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Dibutyl Phosphite

    • Product Name Dibutyl Phosphite
    • Alias Phosphorous acid, dibutyl ester
    • Einecs 213-613-4
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    182685

    Chemical Name Dibutyl Phosphite
    Cas Number 107-66-4
    Molecular Formula C8H19O3P
    Molecular Weight 194.21 g/mol
    Appearance Colorless to pale yellow liquid
    Boiling Point 231-233 °C
    Melting Point -60 °C
    Density 0.994 g/cm³ at 20 °C
    Solubility In Water Insoluble
    Refractive Index 1.425 - 1.427
    Flash Point 113 °C (closed cup)
    Odor Mild
    Vapor Pressure 0.01 mmHg at 20 °C
    Purity Typically ≥ 98%
    Shelf Life 24 months in unopened container

    As an accredited Dibutyl Phosphite factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Dibutyl Phosphite is packaged in a 500 mL amber glass bottle with a secure screw cap and hazard labeling for safe handling.
    Shipping Dibutyl Phosphite is shipped in tightly sealed containers such as drums or bottles, protected from moisture, heat, and ignition sources. The chemical should be handled by trained personnel, labeled per regulations, and accompanied by safety documentation. Transport must comply with local, national, and international hazardous materials regulations.
    Storage Dibutyl Phosphite should be stored in a tightly closed container, in a cool, dry, and well-ventilated area away from direct sunlight, heat sources, and incompatible materials such as strong oxidizers. Avoid contact with moisture. Proper chemical-resistant containers and secondary containment are recommended to prevent leaks or spills. Always follow relevant safety guidelines and regulatory requirements when storing this chemical.
    Application of Dibutyl Phosphite

    Applications of Dibutyl Phosphite in Industrial Manufacturing

    As a manufacturer specializing in high-purity Dibutyl Phosphite, we supply global producers with material tested and proven for precise roles in specialty industrial processes. The following application scenarios reflect real, sustained use cases defined by compliance, formulation specificity, and well-documented downstream final goods.

    1. Polymerization Catalyst Modifier in PVC Stabilizer Synthesis

    Dibutyl Phosphite enters liquid-phase reactors as a key ligand during the synthesis of organotin-based heat stabilizers for polyvinyl chloride. In these production lines, its reducing properties control valence states in catalyst activation, ensuring formulation consistency for demanding extrusion and injection molding end-uses. Our technical teams validate each batch against process-critical residue limits for downstream compounding.

    Industry compliance standards

    • REACH Regulation (EC 1907/2006) for polymer additives
    • ISO 9001-certified manufacturing traceability
    • RoHS Directive 2011/65/EU for heavy metal migration
    • FDA 21 CFR 177.2600 for indirect food contact plastics (when applied to food-grade stabilizers)

    Typical usage ratio

    • 0.05%–0.3% by weight of the stabilizer batch; dosage depends on target tin IV/tin II ratio and downstream polymer type

    Downstream process integration

    • Added in the catalyst charging step before temperature ramp-up in continuous or batch synthesis reactors; monitored via in-line redox titration

    Final product types

    • Methyl tin mercaptide stabilizers
    • Butyl tin stabilizers for PVC compounders
    • Organotin carboxylates for heat-stable pipes, profiles, and films

    2. Intermediate in Organophosphorus Agrochemical Synthesis

    Producers of selective insecticides and fungicides introduce Dibutyl Phosphite as the phosphorus donor in multistep active ingredient synthesis. Its reactivity profile, especially in controlled P-alkylation and P-S coupling reactions, supports yield efficiency while minimizing hazardous byproducts per downstream environmental audits. Quality assurance teams closely track residuals to ensure compliance with global crop protection regulations.

    Industry compliance standards

    • FAO/WHO JMPR (Joint Meeting on Pesticide Residues) specification for active ingredient purity
    • ISO 17025 laboratory validation for impurity analysis
    • EU Plant Protection Product Regulation (EC 1107/2009)
    • US EPA 40 CFR Part 180 for pesticide residual definitions

    Typical usage ratio

    • Ranges from 1.0 to 2.5 molar equivalents per phosphorus functional group introduced; precise ratio set according to target yield and minimization of side reactions

    Downstream process integration

    • Introduced during the phosphorylation or thiophosphorylation synthesis stage, typically after solvent charging and inert gas purging; followed by distillative recovery and aqueous work-up

