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Calcium Bisulfite

    • Product Name Calcium Bisulfite
    • Alias Calcium hydrogen sulfite
    • Einecs 231-830-0
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    150688

    Chemical Name Calcium Bisulfite
    Chemical Formula Ca(HSO3)2
    Molar Mass 202.22 g/mol
    Appearance White or yellowish solid
    Solubility In Water Soluble
    Density 2.45 g/cm3
    Melting Point Decomposes on heating
    Odor Slight sulfurous odor
    Cas Number 1344-81-6
    Ph Acidic in solution
    Stability Stable under recommended conditions; decomposes on exposure to air or heat
    Uses Water treatment, bleaching agent, preservative

    As an accredited Calcium Bisulfite factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Calcium Bisulfite is packaged in a 25 kg tightly sealed, white HDPE drum with hazard warning labels and proper chemical identification.
    Shipping Calcium Bisulfite should be shipped in tightly sealed, corrosion-resistant containers to prevent moisture absorption and oxidation. It must be labeled as a hazardous material and protected from heat, acids, and strong oxidizers. Transport under cool, dry conditions, complying with all relevant local, national, and international regulations for chemical shipping.
    Storage Calcium Bisulfite should be stored in a tightly closed, corrosion-resistant container in a cool, dry, well-ventilated area away from heat, moisture, and incompatible substances like acids and oxidizers. It should be protected from direct sunlight and stored away from food and drinking water. Proper labeling and secondary containment are recommended to prevent environmental contamination and accidental exposure.
    Application of Calcium Bisulfite

    Applications of Calcium Bisulfite in Industrial Manufacturing

    As an established manufacturer of high-grade calcium bisulfite, we deliver reliable supply tailored to stringent industrial application needs. Our material plays a critical process role in core manufacturing sectors requiring precise chemical functionality, strict regulatory adherence, and consistent batch performance. The following application scenarios demonstrate specific integration pathways, industry mandates, and product requirements met by calcium bisulfite in the global industrial market.

    1. Food Processing: Preservation and Color Stabilization in Fruit Canning

    Major fruit canning operations utilize calcium bisulfite for sulphiting applications to prevent enzymatic browning and preserve sensory qualities during long-term storage. Processors dose this material into blanching or immersion solutions, ensuring transparent traceability from raw ingredient input to final packing. The adherence to recognized food additive legislation distinguishes industrial canning deployment, while flexible dosing supports safe, effective preservation even with variations in fruit acidity and mass load.

    Industry compliance standards

    • Codex Alimentarius: Standard for Canned Fruit (CODEX STAN 319-2015)
    • FAO/WHO JECFA Acceptable Daily Intake for Sulfites
    • US FDA 21 CFR 182.3739 (Direct Food Substances Affirmed as Generally Recognized As Safe)
    • EU Regulation (EC) No 1333/2008 Annex II (Food Additives)
    • China GB 2760 (Standard for Food Additive Use)

    Typical usage ratio

    • 300–1500 mg/kg as SO2 equivalent, adjusted based on fruit type (stone fruit, pears, apples) and desired residual SO2 at canning endpoint. Legal maximum varies by territory and fruit category.

    Downstream process integration

    • Added to blanching water or pre-cook treatment tanks before can filling. Monitored by process analytics (e.g., SO2 titration or rapid test kits) before and after thermal processing to ensure regulatory targets and consistent output quality.

    Final product types

    • Canned apples, peaches, cherries, pears, fruit cocktails, and other heat-processed fruit preparations for retail and foodservice use.

    2. Water Treatment: Dechlorination in Municipal and Industrial Facilities

    Water utilities and process industries dosing calcium bisulfite achieve rapid, reliable neutralization of free and combined chlorine residuals following primary disinfection. As a reducing agent, this chemical is added directly to post-chlorination flows, allowing efficient compliance with stringent discharge and reuse guidelines. Plant operators calibrate dosing in real-time according to influent chlorine concentrations, protecting sensitive bioprocesses and complying with strict environmental standards.

