swine, and aquaculture feed markets. Process controls maintain precise handling to minimize contamination and ensure consistent product purity in line with animal feed regulations.

    Industry compliance standards

    • FAMI-QS Certification (Feed Additive and Premixtures Quality System)
    • EU Regulation (EC) No 1831/2003 on additives for use in animal nutrition
    • FDA 21 CFR 573.920 (Methionine activity in animal feed)
    • ISO 22000:2018 (Food safety management for feed ingredients)

    Typical usage ratio

    • Approximates 0.85–1.05 molar equivalents as a sulfur source per mol of key intermediates
    • Final dose adjustment depends on process stoichiometry and optimization data

    Downstream process integration

    • Reacted with acrolein and hydrogen cyanide during hydrothiolation in the core methionine synthesis route
    • Controlled transfer to batch reactors under inert atmosphere to prevent oxidative losses
    • Post-reaction neutralization and separation steps for downstream amino acid purification

    Final product types

    • DL-methionine technical powder
    • L-methionine grade for water-soluble premixes
    • Methionine-chelated trace minerals
    • Amino acid concentrate feed additives

    2. Gas Odorization Compounds

    Methanethiol serves as a primary odorant in the safety marking of fuel gases such as natural gas and liquefied petroleum gas (LPG), enabling the detection of leaks in distribution networks by imparting a distinctive warning smell. We supply stabilized grades for direct injection into gas stream odorization skids and automated blending systems compliant with international norms for occupational safety and environmental release control.

    Industry compliance standards

    • EN 13725 (European standard for olfactometry and odorant dosing)
    • API 2510A (LP-Gas odorization guidelines, American Petroleum Institute)
    • NFPA 58 (Liquefied Petroleum Gas Code, odorization safety)
    • OSHA 29 CFR 1910.1200 (Hazard communication; odorant exposure limits)

    Typical usage ratio

    • 2–7 mg methanethiol per cubic meter of natural gas
    • Exact dosage tailored based on gas mixture, distribution system volume, and national olfactory threshold specifications

    Downstream process integration

    • Continuous metered addition at gas pipeline dosing stations
    • Centralized automated odorization systems, with periodic calibration to account for vaporization rates and substrate absorption
    • Routine QA sampling to monitor odorant persistence across network delivery points

    Final product types

    • Odorized piped natural gas for residential and industrial use
    • Safety-marked liquefied petroleum gas (LPG) for cylinder and bulk applications
    • Odorized biogas and renewable methane distribution lines

    3. Agrochemical Intermediates (Pesticide Synthesis)

    Several crop protection agents and fumigants demand methanethiol as a controllable sulfurating reagent or alkylthiolating building block within active pharmaceutical ingredient (API) synthesis. Applications focus on herbicide and insecticide active ingredient manufacturing under stringent quality assurance to prevent environmental byproduct contamination.

    Industry compliance standards

    • ISO 9001 (Quality management for fine chemical manufacturing)
    • FAO/WHO specifications for pesticide technical materials
    • REACH Regulation (EC) No 1907/2006, MSDS reporting for hazardous intermediates
    • GB 20810-2006 (Chinese standard for pesticide raw materials)

    Typical usage ratio

    • Ranges from 0.3–1.2 molar equivalents per synthesis step, dependent on specific active structure and substitution pattern

    Downstream process integration

    • Charge to closed stirred-tank reactors in the alkylthiolation or sulfuration stages
    • Closely managed reaction temperature and pressure to improve sulfur incorporation and minimize unwanted side-products
    • Followed by solvent extraction, distillation, and final formulation blending

    Final product types

    • Methomyl and related carbamate pesticide APIs
    • Thiadiazole-based fungicide intermediates
    • Herbicide thiomethylated actives
    • Sulfur-containing fumigant technicals

    4. Specialty Chemical Synthesis (Dimethyl Sulfide Production)

    Dimethyl sulfide (DMS) manufacturing facilities depend on methanethiol as a prerequisite starting material, with production lines configured for optimal conversion yield. DMS further supports applications in petrochemical cracking, as well as food-grade processing sectors.

