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Barium Hydride

    • Product Name Barium Hydride
    • Alias Barium monohydride
    • Einecs 233-649-2
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    186641

    Chemicalname Barium Hydride
    Chemicalformula BaH2
    Molarmass 139.34 g/mol
    Appearance White to grayish solid
    Density 4.78 g/cm3
    Meltingpoint 675 °C
    Solubilityinwater Reacts with water
    Casnumber 7803-64-1
    Crystalstructure Orthorhombic
    Reactivity Reacts with acids and water to release hydrogen gas
    Odor Odorless

    As an accredited Barium Hydride factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A sealed 500g metal container, labeled "Barium Hydride," features hazard symbols and moisture-proof lining to protect the reactive chemical.
    Shipping Barium Hydride should be shipped in tightly sealed containers under inert atmosphere, such as argon, to prevent reaction with moisture or air. It is classified as a hazardous material and must be handled with appropriate safety precautions, including labeling as a flammable solid and avoiding contact with water during transport.
    Storage Barium hydride should be stored in tightly sealed containers, under an inert atmosphere such as argon or nitrogen, to prevent its reaction with moisture or air. The storage area should be cool, dry, and well-ventilated, away from acids, oxidizing agents, and water sources, as barium hydride reacts violently with water, releasing hydrogen gas and forming caustic barium hydroxide.
    Application of Barium Hydride

    Applications of Barium Hydride in Industrial Manufacturing

    As the direct manufacturer of barium hydride, we supply this specialized inorganic compound to established downstream sectors. Our focus lies in meeting strict application standards and supporting customers through precise addition ratios, process integration details, and assured quality alignment. Below, we outline the primary industrial use cases where barium hydride delivers tangible benefits in real-world manufacturing settings.

    1. Hydrogenation Catalyst in Organic Synthesis

    Major pharmaceutical and agrochemical plants adopt barium hydride as a selective hydrogen source for reduction and hydrogenation reactions, especially for processing aromatic compounds and unsaturated organic intermediates. Operators prefer this material in place of gaseous hydrogen cylinders for small- or mid-scale batch reactions where safety and controlled dosing are critical. By integrating directly into closed reactor systems, it enables precise hydrogen liberation upon contact with substrate and compatible solvents, with minimal overhead for pressurized storage or transport. Its consistent reactivity simplifies batch characterization and QA release of high-value intermediates required by active ingredient producers.

    Industry compliance standards

    • ICH Q7 Good Manufacturing Practice for Active Pharmaceutical Ingredients
    • EU REACH Regulation (EC) No 1907/2006 for chemical substances
    • OSHA 1910 Subpart Z for hazardous chemicals handling
    • Customary cGMP site SOPs in process development labs

    Typical usage ratio

    • 5–15% molar equivalent relative to target reducible substrate; varies by substrate electronic profile and desired conversion

    Downstream process integration

    • Introduced at the reagent charging stage in jacketed glass-lined or stainless reactors; reacts in situ during substrate hydrogenation under inert gas purge

    Final product types

    • Reduced pharmaceutical intermediates (e.g., substituted anilines, naphthol derivatives)
    • Agrochemical actives containing hydrogenated rings
    • Chiral fine chemicals for API synthesis

    2. Precursor in Barium Metal Refining for Electronics

    Electronics component manufacturers employ barium hydride in controlled reduction pathways for high-purity barium metal production. It serves as a reducing agent, decomposing under heat in a regulated vacuum system to liberate barium vapor and hydrogen, thus ensuring extremely low contamination levels. This step forms a key intermediate transition before metallic barium harvesting, with further vacuum purification to attain DOD and JEITA conforming ultra-high-purity grades, essential for getter alloys and emitter coatings in vacuum tubes and CRTs.

    Industry compliance standards

    • JEITA Standards for Electronic Materials (Japan Electronics and Information Technology Industries Association)
    • IEC 61340-5-1: Protection of electronic devices from electrostatic phenomena
    • ISO 9001:2015 for quality management systems in specialty metal production

    Typical usage ratio

    • Calculated stoichiometrically, typically 100–120% of theoretical reduction requirement depending on target metal purity and scale-up yield adjustment

    Downstream process integration

    • Loaded directly into high-temperature vacuum reduction furnaces where it decomposes to deposit barium metal; recovered metal undergoes further refining for trace removal

    Final product types

    • Ultra-high-purity barium metal rods and ingots
    • Barium-based getter strips for vacuum electronic devices
    • Emitter alloys for cathode ray tubes and photomultiplier manufacture

    3. Hydrogen Source in Specialty Alloy Synthesis

    Specialty metallurgy operations introduce barium hydride during alloying to both act as a controlled hydrogen donor and serve as a fluxing agent in the production of rare earth and alkaline earth alloys. It enables precise grain modification and assists in removing residual oxygen or sulfur impurities from melts under vacuum or inert gas. These factors are critical during master alloy manufacture for the aerospace, nuclear, and advanced electronics sectors, where strict impurity limits govern high-performance end use.

