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Diethylaluminum Chloride

    • Product Name Diethylaluminum Chloride
    • Alias DEAC
    • Einecs 205-488-0
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    261693

    Name Diethylaluminum Chloride
    Chemical Formula C4H10AlCl
    Molecular Weight 120.56 g/mol
    Appearance Colorless to pale yellow liquid
    Melting Point -90 °C
    Boiling Point 130 °C (decomposes)
    Density 0.93 g/cm³ (at 20 °C)
    Solubility In Water Reacts violently with water
    Flash Point -18 °C (closed cup)
    Cas Number 96-10-6
    Main Hazard Highly flammable, corrosive, moisture sensitive
    Storage Temperature Store below 30 °C, under inert atmosphere
    Synonyms DEAC, Aluminum, diethylchloro-
    Refractive Index 1.404 (20 °C)

    As an accredited Diethylaluminum Chloride factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Diethylaluminum Chloride, 500 mL, is packaged in a sealed, amber glass bottle with a secure cap, inside a protective metal can.
    Shipping Diethylaluminum chloride is shipped in tightly sealed, corrosion-resistant containers, typically made of steel or aluminum, under an inert gas such as nitrogen. It must be protected from moisture and handled as a flammable, pyrophoric liquid. Transport complies with hazardous materials regulations to ensure safety against leaks, spills, and accidental ignition.
    Storage Diethylaluminum chloride should be stored in a tightly sealed, corrosion-resistant container under an inert atmosphere such as nitrogen, in a cool, dry, and well-ventilated area away from moisture, heat, and incompatible materials like oxidizers and water. Protect from physical damage, ignition sources, and direct sunlight. Ensure proper labeling and access only to trained personnel, with spill containment measures in place.
    Application of Diethylaluminum Chloride

    Applications of Diethylaluminum Chloride in Industrial Manufacturing

    As a direct manufacturer of Diethylaluminum Chloride, we support a range of advanced chemical industries with market-established, sector-specific applications. Below we present focused, real-world scenarios where this catalyst and reagent plays a pivotal role in scale production, regulatory compliance, and finished material performance. Each industrial pathway reflects our commitment to detail, safety, and process reliability.

    1. Ziegler-Natta Catalyst Synthesis for Polyolefin Production

    In the polyolefins sector, Diethylaluminum Chloride serves as a critical co-catalyst component within Ziegler-Natta catalyst systems, actively participating in the polymerization of ethylene and propylene. Downstream manufacturers precisely dose it to tune molecular weight distribution and polymer microstructure, ensuring controlled process kinetics and consistent polymer properties through targeted catalyst activation and alkylation steps. The quality and residual control of Diethylaluminum Chloride are fundamental in batch and continuous reactor environments for scalable production of high-density and linear low-density polyethylene, as well as isotactic polypropylene grades.

    Industry compliance standards

    • ISO 1872-1 (Polyethylene for general use – Requirements and methods of test)
    • DIN EN ISO 19069-1 (Polypropylene requirements for molding and extrusion)
    • REACH Regulation (EC) No 1907/2006 – Registration and handling for monomer and catalyst residues
    • FDA 21 CFR 177.1520 (Olefins polymers for food contact, residual catalyst limits)

    Typical usage ratio

    • 0.1–0.8 mmol per mol of transition metal catalyst, with adjustment based on targeted polymer grade and comonomer ratio

    Downstream process integration

    • Introduction into solution/slurry/gas-phase reactors during catalyst pre-activation or direct polymerization stage
    • Metered addition using inerted dosing systems
    • Ongoing monitoring for residual removal, with post-polymerization deactivation and purification steps

    Final product types

    • High-density polyethylene (HDPE) Pellets
    • Linear low-density polyethylene (LLDPE) Resins
    • Isotactic polypropylene (PP) Granules
    • Polyolefin copolymers for film, fiber, and blow molding applications

    2. Alkylation Agent in Pharmaceutical Intermediate Synthesis

    Pharmaceutical manufacturers make use of Diethylaluminum Chloride as a specialized alkylating reagent for downstream preparation of organoaluminum compounds and as a facilitator of Friedel-Crafts-type alkylations and acylations. In multi-step syntheses, its precise addition enables construction of carbon frameworks for APIs, especially in steroid, hormone, and non-steroidal pharmaceutical routes. The material’s reactivity under anhydrous conditions helps achieve selectivity and high yields, while careful handling ensures strict compliance with cGMP and pharmacopoeial standards.

