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Ethyl 2-Butenoate

    • Product Name Ethyl 2-Butenoate
    • Alias Ethyl crotonate
    • Einecs 205-460-0
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    342391

    CAS Number 623-70-1
    Molecular Formula C6H10O2
    Molar Mass 114.14 g/mol
    IUPAC Name Ethyl but-2-enoate
    Appearance Colorless liquid
    Boiling Point 126-127°C
    Melting Point -100°C
    Density 0.894 g/cm³ at 25°C
    Refractive Index 1.422-1.424
    Flash Point 23°C
    Solubility in Water Slightly soluble
    Odor Fruit-like
    Structural Formula C2H5O2CCH=CHCH3
    Vapor Pressure 11 mmHg at 25°C
    Synonyms Crotonic acid ethyl ester

    As an accredited Ethyl 2-Butenoate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Ethyl 2-Butenoate is packaged in a 500 mL amber glass bottle, sealed with a screw cap for safe, light-protected storage.
    Shipping Ethyl 2-butenoate is shipped in tightly sealed containers, typically made of glass, aluminum, or compatible plastic, to prevent leakage or contamination. It is transported as a liquid, labeled as a flammable and irritant substance, and stored in cool, ventilated areas away from sources of ignition or incompatible materials.
    Storage Ethyl 2-butenoate should be stored in a tightly closed container, in a cool, dry, and well-ventilated area away from sources of ignition and incompatible substances such as strong oxidizers and acids. The storage area should be equipped for flammable liquids and protected from direct sunlight and moisture. Proper labeling and adherence to local chemical storage regulations are essential.
    Application of Ethyl 2-Butenoate

    Applications of Ethyl 2-Butenoate in Industrial Manufacturing

    Ethyl 2-Butenoate serves as a specialized intermediate in fine chemical, flavor, fragrance, and specialized polymer industries. Below, we detail key downstream application scenarios where this material delivers proven value, specifying compliance expectations, recipe guidance, integration points, and finished product types.

    1. Flavor Compound Formulation (Food & Beverage)

    Ethyl 2-Butenoate acts as a characterizing ester in formulating complex fruit and rum flavor profiles for beverages, confectionery, and bakery applications. The material’s fruity, pineapple-like aroma enables developers to mimic natural notes in scalable, auditable formulations. Food technologists adjust dosage based on regional sensory preferences and layered flavor systems, always adhering to permissible limits outlined by safety regulators.

    Industry compliance standards

    • FAO/WHO Codex Alimentarius (GSFA – General Standard for Food Additives)
    • 21 CFR 172.515 (U.S. FDA: Synthetic Flavoring Substances and Adjuvants)
    • EU Regulation (EC) No 1334/2008 (Flavorings and Certain Food Ingredients with Flavoring Properties)
    • GB 2760-2024 (China National Standard for Food Additives)

    Typical usage ratio

    • 0.1–20 ppm (mg/kg) depending on finished product matrix; lower range common for beverages, higher for bakery or confectionery bases.

    Downstream process integration

    • Added during pre-mix or main flavor blending stages in liquid syrups, dry blends, or emulsions, with rigorous tracking for flavor release consistency during heating or baking.

    Final product types

    • Soft drinks, rum and other alcoholic beverages, candy, baked cakes, pastry fillings, flavored yoghurts.

    2. Fragrance Ingredient for Fine Perfumery

    As a fine chemical ester, Ethyl 2-Butenoate is utilized by perfumers for composing fresh, tropical, and ethereal top notes. Its volatility and distinctive scent profile allow fragrance houses to formulate perfumes and personal care products with controlled release and olfactory longevity, requiring stringent batch traceability and allergen control per industry standards.

    Industry compliance standards

    • International Fragrance Association (IFRA) Standards & Amendments
    • Regulation (EC) No 1223/2009 (Cosmetic Products Regulation – EU)
    • ISO 9235 (International Standard: Aromatic Natural Raw Materials Vocabulary; for synthetic/nature-identical substances)

    Typical usage ratio

    • 0.005–0.2% (w/w) of fragrance concentrate, with concentration tailored based on final dilution and intended olfactory effect; IFRA guidelines limit use based on end application (e.g., skin contact or air care).