    Industry compliance standards

    • US EPA NPDES (National Pollutant Discharge Elimination System)
    • EU Water Framework Directive (2000/60/EC)
    • ANSI/AWWA B600 Standard for Disinfectants and Chemical Additives
    • China GB 5749 (Standards for Drinking Water Quality)

    Typical usage ratio

    • 0.7–1.2 parts per part chlorine by weight; practical field dosing ranges from 5–25 mg/L, fine-tuned by online ORP or chlorine residual meters according to water matrix and operational volume.

    Downstream process integration

    • Injected into mixing chambers or pipeline dosing points post-chlorination (before drinking supply or effluent release), controlled with automated pump skids and feedback from real-time water analysis equipment.

    Final product types

    • Treated potable water, cooling tower makeup water, boiler feedwater, and effluent ready for environmental discharge or reuse.

    3. Pulp and Paper: Bleaching Sequence Residual Control

    Paper manufacturers incorporate our product to eliminate excess bleaching agents and control residual oxidants during pulp washing steps. The addition of calcium bisulfite safeguards equipment integrity, reduces downstream chemical load, and preserves fiber quality, vital for high-grade tissue, printing, and packaging output. Integration is based on close process monitoring, aligned with sector-specific certification systems and customer technical audit protocols for food-safe and print-grade pulps.

    Industry compliance standards

    • ISO 9001:2015 (Quality Management in Pulp and Paper Production)
    • EN 646 (Paper and Board Intended for Contact with Foodstuffs)
    • PEFC/FSC Chain of Custody (for sustainability-certified manufacturing)
    • US FDA 21 CFR 176.170 (Components of Paper and Paperboard in Contact with Aqueous and Fatty Foods)

    Typical usage ratio

    • 400–1800 mg/kg of dry pulp; dosing rate set by pulp type (sulfite, mechanical, kraft) and targeted post-bleaching residuals to achieve desired whiteness and product safety criteria.

    Downstream process integration

    • Added at the pulp washing and neutralization stage immediately after oxidative bleaching (chlorine dioxide, hydrogen peroxide). Monitored by redox potential and residual oxidant testing for continuous operation.

    Final product types

    • Tissue and hygiene paper, food packaging board, coated and uncoated printing paper, specialty technical papers.

    4. Beverage Industry: Sulfiting Agent in Wine and Fruit Juice Production

    Wineries and juice processors employ calcium bisulfite as a controlled sulfiting agent for fermentation stabilization and shelf-life optimization. Enologists depend on tight addition management for microbiological safety and color retention, while production must fully satisfy both international export and local market grade requirements. Our manufacturing traceability supports end-customer documentation for clean label and allergen declarations.

    Industry compliance standards

    • OIV (International Organisation of Vine and Wine) International Code of Oenological Practices
    • EU Regulation (EC) No 606/2009 (Winemaking Practices)
    • US TTB CFR Title 27 (Wine Sulfite Limits)
    • GB 15037 (Chinese National Standard for Wine)

    Typical usage ratio

    • 50–200 mg/L as SO2 equivalent in must and fermenting wine; exact dosage considers natural grape composition, juice pH, and temperature. Compliance with precise maximum permitted levels for residual sulfites is routinely validated.

    Downstream process integration

    • Metered at grape crushing or juice clarification stages, and for adjustment during cellaring/racking. Addition is carefully synchronized with automated dosing and laboratory SO2 monitoring throughout batch processing.

    Final product types

    • Bottled red, white, and rosé wines, blended fruit drinks, clarified or unclarified fruit juices for export and local retail channels.

    5. Photographic Industry: Fixer Bath Additive for Silver Halide Processing

    Analogue photographic film and print processing labs utilize calcium bisulfite in fixer solutions, improving silver residue removal and extending chemical bath life. Integration stabilizes fixative efficiency in continuous and batch operations, directly impacting print clarity and archival quality. Strict photographic processing control standards guide usage to prevent unwanted chemical contamination and maintain reproducibility in high-volume facilities.