    Industry compliance standards

    • ISO 14001 (Environmental management during volatile sulfur compound handling)
    • US EPA NESHAP standards for air emissions control (40 CFR Part 63)
    • GMP Guidelines for food-additive DMS (for food use segment)
    • REACH registered substance dossier for dimethyl sulfide

    Typical usage ratio

    • 1:1 molar ratio to methylating agent (methyl halide or methanol) in batch or continuous flow lines
    • Stoichiometry adjusted to balance process efficiency and downstream purification requirements

    Downstream process integration

    • Continuous gas-phase catalytic methylation in stainless steel reactors at elevated temperatures
    • Gas recovery units for side-stream recycling of unreacted precursors
    • Distillation and fractionation trains to isolate finished DMS with defined purity

    Final product types

    • Dimethyl sulfide (feedstock for petrochemical or food flavoring applications)
    • Downstream DMSO (dimethyl sulfoxide) technical grades
    • Industrial grade DMS blends for chemical synthesis

    5. Pharmaceutical Intermediate Manufacturing

    Methanethiol is integral in several active ingredient synthesis processes for pharmaceuticals, acting as a sulfurizing agent in the preparation of select thioether, thiazole, and related ring systems under validated production protocols. Our supply supports high-purity requirements for further synthesis of patented and generic medication precursors, audited by regulatory agencies.

    Industry compliance standards

    • ICH Q7 (Good Manufacturing Practice for Active Pharmaceutical Ingredients)
    • US Pharmacopoeia (USP) and European Pharmacopoeia monograph conformity, as applicable
    • FDA CFR Title 21 Part 210/211 (GMP requirements for finished pharmaceuticals)
    • EDQM guidelines for declared source materials

    Typical usage ratio

    • Precisely dosed at 0.2–1.0 molar equivalents, based on target thioether formation or ring closure requirements in API-specific routes

    Downstream process integration

    • Sequenced reagent addition during thiazole or thioether ring assembly stage, often under anhydrous conditions
    • Specialized addition techniques including microdosing and low-temperature feeds to control reaction exotherms
    • Follow-on workup and purification steps maintain pharmaceutical residue thresholds

    Final product types

    • Thiazole-based drug substance intermediates
    • Sulfur-containing API precursors
    • Bulk intermediates for further contract synthesis of generic pharmaceuticals
    Free Quote

    Competitive Methanethiol prices that fit your budget—flexible terms and customized quotes for every order.

    For samples, pricing, or more information, please call us at +8615371019725 or mail to admin@sinochem-nanjing.com.

    We will respond to you as soon as possible.

    Tel: +8615371019725

    Email: admin@sinochem-nanjing.com

    Get Free Quote of Sinochem Nanjing Corporation

    Flexible payment, competitive price, premium service - Inquire now!

    Certification & Compliance
    More Introduction

    Methanethiol: Experience from the Shop Floor

    Meeting Real-World Needs with Methanethiol

    Ask anybody who spends years in the business of making chemicals that shape industrial progress—they will tell you, a product’s worth comes down to what problems it solves. Methanethiol, sometimes called methyl mercaptan, backs up this claim in real everyday uses. We have made methanethiol for decades, not only because there is a market, but because entire production floors, wastewater facilities, and chemical transformation lines rely on its performance and consistency, day after day. Its reputation is not from glossy brochures; it is built on the trust of operators who know when things don’t smell right, something isn’t right.

    Understanding Methanethiol’s Role Across Industries

    Workers dealing with amino acid synthesis will recognize methanethiol as a linchpin, especially in the production of methionine, a vital amino acid for animal feed. Output reliability is critical—processes cannot stall. We gear our production lines to stabilize purity levels, generally at or above 99%, because amino acid manufacturers need consistency batch to batch. The model we supply comes as pressurized liquefied gas, delivered under carefully controlled conditions not simply because regulations demand it, but because leaks or contamination disrupt entire operations and present unacceptable risk.

    Gas odorization is another field where methanethiol stands apart. Utility providers purchase it for its recognizable, pungent scent—think of the smell associated with natural gas leaks. The goal here isn’t the gas itself, but safety. Pipelines and distribution networks add methanethiol in tightly measured doses so the public can detect leaks long before the risk escalates. It saves lives and millions in damage. Human noses detect methanethiol at parts per billion—sensitivity that far outruns fancy sensor arrays. Our methanethiol must show reliable dispersion characteristics; it cannot “stick” or cause fluctuating odor intensity as gas flows through old or new pipes. Care with storage tanks, valves, and transfer lines affects every batch. Experience teaches the differences that make the end result truly safe.

