Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing admin@sinochem-nanjing.com 3389378665@qq.com
Follow us:

Isobutylene

    • Product Name Isobutylene
    • Alias 2-Methylpropene
    • Einecs 201-100-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    525201

    Chemicalname Isobutylene
    Iupacname 2-Methylpropene
    Molecularformula C4H8
    Molarmass 56.11 g/mol
    Casnumber 115-11-7
    Boilingpoint -6.9°C
    Meltingpoint -140°C
    Density 0.587 g/cm³ (at 0°C)
    Appearance Colorless gas
    Odor Mild, gasoline-like
    Solubilityinwater Very low
    Flashpoint -77°C (closed cup)
    Vaporpressure 3,100 mmHg (20°C)
    Autoignitiontemperature 465°C
    Explosivelimits 1.8–9.6% (in air)

    As an accredited Isobutylene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Isobutylene is supplied in a 99.5% pure, 50-liter high-pressure steel cylinder, equipped with safety valve and proper hazard labeling.
    Shipping Isobutylene is shipped as a liquefied, pressurized gas in specially designed cylinders or tank cars. It is classified as a flammable gas (UN 1961) and requires secure, leak-proof containers. Proper ventilation, grounding, and clear hazard labeling are essential during transport to prevent fire or explosion risks.
    Storage Isobutylene should be stored in tightly closed, properly labeled pressure-resistant containers or cylinders, kept in a cool, well-ventilated area away from heat, ignition sources, and direct sunlight. Storage areas must be equipped with leak detection and fire suppression systems, and containers should be grounded and bonded to prevent static discharge. Segregate from oxidizing agents, acids, and halogens.
    Application of Isobutylene

    Applications of Isobutylene in Industrial Manufacturing

    As a major chemical intermediate, isobutylene plays critical roles across multiple industrial manufacturing processes. We supply stabilized, high-purity isobutylene directly to downstream processors, supporting quality requirements in automotive, rubber, fuel, and specialty chemical sectors. Below, we detail its main industrial applications with reference to industry-specific standards, real usage ratios, integration into production lines, and typical finished product categories.

    1. Butyl Rubber (Isobutylene-Isoprene Rubber, IIR) Production

    Butyl rubber manufacturers rely heavily on isobutylene as the principal monomer. Polymerization processes require stringent raw material purity for high molecular weight polymers. Isobutylene integrates into cationic polymerization reactors together with low levels of isoprene to generate rubber with excellent gas impermeability and resistance properties for critical sealing applications. Strict compliance with elastomer production standards, controlled ratios, and defined process chain placement define the use in this segment. Finished butyl rubbers target tire inner liners, pharmaceutical stoppers, and other air- and moisture-barrier products.

    Industry compliance standards

    • ISO 9001:2015 Quality Management for elastomer production
    • ASTM D1418 (Standard Practice for Rubber and Elastomer Terminology)
    • REACH Regulation (EC) No 1907/2006 (European elastomer applications)
    • FDA 21 CFR 177.2600 (Rubber articles for food contact in the US market)

    Typical usage ratio

    • 85–99% by mass in monomer feed; isoprene content held at 1–3% depending on the required rubber grades; specific ratios adjusted for molecular weight and end-use gas permeability

    Downstream process integration

    • Direct batch or continuous feed into low-temperature cationic polymerization reactors using aluminum chloride or similar catalysts; raw isobutylene undergoes dehydration and purification steps prior to polymerization

    Final product types

    • Tire inner liners and sidewalls
    • Pharmaceutical rubber closures and stoppers
    • Tank linings and membrane sheets
    • Chewing gum base elastomers

    2. Methyl Tert-Butyl Ether (MTBE) Synthesis

    Refinery operations use isobutylene as a reactant with methanol to produce methyl tert-butyl ether. As a gasoline blending agent, MTBE boosts octane ratings while reducing engine knocking. Refinery-grade isobutylene must meet hydrocarbon purity requirements to avoid catalyst poisoning in etherification processes. This application is strictly regulated in relation to fuel composition and environmental standards. End products serve regional gasoline markets, especially where high-octane or reformulated fuels are mandated.