    Industry compliance standards

    • ISO 18911:2010 (Image Stability—Processed Photographic Materials—Storage Practices)
    • ANSI/NAPM IT9.1 (Stability of Processed Photographic Films)
    • Manufacturer operating specifications for photographic chemicals (e.g., Kodak, Ilford, Fujifilm)

    Typical usage ratio

    • 1–3 g/L in fixer bath formulations, with dosing based on throughput, replenishment rate, and bath silver content. Process adjustment ensures bath performance within set limits for image reliability standards.

    Downstream process integration

    • Added during make-up and periodic maintenance of fixer baths in film and print processing lines. Lab personnel monitor bath composition and chemical purity using silver ion tests and bath life assessment protocols.

    Final product types

    • Photographic films, x-ray films, and finished archival prints for medical, industrial, and creative applications.
    Free Quote

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    Certification & Compliance
    More Introduction

    Calcium Bisulfite: Practical Uses and Production Insights

    Understanding Calcium Bisulfite Directly from the Manufacturer’s Floor

    We make calcium bisulfite every day for industrial plants, water utilities, food processors, and many producers switching away from older or dirtier technology. Our direct approach keeps the product reliable, cost-efficient, and available in the forms that best fit a factory’s routine. A lot of folks know it as an agent for removing chlorine and as a reducing agent, but the way we manufacture and handle it puts us face-to-face with changing demands and practical concerns every shift, every shipment.

    On our line, calcium bisulfite isn’t simply a commodity. Each batch comes together starting with a clear goal. Factories rely on it for its ability to neutralize chlorine in water, especially for water treatment and food processing. Application-specific needs shape our choices, from concentration to purity standards. Customers want a product that consistently performs at predictable rates and keeps their systems running smoothly. The differences between a high-sulfite-content batch and a diluted solution matter in practice, so we tune our specifications to suit those realities.

    Manufacturing with Consistency and Purpose

    The process starts with calcium hydroxide and sulfur dioxide. In our plant, we hydrate lime ourselves to control quality from intake to finished goods. As sulfur dioxide passes through, we watch the reaction closely. The proper ratio maintains a stable pH, ensuring that the calcium content remains within the right limits. Over-acidify, and the mix drifts toward unwanted byproducts. Drift too alkaline and you get precipitates that clog nozzles and lines down the road. Every operator, whether running a batch mixer or testing in the QC lab, knows the value of hitting those targets.

    Specification isn’t a numbers game for us; it’s about real performance. We follow industry-relevant standards and run frequent checks so our solution fits the practical needs of each order. Customers who use calcium bisulfite to dechlorinate municipal water tell us that small differences in active content change dosages and costs. Food processors want assurance that nothing drifts outside their process controls. Every time we increase traceability and testing, we see fewer service calls and better long-term relationships.

    Meeting Different Needs: Grades and Application-Based Preferences

    Most customers want calcium bisulfite as a liquid—either concentrated or at a dilution that’s ready to use in dosing pumps. Others ask for a solid or a powder, but those forms bring other challenges in handling and stability. Our liquid solutions usually carry active calcium bisulfite in the 10-15% range. This suits dechlorination in large-volume water treatment tanks, or continuous processes in food cleaning lines. For pulp and paper mills, larger volumes and custom blends sometimes deliver savings, so we scale batches and adapt concentrate levels to their flow rates.

    One key distinction from products like sodium bisulfite or sodium metabisulfite lies in the role of the calcium ion. Using calcium bisulfite means you avoid adding extra sodium to waste streams—important for customers subject to environmental limits on sodium discharge. Food processors, breweries, and water plants with stricter effluent rules look for this feature above all else. The chemical profile also plays out differently in wastewater applications. Calcium compounds often settle more predictably, making downstream sludge treatment or thickening less troublesome.

    We see requests for low-impurity grades from bottled water facilities and high-volume beverage plants. They tell us standard industrial grades risk introducing off-flavors or residues. So we run extra filtration and more frequent analytical tests, adding an extra layer of diligence to our routine operation. Some clients need products certified allergen-free or compliant with local food safety law. We can’t cut corners—traceability runs from raw materials right through final quality sign-off.