    Industry compliance standards

    • ICH Q7 Good Manufacturing Practice for Active Pharmaceutical Ingredients
    • USP–NF (United States Pharmacopeia–National Formulary) process chemicals guidelines
    • European Pharmacopoeia (Ph. Eur.) raw materials controls
    • GMP audit compliance for critical reagent traceability

    Typical usage ratio

    • Typically 5–20 mol% relative to limiting reactant, adjusted for substrate reactivity and target intermediate structure

    Downstream process integration

    • Addition to dry organic solvents under inert atmosphere at controlled temperatures
    • Staged quenching and extraction prior to final API crystallization and purification
    • Documentation in Master Batch Records and reagent registers

    Final product types

    • Protected steroid intermediates
    • Non-steroidal anti-inflammatory drug (NSAID) precursors
    • Pharmaceutical building blocks for oncology agents
    • Prostaglandin-intermediate esters

    3. Chain Transfer Agent for Specialty Alcohol and Aldehyde Synthesis

    Producers of fatty alcohols and aldehydes for plasticizers, surfactants, and lubricants implement Diethylaluminum Chloride to regulate chain growth in the oligomerization of alpha-olefins (e.g., the ethylene or propylene trimerization/tetramerization route). The material controls molecular branching and distribution, supporting downstream refinement and esterification processes. In continuous operations, quality monitoring systems verify that the reagent’s trace presence complies with product performance and safety standards relevant to plasticizer and surfactant applications.

    Industry compliance standards

    • EN 71-5 (Safety of toys – Determination of phthalates in plastics)
    • REACH Annex XVII restrictions (especially for plasticizer grade intermediates)
    • ISO 9001-certified process controls for specialty chemicals
    • API Q1 certification where supplied to oilfield and lubricant sector

    Typical usage ratio

    • 0.2–1.5 mol% relative to the alpha-olefin feedstock, with adaptation for desired branching and product cut

    Downstream process integration

    • Controlled dosing to oligomerization reactors during alpha-olefin feed
    • Subsequent aqueous workup and distillation to isolate target chain lengths
    • Monitoring of residuals to meet sector-specific end use limits

    Final product types

    • C8–C14 fatty alcohols for plasticizer production
    • Branched-chain aldehydes for surfactant synthesis
    • Lubricant base stocks
    • Oxo-alcohols for acrylate intermediates

    4. Alkylaluminum Precursor for Aluminum Alkyl Derivative Manufacturing

    Within specialty chemical operations, Diethylaluminum Chloride operates as a consistent precursor for preparing a family of higher alkylaluminum compounds through established transalkylation and ligand exchange methods. These downstream derivatives underpin further polymerization catalyst formulations, high-purity olefin epoxidation catalysts, and deactivators for chlorinated hydrocarbon processes. Industrial users emphasize material purity, water content, and control of ancillary halide byproducts to secure full traceability and compatibility across demanding downstream syntheses.

    Industry compliance standards

    • ASTM E2877-13 (Standard Guide for Raw Material Control of Organometallics)
    • ISO 16101 (Handling and storage of dangerous goods – Organometallics)
    • SEFA 9 (Scientific Equipment & Furniture Association – Lab reagent control)
    • Responsible Care® Process Safety Code (as per national implementation)

    Typical usage ratio

    • Stoichiometric or slight excess relative to desired end-alkyl group, typically 1:1–1.2:1 molar equivalents

    Downstream process integration

    • Batch or semi-batch reactor charging with tight temperature and moisture exclusion
    • Subsequent transalkylation, metathesis or reduction reactions to yield higher alkyl aluminum species
    • Product isolation by distillation or crystallization

    Final product types

    • Triethylaluminum and related aluminum alkyls for advanced catalytic systems
    • Modified organoaluminum reagents for fine chemical synthesis
    • Alkylating agents for high-purity epoxidation catalysts
    • Aluminum-based dehalogenation agents for specialty applications
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    Certification & Compliance
    More Introduction

    Diethylaluminum Chloride: A Closer Look at Its Role in Industry

    What We Offer as a Chemical Manufacturer

    Manufacturing Diethylaluminum Chloride doesn’t start or end at a batch reactor. From sourcing pure raw materials to maintaining strict temperature control, the process demands experience and attention at every step. Over years of hands-on work, we’ve refined our methods, not just to stay competitive, but out of necessity. Every drum and every flask leaving our facility reflects this deep respect for detail, because our customers depend on this chemistry staying exactly as expected—no unwelcome surprises, no trace of impurities that risk side reactions or shutdowns.

    Understanding Diethylaluminum Chloride

    Diethylaluminum Chloride, sometimes called DEAC, stands tall among organoaluminum compounds. In our plant, this material gets the attention such a reactive chemical deserves. Alkyllithium chemistry, polymerization catalysts, speciality intermediates—users count on consistent, high-quality DEAC to keep their own operations moving with no hiccups.

