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Chlorotrifluoromethane

    • Product Name Chlorotrifluoromethane
    • Alias CFC-13
    • Einecs 200-914-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    456534

    Chemical Name Chlorotrifluoromethane
    Cas Number 75-72-9
    Formula CClF3
    Molar Mass 104.46 g/mol
    Appearance Colorless gas
    Odor Faint ether-like odor
    Boiling Point -81.4°C
    Melting Point -155.0°C
    Density 1.489 g/L (at 0°C, 1 atm)
    Solubility In Water 16 mg/L (at 25°C)
    Vapor Pressure 2,290 kPa (at 21°C)
    Flammability Non-flammable
    Uses Refrigerant (R-13), aerosol propellant

    As an accredited Chlorotrifluoromethane factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Chlorotrifluoromethane is packaged in a 50 kg steel cylinder with valve, labeled with hazard symbols and detailed chemical information.
    Shipping Chlorotrifluoromethane (Refrigerant R-13, CFC-13) is shipped as a compressed, liquefied gas in high-pressure cylinders. It is classified as a hazardous material (UN1022) and must be transported in accordance with regulations for toxic, nonflammable gases, ensuring proper labeling, secure containment, and protection against heat and physical damage during transit.
    Storage Chlorotrifluoromethane should be stored in tightly closed, properly labeled cylinders in a cool, dry, well-ventilated area, away from heat, open flames, and direct sunlight. Storage areas must be equipped with leak detection and appropriate fire suppression systems. Protect containers from physical damage and temperature extremes. Keep away from incompatible materials such as oxidizing agents, and handle only with proper safety procedures and equipment.
    Application of Chlorotrifluoromethane

    Applications of Chlorotrifluoromethane in Industrial Manufacturing

    As the direct manufacturer of chlorotrifluoromethane, we support multiple specialized industrial sectors by delivering highly controlled, quality-compliant production inputs. Below, we describe precise application fields with industry-specific process details and benchmarks.

    1. Refrigerant Gas Charging for Low-Temperature Cooling Systems

    Major producers of centrifugal and rotary refrigeration equipment use chlorotrifluoromethane as a primary refrigerant in closed-cycle refrigeration circuits designed for low-temperature and cryogenic applications. Its chemical stability and low boiling point underpin reliable performance in equipment requiring non-flammable cooling media. Refrigeration system integrators introduced it during vacuum charging or direct gas feed into evaporators, adjusting the charge according to circuit volume and target operating temperatures. Quality assurance teams monitor purity to maintain consistent vapor pressure and heat transfer qualities throughout long service intervals. The finished units rigorously adhere to sectoral refrigerant safety codes and efficiency requirements.

    Industry compliance standards

    • ASHRAE Standard 34 (Refrigerant Safety Classification)
    • EN 378-1:2016 (Safety and environmental requirements for refrigerating systems)
    • UL 207 (Refrigerant-Containing Components and Accessories)
    • ISO 817:2022 (Refrigerants – Designation and safety classification)

    Typical usage ratio

    • Refrigerant charge typically ranges between 90% and 100% system fill by weight; the exact charge is determined by compressor volume and required evaporator temperature profile, typically from -40°C to -150°C applications.

    Downstream process integration

    • Material is vacuum-charged directly into closed refrigeration loop before system sealing; charging stations use vapor or liquid-phase introduction depending on system size.

    Final product types

    • Low-temperature industrial refrigeration units
    • Environmental test chambers for electronics
    • Cryopreservation storage systems
    • Process cooling systems in chemical manufacturing

    2. Specialty Fluoropolymer and Elastomer Intermediate

    Producers of specialized fluoropolymers and co-polymers utilize chlorotrifluoromethane as a controlled-feed monomer or chain transfer agent during polymerization. The raw material is introduced into reactors with regulated dosing under high pressure, alongside tetrafluoroethylene or vinylidene fluoride, to engineer specific mechanical and thermal characteristics into finished resins and elastomers. Its unique reactivity profile allows for production of low-permeability, chemically inert polymers required in critical fluid handling and high-purity environments. Strict process monitoring ensures batch-to-batch consistency, and downstream purification eliminates unreacted gas and byproducts to guarantee regulatory compliance for technical or food-contact grades.