    Industry compliance standards

    • EN 228 (Automotive Fuels—Unleaded Petrol—Requirements and test methods)
    • ASTM D4814 (Standard Specification for Automotive Spark-Ignition Engine Fuel)
    • US EPA Clean Air Act Oxygenate standards
    • API RP 1626 (Storing and handling facilities for oxygenated fuels)

    Typical usage ratio

    • Isobutylene:methanol molar ratio typically 1:1; ratios may be adjusted slightly by process design to optimize MTBE yield or manage unreacted feedstock recycling

    Downstream process integration

    • Continuous injection into fixed-bed catalytic reactors; on-site dehydration and distillation ensure removal of C4 contaminants before etherification; feedstock purity maintained below 50 ppm sulfur for catalyst longevity

    Final product types

    • Methyl tert-butyl ether for gasoline blending
    • High-octane reformulated gasoline
    • Export-grade MTBE concentrates

    3. Polyisobutylene (PIB) Production

    Polyisobutylene manufacturing plants use high-purity isobutylene as the sole monomer in cationic polymerization. Strategic molecular weight targeting allows for customization of product viscosity from highly reactive oligomers to high-molecular-weight elastomers. Producers emphasize feedstock traceability and inhibitor-free handling protocols for batch precision. The production process differentiates between PIB for lubricants, adhesives, or sealants by controlling polymerization time and temperature profiles. Strict performance standards apply to final PIB grades entering downstream compounding lines.

    Industry compliance standards

    • ISO 9001:2015 Quality Management for polymerization
    • ASTM D2226 (Standard Specification for Polyisobutylene)
    • FDA 21 CFR 175.105 (Adhesives in indirect food contact)
    • REACH compliance for European sales

    Typical usage ratio

    • 100% pure isobutylene; inhibitors present at 10–50 ppm as required for transport but removed prior to reaction; adjustment of catalyst-to-monomer ratio based on desired molecular weight

    Downstream process integration

    • Direct charge into cationic polymerization vessels using Lewis acid catalysts; vacuum stripping and degassing post-reaction to remove residual volatiles

    Final product types

    • Lubricant additives (detergents and dispersants)
    • Sealant and gasket compounds
    • Pressure-sensitive and hot-melt adhesives
    • Plasticizer intermediates

    4. Alkylation for High-Octane Gasoline Components

    In alkylation units, isobutylene reacts with light olefins such as butenes to form high-octane alkylate for premium gasoline. Refiners maintain feedstock specifications to prevent catalyst deactivation. Process engineering requires precise control of isobutylene content in mixed C4 streams, influencing alkylate yield and product quality. This integration strengthens refinery blending pool management under regulatory frameworks requiring low-sulfur, high-performance gasoline.

    Industry compliance standards

    • ASTM D4814 (Automotive gasoline specification)
    • EN 228 Unleaded Petrol Standard (Europe)
    • US EPA Tier 3 fuel sulfur regulations

    Typical usage ratio

    • Generally 50–70% isobutylene in total C4 alkylation feed; the ratio varies depending on crude slate and refinery alkylation technology

    Downstream process integration

    • Isobutylene introduced to acid-catalyzed alkylation systems using sulfuric or hydrofluoric acid; integrated with fractionation and product separation units; rigorous monitoring of water and sulfur content

    Final product types

    • Alkylate blending agents for premium and reformulated gasoline
    • Low-sulfur, high-octane finished fuels

    5. Manufacturing of Oxo Chemicals (e.g., Isobutyl Alcohol via Hydroformylation)

    Chemical manufacturers use isobutylene as a feedstock for oxo synthesis, leading to isobutyraldehyde and then isobutyl alcohol. Platinum-catalyzed hydroformylation requires low-olefin impurities and strict control of water and oxygenates in feed. Isobutylene undergoes high-pressure, temperature-controlled insertion of CO and H2, followed by hydrogenation. Downstream, alcohol intermediates become solvents, plasticizers, or ester precursors for coatings and PVC industries.