    Structurally, each molecule consists of an aluminum center with two ethyl groups and a chloride ligand. It looks simple on paper. But mastery of this compound means everything from aligning feed rates in synthesis to careful control during purification and storage. Moisture spells trouble, so our team builds double and triple redundancies to keep water at bay throughout the handling process.

    Variations and Specifications: What Our Team Sees in Practice

    Customers order Diethylaluminum Chloride by model designation and purity specs, depending on their end use. For many, the focus lands squarely on the color, clarity, and a low concentration of dissolved volatiles. Because these can tip off troubles in polymer catalysis or downstream synthesis, every batch must pass rigorous lab evaluation before it ships out. Common forms include solutions in hydrocarbon solvents such as hexane, heptane, or toluene, with concentrations commonly in the range of 1.0 to 2.5 mol/L. Our own batches trend toward a pale yellow, free-flowing liquid without sediment, and this kind of reliability wins returning clients.

    Some customers want custom blends or tighter impurity specs, especially those working within pharmaceuticals or electronics. We’ve invested in custom distillation and filtration setups, putting us in a position to actually deliver what others only promise. Quality control checks stretch far beyond what regulatory minimums set down, because too many years in chemical manufacturing teach you that “barely meets spec” isn’t worth the risk.

    Use Cases We See Most Often

    The lion’s share of Diethylaluminum Chloride flows toward catalyst preparation in Ziegler-Natta polymerization. Our own team supports customers running large polyolefin lines, where DEAC forms part of the essential co-catalyst package, activating transition metals and kicking off the polymer chain-growth process. Tiny inconsistencies in DEAC quality multiply down the line, so every kilogram we dispatch must align with the high bar set by global producers.

    Other clients order DEAC for role as an alkylating agent, particularly when more traditional Lewis acids or alkylhalides fall short. Its aggressive reactivity opens up specialty organometallic transformations, including key C-C bond-forming reactions or staged intermediates for custom fine chemicals.

    In fine chemicals, agrochemicals, and some areas of pharmaceutical research, DEAC’s use often migrates toward the bench, where synthetic chemists rely on every drop showing the same consistent behavior. Our technical staff regularly fields questions from labs about solutions, titration, and storage—direct dialogue with these groups keeps us sharp, and shapes how we nurture R&D of new grades and solvents.

    Safe Handling and Our Operational Reality

    Nobody working around Diethylaluminum Chloride cuts corners on safety. Contact with water triggers violent reactions—heat, hydrogen gas, and even fires in the wrong circumstances. Our plant floors feature dedicated unloading and transfer spaces, dry nitrogen blanketing, and fixed gas monitors. We build every drum and container with double seals, and we train shipping staff directly in our procedures—because outside logistics companies rarely grasp the nuance of a truly moisture-sensitive cargo.

    Regular audits and staff drills reinforce that safety isn’t paperwork: it means never accepting a shortcut, double-checking every seal, and knowing exactly what to do if something leaks. Our approach to safety management grew out of real events—the sort that leave lasting lessons rather than scars. Every improvement in our plant layout and PPE standards answers to the way Diethylaluminum Chloride really behaves, not an ideal imagined on a spreadsheet.

    Comparing DEAC with Other Organoaluminum Reagents

    Customers often ask what sets Diethylaluminum Chloride apart versus alternatives such as Triethylaluminum, Ethylaluminum Sesquichloride, or Aluminum Chloride itself. Triethylaluminum, for all its reactivity, ignites air far more readily, making storage a bigger puzzle. Ethylaluminum Sesquichloride offers a different activity profile, often narrower and less selective, especially in certain catalyst systems. Aluminum Chloride, meanwhile, trends toward classic Lewis acid chemistry but handles far fewer alkylation roles.

    In our own operations, we see that Diethylaluminum Chloride strikes a balance: reactive enough to enable challenging transformations, but not so overactive that it dictates exotic safety gear or storage nightmares. This sweet spot gives process engineers and research chemists leeway—optimizing yield, selectivity, or cost without constant troubleshooting. We keep all these key compounds on hand, but for regular production lines, DEAC tends to earn repeat business among veteran customers.

    Challenges We Tackle Daily as a DEAC Producer

    Weather shifts, delayed feedstock deliveries, and evolving regulatory expectations all circle our line. More than once, we’ve adapted our plant schedule on the fly due to upstream bottlenecks or increased demand from polymer producers during sudden seasonal surges. Sourcing high-purity aluminum alkyls leads down unexpected roads—sometimes the key to reliable DEAC is nurturing good vendor relationships for hydrocarbon solvents, or swapping in new filtration media when the old standard can’t keep pace with impurity profiles.