    Industry compliance standards

    • ASTM E2999-21 for vacuum induction melting safety and controls
    • AMS 6470 for heat-resistant alloy materials
    • NADCAP (National Aerospace and Defense Contractors Accreditation Program) for nonferrous metallurgy

    Typical usage ratio

    • 0.1–1.2% by weight, optimized based on melt size, base metal matrix, and required purification depth

    Downstream process integration

    • Charged to the melt crucible after initial base metal fusion, prior to rare earth addition; decomposes and reacts at 900–1200°C under vacuum or argon

    Final product types

    • Barium-containing master alloys (e.g., Ba-Mg, Ba-Sr blends for grain refinement)
    • Superalloy ingots for jet engine or nuclear fuel cladding
    • Deoxidized specialty metals for advanced electronics substrates

    4. Reducing Agent in Rare Earth Metal Production

    Downstream rare earth refining plants utilize barium hydride as a potent reducing agent to extract highly reactive rare earth metals such as lanthanum, cerium, and europium from their halide or oxide precursors. In these metallothermic reactions, it outperforms other alkaline earth hydrides due to its lower decomposition temperature and controlled release of hydrogen, providing cleaner product fractions. Its inclusion results in higher metal yields and reduced impurity levels, supporting rare earth producers’ compliance with stringent export and material purity certification.

    Industry compliance standards

    • ISO 9001:2015 for rare earth refining
    • GB/T 24685-2009 for rare earth metal purity (PRC national standard)
    • OECD Due Diligence Guidance for Responsible Supply Chains of Minerals

    Typical usage ratio

    • 10–20% excess above stoichiometric requirement versus rare earth halide/oxide feed; dosage set by reduction potential and feedstock grade

    Downstream process integration

    • Added to solid-state reduction reactors after rare earth halide/oxide loading; undergoes high-temperature reaction (500–850°C) to yield target metal and by-product barium halide/oxide

    Final product types

    • Lanthanum, cerium, neodymium, and europium metals for magnet, display, and catalytic applications
    • High-purity rare earth master alloys

    5. Deoxygenation in Pyrometallurgical Processes

    Nonferrous refining and specialty foundries use barium hydride as an advanced deoxidizing agent in copper, nickel, and titanium melt treatments. By adding it during the high-temperature refining stage, operators improve oxygen removal efficiency compared to elemental barium or magnesium alone, minimizing undesirable oxide inclusion formation that compromises downstream rolling or casting. Plants achieve improved conductivity and mechanical integrity in finished metals, thereby supporting end-user product QC in electrical, transportation, and energy sectors.

    Industry compliance standards

    • ASTM E381-20 for metallurgical melt practice
    • ISO 4955 for steel and nonferrous alloy deoxidation processes
    • CQC (China Quality Certification Centre) for nonferrous product export

    Typical usage ratio

    • 0.05–0.25% by weight of batch, adjusted to melt oxygen content measured by in-line probe

    Downstream process integration

    • Charged to melt prior to final degassing; disperses and reacts in-situ to yield barium oxide by-product, removed as slag

    Final product types

    • High-conductivity copper rod and bar
    • Refined nickel and titanium billets for aerospace forging
    • Nonferrous master alloys with ultra-low oxygen content
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    Certification & Compliance
    More Introduction

    Barium Hydride: Crafting Precision in Specialty Applications

    Our Approach to Pure Barium Hydride Production

    Every kilogram of barium hydride we ship leaves our facility after facing the scrutiny of seasoned technicians and strict internal standards. The process starts with metallic barium, selected for its purity and consistency before it enters our custom-designed reactors. A mix of controlled conditions—temperature, hydrogen flow rate, clean vessel materials—all come together to produce a fine, off-white powder: BaH2 with minimal contaminants. Our teams have tinkered with pressure regimes, experimented with gas quality, and logged thousands of data points, honing this recipe over repeated production cycles. The product’s moisture sensitivity, for instance, pushes us to maintain a water- and oxygen-free atmosphere throughout the entire cycle, storage, and packaging. When our chemists discuss a batch’s history, they point to audit trails, impurity profiles, and documented adjustments. Each batch number ties back to concrete parameters: hydrogen feed rate, conversion yields, vacuum levels, and packaging timestamp.