    Final product types

    • Phosphorothioate pesticides (e.g., Dimethoate, Chlorpyrifos)
    • Phosphonate fungicides (e.g., Fosetyl-Al)
    • Agrochemical technical grade intermediates

    3. Antioxidant Synergist in Synthetic Lubricant Formulation

    Lubricant compounding plants integrate Dibutyl Phosphite as an oxidation inhibition agent, particularly in hydraulic and turbine oil blends. Within these recipes, it interacts with phenolic or aminic antioxidants at microdosage levels to extend service life under thermal loads. Our manufacturing process secures low sulfur and acid value thresholds to avoid downstream deposit formation in customer lubricant systems.

    Industry compliance standards

    • ASTM D4951 for phosphorus content in lubricants
    • ISO 6743-4 Hydraulics (HL/HP/HV fluid) classification
    • DIN 51524 Part 2 and 3 (hydraulic oil requirements)
    • OEM-specific performance trials for industrial lubricants (e.g., Siemens, GE steam turbine oil approval)

    Typical usage ratio

    • 0.02%–0.12% by weight of finished lubricant; dosage tuned for base oil saturation and antioxidant package balancing

    Downstream process integration

    • Post-base oil blending; combined with antioxidant and anti-wear additives after main blending but before filtration and charge to storage

    Final product types

    • Turbine oils for power generation
    • Hydraulic fluids for heavy machinery
    • Compressor and gear lubricants

    4. Reducing Agent in Metal Extraction and Refining

    Specialty metal refineries employ Dibutyl Phosphite as a selective reducing agent in the hydrometallurgical extraction of precious and rare metals, such as palladium and rhodium. Its controlled redox activity enables targeted recovery without excessive generation of unwanted byproducts, supporting downstream catalyst and electronics raw material chains. Batches undergo rigorous QC for organophosphorus impurity monitoring to meet catalyst-grade requirements.

    Industry compliance standards

    • ISO 9001 process control for precious metal recovery
    • Responsible Minerals Assurance Process (RMAP)
    • EN 1811 (for metal-containing materials in downstream applications)
    • National Environmental Protection Standards (NEPS) for waste handling in refining

    Typical usage ratio

    • 0.1–1.0% by weight compared to total metal content in feed solution; ratio adjusted based on target reduction depth and process capacity

    Downstream process integration

    • Introduced during the reduction stage, after leaching and primary filtration; reaction pH and temperature tightly controlled for metal-specific selectivity

    Final product types

    • Palladium black and rhodium sponges for automotive and chemical catalyst production
    • Metal concentrates for electronics
    • Specialty metal powders for coating and brazing

    5. Chain Transfer Agent in Solution Polymerization of Polyacrylates

    Dibutyl Phosphite operates as a chain transfer agent during the controlled polymerization of specialty acrylates for adhesives and coatings. Its selective interaction with growing chains moderates molecular weight distribution, supporting manufacturers’ quality standards in low VOC, high-adhesion final goods. Inline monitoring ensures no residual chain transfer reagent migrates to finished tape or adhesive surfaces.

    Industry compliance standards

    • ISO 14021 for environmental labeling of self-adhesive products
    • EU REACH Annex XVII for acrylate-containing adhesives
    • GB/T 2793-2020 (Chinese adhesive product standard)
    • Food Contact Materials EU 10/2011 for adhesives in packaging (where applicable)

    Typical usage ratio

    • 0.03%–0.15% by weight of total monomers; adjusted per target molecular weight and required rheological properties

    Downstream process integration

    • Injected at the initial monomer blend charging stage, before initiator addition and polymer chain propagation; process validated by GPC/QC

    Final product types

    • Pressure-sensitive adhesives for tapes and labels
    • Acrylic copolymer emulsions for coatings
    • Laminating adhesives in flexible packaging
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    Certification & Compliance
    More Introduction

    Dibutyl Phosphite: Manufacturer’s Perspective on Quality, Use, and Differentiation

    How We Manufacture Dibutyl Phosphite

    Producing Dibutyl Phosphite calls for exacting control at every stage, from raw material sourcing right up to the end of the batch. The compound’s formula — C8H19O3P — lays the foundation for its unique performance in industrial settings, especially as an intermediate and additive. In our facility, we focus on maintaining batch-to-batch consistency for high purity, targeting colorless, low-acid content output with minimal trace impurities. Years of adjusting reaction conditions have shown us that minor changes in temperature or catalyst dosing shift the final product’s characteristics, so we closely monitor every variable.

