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Hydrogen Fluoride [Anhydrous]

    • Product Name Hydrogen Fluoride [Anhydrous]
    • Alias Hydrofluoric acid
    • Einecs 231-634-8
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    127507

    ChemicalName Hydrogen Fluoride [Anhydrous]
    ChemicalFormula HF
    CASNumber 7664-39-3
    MolecularWeight 20.01 g/mol
    PhysicalState Colorless gas or fuming liquid
    BoilingPoint 19.5°C (67.1°F)
    MeltingPoint -83.6°C (-118.5°F)
    Density 0.991 g/cm³ (at 25°C)
    VaporPressure 917 mmHg (at 25°C)
    SolubilityInWater Miscible
    Odor Pungent, irritating odor
    FlashPoint Non-flammable
    UNNumber 1052

    As an accredited Hydrogen Fluoride [Anhydrous] factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A 2.5L high-pressure, corrosion-resistant steel cylinder with secure valve, labeled "Hydrogen Fluoride [Anhydrous]," including hazard warnings.
    Shipping Hydrogen Fluoride [Anhydrous] is shipped in specialized, corrosion-resistant containers (such as steel cylinders with protective linings) due to its highly toxic and corrosive nature. Transportation follows strict hazardous material regulations, including labeling, documentation, and emergency procedures to ensure safety and compliance with international and national shipping standards.
    Storage Hydrogen Fluoride [Anhydrous] should be stored in tightly closed, corrosion-resistant containers (such as Monel or PTFE-lined steel), in a cool, dry, well-ventilated area, away from moisture, incompatible substances (e.g., glass, silica, strong bases), and sources of heat or ignition. Storage areas must be equipped with acid-resistant spill containment and clearly labeled for hazardous, toxic, and corrosive material.
    Application of Hydrogen Fluoride [Anhydrous]

    Applications of Hydrogen Fluoride [Anhydrous] in Industrial Manufacturing

    Hydrogen Fluoride [Anhydrous] serves as an essential chemical raw material in various advanced industries, especially where high-purity and precise control during processing are critical. Below, we detail core application scenarios across key industrial sectors, with each scenario reflecting the unique handling requirements, compliance standards, and technical parameters demanded by downstream users.

    1. Fluoropolymer Manufacturing (e.g., PTFE, PVDF Resins)

    Major fluoropolymer producers utilize anhydrous hydrogen fluoride for synthesis of monomers such as tetrafluoroethylene (TFE) and vinylidene fluoride. The gas phase or liquid phase fluorination reaction relies on controlled delivery and purity of HF, directly impacting molecular weight control and polymer matrix integrity in downstream reactor systems. Only high-standard HF can meet the requirements for consistent batch quality in extrusion and molding operations.

    Industry compliance standards

    • ISO 9001:2015 for quality management systems
    • REACH (EC 1907/2006) registration for fluorinated compound production
    • ASTM D5263 standard for PTFE resins and precursors
    • EPA TSCA (Toxic Substances Control Act) compliance for integrated polymers

    Typical usage ratio

    • HF feed: 1.0–1.2 metric tons per metric ton of TFE produced; precise ratio adjusted based on fluorination yield and monomer recovery rates

    Downstream process integration

    • Direct gas feed into monomer synthesis reactors
    • Batch and continuous fluorination under controlled temperature and pressure
    • Removal of residual HF before polymer isolation

    Final product types

    • Polytetrafluoroethylene (PTFE) pellets, sheets, and films
    • Polyvinylidene fluoride (PVDF) resins
    • Fluorinated ethylene propylene (FEP) copolymers

    2. High-Purity Electronics-Grade Etching for Semiconductor Fabrication

    Semiconductor manufacturers require ultra-pure hydrogen fluoride for wafer etching and cleaning processes in integrated circuit (IC) and photovoltaic cell fabrication. The material enters both wet and dry etch installations, removing native oxides and controlling critical dimension tolerances at sub-micron scale. Stringent batch records and impurity tracking are maintained for each HF delivery to fabs.