    Industry compliance standards

    • ISO 14001 (Environmental management for chemical production)
    • OECD SIDS for chemical intermediates
    • REACH Annex VII for intermediates
    • ASTM D4286 (Standard for isobutyl alcohol)

    Typical usage ratio

    • Isobutylene-to-syngas molar ratios maintained at 1:1:1 (isobutylene:CO:H2); minor process variation exists depending on catalyst system employed

    Downstream process integration

    • Continuous feeding into high-pressure hydroformylation reactors; online monitoring of C4 stream purity; followed by hydrogenation, distillation, and fractionation to isolate alcohols

    Final product types

    • Isobutyl alcohol for solvents
    • Plasticizer intermediates
    • Isobutyl acetate for coatings
    • Fine chemical intermediates

    6. Production of Antioxidant Additives (e.g., 2,6-Di-tert-butylphenol)

    Specialty chemical producers react isobutylene with phenol in the presence of acid catalysts to create alkylphenols such as 2,6-di-tert-butylphenol. Stringent quality controls regulate feedstock hydrocarbon purity to avoid by-product formation. The process requires exact dosing in batch reactors to deliver high selectivity for desired isomers. Resulting antioxidants are standardized for use in lubricants, fuels, plastics, and food-contact polymer stabilization systems. Regulatory frameworks differ across applications by region and product form.

    Industry compliance standards

    • FDA 21 CFR 178.2010 (Antioxidants and stabilizers for polymers)
    • EU Regulation (EC) No 10/2011 (Plastic materials and articles intended for food contact)
    • ISO 9001:2015 (Quality management for specialty chemicals)
    • REACH registration for chemical additives

    Typical usage ratio

    • Isobutylene to phenol ratio typically 2.2:1 (molar); adjusted per reactor performance for minimal side-product formation

    Downstream process integration

    • Isobutylene is metered into stirred-tank batch reactors preloaded with phenol and acid catalyst; after reaction and neutralization, products are isolated via distillation and vacuum stripping

    Final product types

    • Lubricant and fuel antioxidants
    • Stabilizers for polyethylene and polypropylene
    • Antioxidant additives for food-contact polymers
    • Rubber processing stabilizers
    Free Quote

    Competitive Isobutylene prices that fit your budget—flexible terms and customized quotes for every order.

    For samples, pricing, or more information, please call us at +8615371019725 or mail to admin@sinochem-nanjing.com.

    We will respond to you as soon as possible.

    Tel: +8615371019725

    Email: admin@sinochem-nanjing.com

    Get Free Quote of Sinochem Nanjing Corporation

    Flexible payment, competitive price, premium service - Inquire now!

    Certification & Compliance
    More Introduction

    Isobutylene: A Cornerstone Monomer Shaping Modern Industry

    Introducing Isobutylene from a Manufacturer’s Viewpoint

    In our decades of experience operating reactors and maintaining tight controls over gas-phase chemistry, few raw materials measure up to the background utility and strategic value of isobutylene. At our own sites, this C4 hydrocarbon isn’t some distant commodity. We produce it on-site through precise dehydrogenation and separation processes. Every ton is backed by vigilance drawn from history and continuous technical scrutiny.

    Isobutylene—also called 2-methylpropene—might not turn heads like specialty chemicals or new-to-world additives, but our production teams know its reputation as a reliable, consistent monomer. Its distinct branched structure gives it a reactive double bond that stands out when combined with acids or polymerization catalysts. In the lab and on the plant floor, its reactivity goes well beyond linear butenes such as 1-butene. That difference, just a methyl branch in the molecule, amplifies downstream possibilities for value generation.

    Key Physical Properties We Control

    Our isobutylene emerges from highly purified feedstocks and is shipped as a colorless gas with a slight odor, liquefied under moderate pressure to ensure safe handling. We keep moisture, sulfur, oxygenates, and heavier olefins tightly controlled so reactivity downstream never gets compromised. What drives buyers to source directly from producers like us is the attention to purity: ppm-level specs for common contaminants, strict monitoring of hydrocarbon distribution, and routine gas chromatographic analytics give processors confidence batch after batch.

    We package isobutylene in steel cylinders or tank trucks (dependent on customer volume), with an emphasis on ensuring pressure stability and traceability, from the refinery splitter to valve outlet.