    Our standard model meets purity above 98 percent, which isn’t just a claim on paper. We analyze each lot by gas chromatography and acid value titration before any shipment. Every cylinder, drum, or bulk container gets checked for clear, particulate-free liquid and proper specific gravity, so end users aren’t left struggling with off-spec material or short shelf life. We have always found it essential to test beyond industry minimums for acid content and phosphorus recovery; otherwise customers can face downstream fallout.

    Feedback from direct industrial users matters more than any compliance checklist. Our operators most often note that any contamination during distillation or handling leads to polymerization issues for downstream formulations — especially with Dibutyl Phosphite meant for specialty lubricants or fire retardant additives. So our production rooms run with dry nitrogen blanketing and deliberate material transfer, not only to maintain clarity and purity, but to help control odor.

    Applications From Our Customers’ Operations

    Many of the requests we receive relate to Dibutyl Phosphite’s role as a chemical intermediate. It’s used in organic synthesis — particularly for manufacturing agrochemical actives and pharmaceutical intermediates — with companies choosing it for its mild reducing properties and ability to safely transfer phosphorus.

    Lubricant formulators turn to our product when modifying anti-wear or anti-rust chemistry for hydraulic fluids. They need guaranteed levels of phosphorus integration without the byproducts of heavier trialkyl or aryl phosphites such as Triphenyl Phosphite. Over the years, we’ve watched R&D formulators struggle with detergency, foaming, or oxidative instability when using inferior grades. Consistent physical quality from our batches limits the need for excessive post-processing.

    Past interactions with specialty resin makers highlight a concern: yellowing and odor in final polymer blends. Dibutyl Phosphite, when handled properly from the start, does not create the persistent yellow tinges often attributed to more reactive phosphites. That cleanliness is a direct reflection of our quality control from synthesis through to sealed drums. Applications demanding ultra-clear resins — such as optical films — benefit the most.

    We also work with flame retardant developers in plastics and coatings. Our experience shows that the phosphorus groups in Dibutyl Phosphite help form a char layer in the burning process, lowering combustibility faster than some aromatic phosphites. As a result, our product supports compliance in end formulations for electrical housings or circuit materials. This connection between upstream chemical purity and downstream fire performance is clear: higher raw material quality means less risk of failing QA batches at the compounder stage.

    What Sets Dibutyl Phosphite Apart From Similar Products

    From a manufacturing standpoint, Dibutyl Phosphite acts quite differently from its close relatives such as Tributyl Phosphite or Triphenyl Phosphite. Its reactivity under typical conditions is far milder, making it less corrosive and less prone to rapid hydrolysis. This difference matters for customers blending additive packages directly into aqueous or polar media, where rapid breakdown of mixed esters can disrupt production lines or require extra stabilizers.

    Our chemists say the oxygen-phosphorus bond strength in Dibutyl Phosphite balances reduction and stability, whereas Tributyl Phosphite’s higher activity makes it tougher to store and transport without gradual decomposition. Maintaining Dibutyl Phosphite’s stability lets our customers use a wider window of holding times in their storage tanks, which reduces rushed production schedules.

    Scent also tells a story here. Dibutyl Phosphite exhibits a lighter ester odor profile compared to heavier trialkyl or diaryl versions, making it easier for operators to work in closed spaces without the persistent aroma frequently linked to Triphenyl or Tris(2-ethylhexyl) Phosphite. Protections remain necessary, but the handling environment improves, and regulatory triggers fall further below threshold in well-ventilated blending areas.

    Some customers point out regulatory paperwork and labeling differences. For instance, Dibutyl Phosphite has lower aquatic toxicity marks compared to some higher-alkyl phosphites, so downstream users find it easier to meet discharge limitations after formulation. That difference hinged on both synthesis quality and the molecule itself, and we saw an uptick in demand once regulatory language in regions like the EU transitioned to tighter alkyl chain length stipulations.

    Health, Safety, and Environmental Perspectives From Production

    Dibutyl Phosphite doesn’t match the acute toxicity profile seen in older, heavier phosphite additives, but it still calls for attention. At the plant, all operators use nitrile gloves and full-face protection during batch handling, mostly to limit direct skin and eye contact. Prior cases with cargo leaks from improperly sealed drums taught us where process controls break down. That’s why we use sealed nitrogen blankets for storage, not only to keep the product clear, but also to slow hydrolysis, which can build up irritating byproducts.

