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Calcium Hydrosulfide

    • Product Name Calcium Hydrosulfide
    • Alias Baryta hydrosulphide
    • Einecs 235-189-2
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    828036

    Name Calcium Hydrosulfide
    Formula Ca(HS)2
    Molar Mass 106.22 g/mol
    Appearance Colorless crystals
    Odor Characteristic hydrogen sulfide smell
    Solubility In Water Soluble
    Melting Point Decomposes
    Density 2.06 g/cm³ (approximate)
    Cas Number 16313-91-4
    Stability Unstable, decomposes in air
    Primary Hazard Toxic, releases H2S gas
    Common Uses Chemical industry, intermediate compound
    Ph Basic in aqueous solution

    As an accredited Calcium Hydrosulfide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Calcium Hydrosulfide, 500g, is packaged in a sealed, corrosion-resistant HDPE bottle with a tamper-evident cap and hazard labeling.
    Shipping Calcium hydrosulfide should be shipped in tightly sealed, corrosion-resistant containers, clearly labeled, and protected from moisture and acids. It must comply with relevant transport regulations, including hazardous material guidelines. Ensure proper ventilation and avoid contact with incompatible substances during transit. Emergency response information must accompany the shipment at all times.
    Storage Calcium hydrosulfide should be stored in a cool, dry, and well-ventilated area, away from acids, moisture, and incompatible materials. Containers must be tightly sealed, clearly labeled, and made of corrosion-resistant materials. Store away from fire sources and ensure proper secondary containment to prevent leaks or spills. Regularly inspect storage conditions to maintain chemical integrity and safety.
    Application of Calcium Hydrosulfide

    Applications of Calcium Hydrosulfide in Industrial Manufacturing

    As a specialist in high-purity calcium hydrosulfide production, we serve manufacturers who rely on this versatile reagent for vital roles in established sectors. Here, we detail its application landscapes, referencing sector-specific standards, recommended formulation practices, process integration points, and representative end-use product types for reliable, specification-driven B2B demand.

    1. Leather Unhairing in Tanning

    Major tanneries leverage calcium hydrosulfide during the unhairing phase of beamhouse processing to accelerate hair removal while preventing excessive grain damage and maintaining hide quality. This application traces its roots to standardized European and US workflows, where consistency of reagent grade, solution preparation, and effluent management determines process efficiency and product acceptability.

    Industry compliance standards

    • EU REACH Regulation (EC) No 1907/2006 for chemicals used in leather processing
    • ISO 5430-1:2002 (Leather—Chemical Tests—Determination of Sulfide Content)
    • US EPA effluent limitations guidelines, 40 CFR Part 425 (Leather Tanning and Finishing Point Source Category)
    • ZDHC MRSL (Zero Discharge of Hazardous Chemicals—Manufacturing Restricted Substances List for tanneries)

    Typical usage ratio

    • 2%–5% based on rawhide weight, with concentration adjusted for temperature, hide thickness, and beamhouse recipes; soft hides require lower dose, while thick bovine hides need up to upper range.

    Downstream process integration

    • Dispersion into the lime pit or drum following soaking and prior to deliming; introduced as aqueous solution and agitated to ensure full penetration into the hair follicle layer.

    Final product types

    • Wet blue hides
    • Finished full-grain and corrected-grain leathers for footwear
    • Automotive upholstery hides
    • Vegetable- and chrome-tanned side leathers

    2. Heavy Metal Wastewater Treatment

    Industrial and municipal treatment plants apply calcium hydrosulfide to precipitate soluble heavy metal ions (such as Cd2+, Hg2+, and Pb2+) as insoluble sulfide salts, facilitating easier sludge handling and compliance with effluent discharge regulations. Real-time dosing and rigorous monitoring of residuals form critical parts of these applications, governed by clear environmental and occupational standards.

