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Adipoyl Dichloride

    • Product Name Adipoyl Dichloride
    • Alias Hexanedioyl dichloride
    • Einecs 208-740-2
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    367392

    Chemicalname Adipoyl dichloride
    Casnumber 111-50-0
    Molecularformula C6H8Cl2O2
    Molarmass 199.04 g/mol
    Appearance Colorless to pale yellow liquid
    Density 1.266 g/cm3 at 20°C
    Meltingpoint -17°C
    Boilingpoint 213°C
    Solubilityinwater Reacts with water
    Refractiveindex 1.474
    Vaporpressure 0.3 mmHg at 20°C
    Flashpoint 95°C (closed cup)

    As an accredited Adipoyl Dichloride factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Adipoyl Dichloride, 500g, is securely packaged in a sealed amber glass bottle with a tamper-evident cap and safety labeling.
    Shipping Adipoyl Dichloride is shipped in tightly sealed, corrosion-resistant containers, typically made of glass or high-grade plastic. It should be transported under cool, dry conditions, away from moisture and incompatible substances. Proper hazard labeling and documentation are required, as it is classified as a corrosive substance and may release harmful fumes if exposed to water.
    Storage Adipoyl dichloride should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area, away from moisture, heat sources, and incompatible substances such as strong bases and oxidizing agents. It should be protected from light and stored under inert gas if possible. Use appropriate corrosion-resistant materials and ensure clear labeling to prevent accidental handling.
    Application of Adipoyl Dichloride

    Applications of Adipoyl Dichloride in Industrial Manufacturing

    As a direct producer of adipoyl dichloride, we serve a focused portfolio of customers engaged in polymer synthesis, specialty coating production, engineering plastics, and advanced fiber manufacture. The following sections outline how downstream manufacturers integrate adipoyl dichloride across distinct industrial contexts, together with relevant compliance regimes, practical formulation guidance, processing details, and typical end products.

    1. Polyamide Engineering Plastics Production

    Downstream polyamide resin manufacturers leverage adipoyl dichloride as a fundamental monomer during the interfacial or solution polymerization of high-performance polyamides such as Nylon 6,6 and specialty polyamides. Adipoyl dichloride reacts with diamines—commonly hexamethylene diamine or meta-xylylenediamine—to build molecular chains offering high thermal and mechanical stability, making these polyamides well-suited for automotive, electrical, and industrial molded components. Adipoyl dichloride’s reactivity ensures full conversion and high molecular weight, critical for end-use mechanical strength.

    Industry compliance standards

    • ISO 9001:2015 Quality Management Systems
    • UL Yellow Card Register (for flame retardancy and electrical use)
    • VDA 233-102 (Automotive Polyamide Resins)
    • RoHS Directive 2011/65/EU (Electrical and Electronic Equipment Applications)

    Typical usage ratio

    • Stoichiometric ratio with diamines, typically 1:1 mole ratio for Nylon 6,6 polymerization; minor adjustments (up to 5% excess) to ensure full monomer consumption based on purity and process control

    Downstream process integration

    • Introduced during the aqueous-organic phase interfacial polymerization step, added via controlled dosing to react with diamine aqueous phase, followed by post-polymerization extraction and drying

    Final product types

    • Polyamide resin granules for injection molding
    • High-strength engineering plastic components (automotive hoods, gears, connectors)
    • Extruded polyamide films

    2. Aromatic Polyamide (Aramid) Fiber Manufacturing

    Producers of para-aramid fibers such as poly(p-phenylene terephthalamide) (PPTA, analog to Kevlar®) rely on adipoyl dichloride for meta- or partially aromatic polyamide structures, enhancing flexibility and processability. Adipoyl dichloride is used as a comonomer with aromatic diamines to fine-tune the balance of fiber rigidity, thermal resistance, and chemical stability, crucial for personal protective equipment and high-end industrial textiles.

    Industry compliance standards

    • OEKO-TEX® Standard 100 (Textiles Safety)
    • ISO 13934-1 (Tensile Properties of Fibers)
    • NIJ Standard-0101.06 (Ballistic Resistance, PPE Applications)
    • REACH Regulation EC 1907/2006 (Chemical Safety Compliance)

    Typical usage ratio

    • Typically 10–40 wt% adipoyl dichloride relative to total acid chloride content, adjusted based on target aramid fiber flexibility and thermal properties

    Downstream process integration

    • Added during acid chloride-diamine polycondensation, followed by fiber spinning and post-treatment; feedstock purity tightly monitored at this stage

    Final product types

    • Spun and drawn aramid filaments
    • Protective clothing fabrics (fire suits, cut-resistant gloves)
    • Reinforcement yarns for composites

    3. Polyurethane Diacid Chloride Chain Extenders for Specialty Elastomers

    Adipoyl dichloride finds significant use with isocyanate-terminated prepolymers in producing thermoplastic and thermoset polyurethane elastomers demanding precisely controlled soft segment crystallinity and enhanced hydrolytic stability. The diacid chloride reacts at the chain extension stage to introduce linear aliphatic units, providing a balance of flexibility and strength for elastomeric sheets, rollers, and custom gaskets used in demanding industrial environments.