    Industry compliance standards

    • FDA 21 CFR 177.1550 (Perfluorocarbon resins in food contact)
    • ISO 10469-1 (Plastics — Fluoropolymer resins)
    • REACH Regulation (EC) No 1907/2006 (Substance registration and handling)
    • RoHS 2011/65/EU (Restriction of Hazardous Substances for electronics applications)

    Typical usage ratio

    • Monomer or chain transfer agent application varying from 1% to 10% by weight, based on the desired molecular weight and copolymer structure; process engineers optimize loading to balance polymer architecture with safety thresholds.

    Downstream process integration

    • Metered gas-phase feed into the main polymerization autoclave or batch reactor; dosing continues until target conversion levels are reached, followed by off-gas neutralization and high-purity resin recovery.

    Final product types

    • Fluoropolymer gaskets and valve seats
    • Non-stick and chemical-resistant linings
    • High-performance elastomeric O-rings
    • Semiconductor-grade tubing and components

    3. Halon Fire Suppression Chemical Synthesis

    Manufacturers of clean agent fire extinguishing systems use chlorotrifluoromethane as a precursor in synthesizing halon compounds such as Halon 1301 (bromotrifluoromethane). Controlled halogenation reactions in pressurized reactors convert it to targeted halons, with strict handling to control emissions and meet legacy system requirements in specialized facilities where alternatives are not feasible. Facility quality teams implement continuous gas monitoring and follow robust waste gas treatment protocols. Only registered industrial operators with compliance clearance can source and use this raw material for halon synthesis under current chemical regulatory frameworks.

    Industry compliance standards

    • Montreal Protocol Annex C (Substances that deplete the ozone layer: controlled use exemptions)
    • ISO 14520-1:2015 (Gaseous fire-extinguishing systems – Physical properties and system design)
    • UL 2166 (Standard for Halocarbon Clean Agent Extinguishing System Units)
    • National Fire Protection Association NFPA 2001 (Clean Agent Fire Extinguishing Systems)

    Typical usage ratio

    • Stoichiometric feed based on halogenation—reaction can require 100-120% theoretical dosage for conversion; excess managed through recycling and gas scrubbing systems.

    Downstream process integration

    • Direct feed as a vapor or liquefied gas into halogenation reactors; product is continuously monitored for conversion rates and residual reactant management, followed by purification and bottling of Halon end-products.

    Final product types

    • Halon 1301 fire suppression agent
    • Halon blend compounds for aviation, defense, and irreplaceable facility protection
    • Service and refill canisters for legacy total flooding systems

    4. Electronic Component Cleaning and Plasma Etching Gases

    Manufacturers within the electronics sector apply chlorotrifluoromethane as both a precision cleaning agent for delicate components and as a plasma etching gas in semiconductor wafer processing. The gas offers low toxicity, dryness, and chemical inertness, meeting the cleanliness requirements for advanced microfabrication. It is deployed in controlled vacuum chambers or under regulated flow for dry cleaning circuit boards and removing particulate or ionic residues post-fabrication. In plasma etching, it creates reactive fluorine-based plasma to etch silicon or dielectric layers, tightly controlling aspect ratios and etch rates essential for next-generation device production.

    Industry compliance standards

    • SEMI C3 (Specification for Gases – Electronic Grade)
    • IPC-CH-65 (Cleaning and Cleanliness guidelines for printed boards and assemblies)
    • ISO 14644-1 (Classification of air cleanliness for cleanrooms, for process integration)
    • RoHS 2011/65/EU (Substance restrictions in electronics manufacturing)

    Typical usage ratio

    • As cleaning gas, flow rates of 5-20 SLPM (Standard Liters per Minute) depending on chamber volume; for plasma etching, typical gas phase concentration of 2% to 10% based on layer thickness and target etch selectivity.

    Downstream process integration

    • Direct feed into vacuum cleaning or plasma etch chambers, controlled via mass flow controllers and integrated safety cut-offs; systems equipped with exhaust scrubbing to capture any off-gas.

    Final product types

    • High-density semiconductor wafers
    • Precision-assembled printed circuit boards (PCBs)
    • Cleaned microelectronic components and sensor modules
    • Microelectromechanical systems (MEMS)

    5. Ultra-Low Temperature Heat Transfer Fluid Formulation

    Specialty heat transfer equipment manufacturers blend chlorotrifluoromethane into proprietary low-temperature heat transfer fluids for batch and continuous-use systems. Its low freezing point and inertness expand the thermal operating window for closed-loop thermal management in critical environments such as aerospace simulation, pharmaceutical freezing, and scientific instrumentation. Formulators adjust concentration within multi-component mixtures to fine-tune thermal conductivity and viscosity, balancing phase change stability with equipment compatibility. Product stewardship teams closely track material batch traceability and regulatory documentation to satisfy end-use qualifications.

