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Mercury Sulfate

    • Product Name Mercury Sulfate
    • Alias Hydrosulfuric acid, mercury(2+) salt (1:1)
    • Einecs 231-992-5
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    424264

    Chemical Name Mercury Sulfate
    Chemical Formula HgSO4
    Molar Mass 296.66 g/mol
    Appearance White to yellowish crystalline powder
    Density 6.47 g/cm3
    Melting Point 450 °C (decomposes)
    Solubility In Water Slightly soluble
    Cas Number 7783-35-9
    Pubchem Cid 24585
    Hazard Classification Toxic, Environmental Hazard
    Boiling Point Decomposes before boiling
    Odor Odorless
    Ph Acidic in water

    As an accredited Mercury Sulfate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 500g Mercury Sulfate is supplied in a tightly sealed amber glass bottle with hazard labeling, safety instructions, and batch identification.
    Shipping Mercury sulfate must be shipped in tightly sealed, corrosion-resistant containers, clearly labeled as toxic and hazardous. It should be transported according to local, national, and international regulations for hazardous materials, preferably by experienced carriers. Avoid shipping with incompatible substances and ensure appropriate spill containment and emergency procedures are in place.
    Storage Mercury sulfate should be stored in tightly sealed, clearly labeled containers made of compatible, non-reactive material. Store it in a cool, dry, well-ventilated area away from sources of moisture, heat, and incompatible substances such as organic materials and strong acids. Keep the storage area secure and restrict access to trained personnel. Always follow local regulations for hazardous materials.
    Application of Mercury Sulfate

    Applications of Mercury Sulfate in Industrial Manufacturing

    Our direct manufacturing of mercury sulfate supports specialized processes across critical chemical industries. The following scenarios highlight genuine downstream uses, focusing on application-specific integration, regulatory compliance, and end product functionality.

    1. Vinyl Chloride Monomer (VCM) Production with Acetylene Process

    VCM producers utilize mercury sulfate as a heterogeneous catalyst for the acetylene hydrochlorination process. In these units, the precise addition is required as the catalyst drives the reaction between acetylene and hydrogen chloride to form VCM, which then feeds into PVC polymerization. Operational parameters, such as catalyst bed depth and temperature, dictate charge rates. Environmental monitoring for mercury emissions is continuous, with catalyst recovery systems enhancing sustainability under current international agreements. The ultimate quality of VCM depends on catalyst management and process purity at this stage.

    Industry compliance standards

    • EU Regulation (EC) No 1907/2006 (REACH)
    • Minamata Convention on Mercury (Global)
    • GB/T 20188—2006 (China VCM Industrial Standard)
    • OSHA PEL and NIOSH REL for workplace mercury exposure (USA)

    Typical usage ratio

    • Charge level: 0.5–2.5% by mass of total catalyst bed, depending on throughput, acetylene purity, and reactor design
    • Catalyst replacement frequency varies from 6 to 18 months based on conversion and deactivation data

    Downstream process integration

    • Catalyst loaded into fixed bed reactors ahead of VCM monomer recovery stage
    • Deactivation managed by periodic regeneration or refilling

    Final product types

    • Vinyl chloride monomer (VCM)
    • Polyvinyl chloride (PVC) resins

    2. Laboratory-Scale Organic Synthesis and Academic Research

    Many university laboratories and industrial R&D departments employ mercury sulfate for specific organic synthesis procedures, such as the hydration of alkynes to ketones and aldehydes. The compound acts as a Lewis acid, activating triple bonds and forming organomercurial intermediates, later decomposed to target molecules. Researchers maintain rigorous controls over waste disposal and air quality due to toxicity concerns. Quality control of reaction products depends on starting material purity and precise dosing.

    Industry compliance standards

    • GHS/CLP Safety Data Sheet Management (Globally Harmonized)
    • US EPA Resource Conservation and Recovery Act (RCRA) for laboratory hazardous waste
    • Local university or state chemical hygiene protocols

    Typical usage ratio

    • 0.01–0.1 mmol per mmol substrate in batch or micro-scale applications
    • Adjusted based on substrate reactivity and solvent volume

    Downstream process integration

    • Added directly to reaction vessels during key synthetic steps (hydration, oxidation, rearrangements)
    • Quenching and downstream purification involve chelation and liquid-liquid extraction

    Final product types

    • Specialty laboratory standards and reagents
    • Research samples for academic journals
    • Chemical intermediates for R&D evaluation

    3. Manufacture of Mercury-Based Reference Electrodes

    Industrial production lines for electrochemical instrumentation use mercury sulfate to fabricate saturated calomel and mercurous sulfate reference electrodes. The raw material creates the electroactive paste or electrolyte solution inside the cell body, producing standard and reproducible potentials for analytical laboratories and process monitoring. Systems must prevent operator exposure and ensure closed-loop waste management. Electrode consistency and calibration reliability depend on feedstock purity and concentration control at every step.