    On the environmental side, we monitor both air and water discharges. Any spills rapidly self-oxidize on surfaces, so we train maintenance staff to contain and neutralize even small leaks. At scale, Dibutyl Phosphite’s lower vapor pressure compared to lighter trialkyl phosphites keeps evaporation losses to a minimum. That stability plays a role in keeping our plant’s emissions profile below local environmental reporting thresholds.

    During blending or transfer, we rely on closed pumps instead of open transfers and maintain all fill heads above the container to eliminate static build-up. Over the years, we have learned from production floor incidents — static discharge at the filling point frequently causes headaches, so grounding and equipment checks are daily routines. These process controls also prevent contamination, so that the product arriving at the customer’s site matches the certificate of analysis every time.

    Long-Term Product Stability and Customer Support

    Lots of discussions with our technical customers circle back to one issue: storage and shelf life. Used and stored correctly, Dibutyl Phosphite holds quality for a year or more in sealed steel or HDPE drums. Temperature swings speed up degradation, so we ship and recommend storage at moderate temperatures — always out of direct sunlight, always tightly closed, and away from moisture. Any deviation shortens workable lifetime.

    Humidity control isn’t just a good idea: unchecked, it causes acid number drift and a visible haze, which can lead to downstream application failure. We fielded calls in the past about clouding during additive blending in cold weather — analysis traced each case to moisture ingress or long-standing stock. This led us to improve our tank and drum closure systems, as well as run periodic training for our warehouse operators.

    We also keep a dedicated technical team on-hand to review storage feedback, offer handling guidance, and troubleshoot with customers on their own site. These direct lines reduce isolation between plant and customer, and let us learn when practical conditions differ from laboratory assumptions.

    Supply Chain Transparency From the Manufacturer’s End

    Customers rely on us to maintain open communication regarding any adjustments in batch runs, capacity, or supply scheduling. Over the years, raw material shifts and logistics challenges have pushed us to develop safety stock policies that absorb typical production upsets without interrupting customer programs.

    Unlike traders who move product between borders, we hold responsibility for every shipment’s origin, processing, and documentation. This has led us to integrate digital batch tracking across our dispatch operations. Whenever a logistics challenge arises — construction near a route, documentation for emerging regulatory standards, or transport temperature excursions — we communicate as soon as conditions change, not after the fact.

    Customers using Dibutyl Phosphite in regulated applications — especially in agricultural or food contact materials — obtain the necessary declarations and analysis data directly from our controlled batch records. These records tie back to audited raw material lots, not anonymous regional pools. This direct chain means our clients face fewer audits and easier downstream product qualification, supporting long-term production planning.

    Learning From Market Trends and Evolving Regulations

    We’ve watched the phosphite market respond to shifts in environmental regulation and end-user safety criteria. Historically, aromatic and high molecular weight phosphites ruled in flame retardant and stabilizer applications, but as attention to bioaccumulation and persistent organic pollutants increased, we saw migration toward lower molecular weight but more easily handled options like Dibutyl Phosphite. Most regulatory agencies now set sharper boundaries on residual impurities and environmental hazard classes, especially for additives with persistent phosphorus content.

    Over the last few years, the rise of stricter REACH and TSCA requirements prompted us to fine-tune our synthetic and purification methods. Rather than waiting for a compliance officer to flag an issue, we run annual audits on synthetic routes, procure environmental fate data, and monitor world health advisories. Several times, this preemptive approach helped us avoid late-phase batch quarantines or client supply slowdowns.

    Industry watchdogs and environmental NGOs keep a close watch on phosphorus-based intermediates, especially for their aquatic impact. Our team participates in sector association discussions and working groups, ensuring that our information stays current and that our recommendations reflect what’s actually happening in the supply chain, not just what appears in marketing material.

    Solutions For Technical and Process Hurdles

    Customers sometimes face compatibility or blending issues, especially when integrating Dibutyl Phosphite into systems accustomed to higher viscosity or more reactive phosphites. With our support, many have overcome pump cavitation, emulsion breakdown, or unexpected phase separations not by trial-and-error alone, but through direct bench trials at our site under simulated plant conditions.