    From Tires to Chemicals: Industrial Uses

    The vast majority of global isobutylene finds its way into making butyl rubber, specifically butyl and halobutyl types—staples of tire inner liners, curing bladders, pharmaceutical stoppers, protective clothing, and sealants. Our colleagues in the elastomer trade value the way isobutylene reacts with isoprene to deliver impermeability and cold flexibility. Outside of rubbers, it steps up as a key intermediate in the production of methyl tert-butyl ether (MTBE), which has historically raised the knock-rating of motor gasoline.

    Another route leverages its acid-catalyzed propensity to alkylate—at our facility, chemists often prepare high-octane blending components for fuels through paraffin alkylation. It’s an essential feedstock for producing antioxidants, plasticizers, lubricants, and specialty polymers. We rarely think of isobutylene as just a “commodity”—it anchors value chains for ion-exchange resins, polyisobutylene additives, and alkylated phenols.

    Specification Models and Applications Learned on the Floor

    The models we produce vary mainly by purity and intended use. For top-tier butyl rubber synthesis, our technical team supervises polymer-grade isobutylene at 99.5%+ minimum purity. Impurities like butadiene, propane, and heavier C5 and C6 cut fractions can interfere with single-site catalysts; each shipment carries full compositional details. For fuel blending or other downstream chemical transformation (like MTBE production), the demand relaxes slightly, permitting grades in the 99% range but always including certificate of analysis.

    Clients seeking to use isobutylene in tertiary-butyl alcohol or C4 intermediates come to us with questions about trace aromatics or non-volatile residues—which we check through standardized in-house protocols. Our tanks have fed conversion units running at every scale, from bench process chemists needing liter-scale bottles to tire-makers running continuous large-volume lines. The difference comes down to reliability: nothing slows a reactor line like an off-spec lot.

    Why Direct Manufacturer Sourcing Matters

    Direct access to the production line gives us oversight and control that resellers rarely match. We set protocols to monitor the process from upstream fractionation to packaged product, leaving little to chance. Experience tells us that end-users value traceability—if an issue ever arises, our engineers can trace a lot number back to a particular run, operator, and analytical report. We have invested steadily in online analyzers and batch documentation not just for regulation, but to keep outcomes in our direct view.

    Unlike traders who shuffle tanks, our plant operators have a stake in every batch; they know the peculiarities of the distillation towers and the need for midstream adjustments to keep the front-end separation sharp. Problems, like a spike in C5 content or sulfur, become visible early. This culture, refined by many who have spent decades at the same site, does more than secure product—it builds a feedback loop where our teams respond to customers with real insight, offering suggestions when a process issue points back upstream.

    Differentiating Isobutylene from Other C4 Streams

    Some might think any C4 hydrocarbon product could substitute for another, but plant experience tells a different story. In our own operations, 1-butene and n-butane serve as useful intermediaries but lack the dense reactivity profile that isobutylene gives. The position of the double bond and the methyl side group define reactivity both in acid-catalyzed and free-radical environments. We resolve these C4 isomers using selective catalytic or physical separations; a fraction too rich in 1-butene or trace butadiene can throw off downstream polymerizations or alkylations.

    Process operators in the chemical business—particularly those working with butyl rubber, alkylation, or methyl tert-butyl ether—see immediate performance deficits if they run on the wrong C4 cut. Isobutylene’s unique attributes come from its reactivity; it’s not a filler or cheap stand-in, but a workhorse with significant impact on process efficiency and end-product quality. Users making lubricants or specialty resins need just as strict a break from other butenes; cross-contamination between C4 streams can spell downstream fouling, polymer branching, or even hazardous pressure surges in closed systems.

    In our plants, separations run hot around the clock, under real-world constraints—tight overlaps in boiling points, contamination risks, fouling if a column slips in temperature. Our practical knowledge means we separate not only per specification but with continuous improvement in mind. The more we’ve automated, the more margin for error we have eliminated. End-users gain a cleaner slate without unwanted byproducts.

    Maintaining Quality in Every Batch

    Maintaining high-purity isobutylene is not simply a matter of re-running columns or increasing energy input. Our process engineers watch for feedstock anomalies, seasonal variation in crude supply, and changing refinery operations upstream. We automate testing for oxygen, water, and sulfur, and have invested in online GC systems tied directly to the DCS—the digital nervous system of our plant. For those of us in manufacturing, a clean spec isn’t just a promise to a customer; it protects our own process uptime and minimizes incidents.