    Industry compliance standards

    • ISO 9001:2015 for quality management in sensor manufacturing
    • RoHS Directive exemptions (2011/65/EU, Annex III, for specific electrode uses)
    • IEC 60746 for electrochemical sensor performance

    Typical usage ratio

    • Electrolyte solution: 1.06 M (concentrated) or 0.5 M (dilute) mercury sulfate–based systems
    • 20–200 mg per standard reference electrode, adjusted for intended potential and stability

    Downstream process integration

    • Prepared under cleanroom environment and filled into glass or polymer cell housings
    • Electrode assembly calibration and hermetic sealing follow electrolyte addition

    Final product types

    • Saturated calomel electrodes (SCE)
    • Mercurous sulfate electrodes (MSE)
    • Laboratory and industrial reference electrodes

    4. Catalysis in Fine Chemical Manufacturing

    Certain specialty chemical factories use mercury sulfate as a catalyst for specific oxidation or rearrangement reactions, particularly in the manufacture of aromatic aldehydes or ketones from alkynes. These fine chemical plants operate with high selectivity protocols and robust environmental monitoring. Mercury handling systems include secondary containment and strict reporting under chemical safety protocols. End product yields and color depend on tight process control and reagent charge accuracy.

    Industry compliance standards

    • Responsible Care® program (ICCA member companies worldwide)
    • Local chemical industry standards for mercury emissions (e.g., GB 25467-2010, China carbenium salt plants)
    • National hazardous waste management regulations

    Typical usage ratio

    • 0.2–1.5% by mass of the starting material in batch reaction vessels
    • Adjusted according to target product and reactor volume

    Downstream process integration

    • Metered into glass-lined or stainless-steel reaction kettles at the start of oxidation or rearrangement stage
    • Processing under negative pressure and high-efficiency scrubbing

    Final product types

    • Benzaldehyde derivatives
    • Methyl ketone compounds
    • Intermediate building blocks for pharmaceuticals and fragrances

    5. Production of Standard Mercury(II) Solutions for Analytical Chemistry

    Analytical laboratories and certified reference material producers utilize mercury sulfate to formulate precision mercury(II) standard solutions. These solutions calibrate instrumentation or perform trace analysis in water, soil, pharmaceutical, and food safety labs. Manufacturers dissolve calculated quantities in acidified water to create stable references, packaging in certified containers. Traceability and homogeneity validation require documented quality control with direct reference to metrological standards.

    Industry compliance standards

    • ISO 17034:2016 for reference material producers
    • ASTM D3223 for mercury in water by cold vapor AAS
    • US EPA Method 245.7 for mercury analysis

    Typical usage ratio

    • Stock solutions: 1,000 mg/L—10,000 mg/L prepared by dissolving solid in nitric/sulfuric acid solution
    • Adjusted to client specification for target concentration

    Downstream process integration

    • Dissolution in controlled environment using volumetric flasks and analytical balances
    • Bottling into ampoules, with batch-specific certificates of analysis

    Final product types

    • Certified mercury(II) calibration standards
    • Commercial analytical reagent kits
    • Quality control samples for laboratory instruments
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    Certification & Compliance
    More Introduction

    Mercury Sulfate: Properties, Applications, and Manufacturer’s Insight

    Our Approach to Quality in Mercury Sulfate Production

    Producing mercury sulfate in our plant requires discipline both in sourcing and operational control. Our workforce follows strict monitoring processes during the reaction between pure mercury and concentrated sulfuric acid. This creates a crystalline, white or slightly yellow product, either as the monohydrate or anhydrous form. For chemists, the formula is HgSO4; both forms dissolve slowly in water, which makes manipulation easier in certain industrial settings.

