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Arsenic Trichloride

    • Product Name Arsenic Trichloride
    • Alias Arsenic chloride
    • Einecs 233-301-1
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    913539

    Chemical Name Arsenic Trichloride
    Chemical Formula AsCl3
    Molar Mass 181.28 g/mol
    Appearance Colorless to pale yellow fuming liquid
    Odor Pungent, suffocating
    Melting Point -16.2°C
    Boiling Point 130.2°C
    Density 2.16 g/cm³ (at 20°C)
    Solubility In Water Reacts with water
    Vapor Pressure 38 mmHg (at 25°C)
    Toxicity Highly toxic
    Cas Number 7784-34-1

    As an accredited Arsenic Trichloride factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Arsenic Trichloride, 500 mL, is supplied in a tightly sealed amber glass bottle with corrosion-resistant cap and clear hazard labeling.
    Shipping Arsenic Trichloride must be shipped in tightly sealed, corrosion-resistant containers due to its toxic and corrosive nature. It should be classified as a hazardous material, handled by trained personnel, and transported according to international and local regulations, such as UN 1557, with proper labeling, documentation, and emergency response provisions in place.
    Storage Arsenic trichloride should be stored in a tightly sealed, corrosion-resistant container, such as glass or polytetrafluoroethylene (PTFE). Store it in a cool, dry, and well-ventilated area, away from moisture, heat, light, and incompatible substances like strong oxidizers and bases. Clearly label the container and ensure proper chemical segregation to prevent reactions and exposure. Use secondary containment if possible.
    Application of Arsenic Trichloride

    Applications of Arsenic Trichloride in Industrial Manufacturing

    As an established manufacturer of arsenic trichloride, we have identified several key industrial sectors where this specialty chemical plays an essential role in downstream production. The following sections detail its usage, compliance requirements, formulation ratios, process points of entry, and resulting end products within real, regulated application domains.

    1. Production of Organarsenic Intermediates for Agrochemical Synthesis

    Downstream agrochemical manufacturers use arsenic trichloride as a precise chlorinating and arsenating agent when synthesizing organoarsenic compounds, including herbicide and insecticide active ingredients. Formulators introduce it during the initial coupling reactions with organic moieties under controlled temperature, where strict inert atmosphere handling is required due to its reactivity and toxicity. Adjustable feedstock ratios enable fine-tuning of purity and conversion in multi-step batch or continuous processes, ensuring compliance with national and international toxic substance control laws for agricultural inputs. Applications in this sector require integration with monitoring for trace residue and byproduct elimination to meet end-use product regulations.

    Industry compliance standards

    • REACH Regulation (EC) No 1907/2006 for hazardous chemical handling
    • US EPA FIFRA (Federal Insecticide, Fungicide, and Rodenticide Act) registration standards
    • Chinese Agricultural Chemical Quality Standards (GB 20613, GB 2763)
    • OSHA workplace exposure limits for arsenic compounds

    Typical usage ratio

    • 10–22% by weight in initial synthesis stage, adjusted based on specific organoarsenic molecule requirements and targeted conversion yield

    Downstream process integration

    • Chlorination-arsenation during primary reaction sequence
    • Entry via jacketed glass or steel reactors equipped with gas scrubbing systems
    • Operator-controlled dosing to limit exothermic reaction risk
    • Real-time sampling for residual arsenic verification

    Final product types

    • Organoarsenic herbicide actives (e.g., monosodium methyl arsenate)
    • Specialty insecticide intermediates
    • Functionalized phenylarsine derivatives
    • Downstream pre-formulated pesticide concentrates

    2. Semiconductor Doping and Compound Fabrication

    The microelectronics industry employs arsenic trichloride for providing controlled arsenic sources in the manufacture of certain III-V semiconductors such as gallium arsenide (GaAs) and indium arsenide (InAs). Strictly regulated cleanroom environments govern its use as a precursor during metal-organic chemical vapor deposition (MOCVD) and liquid encapsulated Czochralski (LEC) crystal growth. Controlled vapor phase introduction ensures highly uniform doping, with automated feed systems minimizing residual contamination. Semiconductor process engineers closely monitor ratios to balance electrical properties while staying within occupational health limits on fugitive emissions.