    Industry compliance standards

    • ASTM D5182 (Test method for measurement of lubricant properties at low temperatures)
    • EN 12390-7 (Heat transfer fluid properties in industrial systems)
    • ISO 9001:2015 (Quality management system for specialty fluid compounding)
    • REACH Regulation (Declaration for downstream use and transport)

    Typical usage ratio

    • Heat transfer fluid blends typically comprise 10–60% chlorotrifluoromethane by weight, set according to required freeze point and flow curve for each thermal duty; remaining portion includes customized base solvents.

    Downstream process integration

    • Metering into jacketed reactor tanks or mixing vessels equipped with recirculation; followed by filtration and drum or tote packaging under nitrogen blanketing to minimize contamination.

    Final product types

    • Low-temperature circulating coolant fluids
    • Chiller fluid for pharmaceutical freeze-dryers
    • Scientific cryostat bath mixtures
    • High-precision temperature control fluids in aerospace ground support
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    Certification & Compliance
    More Introduction

    Chlorotrifluoromethane: A Straightforward Introduction from the Production Line

    Real-World Experience with Chlorotrifluoromethane

    Chlorotrifluoromethane, which many know as R-13 or CFC-13, has been running through our reactors for decades. It has found its place in several challenging applications, and anyone on the plant floor recognizes the telltale characteristics that set it apart. Our experience isn’t theoretical; it comes from years of daily interaction with this compound, from charge calculations to loading tankers.

    At its core, this chemical’s resilience shines in environments where low temperatures frustrate most alternatives. R-13 boils at -81°C and holds up under pressures that would send weaker molecules scrambling. Its molecular structure—one carbon, one chlorine, three fluorines—delivers consistent performance in high-demand scenarios. We see this every time we fill bulk containers for end-users in high-performance refrigeration, especially ultra-low temperature logistics, laboratories, and aerospace ground support.

    Why Industry Still Turns to Chlorotrifluoromethane

    Global regulations sparked a rush toward replacements in recent years, but despite efforts to phase it out, certain tasks remind us daily that engineered substitutes often fall short, especially under extremes of cold or pressure. Some alternatives struggle with thermal stability or lose energy efficiency in real-world cycles. Chlorotrifluoromethane still holds its ground where reliability at minus eighty means the difference between waste and success—vaccine storage, sample preservation, or aerospace research.

    Every batch leaving our plant follows protocols refined by generations of practical feedback. We prioritize purity since trace moisture or acidity can damage sensitive cooling equipment fast. Every drum is tested for non-condensable gases and checked for acidity well below international maximums. Temperatures stay stable right down to the last gram, even during long shipments. We have dealt with breakdowns caused by chemical impurities from substandard R-13 in the market, so consistency is non-negotiable on our end.

    From Raw Materials to End-Use: What Sets Our Chlorotrifluoromethane Apart?

    We source raw chlorinated and fluorinated feedstocks directly from vetted partners, passing on the lowest possible levels of extraneous byproducts. Over time, we’ve upgraded distillation columns and compression systems to address even minor contaminants. This extra step matters. Long ago, we learned that inconsistent feedstock leads to more equipment downtime and shorter compressor life for everyone downstream. Today, customers come to us specifically after equipment failures caused by trace contaminants in “cheap” alternatives. Our approach is simple: take raw material testing and batch documentation seriously, so no truck leaves the gate until we can vouch for every kilogram.

    Handling, too, makes a difference. Chlorotrifluoromethane can quickly escape ordinary seals or valves. We maintain pressure-rated containers with PTFE seats and run visual checks on every fitting before each fill. Staff on the floor have learned the hard way that even slight procedural drift can mean product loss or environmental discharge. Our packing processes close that gap with regular walk-down inspections and automated monitoring on every transfer.