    We understand the dangers in handling mercury sulfate. Internal controls mean that every batch gets tested for elemental purity and trace metallic impurities. Whatever the market supply or fluctuations in mercury pricing, we hold a standard that every drum or package that leaves our facility has a guaranteed minimum purity of 99.5%. Constant training helps our staff avoid cross-contamination with other metals and keeps errors to a minimum. Hundreds of customers—from university labs to large plants—use feedback, letting us fine-tune parameters batch by batch.

    Key Applications: Industrial and Analytical Uses

    Many users associate mercury sulfate with its primary use in analytical testing labs. Its most recognized role falls in the chemical oxygen demand (COD) analysis in water testing. Here, as a strong oxidant and catalyst, it interferes with the chloride content—removing a major analytical error in wastewater and environmental monitoring.

    In organic synthesis labs, chemists reach for mercury sulfate when catalyzing hydration of alkynes to ketones. Acetylene chemistry textbooks often note the use of this chemical in forming acetaldehyde and similar compounds. We have supplied material for both specialty research and larger batch production, adapting crystal size and packaging, so that the transition from benchtop to pilot scale runs smoothly.

    Another significant, though less public, application pops up in high-density primary cell production and certain pigment syntheses. Not every customer handling pigment manufacturing will need mercury sulfate, and most turn to us for advice on process conditions—troubleshooting incorrect color outcomes or efficiency drops. Decades of technical exchanges help us offer direct assistance instead of generic answers.

    What Sets Our Mercury Sulfate Apart

    Industry players will quickly notice that quality and consistency carry real weight in mercury sulfate. Some suppliers blend in cheaper byproducts or accept a little oxidation during storage. Our system never includes shortcuts. Each lot of mercury and sulfuric acid receives verification records, and we repair or upgrade equipment long before filtration rates drop or residues build up. Silica and trace iron levels always receive close tracking, since even sub-ppm contamination can throw off analytical results or cause side reactions in the customer’s process.

    Transport and storage challenge most chemicals in this class, and mercury sulfate is no exception. Our support teams have built custom containment for both monohydrate and pure form—caked product or fine powder. Instead of standardized secondary packaging, we match moisture and airtightness to the order’s volume and shelf life. The packaging choices help keep the chemical free of decomposition or moisture pickup, which affects both scale-up reactions and spectrometric studies.

    Understanding the Differences: Mercury Sulfate vs. Other Salts

    Our team regularly faces questions about why labs shouldn’t just substitute another sulfate salt or a different mercury compound. Both sides—functionality and safety—matter immensely. Mercury sulfate delivers a unique set of properties: high oxidative power, poor solubility in neutral water, and strong Lewis acidity. Sodium or potassium sulfates won’t catalyze organic transformations or bind to specific contaminants in the same way.

    Some less experienced buyers mistake mercury(II) chloride or mercury(I) nitrate for appropriate replacements. Those chemicals dissolve differently, show higher volatility, or introduce chloride or nitrate ions where they’re not wanted. For example, in COD testing, mercury(II) chloride would elevate background levels or even react with other sample components. Mercury nitrate’s higher solubility would lead to leaching problems in pigment or catalyst synthesis, changing yields and potentially introducing instability to the end product.

    Comparing mercury sulfate to mercuric oxide highlights more subtle issues. Both serve as catalysts, but the sulfate form maintains better structure under humid conditions. Stability through storage and the reaction pathway in ketone or aldehyde production requires salt that resists caking and secondary hydration. Most buyers cannot afford to rework contaminated or spent product, so the right choice up front saves labor and cuts waste by a measurable margin.

    Our Experience on Lab Support and Industrial Solutions

    Large-scale pigment producers often ask for advice beyond a safety data sheet. Over the last decade, we’ve seen shifts in water treatment requirements and pigment regulations that change the target impurity levels in raw materials. Because our technical staff has hands-on experience in analytical chemistry, we spend time with each client on formulation troubleshooting.

    There’s a misconception in some procurement teams that all mercury sulfate behaves the same in every process. Actually, different hydration states (monohydrate vs. anhydrous) affect not only reactivity but also dusting, flow, and storage stability. Our product catalog includes both, refined to specifications based on the past performance of published industrial procedures and verified internal process studies.

    Lab chemists often need smaller amounts, with special focus on preventing water ingress. Resealable packaging with desiccant packets and clear batch number labeling contribute both to product identity assurance and long shelf life. On the industrial side, bulk orders rely on tailored drums and composite containers that support longer storage through changing weather cycles.