    Industry compliance standards

    • SEMI C3.7 and C3.14 standards for electronic-grade HF
    • ISO 14644 Cleanroom Class protocols during handling
    • RoHS (2011/65/EU) compliance for restricted substance content
    • IATF 16949 for automotive IC plants

    Typical usage ratio

    • HF solution concentrations: 0.5% to 49% as per etch bath formulation; neat HF gas supplied in micro-etch reactors depending on wafer load and oxide thickness

    Downstream process integration

    • In-line injection for wet etching (silicon oxide removal)
    • Vapor-phase HF dosing in ALD (Atomic Layer Deposition) equipment
    • Final rinse protocol to neutralize trace HF following etch

    Final product types

    • Finished silicon wafers and bare substrates
    • Photovoltaic solar cells
    • Integrated circuit dies and MEMS devices

    3. Metal Surface Treatment in Aluminum Production

    Aluminum refiners and extruders control surface characteristics by using anhydrous hydrogen fluoride for removing oxides prior to alloying, anodizing, or finishing. This produces clean surfaces for better bonding or coating performance. Processing plants integrate dosing systems to control exposure time, minimizing fluorine wastage and downstream wastewater challenges.

    Industry compliance standards

    • ISO 7599 for aluminum anodizing
    • ASTM B921 for high-purity aluminum alloys
    • OSHA 29 CFR 1910.119 for hazardous chemical safety
    • EN 13980 for plant safety in aluminum processing

    Typical usage ratio

    • Etchant concentration: 3–12% HF (aqueous) dependent on aluminum grade and oxide layer thickness; chemical consumption calculated by surface area processed per hour

    Downstream process integration

    • Immersion tanks for strip-cleaning extrusions and billets
    • Automated spray or dip process in continuous aluminum finishing lines
    • On-site neutralization of spent HF before wastewater discharge

    Final product types

    • Anodized aluminum profiles for construction and transportation
    • Aluminum foil and sheet with enhanced surface uniformity
    • Precision components for electronics housing and automotive frames

    4. Uranium Hexafluoride Conversion in Nuclear Fuel Cycle

    Civil nuclear fuel processors depend on anhydrous hydrogen fluoride for converting uranium oxides to uranium hexafluoride (UF6), a step essential for isotope enrichment. Rigid process controls ensure material traceability and minimization of HF losses. All materials and procedures are rigorously documented to comply with global nuclear safeguards and worker safety requirements.

    Industry compliance standards

    • IAEA INFCIRC/153 for nuclear material accountancy
    • ANSI N14.1 for UF6 cylinder handling
    • US NRC 10 CFR Part 70 for fuel facility safety
    • ASME Boiler and Pressure Vessel Code for plant equipment

    Typical usage ratio

    • HF feed: 6–8 tons per ton of UO2 converted, with exact input adjusted for ore grade and yield recovery

    Downstream process integration

    • Continuous reactor loading with HF for UO2 to UF4 and then UF6 transformation
    • Integration with gas purification lines and byproduct neutralization
    • Monitoring of fluorine mass balance for regulatory audit

    Final product types

    • UF6 cylinders for enrichment facilities
    • Depleted uranium tetrafluoride (UF4) as a by-product
    • Certified UO2 fuel pellets for light water reactors

    5. Alkylation Processes in Petroleum Refining

    Petroleum refiners inject anhydrous hydrogen fluoride as a catalyst in isobutane-olefin alkylation reactors for producing high-octane gasoline blending components. Accurate vapor-liquid control and catalyst regeneration ensure HF recycling efficiency. Environmental emissions and acid catalysis residues are monitored hourly to meet plant permit conditions.