    Industry compliance standards

    • ASTM D412 (Physical Properties of Elastomers)
    • FDA 21 CFR 177.2600 (Elastomeric Materials for Food Contact, where approved)
    • ISO 10993-5 (Biocompatibility, for medical elastomers)
    • REACH SVHC Assessments (Consumer and Industrial Applications)

    Typical usage ratio

    • Usually 1–8 mol% relative to soft segment isocyanate prepolymer, adjusted to influence modulus and hydrolytic resistance depending on the application

    Downstream process integration

    • Chain extension proceeds after prepolymerization, where adipoyl dichloride is reacted with excess diol or diamine-terminated prepolymers under controlled temperature and pH, followed by molding or extrusion

    Final product types

    • Industrial polyurethane sheets
    • Translucent and colored elastomeric rollers
    • Custom molded seals and vibration isolators

    4. Synthesis of Aliphatic Polyesters for High-Performance Coatings

    Advanced coatings manufacturers incorporate adipoyl dichloride as a key aliphatic acid chloride in synthesizing high molecular weight polyesters for two-component (2K) and UV-cured coatings. The compound reacts with glycol or polyol components to provide enhanced weatherability, chemical inertness, and flexibility in surface coatings used on metals, plastics, and architectural substrates. Adipoyl dichloride's precise reactivity helps formulators achieve targeted crosslinking densities and ensures batch-to-batch consistency in resin performance.

    Industry compliance standards

    • ISO 12944 (Protective Paint Systems)
    • ASTM D3363 (Film Hardness by Pencil Test)
    • EN 13523-10 (Coil Coated Metals Performance)
    • VOC Regulations: EC Directive 2004/42/EC

    Typical usage ratio

    • 5–25 wt% of total acid chloride content for polyester polyol synthesis; calculated stoichiometrically vs polyol functionalities and adjusted to meet target Tg and flexibility

    Downstream process integration

    • Directly charged with polyol or glycol stream during controlled condensation, followed by neutralization, purification, and formulation into high-solids or waterborne coating systems

    Final product types

    • Industrial metal primers and topcoats
    • Architectural facade coatings
    • Protective clear coats for automotive aftermarkets

    5. Synthesis of Polyamide-Imide Resins for Electrical Insulation

    Manufacturers of wire enamels and high-temperature composite binders use adipoyl dichloride to introduce flexible segments within polyamide-imide polymers, balancing film-forming capabilities and dielectric properties while ensuring processability during wire coating or laminating operations. This enhances the thermal class and mechanical performance of insulation systems, extending the service life of motors and transformers in mission-critical environments.

    Industry compliance standards

    • IEC 60317 (Specifications for Winding Wires)
    • UL 1446 (Systems of Insulating Materials)
    • NEMA MW 1000 (Magnet Wire Standards)
    • RoHS Compliance (Low Halogen Content for Electronics)

    Typical usage ratio

    • 3–15 mol% adipoyl dichloride in acid chloride content (balance with trimellitic anhydride/other diacid chlorides), optimization based on flexibility and breakdown voltage targets

    Downstream process integration

    • Dosage introduced during one-pot condensation with aromatic diamines and anhydrides, followed by solvent removal, resin purification, and dispersion preparation for wire coating baths

    Final product types

    • Wire enamel resins for copper and aluminum magnet wire
    • Laminating resins for electrical core insulation
    • High-thermal class binder resins for electronic component assembly

    6. Polyamide Membranes for Water Treatment and Filtration

    Producers specializing in reverse osmosis (RO) and nanofiltration membranes utilize adipoyl dichloride to tailor polyamide layer permeability and fouling resistance. Introduced into the interfacial polymerization process, adipoyl dichloride provides an optimized balance between salt rejection and water permeability for liquid separation in desalination and ultrafiltration systems. Its role is essential in customizing thin-film composite membranes for specific end-user performance targets.