    Differences That Matter—Not Just a Substitute for Other Sulfites

    Some questions come up from buyers used to sodium-based products. They notice that calcium bisulfite can appear less soluble, especially at lower temperatures or higher concentrations. On our line, that means we adjust process water temps and agitation. We form our solutions to minimize undissolved residues. Sometimes a competitor’s batch will yield more precipitate, and clients find their tank lines plugging or injections drifting off-target. We design our production steps to keep calcium ion in check, which often avoids fines and downtime after installation.

    Cost comes into play when you compare calcium and sodium bisulfite options. Calcium bisulfite sometimes runs less expensive per ton when lime and sulfur supplies hold steady. Its use means customers face less pressure from sodium limits, and it often generates less regulatory paperwork. Over time, the operational savings stack up from reduced corrosion on pipes and fitments, as calcium is less aggressive than sodium in many settings. For plants facing older infrastructure, equipment longevity is worth more than a headline price difference.

    Chlorine Removal and Industrial Hygiene

    Our customers share their stories about chlorine reduction. Calcium bisulfite acts fast, transforming chlorine into harmless chloride. Reaction time lags if you push the limits on dilution or mixing. In large tanks or inline dosing, we remind plant staff to check pH and temperature for full reaction. We’ve had operators mix up sodium-based and calcium-based dosing, only to see mismatches in their test readings until we walk through the adjustments. That root-level support, backed by knowing how different batches respond, sets a true manufacturer apart from a trader or reseller.

    Food processors watch for taste and safety side effects. Any chemical that stays around too long or leaves an odor means product recalls or regulatory scrutiny. We supply a feedstock that breaks down quickly and doesn’t linger in the system. In our plant, we keep records on batch processing and distribution dates, and we alert customers if unusual results turn up in our post-shipment testing. Water utilities count on our product to keep within tough residual limits, protecting their end-user reputation.

    Why Purity and Traceability Count in Real Use

    We’ve seen what happens when markets flood with poorly tracked sulfite products. Sub-optimal raw materials, dirty packaging, or slip-ups in labeling all show up in our lab when new customers send samples for comparison. We maintain precise sourcing, regular audits, and full traceability to protect our own operation and to guarantee that each drum or shipment matches previous lots. It reassures long-term buyers who remember past industry scares involving contaminated batches or mislabeling.

    Calcium bisulfite also supports closed-loop operations, especially in locations where waste minimization regulations grow tighter year by year. Plants ask about stable, low-side-stream solutions because they help cut cleaning and disposal costs. With in-plant batch reactors and storage adapted to solid or liquid forms, we help customers redesign flows to recover more water or reduce hazardous waste. From the burner to final packaging, we report key QC marks and shipping information, closing the information gap between us and the technician at the dosing station.

    Typical Scenarios and Operator Know-How

    An operator at a municipal water plant spends nights monitoring dosing pumps. Once every few shipments, they notice changes—cloudier solutions, or inconsistent dechlorination at the usual dose rate. In these cases, we help troubleshoot. Sometimes equipment drift causes issues, but more often, water chemistry itself shifts. We coach plant maintenance on checking for unexpected pH or upstream changes, offering practical suggestions drawn from hundreds of deliveries. Consistency in every batch remains our pledge.

    At a pulp and paper factory, waste streams can swing in composition. Here, calcium bisulfite stands out for agents responsible for wastewater compliance. In our experience, new facility upgrades trigger more requests for custom concentrations and delivery options. Because we assemble and ship in bulk, tankers, or drums, switching formats is straightforward and cuts delivery lags. We spend time gathering feedback so the next load fits a plant’s evolving needs, not just a standard grade or formula.

    The Environmental Angle—Reducing Footprint, Smoothing Compliance

    Strict environmental limits on sulfite and sodium discharge lead customers to look for practical alternatives to sodium bisulfite. Calcium bisulfite fits their goals. Its use reduces sodium impact while maintaining efficient chlorine removal. Many clients don’t have spare resources to handle tough environmental paperwork or replace expensive plant components. We recognize that and match product grading to the strictest rules we see, from local discharge limits to overseas requirements.