    Industry compliance standards

    • JEDEC JESD625B Handling of Electrostatic Discharge Sensitive Devices
    • SEMI S2 Environmental, Health, and Safety Guideline for Semiconductor Manufacturing Equipment
    • RoHS Directive 2011/65/EU (for downstream electronic products)
    • Local workplace air quality codes for arsenic exposure (e.g., NIOSH RELs)

    Typical usage ratio

    • 0.5–2% molar ratio relative to metallic input based on crystal growth target and doping level requirements

    Downstream process integration

    • Arsenic source fed via vapor injection to MOCVD or LEC furnaces
    • Automated, closed-loop delivery systems interfaced with process control software
    • Integrated gas scrubbing for off-gas
    • Periodic analytical QC for trace arsenic uniformity

    Final product types

    • Gallium arsenide (GaAs) wafers and substrates
    • Indium arsenide (InAs) crystals and ingots
    • Infrared detector chips
    • High-frequency optoelectronic components

    3. Synthesis of Wood Preservative Compounds

    Formulators in the wood treatment industry utilize arsenic trichloride as a chlorinating reagent to prepare specific arsenic acid-based preservatives. These reactions require tightly controlled process parameters to generate the correct arsenate oxidation state for subsequent blending into preservative formulations, including chromated copper arsenate (CCA). All synthesis steps mandate scrupulous containment and effluent management due to environmental and personnel safety regulations governing arsenic release.

    Industry compliance standards

    • EPA Pesticide Registration Notice 96-10 (for wood preservatives)
    • ASTM D1760 Standard for Pressure Treatment of Timber Products
    • REACH Annex XVII restrictions on arsenic compounds
    • ISO 14001 Environmental Management Systems (applied to processing plants)

    Typical usage ratio

    • 5–12% by reactant weight, modulated per preservative product specification, typically matched to targeted arsenic oxide output

    Downstream process integration

    • Batch reactor chlorination with alkali activation
    • Intermediate product feeds to blending tanks
    • Integrated emissions capture and waste stream treatment
    • QC verification prior to formulation

    Final product types

    • Chromated copper arsenate (CCA) concentrates
    • Arsenic acid solutions for pressure-treating lumber
    • Wood poles and cross arms treated for utility sector
    • Marine piling preservative products

    4. Manufacturing of Glass and Speciality Alloy Additives

    Selected specialty glass and non-ferrous alloy producers incorporate arsenic trichloride as a fining and impurity control agent. Its introduction to glass melts oxidizes and separates unwanted color-forming metal ions and controls gas bubble formation. In copper and lead alloy refining, it serves to manage non-metallic inclusions and grain boundaries. Stringent process controls ensure dosing accuracy to achieve target clarity and microstructure, with exhaust treatment geared to local environmental discharge limits.

    Industry compliance standards

    • EN 1748-2-2: Glass in Building – Special Glasses
    • ISO 9001 Quality Management Systems for continuous process monitoring
    • Local environmental permitting conditions for arsenic emissions
    • European Pressure Equipment Directive 2014/68/EU (for metal casting)

    Typical usage ratio

    • 0.02–0.2% by melt mass for fining glass; up to 0.3% for copper/lead alloy refining, set according to impurity load and batch size

    Downstream process integration

    • Arsenic trichloride metered to glass furnaces at melt stage
    • Alloy shops introduce measured doses during crucible melting
    • Residue extraction through flue gas abatement systems
    • Post-process material validation and waste tracking

    Final product types

    • Specialty lead crystal glassware
    • Optical and display glass panels
    • Copper and lead-based bearing alloys
    • Sheet and container glass with high visual clarity

    5. Analytical Reagent Manufacture for Laboratory Testing

    Producers of analytical reagents prepare standardized titration and trace-element solutions using arsenic trichloride as a key input. Its purity and traceability are documented for supply to academic, industrial, and regulatory labs involved in arsenic quantification and reaction studies. Reagent producers adjust concentrations according to certified reference material requirements and ensure compatibility with analytical instrumentation for colorimetric, spectroscopic, or electrochemical tests.

    Industry compliance standards

    • ISO 17034:2016 for reference material producers
    • ISO/IEC 17025:2017 for analytical laboratories
    • Accreditation under ASTM E29-13 for chemical reagent quality
    • CLP Regulation (EC) No 1272/2008 for safe labeling and shipping

    Typical usage ratio

    • Varies from 0.1–1% w/v, set by calibration curve endpoints and minimum detection limits for each analytical procedure

    Downstream process integration

    • Dilution and stabilization in high-purity solvent systems
    • Bottling in inert-atmosphere production zones
    • Batched with standards for internal laboratory controls
    • Distribution with full certificate of analysis and MSDS

    Final product types

    • Certified titrimetric reagents for arsenic determination
    • Trace element analysis kits
    • Reference stock solutions for spectrophotometry
    • Analytical controls for quality assurance laboratories
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    Certification & Compliance
    More Introduction

    Arsenic Trichloride: Our Approach as a Chemical Manufacturer

    A Longstanding Journey with Arsenic Trichloride

    As a chemical manufacturer specializing in highly reactive inorganic materials, few products have challenged and fascinated us like Arsenic Trichloride. Over several decades, each batch of this compound tells the story of careful handling, close environmental monitoring, and ongoing technical refinement. Its distinctive reactivity—clear, fuming liquid, dense aroma—is matched by a long history in the chemical industry. Every time a new inquiry about Arsenic Trichloride comes across my desk, those realities return: the strict safety requirements, the deep responsibility, and the possibilities this compound opens across multiple fields.