    Consistency and Traceable Quality

    Drum-to-drum consistency sets the ground for work in high-precision synthesis, so our team runs a strict battery of internal analyses before sending out a single sample. We don’t just rely on a certificate; we open containers, withdraw samples, and test everything from particle size distribution to spectrographic trace levels. Our analytical chemists recount batches that taught us how environmental fluctuations creep into finished goods—humidity on rainy days, subtle metal contamination from worn vessel liners, even operator error during handling. Experience has led us to invest in sealed, argon-filled gloveboxes, proprietary packaging techniques, and continuous staff training. Our products must meet not only published chemical standards but also the often unwritten requirements voiced by long-term industrial users—reactivity curves, color, storage behavior during transit, and batch-to-batch reactivity for niche reactions.

    Barium Hydride: A Strong Reducing Agent

    Researchers and industrial chemists often turn to barium hydride when sodium hydride, lithium aluminum hydride, or calcium hydride don’t deliver the right reactivity profile or selectivity. In our practice, customers opt for our product to drive hydrogenation reactions, deoxygenate refractory metals, or synthesize rare-earth hydrides. Its particular balance—powerful enough to break down refractory oxides, yet easier to filter from product mixtures than some hydrides—comes from its unique solubility, particle morphology, and reaction kinetics.

    Our in-house teams have tested barium hydride across multiple transformation pathways: reducing certain organic substrates to alcohols, modifying inorganic matrices, and serving as a hydrogen donor in the synthesis of complex metal hydrides for solid-state research. Each use case exposes different challenges: fine suspended particles impacting downstream filtration, background moisture content raising the risk of violent exotherms, or batch aging subtly reducing reactivity. We view feedback from our customers—positive and otherwise—as indispensable. Our R&D group keeps every note describing unusual behavior in a real-world rig. For instance, we once rebuilt an entire gas-feeding manifold after a customer in the fine-chemicals sector flagged an unexpectedly slow reaction initiation. Problem-solving in-house let us add an extra assurance check that stands today as part of our standard QC.

    Different Faces of Industrial Hydrides

    It’s easy on paper to lump barium hydride in with other alkaline earth metal hydrides, but field experience tells us the distinctions matter once you’re running a tight process. Barium hydride, for example, reacts more slowly with water than calcium hydride, giving operators a bit more margin for careful handling—but this still demands expertise and proper safety setups. Technicians who have handled sodium hydride see the difference in tactile response and the degree of dust, since barium hydride compacts differently and kicks up fewer fine particulates. Our own workers developed specific transfer protocols and customized scoops to match barium hydride’s handling quirks, finding that standardized tools meant for other hydrides sometimes create hazardous static discharge risks or inefficient loading.

    Its reactivity profile often fits best in temperature regimes that would melt or degrade lighter hydrides. We’ve mapped out decomposition points and optimal activation temperatures using real process data, not just textbook references. Our customers count on us to share this practical know-how; our technical dossiers describe not simply the theoretical hazards, but also what we see day after day—how the material behaves in pipelines, what clumping looks like in storage, and under what conditions we see rapid hydrogen evolution.

    Specifications That Matter in Practice

    We manufacture barium hydride to meet laboratory, pilot, and full commercial demand. Our standard product falls within a narrow purity range, but over the years, special projects have driven us to push boundaries. One aerospace customer required lower strontium traces for a fuel cell application. We responded with a re-benchmarked cleaning and vessel-lining routine, and built a QC protocol around those requirements. That variant—down to strontium parts-per-million—helped unlock a successful fuel test for them.

    We supply several granulation sizes, reflecting lessons from different customer plants. Some want the finer grade for rapid suspension in non-aqueous solvents, where higher reactive surface area shortens batch time. Others, especially those running bulk reactors, want a coarser, free-flowing product for safer dosing. Our teams recognize granulation isn’t just about particle size distribution analysis: it’s about understanding customer process layouts, their charging systems, and their filtration limitations.

    Handling barium hydride safely is not an afterthought. All our packaging is sealed under argon atmosphere, heat-sealed in moisture-barrier film, and double-lidded in cans or kegs rated for reactive metal storage. Every year, we see how real-life logistics—long hauls, storage in sub-optimal warehouses—challenge our packaging. By tracking returned empties and consulting with logistics partners, we’ve strengthened our outer lining and redesigned container gaskets more than once.

    Difference From Calcium and Sodium Hydride: More Than Just Chemistry

    In our day-to-day work, we get questions comparing barium hydride to calcium, lithium, or sodium hydride. Chemically, each brings a certain hydride donor strength, but their differences on the plant floor aren’t purely academic. Calcium hydride is a common choice for drying solvents; it’s less expensive but leaves behind a stubborn, fine dust that complicates filtration and pump operation. Sodium hydride packs more punch as a base, with powder behavior that demands careful antistatic handling. Barium hydride provides a balance, offering strong reduction power with less risk of spontaneous, dust-induced ignition. We’ve engineered our process conditions to deliver a material that pours noticeably more smoothly and distributes evenly in feeder equipment.