    Industry compliance standards

    • US EPA NPDES Permitting (40 CFR 122), Effluent Guidelines for Metal Finishing (40 CFR 433)
    • EN 12255-14 (EU standard for chemical treatment in wastewater plants)
    • International Cyanide Management Code for gold mining operations using sulfide precipitation
    • Local groundwater protection ordinances regarding metal residuals

    Typical usage ratio

    • Stoichiometric addition: 1.1–1.25 molar equivalents per mole of target heavy metal ion, adjusted via process control based on influent metal loading and pH control (typically pH 9–10).

    Downstream process integration

    • Dosed inline after equalization and neutralization stages, prior to primary clarification; introduced via metered pumps into mixing tanks allowing for immediate precipitation reactions.

    Final product types

    • Dewatered metal sulfide sludge for secure landfill or offsite treatment
    • Treated effluent meeting regulatory metal discharge limits
    • Byproduct streams for cement kiln utilization in select cases where stabilization permits
    • Press-filter cakes for hazardous waste management

    3. Pulp and Paper Kraft Process

    In the pulp and paper sector, calcium hydrosulfide enters white liquor preparations to sustain the chemical balance required for effective wood delignification during the kraft pulping cycle. Its integration is tightly regulated to modulate the sulfidity of the cooking liquor, which determines pulp yield, fiber strength, and residual black liquor composition. Data-driven dosing prevents yield losses and adheres to sector QC demands.

    Industry compliance standards

    • TAPPI T650 om-15 (Test Methods for Chemical Recovery)
    • NCASI Protocols for Kraft Pulping Environmental Compliance
    • ISO 302:2015 (Determination of Kappa Number of Pulp)
    • OSHA 29 CFR 1910 (regulations for sulfide exposure in mill operations)

    Typical usage ratio

    • 6–12 kg per metric ton of oven-dry wood chips, depending on required sulfidity (18%–30% of total alkali) and wood species (softwood requires higher loading for effective lignin removal).

    Downstream process integration

    • Dissolved into white liquor alongside sodium hydroxide in the liquor furnish tank prior to impregnation and cooking; monitored by titration and online sensors for tight process control.

    Final product types

    • Kraft unbleached pulp for linerboard and bag paper production
    • Semi-bleached pulps for printing grades
    • Market pulps shipped for tissue and specialty paper
    • Black liquor for recovery boiler feed

    4. Mining Flotation Reagents

    Non-ferrous mineral processing plants—especially those extracting copper, lead, zinc, and precious metals—call on calcium hydrosulfide to regulate pulp surface chemistry during flotation. Used as a sulfurizing agent, it enhances selectivity for valuable sulfide ores (e.g., chalcopyrite, sphalerite) by modifying mineral collector adsorption. Dosing strategies match precise ore compositions, ore throughput rates, and ISO/ASTM methods for validation.

    Industry compliance standards

    • ISO 9001:2015 (Processing QC Management System)
    • ASTM D4188-19 (Standard Practices for Flotation of Copper Ores)
    • ICMM Guidance on Hazardous Chemical Management in Mining Environments
    • MSHA regulations (30 CFR Parts 56 & 57 Occupational Exposure Standard)

    Typical usage ratio

    • 50–500 g per metric ton of ore; exact dosage tailored via lab-scale trials to account for ore type, pH buffer, and collector strength.

    Downstream process integration

    • Injected into conditioner tanks before or during flotation cell operation; staged addition permitted for multiple float circuits with varying mineralogies.

    Final product types

    • High-grade copper, lead, zinc concentrates
    • Enriched gold or silver-bearing sulfide concentrates
    • Sulfide tailings for downstream treatment or stockpiling
    • Byproduct elemental sulfur or acid plant feedstock

    5. Chemical Manufacturing: Thioorganic Synthesis

    Producers of thioorganic chemicals and specialty organosulfur intermediates utilize calcium hydrosulfide as a controlled sulfur donor in the synthesis of compounds like mercaptans, thiols, and sulfides for industrial and agricultural applications. Careful management of purity and reaction rate at each stage ensures compliant yields and downstream acceptability in line with industry and customer regulatory frameworks.