    Downstream process integration

    • Integrated during the fragrance oil compounding phase, before dilution with ethanol or carrier solvents; batch released following organoleptic panel testing and regulatory screening for restricted components.

    Final product types

    • Eaux de toilette, eau de parfum, aftershaves, scented body lotions, fine mists, luxury candles, air fresheners.

    3. Raw Material for Pharmaceutical Intermediate Synthesis

    Ethyl 2-Butenoate functions as a carbon–carbon building block in the synthesis of active pharmaceutical ingredients (APIs) and veterinary molecules. Process chemists exploit its unsaturated ester functionality for selective transformations by Michael additions or aldol condensations during multi-step API manufacture, ensuring robust documentation and qualification per GMP systems.

    Industry compliance standards

    • ICH Q7 (Good Manufacturing Practice for Active Pharmaceutical Ingredients)
    • USP/NF Monographs (for intermediates and impurity control)
    • EU GMP Part II (Basic Requirements for Active Substances)

    Typical usage ratio

    • Dosage determined case-by-case, commonly 0.5–3 molar equivalents relative to targeted coupling partner; stoichiometry detailed in process batch records.

    Downstream process integration

    • Charged into reaction vessels during early- or mid-stage API synthesis steps; frequently used in solution-phase reactions under inert atmosphere, with subsequent inline purification or distillation.

    Final product types

    • Pharmaceutical intermediates for cardiovascular, anti-infective, and CNS compounds; veterinary drug ingredients.

    4. Polymer Modifier for Specialty Coatings

    Engineers use Ethyl 2-Butenoate as a co-monomer or functional group modifier in the synthesis of specialty acrylic and alkyd coatings, providing improved flexibility, adhesion, and solvent resistance. Its unsaturated structure facilitates grafting or copolymerization for niche coating applications on metal, glass, or flexible substrates, requiring careful validation under region-specific material controls.

    Industry compliance standards

    • REACH (Registration, Evaluation, Authorisation and Restriction of Chemicals — ECHA)
    • ASTM D16 (Terminology for Paint, Related Coatings, Materials, and Applications)
    • EN 71-3 (Migration of Certain Elements for toys and coatings in the EU)

    Typical usage ratio

    • 2–8% by weight of total monomer content in copolymerization batches; level depends on performance balance between film properties and cost-in-use.

    Downstream process integration

    • Metered into polymerization reactor with main monomer charge or used as post-modification agent for oligomer chain-ends; processed under temperature-controlled, oxygen-limited conditions.

    Final product types

    • Anodic/cathodic electrodeposition coatings, automotive touch-up paints, flexible protective films, corrosion-resistant lacquers.

    5. Precursor for Agrochemical Synthesis

    Chemical manufacturers employ Ethyl 2-Butenoate as a critical starting material for synthesizing certain herbicide and insecticide actives. The compound’s reactivity with nucleophilic and oxidative reagents supports controlled construction of functionalized agrochemical intermediates, with QA procedures tailored to mitigate cross-contamination risk and ensure regulatory traceability.

    Industry compliance standards

    • FAO Specifications for Plant Protection Products
    • OECD Guidelines for the Testing of Chemicals (AgChem Synthesis)
    • ISO 9001:2015 (Quality management for chemical manufacturing)

    Typical usage ratio

    • Typical batch synthesis employs 1–2 equivalents versus key intermediate; ratio optimized for yield and downstream conversion efficiency.

    Downstream process integration

    • Fed as a liquid reagent in stepwise synthesis or continuous flow systems; subjected to catalytic transformations and final purification before formulation into technical concentrate.

    Final product types

    • Select herbicide technicals, pre-emergent weed control actives, intermediate building blocks for pyrethroid insecticides.
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    Certification & Compliance
    More Introduction

    Ethyl 2-Butenoate: A Reliable Choice for Flavor and Fragrance Formulation

    Decades of Manufacturing Insight

    Ethyl 2-butenoate draws the attention of skilled formulators and product developers because behind its clear appearance lies years of technical learning and labwork. From our own experience scaling batches, the consistency of its synthesis directly affects the results downstream—no one wants off-notes in a batch meant for a high-value flavor. Unlike generic esters that enter the market through third-party trading channels, our output reflects the chemistry controls, operator vigilance, and raw material selection we've spent years refining. Each production run tests our eye for details: single-digit temperature swings or material variations in the early stages can echo through the entire process. Hands-on batch operators, not software, pick up the subtle variations in reaction rates and purity yields. You can taste and smell the effort.