    We welcome feedback on filtration challenges and downstream clarification. For instance, when secondary additives in the blend threaten to form gels, we help optimize co-additive dosing sequences and injection points — often by sharing pilot plant findings. Our technical laboratory recreates customer blend conditions, identifying problematic interactions with polymer stabilizers, anti-wear packages, or detergent dispersants before the final scale-up.

    Another technical topic involves the prevention of oxidative color changes during storage or transport. We operate in partnership with packaging manufacturers to make sure that our filled containers — whether small drums or bulk tankers — can withstand the mechanical and temperature exposures common in international freight. One example happened during a particularly hot shipping season, when we responded by switching to light-blocking drums and double-sealed lids as a standard.

    Early customer notification of production changes also plays a role. When we modified our drying step, we informed all bulk clients and ran joint compatibility testing before shipping wider volumes. As a result, no one encountered unexpected variance in their downstream performance.

    Quality Isn’t Just a Buzzword – It’s Measured in Our Labs

    Quality for us means verifying every lot against three key factors: phosphorus content, acid value, and visual clarity. Over many years, we’ve developed in-house analytical benchmarks stricter than typical industry norms. Each day’s output undergoes multiple checkpoint analyses, with samples taken at different stages across the plant, not just from the final drum.

    Direct collaboration with our largest clients let us set early warning limits for off-spec changes: if phosphorus content dips below specific thresholds, alerts go out and no delivery gets released. We created these standards after incidents with earlier partners, who received variable product from resellers. Consistency becomes the hallmark of direct-from-manufacturer supply.

    Our lab staff don’t just sit behind machines — they visit production areas, review procedures, and track deviations back to source material changes or process control drift. This hands-on approach links quality control tightly with actual production, not only with paperwork or technical bulletins.

    The Role of Relationships in Product Development

    Our product evolution owes just as much to ongoing customer discussion as to technical speculation. Many of the upgrades to packaging, purity, and batch control occurred because an existing client raised a concern or asked about a new application. The relationship isn’t just transactional: it’s built on regular feedback, collaborative troubleshooting, and a willingness to retool manufacturing lines for long-term benefit.

    One memorable example involved an agricultural intermediate producer who needed pinpoint phosphorus levels without excess byproducts. Over a series of trials, joint lab teams fine-tuned the process, which led to adoption of a new phase separation stage in our reaction line. This change lifted quality for all Dibutyl Phosphite lots across sectors.

    The Manufacturer’s Role in Supporting Industry Growth

    Manufacturers stand at the intersection of chemistry and practical application. The choices we make, from raw material source to process optimization, ripple downstream into customer processes and, in turn, final consumer products. It’s our responsibility to maintain transparency on batches, rapidly share technical developments, and work hand-in-hand with end users to identify problems and engineer solutions.

    Our ongoing investment in staff training, compliance systems, and plant upgrades translates into stable Dibutyl Phosphite supplies, predictable performance, and fewer customer line slowdowns. Feedback loops with customer R&D and production teams help us keep product in line with evolving industry needs without causing supply delays or surpluses.

    Why We Continue To Improve Dibutyl Phosphite Production

    The field of phosphorus-based intermediates keeps advancing. New demands from electronics, agriculture, polymers, and specialty additives push us to continuously test our output and manufacturing systems. What worked a decade ago rarely meets market or regulatory standards today. Perpetual refinement makes sense, not only for our growth but for the performance and safety of our customers’ products.

    By holding to transparent, fact-based manufacturing and customer engagement, we earn trust that lasts longer than a delivery cycle. Whether a customer faces technical hurdles, compliance audits, or new market requirements, ongoing dialogue and proven reliability provide the assurance that their Dibutyl Phosphite source supports both innovation and consistent production stability.

    Final Thoughts From Our Production Floor

    Dibutyl Phosphite doesn’t exist in a vacuum. Its performance depends on choices made every day in the plant, from distillation rates to drum sealing, and on the conversations we have with users facing real-world blending and regulatory pressures. What distinguishes us isn’t just a purity figure or a batch code, but a history of engagement with the realities of industrial chemistry.

    We maintain this standard not just to tick a box or satisfy a single order, but to ensure each new customer can rely on Dibutyl Phosphite that performs to requirement, reduces downstream risk, and meets or exceeds evolving safety and environmental standards. Our work, like the product itself, reflects ongoing care, long-term commitment, and an open line between manufacturer and user.