    Our R&D group craves challenges, so every unusual request gets a review—could we develop an even lower-impurity blend, or find ways to tune reaction kinetics for a partner designing a new polymer grade? We listen first, then experiment. Most days, problem-solving crosses between the bench and the plant floor, with chemists and operators working shoulder to shoulder. This sort of atmosphere keeps ideas flowing, often leading to incremental improvements across the product line.

    Handling the bureaucracy of transport regulations and export controls introduces its own grind. At our end, we never assume a shipper or customs broker fully understands Diethylaluminum Chloride’s hazards, so we walk through every shipment, sometimes training external partners ourselves.

    Quality Control in the Real World

    In the business of Diethylaluminum Chloride, lab results rule the day. Our quality control team spends as much time talking with our production operators as they do crunching data from titrations, Karl Fischer moisture readings, or GC impurity scans. Nothing leaves our plant unless it passes the full battery of tests. Even small deviations in color or odor send us back up the line—customers working in high-stakes industries expect nothing less.

    Equipment maintenance claims a good chunk of attention, since even minor corrosion, gasket failures, or valve leaks mean risks of water infiltration. The team documents every maintenance cycle, understanding that a single valve can mean the difference between a solid batch and a costly recall.

    Our approach to quality isn’t static. Seasoned operators train new hires in the quirks of real-world manufacture—what to watch for in a transfer line, why a particular still runs hot on humid days, where contamination most often sneaks in. There’s a direct line between shop-floor mentoring and the tight quality specs many customers need.

    Environmental Responsibility and Facility Upgrades

    In our part of the chemical sector, regulations around emissions, waste storage, and spill response remain tough but fair. We invest in on-site containment, vapor recovery, and routine soil and water testing. No plant can claim zero emissions, but minimizing environmental impact isn’t optional; it is standard practice that holds up under real inspection.

    Continuous improvement cycles drive plant investments. We’ve added double-walled tanks, upgraded solvent recovery systems, and kept a strict audit trail for every raw material drum coming through the gate. These upgrades mean steadier, cleaner batches and, in the long run, stronger customer trust. Lessons from past incidents—not just at our own facility but across the sector—filter directly into our engineering plans.

    Building Trust with Customers

    In the Diethylaluminum Chloride market, a handshake often means as much as a contract. Long-term relationships take years to build but evaporate fast if product quality or delivery confidence slips even once. We field regular customer audits, site visits, and performance reviews without hesitation. It pays off: many of our clients have worked with us for a decade or longer, looping us into their own process development and even inviting us on-site when rolling out new polymer lines or catalyst systems.

    We support our products with person-to-person technical support. If a customer’s process veers off target or a batch yields odd results, our chemists pick up the phone or join a call. We rarely deal with mega-firms staffed by faceless purchasing teams; most buyers are highly technical, know every quirk in their own process line, and value clear conversation over “marketing speak.” Bringing decades of direct production experience helps these customers through their challenges, and their feedback keeps us sharpening our own product miles beyond generic supplier specs.

    The Road Ahead for Diethylaluminum Chloride

    Industrial chemistry continues to evolve. New catalyst technologies, emerging focus on sustainability, and changing polymer requirements all drive demand for even tighter control over every batch. We stay close to technical forums, standards groups, and academic circles, learning from the broader field even as we hone our own process. This two-way dialogue puts us in position to advise customers intelligently—sometimes discouraging risky substitutions or offering new blends that save time and money without compromising safety.

    Developing next-generation Diethylaluminum Chloride systems means bigger investments in automation and process analytics. We’ve already installed inline molecular detection and remote plant monitoring, shortening the response lag between plant events and quality control action. These steps mean faster cycle times and sharper control, while also keeping volumes up during demand spikes.

    We monitor global regulatory changes closely. Restrictions on hazardous material transport, new occupational safety requirements, and shifting environmental standards all shape our progress. Fast adaptation matters—a flexible manufacturing team and nimble supply chain partners prove just as important as state-of-the-art instrumentation.

    Direct Insights from Our Team

    Many of our best process improvements start with floor staff observations. The technician who notices a subtle drift in color over an eight-hour shift may prevent an out-of-spec batch. Our operators continue developing practical ways to improve performance, and junior chemists bring a fresh eye to longstanding routines. This culture of responsibility and open feedback loop means challenges rarely fester—the team’s collective experience flows into daily operations and, ultimately, into stronger Diethylaluminum Chloride.

    Quality products come from a tight-knit, experienced crew, not from paperwork and protocols alone. By understanding both the science and the craft, our facility aims to set the benchmark year after year for Diethylaluminum Chloride.