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Lithium Dichromate

    • Product Name Lithium Dichromate
    • Alias Dichromic acid dilithium salt
    • Einecs 233-660-5
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    183141

    Chemical Name Lithium Dichromate
    Chemical Formula Li2Cr2O7
    Molar Mass 254.88 g/mol
    Appearance Orange-red crystalline solid
    Density 2.35 g/cm3
    Solubility In Water Soluble
    Melting Point 570 °C (decomposes)
    Cas Number 13453-66-8
    Oxidizing Agent Strong
    Hazard Statements Toxic, carcinogenic, and environmentally hazardous
    Storage Conditions Store in a cool, dry place away from reducing agents
    Pubchem Cid 23673558

    As an accredited Lithium Dichromate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Lithium Dichromate is securely packaged in a 500g amber glass bottle with a tamper-evident seal and hazard label.
    Shipping Lithium Dichromate is shipped as a hazardous material due to its oxidizing and toxic properties. It must be stored in tightly sealed, corrosion-resistant containers and clearly labeled. Transportation follows strict regulatory guidelines, such as those from the Department of Transportation (DOT) and IATA, to prevent spillage, contamination, or accidental exposure.
    Storage Lithium dichromate should be stored in a cool, dry, and well-ventilated area away from combustible materials, reducing agents, organic substances, and sources of ignition. It must be kept in tightly closed, corrosion-resistant containers clearly labeled as hazardous. As a strong oxidizer and toxic compound, storage areas should also feature proper containment for spills and access to safety equipment such as eyewash stations and showers.
    Application of Lithium Dichromate

    Applications of Lithium Dichromate in Industrial Manufacturing

    Lithium dichromate serves as a specialized oxidizing agent in several advanced industrial manufacturing sectors, where its unique chemical properties match stringent performance, quality, and regulatory requirements. As the original producer, we support customers’ technical processes with consistent purity grades and process consultation, ensuring compliance and reliable production results across all applications.

    1. Specialty Organic Synthesis for Pharmaceutical Intermediates

    Pharmaceutical manufacturers incorporate lithium dichromate in targeted oxidation reactions during the synthesis of specific heterocyclic intermediates. The compound’s strong oxidizing power, selective reactivity, and compatibility with controlled reaction conditions enable chemists to effect transformations not easily achieved with alternative oxidants. It plays a key part in the oxidative cleavage, alcohol-to-aldehyde conversion, and aromatic ring functionalization steps within the multi-stage synthesis of active pharmaceutical ingredients (APIs). Formulation chemists typically design batch and semi-batch reactor protocols for precise reagent addition and quench procedures to control chromium(VI) residue within regulatory thresholds.

    Industry compliance standards

    • ICH Q3C for impurity control
    • European Pharmacopoeia (Ph. Eur.) monographs 2034, 2035 for intermediates synthesis
    • Current Good Manufacturing Practice (cGMP, 21 CFR Parts 210 and 211)
    • REACH Annex XVII for chromium(VI) compound limitations

    Typical usage ratio

    • Ranges from 0.1 to 2.0 molar equivalents per batch, adjusted based on substrate complexity and target molecule yield

    Downstream process integration

    • Metered into oxidizer addition steps, followed by controlled workup (filtration, solvent exchange, neutralization, and heavy metal removal columns)

    Final product types

    • Active pharmaceutical ingredient (API) building blocks
    • Complex heterocyclic pharmaceutical intermediates
    • Bulk API precursors for further functionalization

    2. Corrosion Inhibitor for Aerospace Hydraulic Fluids

    Aerospace hydraulic system formulators use lithium dichromate as a corrosion inhibitor additive in phosphate ester and synthetic hydrocarbon fluids. Its role is to stabilize fluid systems by passivating metallic surfaces, particularly high-alloy steels and aluminum components, exposed to high-pressure and high-temperature operating conditions. Integration of this additive demands precise calculation, as overuse can impact fluid compatibility and residue formation, while underuse fails to deliver required corrosion protection during FAA certification endurance testing.

    Industry compliance standards

    • SAE AS1241 (hydraulic fluid stability and compatibility)
    • DEF STAN 91-48/1 (UK Ministry of Defence hydraulic fluid requirements)
    • REACH and TSCA registration/reporting obligations for chromium compounds
    • OEM-specific aerospace material and process specifications (e.g., Boeing BMS 3-11)

    Typical usage ratio

    • 0.02% – 0.1% w/w, with proportion optimized through corrosion testing per ASTM D665 and ASTM D130

    Downstream process integration

    • Added during fluid blending in closed systems, followed by vacuum dehydration, fine filtration, and batch QC for additive homogeneity