    Industry compliance standards

    • GMP Certification (for agricultural and pharmaceutical intermediate uses)
    • REACH (EC No 1907/2006) Registration for thioorganic intermediates
    • ISO 9001:2015 (Production Process Consistency)
    • Specific customer environmental and trace impurity specifications

    Typical usage ratio

    • 0.8–1.2 molar equivalents per target reactant, varying with the desired length of the aliphatic or aromatic thiochain; small adjustments made to optimize selectivity and minimize byproducts.

    Downstream process integration

    • Pumped as aqueous solution into jacketed batch or continuous reactors charged with halo-organic substrates; introduced post-initiation for exothermic control and selectivity enhancement.

    Final product types

    • Ethyl mercaptan and related thiols for odorant markets
    • Dialkyl sulfides for polymer industries
    • Thioacid intermediates for agrochemicals
    • Sulfur-containing antioxidants for lubricant formulations

    6. Industrial Gas Sweetening (Desulfurization)

    Operators of industrial fired equipment, biogas plants, and refineries make use of calcium hydrosulfide as a component in wet scrubbing systems, capturing hydrogen sulfide (H2S) from sour gas streams. This integration supports air quality management, plant equipment longevity, and compliance with national and international emissions frameworks, demanding accurate formulation and consistent operation to ensure minimal slippage of sulfur compounds.

    Industry compliance standards

    • European Union Industrial Emissions Directive (2010/75/EU) for sulfur discharge
    • US EPA Clean Air Act Title V Permit—SO2 and H2S emissions monitoring
    • ISO 23251:2020 (Gas processing—Prevention of over-pressurization from gas scrubbing)
    • Occupational exposure standards for H2S—OSHA and ACGIH TLV

    Typical usage ratio

    • Dosed to achieve 1.05–1.2 times the stoichiometric requirement for H2S scrubbing, accounting for anticipated inlet gas variability and system absorption efficiency; monitored to prevent calcium scaling.

    Downstream process integration

    • Continuously added (automated or manually controlled) to wet scrubber recirculation loops or absorber vessels; interfaces with gas analyzers and feedback controls for ppm-level H2S removal.

    Final product types

    • Purified biogas or process gas for energy recovery
    • Recovered elemental sulfur or gypsum byproducts
    • Cleaned fuel gas for boiler, kiln, or engine use
    • Sulfur-compound stabilized effluents for regulated release
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    Certification & Compliance
    More Introduction

    Calcium Hydrosulfide: Behind the Scenes of Crafting a Reliable Chemical

    Real Insights from an Everyday Producer

    Those of us who have spent years in the chemical plants know the journey of turning raw elements into something as niche as calcium hydrosulfide. For us, this compound isn’t just a line in an order book—it’s the product of careful process design, safety focus, and commitment to batch consistency. Our batch models range for different industries, but the core of our craft remains the same: making sure every drum or tanker holds the same chemistry we stand behind.

    The Physical Stuff: How We Control Quality and Specs

    Producing calcium hydrosulfide means thinking through each variable that could go sideways. We pay close attention to purity. Impurities can cause issues in downstream applications. Early on, we decided to emphasize thorough filtration and precise reaction control. Typically, we produce the compound in aqueous solution, aiming for concentrations dictated by customer application—most often between 15% and 20% by weight.

    The solution carries a pale-yellow hue. If you’ve worked with calcium hydrosulfide, you know the sulfurous odor—unmistakable, not just in the drums but in the ambient air around the tanks. We monitor pH and density on every batch. Contamination can sneak in at transfer points, so our crew double-checks lines and fittings. Temperature control during synthesis helps us minimize byproducts and keep H2S content predictable.

    Building for Consistency: Why Batch Records Matter

    One thing we’ve learned over the years: tracking every step makes a difference. Our batch records aren’t just paperwork—they’re a playbook for finding mistakes before they reach the end user. This discipline helps especially when a customer reports an off result in pulp processing, or a lab flags a variance in a gas scrubber application. If we know our own process, we don’t have to guess where things went astray.