    Chemically, ethyl 2-butenoate presents as a pale, mobile liquid with a sweet, fruity scent. Its molecular formula, C6H10O2, keeps it compact—easy to pipette or pour but not volatile enough to disrupt safe handling in regular plant environments. The real story, though, unfolds during purification. Precision drives us here. Our team tracks fractionation output to verify low residuals of cis- or trans-isomers, ensuring the authentic fruity note for which this ester is prized.

    Differentiation in a Mature Market

    Blenders and formulators routinely face questions about price, delivery, and documentation, but veteran buyers look deeper. Ethyl 2-butenoate can be sourced from a range of suppliers, all with their own pros and cons. Some offer short lead times directly from inventory, others sell lesser material at discount rates. The distinguishing factor is usually the synthesis route and final product traceability. Our site favors controlled esterification, monitored to limit side reactions. Each drum represents repeatable metrics: GC area percent purity above 99%, batch chromatograms on record, reagent lot tracking with auditable records. Such detail orients us for compliance with regulators and gives downstream formulators assurance of batch-to-batch stability. The absence of excessive aldehydes or non-volatile residue also reduces cleanup and rework in plant and lab environments—details only apparent after years of scale-up and batch troubleshooting.

    Many downstream users compare ethyl 2-butenoate with other flavor esters like ethyl crotonate or ethyl butyrate, evaluating both the olfactory impression and process compatibility. In our experience, ethyl 2-butenoate sustains its aroma profile even through intensive heating. It stands apart by offering sustained fruity top notes without heavy waxiness seen in some alternatives. For flavorists, this means flexibility: clean, sweet, true-to-nature fragrance impressions in fruit or citrus blends, often without the need of masking agents. In confectionery and beverage applications, minor impurities—a result of rushed or careless manufacturing—can dominate the sensory profile. Reliability in synthesis controls prevents these defects, supporting food-grade demands where “close enough” doesn’t meet industry standard.

    Plant-Level Experience with Ethyl 2-Butenoate

    At our facility, batches can range from pilot-scale trial runs for new clients up to multi-ton custom orders. Each scale brings its own technical hurdles. In small batches, minor contaminants go unnoticed until the GC run at the end. In large-scale production, equipment fouling and line carryover from other esters can compromise both yield and quality. We manage this risk by scheduling dedicated cleaning between campaigns, and never re-circulating any offgrade material back into bulk feedstock. These operational choices cut into throughput rates, but they allow us to claim high reproducibility—a point our customers rely on when designing product launches or scaling up blends.

    Every drum we ship includes explicit chromatographic data, not just bland test summaries. In our experience, buyers across food, beverage, and fragrance sectors increasingly demand this level of transparency. They value speed of delivery but not at the expense of traceability. Even a minor deviation in sensory notes can undo a supply agreement or spoil weeks of secondary blending work on their own shop floors. Our technical staff often consult directly with downstream QC teams, comparing chromatograms and troubleshooting batch queries in plain language. Open lines of communication build more trust than transactional order forms, which invariably miss crucial details.

    Why Ethyl 2-Butenoate Matters in Modern Product Design

    Formulators reach for ethyl 2-butenoate not just to recreate familiar sweet aromas, but for its blending power. It sits near the front of the palette when building complex fruit notes. Unlike heavier esters that overstay or vanish during processing, ethyl 2-butenoate retains its identity after mixing and moderate heat exposure. Beverage houses and candy makers turn to this molecule for its clarity of flavor—the delicate balance between top notes and finish mimics real fruit more closely than many alternatives.