    Final product types

    • Aerospace-qualified phosphate-ester hydraulic fluids
    • Fire-resistant hydraulic oils for commercial and military aircraft
    • Industrial hydromechanical system lubricants

    3. Electrochemical Chromium Plating Solutions (Passivation and Bright-Dip)

    Manufacturers of high-performance metal surface finishing solutions rely on lithium dichromate in highly specialized, mixed-acid electroplating baths. The compound introduces chromium(VI) ions necessary for achieving controlled passivation, surface leveling, and color uniformity in bright-dip treatments on high-value copper and brass components. Proper selection and dosing of lithium dichromate, in combination with proprietary additives and controlled cathodic current densities, are crucial to attaining repeatable surface quality, avoiding irregular deposition, and minimizing environmental impact by limiting hexavalent chromium carryover into effluent streams.

    Industry compliance standards

    • ISO 4527:2020 for decorative chromium plating
    • RoHS Directive (2011/65/EU) exemption management for electrical components
    • ISO 9001-certified processes for traceability
    • Hazardous Waste Regulations for chromium(VI) process effluent (e.g., US EPA 40 CFR Parts 260-273)

    Typical usage ratio

    • 5 – 25 g/L in electroplating baths, adjusted via coulometric titration and in-line bath monitoring

    Downstream process integration

    • Dosed during make-up and maintenance of plating baths, with integration into continuous or batch plating lines equipped with ultrafiltration and chromate recovery loops

    Final product types

    • Decorative and corrosion-resistant metal fittings (plumbing, automotive trim)
    • Connector pins and sealed switch contacts
    • Architectural hardware and fasteners requiring passivated finish

    4. Analytical Chemistry Reagents for Oxidimetric Titration

    Chemical laboratories and certified reagent packers formulate analytical grade oxidizers containing lithium dichromate for use in redox titration, specifically in the quantification of organic matter by dichromate oxidimetry. The consistent reactivity, solution stability, and traceability to primary standards make this material essential in environmental, food, and industrial laboratories for chemical oxygen demand (COD) determination and other analytical protocols that call for standardized hexavalent chromium reagents. High-purity processing, contamination control, and standardization against NIST-traceable references are critical at each production stage.

    Industry compliance standards

    • ISO 6060 for water quality—COD testing
    • EPA Method 410.4 (USEPA approved)
    • ASTM D1252 for chemical oxygen demand of water
    • GLP (Good Laboratory Practice) as per OECD Principles

    Typical usage ratio

    • 0.025 N to 0.250 N normality in prepared titration solutions, standardized immediately before use against sodium oxalate

    Downstream process integration

    • Blended during laboratory reagent formulation with deionized water and controlled acid concentrations, dispensed into pre-cleaned volumetric glassware, and sealed to prevent contamination or concentration drift

    Final product types

    • Certified titration kits for environmental analysis
    • Off-the-shelf analytical reagents for academic and industrial labs
    • Standardized oxidizing solutions for water treatment QC laboratories
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    Certification & Compliance
    More Introduction

    Lithium Dichromate: A Manufacturer’s Perspective

    Unlocking the Strengths of Chromate Chemistry

    Working on the plant floor and managing the daily pulse of production, you learn more from the raw material bins and the feedback from our customers than from any conference room session. Over several years handling lithium dichromate, we've come to see how the unique properties of this compound continue to shape both niche and high-throughput industrial applications. Our direct involvement in sourcing, refining, and quality monitoring gives us an understanding of what matters most to those who rely on lithium dichromate.

    Characteristics and Model

    Producing lithium dichromate requires absolute attention to detail, as even a minor deviation in process conditions will affect the purity and physical characteristics. Our most in-demand grade contains a high percentage of Li2Cr2O7 in free-flowing, bright yellow-orange powder form. The crystalline nature enhances batch consistency, which many of our partners appreciate for precise dosing. Average particle sizings remain tightly controlled — for example, our current specifications deliver particles under 100 microns with rare deviation. These fine grains dissolve efficiently in laboratory and production environments.

    We consistently source our lithium carbonate and sodium dichromate inputs from audited, reliable channels. Downstream, our controlled conversion system prevents cross-contamination, which is often a weak link in chromate chemistry. Final drying and packing steps minimize caking, so our shipments arrive easy to measure and introduce into processes. Every batch runs through our own comprehensive QA to verify Li, Cr, water content, and ensure minimal residual sodium, magnesium, or sulfate. Returns on our internal analyses match closely with independent labs, a record that’s allowed us to build trust with industrial and academic users alike.

    Lithium Dichromate in Use: Experience from the Shop Floor

    Lithium dichromate’s main strength shows while managing oxidative reactions in organic synthesis labs and pigment manufacturing. Unlike potassium or sodium dichromate, lithium’s smaller cation lets it act with slightly different solubility and reactivity. Chemists working on specific oxidations often prefer it because they can tune results more finely, dialing in reaction rates while keeping unwanted byproducts low. From our end as a manufacturer, we notice the best feedback comes from users who demand this fine balance.