    The physical handling differences aren’t trivial. Some operators transitioning from calcium hydride find our product surprisingly easy to weigh and dispense, as the denser granules resist airborne dispersal. For high-purity vacuum metallurgy, customers prefer barium hydride for its lower content of interfering cations, and our process keeps these within strict limits. The feedback loop—operators remarking on floor-level challenges, users reporting changes to their batch times or observed yields—feeds our ongoing process optimization.

    Applications Driving Production Choices

    Demand for barium hydride doesn’t follow boilerplate market cycles. In semiconductor production, for instance, stringent requirements around trace metals and moisture sensitivity breed a whole new set of QA routines. Materials destined for rare-earth hydride research or hydrogen storage technology need to hit purity levels that go beyond standard spec sheets. Questions aren’t just about product code—they’re about surface reactivity, off-gassing during heating, and technical support available at odd hours.

    Besides those in research or materials innovation, our largest-volume clients operate in large-scale reduction processes. They value not only price and purity, but also shipping reliability and technical transparency. We keep our team available for troubleshooting and process risk review. If a customer reports off-standard reactivity or packaging breakage, we log the issue, backtrack shipment records, and sometimes pause future lots while our site QA group investigates. These aren’t rare events—they’re proof that close customer communication improves every production run.

    Continuous Improvement From the Shop Floor to the End User

    Nothing in chemical manufacturing stays static. Equipment wears down, feedstock purity moves over time, seasonal conditions drive subtle variability in inbound gas and reagent supply. Our site takes ongoing process audits seriously: we’ve torn down and rebuilt reactors in response to just a small uptick in particle size variability. From the plant floor, maintenance engineers highlight possible pressure leaks or dead spots in piping that may impact conversion yield. Internal communication—between shift supervisors, QC chemists, and the order management desk—remains the backbone of product quality.

    Any time we address a persistent issue, we drill past surface-level fixes. Once, repeat minor contamination arose from an overlooked gasket material that released trace silicon. After seeing small spikes in select impurity screens, our team escalated to engineering, traced the issue across several batches, then replaced the seals with a more robust, non-reactive option. We updated batch records, followed up with affected users, and implemented an extra verification test for all outgoing lots. We consider our job unfinished if we stop at simply meeting published specifications.

    Value-Driven Support: Beyond Just Product Supply

    We believe that selling barium hydride means providing ongoing technical support, data sharing, and real conversation. Our staff fields questions from both process engineers looking to optimize yield and from plant maintenance crews troubleshooting a sticky transfer. We value clarity and honesty, even when it means admitting past mistakes or describing limitations with current process capability.

    Recent improvements in air monitoring and remote-reactor diagnostics have helped us add another assurance layer. Customers deploying automated feeders now benefit from our detailed flowability and compaction data, much of it taken from feedback during trial shipments or site visits. On request, we’ve also tailored safety advisories drawing on real-world incident logs rather than canned, legalistic warnings. Our goal is to provide resources that plant managers, safety coordinators, and line operators can actually use. We encourage plant visits, phone walkthroughs, or live video calls to help resolve issues in context.

    We keep up with regulatory updates and provide honest, practical advice for shipping and handling reactive powders. Whenever a rule or logistical bottleneck affects supply, our commercial team circles back to both shipping coordinators and customers, ensuring transparency around delays and compliance documentation requirements.

    How We View the Future of Barium Hydride

    From our side, innovation in barium hydride starts not in a control room, but at the interface between chemist and equipment, supervisor and delivery truck, handler and reaction vessel. The market is poised to shift as hydrogen storage, battery development, and specialty reduction processes increase. We’re investing in next-generation reactor materials, closed-system handling, and smarter packaging options that resist moisture even during extended transit.

    Our R&D leads work with academic partners and end-users to test barium hydride in new synthetic routes, exploring performance limits and supporting applications that didn’t even exist a few years ago. The lessons we learn in unusual pilot batches—sometimes from unexpected clumping, sometimes from subtle yield drop-offs—filter back into standard production improvements. We value open, honest collaboration, and know that adaptation—not rote repetition—keeps us at the technical forefront.

    The complexity of making, shipping, and supporting barium hydride teaches us that success lies as much in careful communication and flexibility as in chemistry or equipment. We take pride in the small details: a tweak in glovebox purging, a well-packed drum, a phone call made before shipping a rush order. In this field, every small improvement adds up, strengthening both product performance and long-term relationships.