    How Customers Use Calcium Hydrosulfide—and Why Purity Counts

    Most of our customers use calcium hydrosulfide as a reducing agent or a source of sulfide ions. Pulp mills count on its reactivity for lignin removal or as a sulfidizing agent. In gas treatment, it grabs onto undesirable compounds in flue or natural gas. Some wastewater operations use it to precipitate metals or to control odors, leveraging its sulfide chemistry. For each use, off-spec material causes headaches: in pulp, wood fibers might not break down right; in industrial water, improper precipitation leads to downstream fines or regulatory headaches for the plant operators.

    Comparing Ourselves: What Makes This Product Different?

    As direct manufacturers, we have a unique view compared to traders or third-party resellers. We design our formulations for process compatibility, not just for hitting a spec sheet. Compared with sodium hydrosulfide, for example, our product brings lower solubility but offers advantages where calcium’s lower reactivity curbs unwanted side reactions. Customers in industries like carbon disulfide processing lean toward calcium hydrosulfide to reduce corrosion risks and manage downstream ion loads more predictably.

    A lot of competitors sell calcium hydrosulfide packaged from generic sources. That approach introduces uncertainty—each time a supply chain changes hands, documentation and traceability suffer. By sticking with vertical integration, we can keep control all the way back to the initial lime and sulfur sources. We test our input materials and tweak the reaction steps if we see upstream variances.

    Regulatory Footprints: Practical Reality on the Plant Floor

    Compliance isn’t just about paperwork. On our shop floor, it comes down to build quality, operator training, and regular upgrades to air handling systems. This compound brings its own hazards. Anyone walking through the plant will notice our sulfur dioxide scrubbers and the protocol for handling leaks. Regular safety drills make a difference in responding calmly to accidents or process upsets. These aren’t just precautionary—they keep both our teams and our surrounding community safe.

    For customer shipments, regulatory documents aren’t an afterthought. Our logistics team knows every drum must carry the right hazard labels. We routinely sample outgoing batches for standard parameters—pH, total sulfide, free calcium, and unwanted trace metals like iron or magnesium.

    Feedback from the Field Drives Innovation

    Over many years, our engineers keep open lines to client operators. We value field input because it signals how the product performs in real applications, not just in the lab. Teams at water treatment plants report back to us about precipitation rates; pulp mills notice color shifts in liquor; metallurgical operators sometimes call up with data on yields or scale deposits. This network of everyday conversations—unfiltered and direct—often leads us to update our filtration equipment or rethink packaging formats.

    One major evolution grew out of this feedback. Early on, we only offered calcium hydrosulfide in liquid form, tanker or drums. Customers wanted less product loss and fewer handling risks, so we invested in pump-and-return storage tanks to reduce transfer steps. This not only improved convenience; it dropped the rate of exposure incidents during delivery by noticeable margins. We only learned this by listening, testing, and watching outcomes month after month.

    Facing Common Problems and Finding Workable Solutions

    Anyone who has handled calcium hydrosulfide long-term has faced its inherent challenges. The biggest practical issue we see: product stability during storage. As a strong reducing agent, calcium hydrosulfide reacts with oxygen—the longer it sits, the bigger the drop in available sulfide. To counter this, we’ve designed closed-loop storage and minimize agitation wherever possible. Investing in nitrogen blanketing for bulk tanks has paid off, providing an extra buffer against oxidation. These are steps we chose after early batches lost too much potency in summer heat or after extended storage.

    Product safety can’t be an afterthought, either. Anyone opening a containment vessel experiences the distinct risk of hydrogen sulfide gas release—undetectable at dangerously high levels after a minute or two of exposure. Our protocols require ventilation and continuous gas monitoring in transfer zones. As a producer, we install redundant monitors and staff wear detectors in storage bays. Our frequent refresher training ensures nobody gets careless, even if nothing happens for months on end.