    Safety and Environmental Responsibility

    No mercury compound comes with simple handling. Our staff abides by national and international safety regulations, using established best practices for hazardous material storage and transport. Plant-level investments in spill containment, air filtration, and worker monitoring keep incidents at zero. Before shipping, we review requirements for Mercury Export Ban Act compliance and end-use certificates for non-domestic buyers.

    End-user safety involves more than locked storage. We only supply customers who provide clear end-use declarations, especially in countries with restricted applications. Internal audits, regular emergency drills, and continuous staff certification anchor our standards. Most of our customers handle the material in ventilated hoods or isolated facilities, and we share practical guidance on safe disposal of spent residues.

    Waste management is not a back-office afterthought. We guide buyers on responsible cleanup—for instance, bundling materials for return shipments or neutralization depending on local options. Closure of the loop, where possible, ensures that spent catalyst or lab residues don’t reach the environment. Our engineers regularly review process upgrades to minimize worker exposure and waste load, sometimes in partnership with local authorities or academic advisory teams.

    Traceability, Documentation, and Regulatory Experience

    We document every step from raw mercury sourcing to drummed product shipment. Each customer receives a full traceability record for their purchase, backed up by independently verified analysis results. Batch labelling practices date back years before industry tracking became standard practice, and we still keep digital and physical backup records for every outbound container.

    Documentation serves both compliance and practical troubleshooting. Regulatory reviews sometimes call for in-depth purge records, and our team supports clients with experience in REACH, TSCA, and local hazard communications. We place equal emphasis on correct shipping forms for international parcels, and work alongside freight forwarders to clear customs without delays or excess scrutiny.

    As regulations tighten on persistent and bioaccumulative substances, some customers find themselves facing new operating permits. We stand ready to walk buyers through risk assessments, end-use declarations, and the correct framing of notifications to authorities, avoiding unnecessary churn or shipment rejections.

    Challenges the Industry Faces and Our Practical Solutions

    Transporting and storing mercury sulfate has grown more complex with international attention on hazardous materials. We’ve experienced limitations on certain air and sea routes, with periodic customs seizures or blocks. Practical knowledge—gained from decades of direct negotiation with officials—helps prevent misclassification. Every outgoing order passes through a documentation audit and dry-run packaging check. Real supporting staff—not just online forms—track each route in real time until internal receipt confirmation.

    New lab buyers sometimes come in unaware of local restrictions, leading to delayed shipments. We do proactive outreach, sending guidelines on proper licensing and environmental reporting. The investment up front helps streamline repeat orders, reducing disruptions from rejected customs clearance or last-minute compliance issues.

    Pricing volatility in basic raw mercury markets poses another challenge. We built long-term relationships with mercury refiners, ensuring a constant high-purity input. These relationships mean we rarely scramble for material even in periods of market shortfall, so clients never face sudden supply stops or questionable quality substitutions.

    Commitment to Transparency and Open Collaboration

    Transparency with mercury sulfate means open lines of communication. We invest in a capable technical team that answers questions fast, leaning on decades of practical process experience instead of only referencing literature or second-hand data. Customers send us sample residues for troubleshooting, and we run our own parallel degradation or interference tests. These results flow straight back to the customer, with process notes and recommendations for best outcomes.

    True collaboration with our enterprise and research partners goes well beyond the sales contract. Joint tests on pigment stability, COD repeatability, or catalyst activity provide mutual feedback. Our production lines adjust if a recurring purity issue emerges, and we help clients update protocol documentation as needed. Our commitment means every lot and shipment comes with an open offer for post-purchase support and technical follow-up.

    Looking Forward: Innovation in Mercury Sulfate Handling

    Innovation grows out of small production tweaks, process improvements, and better safety measures. We are running ongoing trials in sealed system manufacture, aiming to reduce operator exposure even further. Packaging innovations—like anti-static inner sleeves or quick-check seals—aim to make storage and opening safer and more convenient for the end user.

    We have also begun working with several research partners on potential alternatives and recovery processes for mercury compounds in general. Even if regulations and industrial demand change, we retain our commitment to environmental stewardship and worker safety.

    As the market for high-purity mercury sulfate evolves, experience drives our ability to deliver. We keep seeking feedback, scrutinizing each shipment, and updating both process and product in line with the best available scientific evidence and honest, direct customer input.