    End-Use Realities: Ultra-Low Temperature and More

    We see the real impact of Chlorotrifluoromethane in applications where a failed refrigerant creates costly downtime or irreplaceable product loss. The pharmaceutical industry, for instance, demands continuous storage below -70°C, especially for vaccines and biological samples. Some distributors claim new HFCs do the job, but complaints of compressor noise, rising amp draws, and loss of cooling led multiple customers straight to our office. Lab technicians report that R-13 runs quieter and keeps thermal swings at bay, so they stick with what works—especially when one failed freezer means months of ruined work.

    Aerospace groups rely on R-13 to keep test chambers and guidance electronics stable during preflight checks. The difference shows up in smooth ramp-downs during system cooldowns and minimal temperature deviation throughout the test cycle. We provide direct technical support for these customers because their margin for error is essentially zero. No one wants to see a launch slip due to cooling system hiccups from questionable refrigerants. We’ve watched end-users troubleshoot with us side-by-side, chasing leaks and correcting pressure faults, and that boots-on-the-ground experience makes its way back to the plant—modifying our own quality checks and packaging, again putting reliability above everything else.

    Comparing Chlorotrifluoromethane to Alternatives

    Over the last ten years, the pressure to swap legacy refrigerants for new blends is everywhere. Many HFCs like R-23 or blends with R-503 market themselves as drop-in replacements. We have tested several ourselves, both in-house and with partners in the equipment manufacturing sector. Often, alternatives break down faster under repeated cycling below -70°C. Complaints about lubricant separation, erratic expansion valve behavior, and system fouling have all traced back to formulation variation from distributers sourcing offshore blends.

    Chlorotrifluoromethane’s non-flammability remains a critical safety advantage. Not every new replacement offers that margin. Working daily with bulk amounts, our staff learned to respect pressure dynamics and venting procedures. We never compromise on systems for detecting leaks or instructing customers on safe canister storage, especially for older facilities whose venting and pressure relief equipment might not meet new codes. Technicians and plant managers gain peace of mind handling a proven molecule with a transparent, well-documented risk profile.

    Whereas many alternatives require system redesigns—different expansion valves, compressor swaps, or complete oil changes—Chlorotrifluoromethane often streams right into legacy gear. People keeping old gear running appreciate not having to recalibrate sensors, swap out seals, or tinker with motor controllers. Our factory service teams find that workhorse low-temp freezers from the nineties still run at spec with fresh R-13, so long as care is taken with retrofitting gaskets and checking for age-related leaks.

    Three things jump out in daily practice: chemical stability, physical safety, and backward compatibility. Real-world end-users want to minimize downtime from failed attempts to switch. Engineers have stood with us in test bays, racing the clock before sensitive turbines or lab chillers reach critical thresholds again. These working relationships underscore why our plant keeps tanks of R-13 ready while keeping a sharp eye on technical bulletins around new blends. Testing real-world service performance means more than a spreadsheet promise or laboratory cycle—it means predictable, reliable operation in the field.

    Environmental Challenges and Regulation

    Manufacturing and using any chlorofluorocarbon today means facing environmental restrictions head-on. The Montreal Protocol forced a steep production cut, and compliance audits are part of our daily life now. Each year, we adjust batch sizes and batch frequency according to global and national quotas, submitting detailed documentation to regulatory agencies. Every tank that leaves the plant gets matched with end-use declarations, in compliance with evolving import and export controls. No shipment leaves without complete tracking from our gate to the end-user’s dock.

    We’ve invested in emission reduction: modernized seals, automated leak detection, and full capture during transfer. Recovery units for spent refrigerant run on every line, with on-the-spot reclamation where practical. Training each new technician matters, as one careless vent can undo months of emission savings. Most end-users work with us because they know that full chain-of-custody accountability isn’t optional anymore. Any part that shortens the refrigerant lifecycle through premature venting means more scrutiny down the road, and as a manufacturer, we shoulder that responsibility.

    Efforts to reclaim and recycle R-13 keep growing. Customers send used product back to our site for batch testing, cleaning, and requalification. We clean out oil, water, and acid residues that have slipped past field separators, then re-distill and analyze before packaging for reuse. This process isn’t easy, but the shared cost of recycling means legitimate customers have a steady, verifiable stream of product that keeps older critical systems running without relying on illegal or black-market imports. Real recycling efforts result from hard environmental realities and supply constraints.