    Industry compliance standards

    • API 751 for safe operation of HF alkylation units
    • EPA Clean Air Act process emissions limits
    • NFPA 30 for flammable liquid storage
    • OSHA 1910.119 PSM for process safety

    Typical usage ratio

    • HF charged: typically 2.5–3.5 kg per barrel of alkylate produced; adjusted according to reactor design and cycle times

    Downstream process integration

    • Continuous acid phase injection into fixed- or moving-bed alkylation reactors
    • Side-stream regeneration to recover and recycle HF
    • Hydrocarbon-phase separation and post-reaction deactivation

    Final product types

    • Alkylate gasoline components (C7–C9 isoparaffins)
    • Refined high-octane automotive fuels
    • Feedstocks for further petrochemical upgrading
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    Certification & Compliance
    More Introduction

    Hydrogen Fluoride [Anhydrous]: Built for Industrial Precision

    Tough Demands in Manufacturing, Critical Ingredients in Chemistry

    We manufacture anhydrous hydrogen fluoride (HF) at industrial scale using a carefully monitored synthesis process that hinges on mineral acid reactions and strict temperature controls. The result is a clear, colorless and highly penetrating gas with a pungent odor, often handled in steel cylinders or tankers under pressure. A typical analysis delivers high purity levels above 99.9 percent, with virtually no water content. This isn’t just a matter of chasing numbers – trace moisture, atmospheric leaks, and metallic impurities can cripple process yields or damage sensitive pipelines in the very industries where HF plays its strategic role.

    Most buyers ask about model numbers, but on our end, every batch is traceable by lot and quality report; lab chemists match each cylinder or tanker to its origin, titration values, and moisture test. Only after passing rigorous inspections does our product reach the market. We earn our edge from the way we control our raw fluorite, optimize sulfuric acid digestion, and operate dedicated lines for anhydrous products, keeping the water content well below the 0.01 percent that disrupts etching and fluorination. Years of investment in plant design, strict maintenance of alloy-lined reactors, and live gas detection build trust in our HF’s consistency from drum to drum, year-round.

    Difference Between Anhydrous and Aqueous

    Hydrogen fluoride exists in several physical forms, but anhydrous HF serves a different purpose than aqueous, which is diluted with water. Once HF absorbs even slight traces of moisture, its reactivity changes. For silicon etching, semiconductor cleaning, Teflon and fluoropolymer synthesis, or specialty refrigerant production, only the dry version does the job – it doesn’t bring in water, won’t hydrolyze product streams, and keeps every valence free for pure fluorination. Layers of dehydration and water-free handling set it apart. Most mistakes we see in new users happen when assumptions are made about mixing or replacing dry HF with commercial hydrofluoric acid.

    Why can’t you substitute aqueous in the same role? In refining and microelectronics, water content spawns unplanned corrosion, electrical leakage, or fouled catalytic stages. This damages both products and expensive equipment. Over countless years, process engineers learned this lesson, sometimes the hard way.

    Where Hydrogen Fluoride Anhydrous Shines

    No two HF customers are quite the same, but the common ground comes down to chemistry that demands top-end reactivity and zero water. Fluorochemical production, for one, counts on our supply to make refrigerants, fluoropolymers like PTFE, and specialty surfactants. Steel pickling lines pull from pressurized cylinders to clean stainless and titanium, using the gas’s raw power to dissolve stubborn oxides without introducing water vapor that would harm later surface treatments.

    Microchip foundries and solar panel makers buy dry HF in bulk because every speck of moisture affects the critical thin-film growth and semiconductor etching steps. Glass manufacturers need it to cut shapes and frost surfaces—adding water would shatter the glass or change the finish. In these shops, our engineers switch between steel tonners and custom supply modes, fine-tuning for the safe, dry handling that customers count on. We supply regular field audits and practical advice in person; it’s not just about shipping gas but troubleshooting real-world pipelines, cold traps, and leak zones.

    Learning From Experience: Handling and Logistics

    Working directly at the manufacturing level, we've seen every mistake and engineered countless solutions. Where traders talk documentation, our reality is daily logistics, live handling, and emergency planning. Few chemical operations demand higher discipline; HF attacks everything from glass to skin, and the dry form moves by pressure—accidents prove expensive or catastrophic.

    Our teams invest in training every plant operator, from raw material receiving through cylinder loading. Delivery systems use Monel or specialty alloys—standard steel or brass quickly fails. Regular leak testing, automated area monitoring, and predictable HAZMAT drills are muscle memory for our staff. Bulk users rely on a different setup: we customize cylinder manifolds and fixed piping networks with triple-sealed connections, drawing on decades of data from plant incidents, regulatory audits, and field service calls.