    What We Produce: Our Model and Specifications

    We manufacture Arsenic Trichloride with a purity that meets the requirements of organoarsenic synthesis, glass surface treatment, and electronics intermediates. The standard product leaves our facility as a clear, colorless to pale yellow liquid, verified above 99% purity (as determined by titration and spectroscopy). Trace analysis of iron, lead, and selenium aligns with industry demands for semiconductor applications. Our typical packaging comprises corrosion-resistant, sealed containers designed for both domestic and export use, commonly in net weights of 250 kg and 500 kg, each batch traceable by unique production lot.

    Our experience shows that controlling water contamination is crucial. Hydrolysis leads to hydrochloric acid fumes and arsenic oxides, both hazardous and problematic for high-value end uses. By investing in improved seal technology and advanced inert gas blanketing during both synthesis and filling, we extend shelf life and reduce impurity formation. We invest heavily in maintenance and staff training around these protocols, because every leak or contamination slips right into the value chain, especially for partners in pharmaceuticals or high-end glass etching.

    Uses in Real-World Manufacturing and Research

    Many users in the lab or at scale know this product for its role in synthesizing organic arsenic compounds. Dialkylarsines and arsonic acids both rely on it as a versatile precursor, benefiting from its high reactivity toward nucleophilic substitution. In practice, researchers in agrochemical development or semiconductors prefer our high-purity material to minimize background signal in sensitive equipment. Some glass etchers and specialty ceramic manufacturers have adopted it for controlling surface structure—Arsenic Trichloride facilitates unique thin-film features compared to other metal chlorides.

    In our experience, these industries need not just pure product but clear communication throughout the supply chain. For every order, technical teams reach out because questions run deeper than a spec sheet: temperature stability during shipment, risk of contamination, effectiveness in chlorination reactions, and compliance with both local and international regulatory expectations. That technical back-and-forth, based on real analytical results from our own labs, becomes the difference between successful scale-up and a failed synthesis.

    Key Differences from Other Chlorides and Inorganic Reagents

    Some clients ask why they cannot simply use antimony trichloride, phosphorus trichloride, or other group 15 trichlorides in similar applications. Based on repeated trials and feedback from both our internal chemists and years of customer dialogue, Arsenic Trichloride stands apart for its balance of volatility and reactivity. Unlike the strongly reducing properties of phosphorus trichloride or the greater toxicity of arsenic pentachloride, Arsenic Trichloride meets specific needs: it preserves organic moieties while introducing the arsenic element under controlled conditions.

    Operationally, its handling profile sits somewhere between those two extremes. It fumes on exposure to moisture, yet it resists uncontrolled violent decomposition better than its pentachloride cousin. For most industrial users, this makes it preferable where both safety profile and chemical selectivity matter. Our technical staff has run direct comparisons with antimony and phosphorus analogs in arylation and alkylation protocols; the outcomes diverge at scale due to differences in byproduct formation, purification challenges, and end-product stability.

    Looking at the environmental management side, arsenic itself is strictly regulated. The trichloride enables creation of value-added intermediates without widespread downstream arsenic pollution, provided containment and destruction of waste are implemented. Our plant operates integrated scrubbing and waste management units that neutralize arsenic emissions; we discuss these designs regularly with downstream manufacturers aiming to mirror our compliance systems.

    Challenges and Solutions We Encounter Regularly

    It would be misleading to describe manufacturing Arsenic Trichloride as routine. As production ramps, batch reproducibility becomes paramount. Even small variations in raw arsenic purity or moisture in the reaction vessels translate to measurable differences in final product quality. In our line, that margin of error surfaces quickly, especially when serving the electronics or pharmaceutical industries.

    We draw heavily on statistical process control, overlapping with direct analysis of feedstocks to prevent off-spec batches. Routine GC-MS and ICP-OES scans of each lot flag any deviations long before shipment. Adopting digital batch records ten years ago drastically cut cross-contamination incidents, allowing us to spot batch-to-batch drifts and rectify them.