    Staff Experience Shapes Our Product Ethic

    For many of us, the process of making and delivering calcium hydrosulfide has taught us respect for the details. We see new hires pick up the habits we try to model: checking tank gauges every shift, keeping hose ends capped until absolutely necessary, storing containment pallets under maintained roofs. Mistakes only take a moment, but a sulfur spill or a miss-labeled drum sticks in memory for years. Some of us have worked here through plant modernizations or management shifts; that lived experience feeds into every small improvement we make.

    Down the line, customers notice the difference. They don’t have to chase us for batch documentation; our deliveries don’t turn up with unexpected contamination or off-odors. This stability means fewer shut-downs, less unexpected troubleshooting, and smoother integration with their own recipes. Trust builds batch by batch, mostly through quiet, predictable performance.

    Transparency as a Business Model: What We Share Matters

    Some in our sector stick to supplying the minimum required documentation. We go further. With every order, you’ll see detailed batch certificates. Our lab tracks key results: sulfide content, calcium numbers, the absence of iron, and clarity/opacity readings. If a customer ever wants third-party analysis, we cooperate without hesitation. That open book approach has cost us a client or two in highly price-focused segments—but more often, it forges long-term relationships with operators who value transparency.

    We don’t hide flaws. Over the years, we faced occasional off-spec results and owned up quickly. In a few cases, we even exchanged full shipments at our cost based on early feedback. That choice looks expensive at the time, but it keeps our standards honest and keeps word of mouth strong in a tightly networked industry.

    Environmental Impact: Balancing Chemical Value and Responsibility

    There’s no denying that calcium hydrosulfide holds some environmental drawbacks—mostly tied to its sulfide content and risks of accidental H2S release. Our team gives this a lot of thought, both from regulatory pressure and a sense of personal responsibility. Years ago, we added additional vapor recovery systems and built upgraded containment for spill events. Our wastewater team runs regular checks on neutralization effluent. Keeping discharge parameters inside limits isn’t just about avoiding fines—it’s about protecting our local watershed, where many of us fish or hike on weekends.

    We’re realistic on life-cycle impact. Every time a caustic solution is needed downstream, we explore whether calcium hydrosulfide can help reduce unwanted byproducts or lower overall chemical load. Some clients push us for data on residuals. We run creditable, third-party life-cycle analyses to spot areas where we need to improve, whether by optimizing delivery routes or refining synthesis steps to cut energy use.

    Future Outlook: Finding Value in Precision, Not Volume

    We see the market for calcium hydrosulfide shifting. More customers are asking for tighter specs, not just bigger batches. Automated dosing systems in modern mills demand consistent concentrations—no room for swings. Our plant responded by updating inline analyzers for each batch, feeding QA feedback directly back into reaction control rather than waiting for slow lab confirmation. As QA manager, I’ve watched startup times drop and customer complaints shrink almost to zero since installing more feedback loops.

    In the next few years, we expect growth to come from specialty users looking for more than a generic drum of chemical. There’s real demand for traceable, low-contaminant product, often for use in sensitive water applications or in closed-loop manufacturing systems. We’re betting on this model. Fewer rushed shipments, more careful formulations, more honest conversations with our end users.

    In the End: Trust Earned One Batch at a Time

    Every day, our focus revolves around a simple premise: if we take pride in our process, our calcium hydrosulfide stands out. Consistency isn’t luck; it’s checking level sensors after every flush, swapping out tired gaskets before they fail, bringing every new hire up to speed with hands-on detail. Customers don’t always see every step, but the quality in each tanker tells its own story.

    Our lived experience shapes every decision, whether that means absorbing the cost of extra filtration or driving out at midnight for an on-site humidity reading at a client’s depot. The market may shift, but those investments pay back. In a field where trust, process control, and safety make all the difference, we keep delivering the kind of result that keeps customer lines quiet and their systems running smoothly.