    Beyond those main uses, methanethiol fills roles in pesticide and jet fuel manufacture, where its reactivity as a building block makes a difference that operators feel. Nobody who has stood next to reaction columns running at full load wants shortcuts—they want chemical properties that stay predictable under stress. Facilities making dimethyl sulfide, dimethyl sulfoxide, and other downstream sulfur-containing organics rely on its timely, steady delivery. Our technical team works close to synthesis crews; we’ve seen enough troubleshooting to know what matters: not just purity, but control over moisture, stability over time, and delivery methods that handle transfer and vaporization safely. This direct link to operations keeps the bar higher than technical specification papers could ever capture.

    Comparing Methanethiol with Similar Sulfur Compounds

    Some buyers encountering methanethiol for the first time ask about alternatives, mainly ethanethiol or dimethyl sulfide. Each sulfur compound brings different attributes and, from a manufacturer’s viewpoint, also brings different risks and costs.

    Ethanethiol does some of the same odorization jobs. Its odor threshold is even lower—sometimes too strong for certain public-facing projects. Processing ethanethiol tends to present higher volatility. Handling equipment takes more wear, containment protocols run tighter, and the price tag often reflects those extra layers of risk. Methanethiol, by contrast, offers a more balanced safety profile: pungent enough to raise alarms, lower corrosivity to piping, and enough stability to suit most utility network requirements. Over the years, field data show pipework suffering less corrosion with methanethiol additions compared to more aggressive thiols. Fewer maintenance shutdowns mean real operational savings, a fact that sticks with purchasing and maintenance teams.

    Dimethyl sulfide enters the picture in specialty solvent applications and as a flavor precursor. As an industry producer, we see the differences most clearly during synthesis chain planning. Methanethiol brings more reactivity in cross-coupling and alkylation routes. Dimethyl sulfide, being less reactive and more volatile, handles differently—requiring more vigorous containment and often additional purification to keep byproducts low.

    We know from experience: sometimes switching from methanethiol to a substitute makes sense, but often the promised improvements in “performance” come at the cost of tougher handling rules, extra safety downtime, or unwanted side reactions. The best fit depends not on superficial comparison, but on supporting teams through real-world pilot runs and keeping the supply chain nimble.

    Tackling Storage and Safety Challenges Head-On

    Years in this business have taught us a plain lesson: methanethiol demands respect on the job. It is highly flammable and releases toxic fumes, so plant layout cannot cut corners. Our approach includes sealed, stainless-steel containment, PLC-managed gas detection, and dedicated fail-safe venting systems. Every batch we ship is checked by onsite teams for pressure integrity and trace moisture—operators have seen what one bad fit or gasket can do. Our storage tanks feature double-walled construction and nitrogen padding to prevent air ingress.

    We train all staff in emergency procedures and PPE expectations, driven not by compliance but by what works in a real plant where mistakes have consequences. Regular joint drills with local fire services come not from policy, but the realization that chemical incidents do not wait for paperwork. Safety data and training are part of our job; we share lessons learned across facilities and update methods as soon as field events point to a new risk or process gap. Over the years, these habits cut reportable incidents and helped both us and our customers avoid what older hands remember as “learning the hard way.”

    Guaranteeing Consistency, Not Just Specifications

    Mass-producing methanethiol and hitting spec sounds easier than it is. Down at process scale, the difference between a clean, uniform batch and a fouled one can come down to half a degree in the heat exchanger or trace water in the sulfur feed. On occasion, anecdotal reports from customer reactor operators pointed to erratic side-reactions, only for our technical lead to catch micro-contaminants below declared spec. In such cases, lab data and plant adjustments go hand in hand. Every plant run draws on operator memory and a troubleshooting database built by years of feedback from customer shutdowns and process tweaks.

    We found that simply “meeting spec” does not guarantee user satisfaction. Animal nutrition plants, for example, have zero tolerance for odorous contaminants, which can transfer taste to the end product. Water utilities suffer if residue builds up in dosing pumps or corrosion starts appearing in metering valves. For us, it means tracking every variable possible: run-time temperature, pressure, sulfur grade, catalyst performance, evaporator condition, and bulk transport stability. We log and trace all major process inputs and conduct periodic validation with external labs. Continuous improvement loops—lean, practical, and driven by operator input—ensure each tanker or cylinder received at the customer site matches the last, not just on paper but in daily use.

    Tailoring Logistics to User Realities

    Delivery isn’t just about shipping on time. Methanethiol’s odor and volatility mean there are no shortcuts between our tank farm and your storage unit. Our road fleet runs pressure-rated vessels certified for hazardous materials, equipped with sniffers and double redundant sealing. Every driver spends days in safety training, a practice started after one transport-related spill caused by a third-party courier that shut down operations for a week and required months of cleanup.