    On our end, we invest in closed-loop production. Spent lime goes to controlled reuse, sulfur inputs get monitored, and off-gas handling complies with air emissions law. This keeps our operation and the communities around us safer. We share these details with partners upfront, knowing transparency builds trust in the face of tighter reporting standards.

    Adaptation to Change: Short-Term Supply Hiccups and Long-Term Growth

    Pricing and powder availability shift with regional lime and sulfur dioxide swings. As a manufacturer, we keep a flexible supply line for core feedstocks. We keep steady communication with bulk suppliers and stock extra for unplanned surges. During plant upsets or demand spikes, we flex production to deliver large runs at short notice, never cutting corners on analysis or packaging. Feedback from end users shapes our planning—we produce how industry schedules dictate, not how a warehouse in some distant city tells us.

    Global regulations, particularly around food and beverage applications, keep changing. Sodium alternatives often draw more attention from plant auditors. Having a calcium-based solution gives our customers an edge when standards tighten. We devote resources to continuous testing, so our specifications hold up to new rules or changing raw material grades.

    Looking Beyond the Label: Skills and Service from Real Production

    Distributors and traders talk mainly about grades and jargon, but in the plant, it’s about predictable supply and on-the-spot help. Years of manufacturing calcium bisulfite have taught us that real value comes from fast support and openness about changes. In the field, maintenance staff call not about certificates, but about how to clear blocked lines, adjust pump rates, or detect an off-batch. We offer clear, actionable advice based on personal experience, not copy-pasted product sheets.

    A few times each year, new plant-built dosing systems need tweaks. Tubing has to match viscosity; metering pumps need calibration for actual site temperatures and water pH. We lend advice based on what works, and send out field engineers during plant upgrades. Our team traces every step: from batch formulation through logistics and after-sales calls—minimizing headaches down the line.

    Safety: Built into Each Delivery

    Everyone in our facility handles chemicals daily—so safety means more than paperwork. We train each operator in safe material transfer and emergency response, and we keep current on best practices from industry authorities. We review each product form—not just for standard hazards, but for practical on-site usage. Calcium bisulfite solution, stored in the right containers, keeps risks low. Drums ship with tamper-evident seals and clear handling instructions. We walk customers through on-site risk assessments and spill procedures on first shipments, keeping safety real and not just regulatory.

    Attendance and low staff turnover mean our operators know every corner of our process. If we spot an abnormal batch or suspect contamination, production freezes until we have answers. This vigilance has meant zero major incidents in recent years—a record our industrial neighbors ask about when considering supply partners.

    Every Order, an Ongoing Partnership

    Calcium bisulfite makes life easier for our customers because we focus on what’s inside the drum and the regular people put in charge of putting it to use. We build extra time into deliveries to account for site-specific needs. Sometimes that means extra short-run orders, sometimes batch notes tailored to local reporting. Whether filling a tanker for a wastewater plant or packing small drums for a beverage line, we work from the factory floor, not a trade desk.

    Our reliability comes from years on the production line—watching the reaction, running the analytics, and listening to the crew on both sides of a shipment. By handling every aspect ourselves, from sampling through shipment, we keep a straight line to what works. No gloss, just real-world results.

    Choosing Calcium Bisulfite: Not Just a Substitute, but an Advantage

    Ultimately, every plant picking calcium bisulfite weighs tradeoffs. Some stick with sodium, some with metabisulfite, but more are turning to calcium for real environmental and operational payoffs. Plant operators, engineers, and maintenance staff all notice the difference—less sodium in the waste stream, steady chlorine removal, and fewer process disruptions. We keep up with those evolving needs with hands-on support and a commitment to process improvement, batch after batch.

    For those on the front lines—technical managers, plant supervisors, maintenance crews—the value of a direct manufacturing partner shows up in unplanned downtime avoided, compliance worries eased, and headaches reduced. We’re here, on the line, ready to share what we’ve learned, and prepared to keep advancing as regulations and customer needs evolve. Calcium bisulfite isn’t just another sulfite product. In the hands of real operators and real manufacturers, it becomes a better solution for cleaner water, safer processing, and a stronger bottom line.