    Every drum, every tank truck, must meet the latest quality assurance protocols. We work closely with customers to tailor impurity profiles—sometimes even running small-scale tests on their own processes using our product, feedback guiding our adjustments to purification steps or logistics. In the rare event a shipment fails to perform, our technical team investigates with urgency, interfacing with both operations and R&D to resolve root causes.

    Impact of Isobutylene on Downstream Innovation

    Our long-running R&D program focuses not just on incremental certification but on enabling customers to push the boundaries of performance—whether in tire durability, fuel cleanliness, or plasticizer longevity. Isobutylene, in the hands of creative chemists, gives rise to specialty additives for lubricants, new variations of butyl rubbers, and cross-linked polymers for energy storage. We have provided custom grades for electronics and pharmaceutical closure innovators exploring tighter leachables specs.

    Having a direct relationship with a manufacturer rather than a middleman opens the door to day-to-day collaboration—a plant can reroute a specific cut, tweak flow rates, or introduce advanced filtration so a niche producer can launch a new product line. We welcome pilot trials and shared analytics with customers developing next-generation products, refining grades for special catalyst systems, or implementing their own green chemistry initiatives. The continuity of working directly with operations develops both insight and flexibility to solve real problems, not just meet certificates.

    Process Safety and Environmental Responsibility

    Handling isobutylene safely means more than following paperwork or using standard PPE. For each process change—switching feedstocks, reconfiguring towers, expanding capacity—our engineers carry out hazard studies and operational risk reviews. Mitigating flammability hazards and VOC emissions sits squarely in the daily practices of everyone on the production team. Onsite detectors, procedural controls, and regular training sessions have built a culture where frontline feedback gets acted on promptly.

    Our plant operations teams track atmospheric releases and strive to recover light ends for recycling back into process streams. Wastewater and process off-gas are treated on-site before discharge, always meeting or beating regulatory baselines. The environmental team shares real metrics openly with local regulators—a step that builds trust with neighbors and drives our own accountability. Our investments in flare reduction, recycling of purge gas, and lower-emission process heaters keep us in step with tightening emissions standards.

    Market Challenges and Solutions from the Plant Floor

    Volatility in feedstock pricing, regulatory pressure on fuel ethers, and evolving end-user purity specs present challenges to every isobutylene producer. We weather these pressures through operational agility and cultivated supplier relationships. For example, when upstream crude splits tighten, our procurement team works closely with process engineers to explore alternative feed slates like propane dehydrogenation. We routinely invest in advanced separation units that reduce energy, maintain yields, and assure more stable quality even amid market swings.

    To adjust to tightening purity standards—particularly from pharmaceutical or food-contact customers—our technical services and quality groups keep lines of communication open with end-users. In recent years, we shifted from batch testing to continuous quality monitoring, leveraging chromatographic and spectroscopic tools right on the line. Rapid detection and correction allow us to avoid costly, time-consuming recall or downgrades to lower-value outlets.

    Regulatory changes—such as tightening on MTBE or preference for bio-based intermediates—challenge us to keep product relevant and processes efficient. Our response has been targeted research into catalyst improvements, process intensification, and waste minimization, offering not only compliance but often better economic performance for users open to new technologies.

    Outlook and Commitment to Our Partners

    Our teams remain committed to strengthening isobutylene’s role as a foundational material for energy, materials, and advanced manufacturing. Beyond standard supply, the relationship we cultivate with partners extends across product development, technical troubleshooting, logistics planning, and future-focused innovation. We invite feedback, host plant visits, and troubleshoot hands-on, because we know that every drum shipped carries the reputation not only of our product, but also of the people behind it.

    For newcomers considering isobutylene as a feedstock, or experts advancing materials chemistry, our door remains open. Decades of sustained plant operation, real-time control over quality parameters, and willingness to co-develop downstream upgrades set us apart in a volatile market. We look forward to collaborating on the next generation of applications, and to carrying the lessons of past production into the challenges of a changing industrial world.