    Our packaging team works with clients to match on-site needs: some industries require large bulk tank fills, others want smaller returnable cylinders to control exposure risk. With every use scenario, our technical staff helps set up unloading lines with active vent recovery and compatible seal materials. Even minor mismatches—wrong valves, incorrect hose lining—can release odors or create static build-up. Each customer’s process is different; so, we try to anticipate and adapt before the first shipment leaves our plant.

    Feedback loops are everything. Users still uncover issues faster than any third-party auditor. For example, one batch loaded onto standardized cylinder skids for an overseas shipment was delayed by regional safety inspection, which flagged newer valve material that differed from local regulations. That real-world experience led us to develop protocols to match each destination’s codes before filling, not just after arrival.

    Problems, Fixes, and Forward Thinking

    On the manufacturing side, our main battles involve feedstock reliability, energy management, and continuous emissions monitoring. Methanethiol’s production relies on methanol, hydrogen sulfide, and specialized catalyst systems—the supply security for each sets the pace for downstream production. To manage risk, we keep close ties with core suppliers and maintain strategic stockpiles for unexpected plant shutdowns or transport interruptions. Unplanned downtime costs everyone: us, our clients, and the industries they serve.

    Emissions and fugitive odor control shape every facility upgrade. Methanethiol’s low odor threshold means a pinhole leak can prompt complaints miles from the site. Plant upgrades focus on high-integrity joints, scrubber units, and enclosed transfer lines. We run routine audits not just for regulatory boxes, but because underestimating odor fatigue can hurt hard-earned community trust and the social license to operate.

    Product reformulation pressures arise, especially when customers shift to more environmentally driven purchasing. Methanethiol, produced to “green” standards—using closed-loop water management and lower-emission process routes—opens new contract opportunities. Over the last few years, we’ve invested in process mapping for lower carbon footprints and worked with end-users to substitute problematic additives. Production staff have seen first hand how recycled process heat or more robust waste gas capture delivers cost savings alongside environmental gains.

    We participate in regional chemical safety partnerships and share operational learnings with nearby sites. Industry incidents anywhere become learning moments for crews everywhere. Not every plant wants to open its operations, but real risk management beats image management every time.

    Supporting Customers Throughout the Product Life Cycle

    Our role doesn’t stop at the gate. Many users operate with lean technical teams or face challenges scaling up new process lines. That’s why we run quarterly knowledge sessions—no extra charge—covering everything from odor management to minor on-site blending for specialty applications. Experienced operators from our sites give the presentations, some with years of hands-on troubleshooting. Their advice often proves more valuable than any instruction manual.

    For facilities adopting methanethiol for the first time, our technical service group supports on-site commissioning, helping rig up the first fill, test closed-return vapor paths, and train staff. This partnership model traces back to earlier days when “ship and forget” gave way to ongoing relationships. We keep a clear channel for round-the-clock incident support—not because we expect problems, but from lived reality—failures don't always wait for office hours.

    After-sale support includes return handling for empty cylinders and technical refreshers as plant staff turnover. We’ve witnessed more than one transfer mishap caused by skipped handoffs or faded labeling on containers. Our staff make regular site visits, review logbooks with the customer, and double-check process compatibility for any planned expansions or upgrades. Most process engineers who have faced an unplanned shutdown or sensor failure know that knowledge often arrives alongside spare parts or a well-trained outside tech—our people treat these service calls as essential to doing the job right.

    Building Confidence through Experience

    Years of hands-on manufacturing deliver hard lessons. Methanethiol’s place across industries isn’t built only on lab specs or paperwork but on trust built through joint projects, consistent supply, and backing up users in a pinch. Each plant manager who relies on our shipments, each technician who runs that first new line, gives us feedback that informs our process. They point out rough edges, suggest new delivery formats, or flag minor incompatibilities before they become bigger headaches.

    Working this long with methanethiol, we have a clear perspective: details matter. Purity, moisture, packaging format, valve type, and documentation are not afterthoughts—they represent the difference between successful runs and costly shutdowns. Customers return to us not only for spec sheets but for the people behind the product, and for the long-standing experience that smooths each transaction.

    Methanethiol plays a small but essential role in larger manufacturing and service networks. Our commitment is to keep it safe, reliable, and delivered in ways that fit real-world operations. That approach doesn’t come from abstract promises—it comes from history, from learning alongside our customers, and from refusing to compromise on standards learned in the field.