    Food safety and regulatory compliance matter as much as aroma. We understand that traceability runs all the way from initial lot selection to final drum seal. Food manufacturers must comply with global regulations, from FDA to EFSA, which means every component down to micro-level contaminants matters. Our documentation extends beyond routine COA sheets; we track every raw material back to initial procurement, logging storage, reaction conditions, and operator oversight. This level of diligence only emerges through dozens of annual audits, recall drills, and transparent communication with quality authorities. A supplier who skips this attention risks not only supply interruptions but severe downstream recalls.

    In our time handling large-volume projects, we’ve joined technical workshops with buyers to streamline secondary processing—solving issues like ingredient carryover, homogeneity during mixing, and minimized batch rejects. Ethyl 2-butenoate, by virtue of its chemical stability, saves our partners troubleshooting time. We keep detailed work logs on past batches, supporting each new project with real-world evidence. These accumulated reference points underpin both process efficiencies and regulatory submissions, removing guesswork for teams assembling new product dossiers.

    Differences from Other Common Esters

    Chemically close kin, such as ethyl butyrate or ethyl crotonate, often serve similar markets but behave differently under plant conditions. In our hands, ethyl butyrate gives a more “buttery,” broad aroma, often trending toward heavy and cloying as concentration rises. Ethyl 2-butenoate, on the other hand, offers a sharper, more definitive note, making it preferable for bright, crisp fruit blends. Ethyl crotonate carries an extra carbon atom in its unsaturated chain and can produce green, earthy top notes which are sometimes unwelcome in fine confectionery or soft drink bases.

    These nuances only become apparent after actual mixing and shelf testing, something few traders or brokers witness firsthand. In our test kitchens and pilot lines, we combine these esters across varying ratios, monitoring not just aroma fade or flavor breakdown but also impacts on viscosity, emulsification, and downstream ingredient compatibility. Real-life sensory panels reveal what chromatography can’t—unexpected flavor “holes,” or masked off-notes that develop during storage. Our own batches of ethyl 2-butenoate provide consistently clean profiles even through extended shelf and stress testing. Product developers tell us this puts more control in their hands. It streamlines flavor tweaks, simplifies regulatory filings, and shortens time from prototype to shelf.

    Most chemical suppliers list basic specs and hope for the best. We work with our partners long after shipment—revisiting process parameters, reviewing new batch results, and troubleshooting formulation hiccups on the ground. Over the years, this collaborative cycle gives us a database of real-world performance feedback. These data points refine each production run and ensure our plant output keeps pace with shifting market demands and regulatory reviews.

    Supporting New Applications and Regulatory Shifts

    Ethyl 2-butenoate’s appeal continues to expand. In recent seasons, plant-based and natural beverage makers have turned to our batches to enrich non-dairy yogurts and alternative protein energy bars. The molecule integrates with these bases without overpowering delicate secondary flavors. Our R&D team, staffed by hands-on flavorists and process chemists, works directly with clients to adjust batch strength, purity, and sensory cues depending on their target market. Such customization stems only from direct production experience and data transparency—not from stockroom reselling.

    Regulatory landscapes never stand still. This ester falls under multiple compliance frameworks, with limits on residuals and purity thresholds set by food safety authorities worldwide. We predict changes by running simulations with substitute feedstocks in our pilot facility and scenario-testing any adjustment in reaction conditions. Years of batch data give us baseline metrics, so even as authorities shift allowable limits, we pivot processes without disrupting client supply chains. Early engagement with regulatory advisory groups lets us mop up new documentation requirements before they enter into force, keeping our partners off audit red flags and their launch timelines unthreatened.

    In the context of green chemistry and sustainable sourcing, ethyl 2-butenoate poses fewer hurdles than multi-stage synthetic molecules. Our team has piloted renewable feedstocks for precursor alcohols and acids, measuring performance impacts at each stage. At-scale change always reveals unexpected hurdles; some biological sources introduce more off-odors or complicate downstream filtration. Lessons from early mistakes influence future projects, and only after extensive in-house validation do we release any new process batch to commercial orders. Over time, these sustainability trials build confidence—not just in “green” marketing claims, but in plant efficiency, batch stability, and downstream supply reliability.