    Some processes see advantages from lithium dichromate's moderate solubility. It avoids the rapid precipitation issues common with bulkier alkali metals. Our partners in analytical chemistry pointed out how the lithium ion introduces fewer interferences, especially when their downstream testing needs a clear background. Colorimetric or spectrophotometric analyses benefit from sharp color transitions and predictable dissolution rates, supported by our dense and well-crystallized powder.

    I remember one specialty glass producer visiting us for a line audit, looking for ways to increase glass brightness and chemical resistance. By adjusting a minor dopant level in their glass with our lithium dichromate, they could hit their desired brightness without compromising structural properties. The lithium ion brought measurable differences, enhancing certain refractive qualities unavailable with sodium or potassium analogs. In ceramics, similar tweaks in firing led to notable changes in color vibrancy and glaze smoothness.

    Key Differences from Other Chromates

    In the chromate family, each product carries its own quirks. Lithium dichromate offers a more compact cation than sodium or potassium forms. This subtle difference shifts the behavior in various chemical matrices. While sodium and potassium dichromate hold their place for many oxidations or as corrosion inhibitors, requests for lithium dichromate come from teams looking for more nuanced control in sensitive reactions.

    The solubility curve stands as one of the more visible differences. Lithium dichromate dissolves to a moderate degree in water, typically offering smoother control over saturation without the overshooting that potassium dichromate can sometimes cause. As an oxidant, it’s no less potent, but often introduces less alkali contamination. Purification of final products sometimes hinges on this smaller footprint, as downstream separation and residue removal become easier with lithium’s less persistent presence.

    Handling lithium dichromate also means dealing with a lighter-weight compound per volume compared to potassium or sodium versions. Storage conditions change, as does the amount needed to match the oxidizing power in batch recipes. Our regular customers often comment on the ease of transfer and weighing, thanks to the free-flowing powder and its relatively low tendency to absorb atmospheric moisture.

    Our Commitment to Safe Production

    Any time we work with chromium(VI) products like lithium dichromate, we keep safety and responsibility at the front of every step. We run full air filtration in production halls, using local exhaust and HEPA scrubbers around every blending, drying, and packing zone. Our staff cycles through regular health checks, and every worker has personal monitoring that logs exposure in real time. We train our team extensively — not just because it’s required, but because long service on the job teaches you the risks and respect needed when handling potent oxidizers.

    Hazardous waste from our process never mixes into municipal streams. Dedicated collection vessels and offsite treatment ensure that our environmental load stays tightly managed. The spent chromate solutions get reduced and solidified before disposal, a steady routine audited by outside agencies. Even as regulations have tightened, we have met expectations without cutting corners. Our goal is a facility that exceeds compliance year after year, and that commitment reflects in long-term employee retention and near-zero incident rates.

    Feedback from long-time partners in manufacturing, research, and materials development often centers on the reliability and consistency of our material quality. Consistent batches help labs reduce their own safety overhead, and predictable powder flow supports cleaner, faster work in enclosed blenders or reactors. A few of our R&D partners have shared stories of reducing glove box entry and washdown times because of the nature of our powder, and any opportunity to cut exposure and handling complexity matters to both health and project budgets.

    Keeping Up with Research and Regulation

    Production of lithium dichromate exists in a world shaped by both tradition and change. On one side, researchers look for greener alternatives or improved recycling options. On the other, regulatory agencies require tighter tracking and continuous upgrades in handling practices. As a manufacturer, we have invested heavily in tracking systems from raw input to finished product. We log every kilogram with transparency, preparing annual reports for both local agencies and our multinational customers.

    In recent years, the focus on reducing airborne particulate emissions pushed us to rework our dust collection systems. Newer bag house filters and negative pressure rooms now maintain workplace dust at levels safer than the old national standards. Ongoing investment in staff training allowed us to run pilot lines for chromate waste recycling, turning hazardous byproducts into less harmful forms. This work remains a priority, as we believe the most sustainable future for lithium dichromate lies in pairing world-class chemistry with responsible stewardship.

    Having worked both with seasoned chemists who remember the days before automation, and younger process engineers keen on rapid-deployment technology, I have seen how solution-driven manufacturing keeps product quality steady through shifts in regulation and market demand. The dialogue between plant, lab, and customer facilities enables fast feedback to improve every stage — from raw input to packaging design.