    Shipping HF across borders or to remote locations calls for robust containers, certified labeling, cold-chain or insulated truck routing during seasonal extremes, and chain-of-custody logs. We monitor all this directly, with 24/7 phone support and live GPS for high-value loads. Not every customer realizes the tightrope act that keeps the product pure and the supply chain running without incident.

    The Challenge of Purity and Consistency

    Making anhydrous HF is not just a batch process—every stage, from mineral source selection, acid digestion, gas absorption, distillation, to final cylinder filling, carries risk of unwanted contamination. Our chemists run continuous inspections on feedstocks, not just for fluoride concentration but for heavy metals, residual silica, and trace chlorides. Each impurity, in low parts-per-million, can shut down a high-spec refinery or damage a microelectronic tool.

    Distillation columns, chillers, and sealed reactors form the backbone of our manufacturing lines. Maintenance runs on strict schedules, and every cleaning is logged. Over the years, we have invested in automating feed control and using non-contact sensors—and these upgrades pay off in two ways: fewer operator mistakes, and increasingly repeatable purity in every delivered lot.

    When a product recall strikes the industry, it typically traces back to skipped tests or aging infrastructure. We’ve closed these gaps by building a feedback loop between plant lab, maintenance, and customer technical service. If a customer faces unexpected corrosion or poor etch uniformity, our teams work back through process data, track cylinder shipment, and review every scrap of quality control for that batch.

    Tackling Emissions and Workplace Safety

    Nothing about making or handling HF, especially anhydrous, comes easy. Strict emissions limits on airborne fluoride force us to run double-scrubbing loops and collect every vent stream. Leaks can harm workers or the community, so we built a culture that rewards near-miss reporting and drills every staff member with hands-on training.

    Our record shows that best results don’t come from defensive paperwork but plain repetition: making sure every valve connects right, every monitor works, every operator suits up with proper gear and reviews emergency wash stations daily. Local regulations keep changing, and we do our own air sampling beyond any inspector's minimums. Constant review and investment in new methods—high-performance monitors, sealed pump designs, zero-bleed filling manifolds—raise the bar year by year.

    We've spent years working with neighbors, hazmat teams, and local authorities to prepare for every scenario. Emergency leak response isn’t theory for us—it’s regular, on-site practice. Working as a manufacturer, not just a supplier, we take full responsibility for every molecule that leaves our site.

    Supporting Customers Across Sectors

    Our technical teams routinely troubleshoot questions that don’t show up in text books. Down to the roll-off time of cylinder changeovers, ambient humidity in local warehouses, odd discoloration inside glassware, or compatibility of newly sourced PTFE valve seats, our experience matters. Customers count on more than a standard spec sheet; they come to us for details about pipeline cleaning, recovery of used HF, or odd odor complaints that crop up in old plant buildings.

    Working this closely with customers drives changes in our product line. We offer various package sizes, pressure options, and vapor withdrawal designs because no two factories run the same. Some buyers need stabilized grades for long-distance shipping in harsh climates. By keeping a short feedback loop, we tweak our process faster than big, slow-moving competitors or third-party re-packagers. We learn which cylinder batches flow best in automatic regulators and which valves hold up longest, adjusting our gear to real-world lessons.

    Environmental Responsibility and Compliance

    Managing HF production responsibly extends beyond plant gates. Fluoride emissions and wastewater treatment, regulatory audits, and community transparency sit at the core of our daily work. Our environmental group runs in-plant fluoride scrubbers and takes daily compliance readings; every discharge stream gets checked for fluoride and acidity before release. Any anomaly triggers a wider investigation—source, cause, and fix, with documented closure.

    Working to exceed legal minimums, we invested in closed-loop recirculation units and concentrate spent acids for further recycling wherever possible. The aim is to reduce overall fluoride throughput and shrink our environmental footprint. Every spent cylinder undergoes thorough degassing and tested before being returned or sent for recycling. We share monthly updates with regulatory authorities and take part in local safety events to keep our impact open and accountable.