    From Plant Floor to Final Product: A Manufacturer’s Responsibility

    Years on the production floor teach that chemical quality affects not just product sensory appeal but production safety and sustainability. Handling esters like ethyl 2-butenoate involves balancing urgency with caution. Many overlook the impact of storage temperature, drum condition, and even warehouse humidity on ester quality. Our crew inspects every shipment on arrival for closure integrity and labeling—these hands-on checks stop contamination or mishandling from entering the chain. We’ve seen third-party drums arrive with faint leaks or confusing batch stamps, which complicate traceability and risk regulatory violations. Managing everything in-house allows problems to surface sooner and solutions to develop faster.

    Blending and dilution steps reveal another layer of complexity. Some newer plant teams treat ester mixing as “by-the-book,” yet real-world handling exposes the limits of simple directions. Overdosing concentrates can tip flavor scales or undermine shelf stability, requiring costly recalls. Our support extends beyond the sell—walking customers through dilution protocols, initial pilot blends, and batch scaling. This real-world guidance comes not from manuals but from repeated plant trials, batch fails, and troubleshooting calls at odd hours. This boots-on-the-ground perspective underpins all our recommendations.

    Reputation in the fine chemicals sector lasts only as long as your last successful product launch. Failures—due to off-grade batches, regulatory compliance slips, or unresponsive support—linger in the market and damage trust. We invest directly in plant upgrades, equipment calibration, and team training to reinforce every shipment’s reliability. Every improvement, whether in column efficiency or energy use, feeds back to customers: cleaner material, fewer reworks, and less downtime. These investments, while costly, maintain both our technical edge and our standing with regulators, auditors, and end users.

    Practical Solutions to Evolving Industry Demands

    Both global brands and mid-sized innovators appreciate flexibility—something stockholding distributors rarely offer. Our lean production approach means we can schedule custom runs for unique sensory blends, process modifications, or tailored delivery formats. We support cold-chain shipment for sensitive clients, supply refilling in returnable drums to minimize waste, and work with specialized packaging teams to prevent cross-contamination. Each adaptation draws from operational data, client feedback, and a direct understanding of limiting process variables.

    Ingredient cost pressures grow as natural disasters, supply chain shocks, and global events tighten feedstock markets. By consolidating raw material suppliers and holding secondary procurement contracts, we stabilize at least part of our input costs. These measures let us warn clients about potential volatility before it hits finished product pricing or delivery reliability. With direct batch-to-client communication, partners can plan around sourcing hiccups or reformulate in advance, not in a crisis. Few traders offer this proactive, technically grounded guidance.

    Product recalls cause chaos: scrambled production schedules, loss of partner trust, and regulatory heat. Mitigation approaches run through every batch—component screening, redundant testing, and online batch stat tracking. Digital logging confirms every control point from weighing to drum seal. Our investment in process automation reduces human error, but frontline operators still check anomalies by hand, nipping small defects before shipment. These process layers—unseen by outsiders—form the actual backbone of chemical reliability.

    Sustainability pressures aren’t just a marketing line. Buyers and regulators expect detailed evidence of green credentials, waste management, and energy efficiency. Our plant’s environmental audits trace water, energy, and byproduct use over rolling cycles, with corrective actions led by the same team that works daily lab and production shifts. Results feed into annual review and future project design. Trust isn’t built on slogans—decades of transparent reporting and shared know-how draw a clearer line.

    Direct Engagement: Manufacturing Experience Makes the Difference

    Ethyl 2-butenoate, carefully synthesized and thoroughly controlled, anchors many complex consumer products. It isn’t a showpiece chemical, but it represents a standard by which manufacturing diligence, batch traceability, and collaborative technical support are measured. Process refinements learned over scores of campaigns feed straight back into both our plant practice and client success. This chemical’s impact travels through every technical call, regulatory briefing, and product trial, knitting together the kind of trust that can’t be bought by lowest-bid brokering.

    Markets for esters continue to change—driven by global flavor trends, shifting consumer preference, and tighter regulatory frameworks. We stand by our hands-on approach—backstopped by data, improved through experience, and shaped by the needs of researchers, blenders, and brand owners worldwide. The value of ethyl 2-butenoate rests not just in analytical purity or specification compliance, but in the troubleshooting, communication, and real-world support that begin long before any drum leaves the plant.