    Where Chlorotrifluoromethane Succeeds and the Future

    Certain scenarios keep R-13 relevant longer than anyone projected. In technical refrigeration—such as semiconductor lithography and scientific research—the smallest fluctuation in temperature can throw off months of work or damage million-dollar runs. Industry colleagues in cryo-storage call with news on their latest test cycles, swapping feedback on energy demand, compressor maintenance, and thermal readings. The shift to “greener” refrigerants is underway, but the margin for error shrinks as stakes rise, so transition plans turn more on operational data than regulatory deadlines.

    We have worked directly with equipment makers and research labs to document performance curves across thousands of hours. Reports match our own experience: stable enthalpy, low pressure drop across evaporators, predictable oil return, and strong resistance to polymer degradation even after repeated cycling. It’s not a perfect molecule—no CFC deserves that description—but some roles make it too valuable to phase out carelessly.

    Safety Knowledge from the Plant Floor

    No editorial on this refrigerant is complete without discussing direct handling risks. We run safety briefings every shift, making sure each team member recognizes symptoms of leaks and pressure build-up. Monitors track background concentrations on the production floor and throughout loading bays. Our culture has absorbed the lesson that ignoring a small pressure alarm or drips around a transfer hose can result in problems far bigger than lost product or downtime—exposure risk is real, as is environmental impact. For teams that worked with older refrigerants, the distinct sharp odor and rapid evaporation of R-13 offered early warning, but nowadays, sensor alarms back those instincts.

    Every plant operator learns to handle the product with engineering controls: remote fill setups, carefully maintained pressure regulators, triple-redundant relief valves, and personal protective equipment. Proper labeling, meticulous inventory records, and strong ventilation systems give the margin needed for safe operation. Over the years, colleagues have retooled everything from valve designs to fill station layouts, sharing best practices throughout the industry. Handling CFCs the right way means giving the job constant, undivided attention, even as regulatory pressure ratchets higher.

    Supporting Transition Strategies

    Our factory has supported partners through changeovers to alternative systems as technologies mature. Consulting with engineering and facilities staff on site, we offer performance data and hands-on advice to ease the transition, where business demands or regulations mandate it. Not every plant or freezer can switch out overnight. For legacy equipment that can’t migrate without major capital outlays, we fill a gap—supplying high-purity R-13, supporting upgrades, and ensuring responsible disposal or reclamation. It is a balancing act: meeting today’s needs without ignoring tomorrow’s climate impact.

    We hear the same refrain from customers forced to pivot to new refrigerants: unexpected failures, system pressure spikes, wear on seals, even safety incidents from misapplied blends. Direct experience tells us that safe phase-out hinges on slow, data-driven transitions, not arbitrary deadlines. Providing technical field support and sharing know-how around system prepping, oil flushing, and pressure settings cuts down on calls about failed conversions.

    Quality Above All: The Key to Reliable Operation

    Experience proves that controlling impurities, water content, and acid levels in each drum is what keeps sensitive applications running. Complaints about marginal producers skip out on basics like real-time purity checks, on-site gas chromatography, or filtered fill lines. We print batch test results with every shipment; no surprises, no guesswork. Customers needing uninterrupted performance in biomedicine, aerospace, or industrial R&D insist on this level of transparency. Our best technical relationships started with a call about a failed compressor or wild temperature swings traced back to subpar R-13 sourced elsewhere. Years of these service calls have shaped our current best practices, from incoming feedstock testing to final pressure inspection before a drum leaves the dock.

    Lessons Learned and Looking Ahead

    Making and supplying Chlorotrifluoromethane means accepting tough scrutiny, juggling operational risks, and adapting to global environmental policies that change regularly. The chemical’s unique properties—strong cooling at the lowest temperatures, non-flammability, compatibility with legacy equipment—remain unmatched in select settings. Meeting demand for both quality and climate responsibility is a careful dance that comes down to operational discipline and open collaboration with those using the product in the field. Every customer complaint and every regulatory change has taught us something new, prompting improvements both on the plant floor and in documentation. Chlorotrifluoromethane isn’t likely to fade from specialized use until true one-to-one replacements reach the same level of reliability.

    In the meantime, real-world knowledge—drawn from the intersection of daily plant work, regulatory compliance, and hands-on technical support—guides our every batch. The pathways for phase-downs, reclamation, and safe transition get mapped in conference calls, training sessions, and site visits, where lessons move quickly from incident report to standard practice. For everyone in critical low-temperature fields, Chlorotrifluoromethane’s future, for now, still depends on quality manufacturing, grounded safety culture, and the trust built through years of shared experience where mistakes are too costly to risk.