    Perspectives On Industry Trends and Market Evolution

    Demand for anhydrous HF has shifted in recent years. Refrigerant regulations and the phase-out of some older fluorocarbons stress chemical suppliers to both innovate and ensure continuity. Some buyers want higher grades, free of even lower metals and organic residues. Others require flexible supply networks to adapt to fluctuating quotas in refrigerant and polymer production.

    Regulatory pressure to lower greenhouse gas emissions has changed the downstream uses of HF: customers producing new low-global-warming refrigerants require consistently dry and pure product to maximize reaction efficiency. The electrification trend in vehicles and renewable power pushes demand for precision etching and specialty surface treatments in battery and photovoltaic parts.

    Plant upgrades reflect this push for quality—new packed columns and cryogenic traps enter our process lines as soon as they prove their value in production trials. Investing in more automated quality tracking gives us shorter troubleshooting times and faster release for our customers. Smaller runs of customized anhydrous grades and new container formats are part of how we respond to market pulls that come almost overnight.

    Continuous Improvement in Production and Quality

    Life as a chemical manufacturer runs stepwise, every day geared toward shaving off risk and fine-tuning output. Every plant outage, every equipment breakdown, or unsigned quality report brings lessons. We keep rigorous logs on every tank farm valve swap, pressure spike, and customer return, building a quiet library of fixes and never-repeats. Operators rotate through cross-training not just to avoid boredom, but to spread critical process knowledge, short-hand signals, and hard-earned tricks of the trade.

    We learned over the years that even tiny changes in raw material quality ripple through every step and can derail a delivery. That’s why we won’t cut corners on sampling, and we rotate senior team members through turnaround meetings and customer audits. If someone reports a failed batch in the field, field service runs root cause analysis within hours—no back-and-forth between departments, no waiting weeks for answers.

    Plant automation is strong support in pursuit of process control. In earlier years, so much was done by hand, but now in-line analyzers and automated reporting catch trends before a problem expands. Still, nothing replaces a skilled operator with an eye for a tiny leak or a whiff of acid somewhere the monitors miss.

    Why Managing Anhydrous HF Requires Real-World Know-How

    Textbook chemistry explains the hazards of hydrogen fluoride, but working with the substance, especially dry, teaches a different level of respect. We've learned that safe handling is a blend of constant attention, thorough training, and careful maintenance. We treat water exclusion as an absolute, not an ideal, knowing one stray droplet can set off a chain of events from corroded lines to ruined product quality.

    Clients sometimes push for cost or speed, but we’ve learned nothing beats discipline in systems and recordkeeping. Every maintenance shut, every purge, and every sample carries weight. Regulators, customer auditors, and our internal team work together to keep standards high and response times short.

    Taking shortcuts never pays out—we’ve tracked how even a small practice change causes notice at customer sites, sometimes weeks after a shift. That’s why continuous direct involvement from our technical and operations staff, plus regular feedback calls and site visits, stay part of our business model.

    Looking Forward: Challenges and Goals in Manufacturing Anhydrous HF

    Global supply chains bring fresh challenges, from raw mineral shortages to new shipping rules for hazardous goods. Leading as an experienced manufacturer means we plan for every scenario: storage expansions before outages, dual-sourcing of critical alloys and gaskets, and running buffer stocks on key consumables. This forward planning allows us to keep commitments to long-standing customers, regardless of market swings or weather events.

    Technology will keep pushing demands higher. Purity targets will tighten, container and monitoring standards will rise, and auditing will reach new levels of detail. We’ll keep evolving our plant design and field support, investing in real-time process controls and new containment innovations—always based on the fine details that dozens of years in chemical manufacturing have taught us.

    On the horizon, sustainability goals raise new expectations about how HF is produced, used, and eventually recycled or neutralized. Supporting our customers as they adapt, providing credible documentation, and backing claims with real-world data, we stand ready to meet these changes head-on. That’s the only way to keep trust and leadership across the industries that rely on us for anhydrous hydrogen fluoride.