    On the logistics front, safe draining and repackaging inevitably raise both operational and insurance costs. International transport faces a thicket of customs regulations, particularly for materials with high toxicity. We consolidate shipments or book dedicated hazmat tankers only after full documentation is secured. This approach minimizes delay and aligns with safety review protocols required by downstream users—especially those running batch reactors for specialty syntheses on tight timeframes.

    We've found that many buyers underestimate the challenges of storing and handling volatile inorganic chlorides. To address this, our technical support teams run regular workshops and supply detailed pre-commissioning checklists for customer sites. We advocate for secondary containment, rigorous fume control, and ongoing staff training tailored to the particular reaction environment of each user.

    Speaking Frankly: Risks and Responsibility

    Nobody in this line can ignore the risks connected to Arsenic Trichloride—occupational exposure, process leaks, and the serious regulatory landscape are all realities. Our teams undergo frequent safety drills and have established redundant emergency protocols. In recent years, we have implemented real-time gas monitoring and improved local exhaust engineering for transfer stations.

    Some buyers, especially new ones, ask searching questions about environmental fate and worker safety. It’s not enough to state “regulations are met”—shared accountability builds trust. We have opened our plant to independent audits and industry peer reviews. All relevant authorities receive reporting on annual output, incidents, and corrective actions. We encourage buyers to adopt similar openness in their own traceability and review practices, forming a wider community that takes both environmental stewardship and occupational safety seriously.

    Our technical staff regularly engage with regulators and academic partners. Shared research, such as long-term studies into the degradation and containment of arsenic compounds, informs our approach both upstream and downstream. Once, we partnered with a university laboratory to trial new scrubbing agents—it resulted in changes to both our exhaust treatment systems and those used by key customers.

    Innovation, Adaptation, and Customer Partnership

    On a practical note, development of Arsenic Trichloride has driven changes in our plant that ripple outward into every line of production. For instance, demand for extremely low-iron grades required switching from some legacy steel parts to custom glass-lined or PTFE-lined equipment. What seems like a technical footnote often means large capital commitments and retraining entire maintenance departments, but we have found that staying ahead in quality opens new markets faster than sales teams alone.

    Sometimes, shifts in regulatory requirements force adaptation on short timelines. When European and North American agencies tightened allowable limits for trace lead and selenium in arsenic compounds, our quality engineers re-evaluated both suppliers and internal workflows. Regular exchange with our customer base, especially those running high-spec electronics synthesis, guided much of this process: feedback from those using finished products in sensitive applications shows where incremental purity gains translate directly to field performance.

    From early-stage process development through late-stage manufacturing, the dialogue between supplier and user evolves. We have responded to requests for new packaging sizes, alternate closure mechanisms, and customized documentation. For example, in 2022, a customer developing a new agricultural treatment requested a bespoke sub-100 kg lot to facilitate pilot testing. Our teams turned this request into a rapid-deployment project, adjusting line configuration and implementing new degassing routines to maintain quality at smaller scale.

    Looking Beyond Immediate Delivery: Sustainability and Risk Reduction

    Chemicals like Arsenic Trichloride demand a broader view than simple transaction: safe handling, environmental sustainability, and transparent logistics stand as important as the final chemical property. As environmental scrutiny on arsenic compounds has increased, we have worked internally to strengthen both our containment measures and our product stewardship efforts.

    Our R&D group evaluates potential substitute reagents for some downstream processes, yet demand for Arsenic Trichloride persists where alternatives cannot offer equivalent chemical efficiency. We continue to work with public policy and environmental groups—clear communication about real risks and authentic mitigation strategies keeps both our facility and the communities around us safer.

    This approach carries into our relationships with long-term buyers. Many rely on us to provide regular updates on regulatory trends, changes in research, and advances in detection or containment technology. By building open channels for real-time technical support, incident reporting, and shared learnings, the users of Arsenic Trichloride gain more than a chemical feedstock—they participate in a knowledge network.

    Our Experience Shaping the Product’s Future

    In closing, our work with Arsenic Trichloride reflects a journey of balancing opportunity and responsibility. Developing, manufacturing, and supporting this compound brings challenges that only direct engagement can solve. Each change in production technique, packaging, testing protocol, or customer support call reveals new insights. We learn as much from technical roadblocks as from breakthroughs.

    Precise reactivity, reliable sourcing, and enhanced safety meet real-world needs in specialties ranging from organoarsenic intermediates to electronics. Our actions, born from hands-on manufacturing experience and shaped by collaboration, define the real value of the Arsenic Trichloride we put into the market. Every bottle, drum, and technical call reflects the lessons learned over years. As underlying technologies and industry requirements change, we remain focused on both product quality and the broader context in which this challenging chemical finds its place.