    Challenges and Solutions in Manufacture and Application

    Operating a chromate production line brings its share of complications. Moisture can clump powders; reactive air can trigger color shifts. We have modified our storage and packing lines to use food-grade liners that resist puncture and moisture seepage, reducing waste and aging of the powder. High-precision weighing equipment at filling points controls unit pack weights within a range tighter than the industry norm. Regular calibration and batch mixing checks prevent cross-batch contamination, further strengthening our position with customers who value batch-to-batch repeatability.

    Another ongoing challenge is the sourcing of lithium carbonate, one of the main precursors. As the global demand for lithium increases — especially due to battery manufacturing — we work closely with our suppliers, often securing contracts months ahead. We audit suppliers onsite, not only through paperwork, focusing on environmental and labor practices as well as shipping timelines. Our procurement team pairs this with large onsite warehousing, insuring our ability to fulfill orders reliably even as the market shifts. This diligence is born of necessity: we’ve experienced the consequences of missing a raw material shipment and the resulting scramble that comes from trying to substitute with imports of unknown quality.

    Technical support for users is part of our everyday work. Beyond shipping product, we maintain a field team and direct technical hotline, where real chemists answer questions about optimal dissolution temperatures, oxidant dosing, or safe transition from other dichromate forms. Our lab has taken samples from customer returns and diagnosed everything from water-intrusion failures to subtle process impurities, working hands-on to solve problems. These collaborations have upgraded both our internal quality metrics and the capabilities of our customers.

    Supplying Research and Industry Needs

    Lithium dichromate lands in some of the most precise applications: specialty glass, ceramic frits, pigment precursors, fine chemical synthesis, and even controlled wood preservation. Each sector brings distinct requirements. Specialty ceramics producers often need highly pure, low-sodium material, as even a sliver of impurity can mar final color or structure. They have shared how they value our powder’s neutral taste in color tests, with no bitter orange undertones, allowing for purer, brighter blues or greens in glazes.

    Our work with analytical labs using lithium dichromate as a spectroscopic standard has underscored the importance of stable particle size and moisture control. Their feedback pushed us to overhaul drying tunnels and anti-static packaging, significantly improving sample stability for long storage. For chemical synthesis, groups regularly point to how reliable powder flow and accurate dosing in small-scale batch reactions simplify workflow and avoid the headaches of re-dissolving lumpy, caked media.

    Because many customers run environmentally conscious operations, we document the cradle-to-grave path for every batch. This enhances accountability and reassures partners that any issues in shipment or handling are quickly traced back and resolved. The regularity of our technical bulletins and collaborative site visits signals to all partners — from new university labs to repeat high-volume users — that a chemical manufacturer’s job no longer ends at the freight dock. This approach helps all parties improve safety, yield, and sustainability together.

    Pushing Forward Through Ongoing Development

    As our experience base grows, we carry a greater responsibility to anticipate the needs of changing industries. Research into low-dust, high-density pellets offers promise for automated handling systems. Early pilot runs into pelletized or granulated lithium dichromate, done at the insistence of a major pigment user, showed strong returns in terms of reduced airborne chromium levels and faster integration into continuous reactors. These successes guide our R&D team to move forward on improving product forms, packaging, and even custom blend options that further benefit our customers’ processes.

    We have also focused on circular economy principles. Our engineers are experimenting with closed-loop water recycling in the plant and continual reduction of waste streams. These investments increase both environmental safety and operational efficiency, helping us manage costs and maintain supply integrity without passing unnecessary expense onto partners.

    Building Trust Through Experience

    Longevity in the field affords perspective. Few appreciate the full capability of lithium dichromate without spending years tracing its progress from raw ore to finished glass, pigment, or fine chemical. As direct manufacturers, every batch becomes a learning opportunity. By building ongoing relationships with both buyers and research teams, we stay ahead of industry standards and regulatory shifts, shaping new solutions long before demands reach the marketplace.

    The insight gathered across decades — from lab bench to large kilns — shapes the standards we set for purity, particle size, packaging, and technical support. We have learned that consistency, not flash, breeds trust. By delivering batches that perform predictably and offering open support for troubleshooting, we have built a reputation as more than a vendor, but a technical resource embedded in our partners’ success.

    Looking ahead, we remain clear-eyed on both the opportunities and risks in chromate chemistry. While environmental and workplace safety challenges persist, our investment in monitoring, innovation, and open channels with users helps resolve many practical problems swiftly. Confidence comes not from claims, but from long-term quality and the collaborative improvement that only direct involvement can bring.

    Conclusion: Reliable Supply, Proven Performance

    Lithium dichromate stands as a widely misunderstood but valuable specialty chemical. Our years in the business taught us that customer needs evolve, but the fundamentals of precise chemistry, safe handling, and accountable production remain unchanged. With every shipment, we supply much more than a bag or drum — we deliver the cumulative strength of practical experience, technical know-how, and a commitment to helping each customer achieve lasting results.