    Industry compliance standards

    • NSF/ANSI 61 (Drinking Water System Components – Health Effects)
    • ISO 9001:2015 (Membrane Manufacturing Quality)
    • EN 14743 (Water Conditioning Equipment)
    • European Regulation (EC) No 1935/2004 (Contact with Drinking Water)

    Typical usage ratio

    • Typically 2–12 mol% of acid chloride feed for selective “skin” layer formation; ratio adjusted according to required membrane salt rejection and flux ratings

    Downstream process integration

    • Enter the interfacial polymerization bath as part of the acid chloride mixture to react with aqueous diamine phase on microporous supports, followed by curing and post-treatment

    Final product types

    • Spiral-wound RO and nanofiltration membranes
    • Hollow fiber water purification units
    • Polyamide flat sheet membranes for industrial water treatment
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    Certification & Compliance
    More Introduction

    Adipoyl Dichloride: Precision Chemistry from an Experienced Manufacturer

    Bringing Consistency and Purity to Polymer Production

    Over the last two decades, our production lines have handled a wide range of organic intermediates, but few drive innovation in polyamide production as much as adipoyl dichloride. In our facility, the process starts with meticulously sourced raw materials, moving through reactors monitored to keep temperatures and pressure in tight control. This approach yields an exceptionally pure adipoyl dichloride with minimal color, consistent moisture, and the reliability our long-term partners rely on to prevent batch-to-batch issues downstream.

    Understanding Adipoyl Dichloride’s Place in the Chemical Industry

    In our experience, the real value of adipoyl dichloride comes from its performance during polycondensation. With a molecular formula of C6H8Cl2O2 and a molecular weight of 183.04 g/mol, this diacid chloride brings clarity and responsiveness to nylon and specialty polymer production. Adipoyl dichloride’s high reactivity toward diamines such as hexamethylenediamine sets the foundation for PA66—one of the highest-volume engineering thermoplastics. The market for these materials remains strong as automotive, electronic, fiber, and film applications push for performance and processability.

    Specs That Matter in Real-world Applications

    From our years of manufacturing, the clearest lessons come from technical feedback. Consistent purity—typically above 99.5%—ensures a smooth polymerization reaction. Low hydrolysis and minimal acid content also matter, especially when customers run continuous, high-throughput lines for nylon 66 synthesis. Our vacuum distillation units help us achieve moisture contents less than 0.05%, and our packaging lines keep every drum protected against ambient humidity, reducing risk of hydrolysis between shipment and use. Chlorine content remains tightly regulated in our process, since excess contaminant ions compromise the mechanical strength of finished polymers.

    Adipoyl Dichloride’s Impact on Modern Materials

    Around the globe, innovation in textiles, automotive parts, and electrical housings connects back to adipoyl dichloride. Makers of airbag fabrics, tire cords, conveyor belts, and engine covers depend on the unique ability of this molecule to deliver high molecular weight, robust nylons. Engineers prioritize its reactivity and straightforward removal of byproducts, which streamlines water-based synthesis routes and cuts down on the need for harsh, secondary purification steps.

    From our point of view, the advantage grows with project complexity. Producing specialty co-polymers and tailored high-strength plastics means customers require purity, quick release of HCl, and repeatable handling characteristics. By tuning our purification steps and in-process controls, we answer this demand with batches that resist oxidative discoloration and support higher-end polyamides, including those for medical, aerospace, and semi-crystalline applications.

    Route to Market: From Factory Floor to Laboratory Bench

    Our facility not only scales up large tonnage for industrial polymer synthesis—thousands of kilograms per batch—but also supplies adipoyl dichloride in high-purity lots for pilot plant trials and advanced R&D labs. We understand how a kilogram-scale batch destined for a university lab in Europe faces different bottlenecks compared to hundreds of drums shipping to a tire producer in Southeast Asia. Chemical compatibility, regulatory paperwork, and logistics all pose challenges, so our team checks for tight drum seals, up-to-date Certificates of Analysis, and customs compliance before any shipment leaves our site.

    After decades partnering with nylon producers and specialty material startups, we learned to adjust to changing regulatory landscapes. Adipoyl dichloride, like other acid chlorides, falls under transport restrictions due to its corrosivity and reactivity. We use lined drums and prompt documentation, not to add ritual, but to keep handlers safe and ensure product integrity arrives uncompromised. Our teams conduct recurring safety drills, and we offer application-specific training to customers who request it.

    What Sets Our Adipoyl Dichloride Apart

    Many commercial acid chlorides surface in the market, from phosgene-based syntheses to less stringent purification models. Through continuous investment in process controls, our adipoyl dichloride stays free from residual solvents found in older, batch-mode chlorinations.

    Trace iron, magnesium, and other metal contaminants remain a constant threat to polymer clarity and molecular weight distribution. Our integrated purification and quality monitoring systems screen for these ions down to the ppm range, eliminating a major variable in demanding applications. This attention goes beyond commodity nylon production: dye intermediates and performance polymers both need a rigorous approach to QA.

    Customers often comment that our product offers less yellowing of finished materials and fewer handling incidents in their own processes. We attribute this to the controlled HCl evolution in our closure system, tight drum specifications, and rigorous training of our loading teams. For smaller research requests, we deliver in glass ampoules and PTFE-lined bottles to further eliminate risk.

    Technical Feedback and Continuous Improvement: Insights from Use in the Field

    No lab data or pilot plant run matches the learning that comes from frequent customer troubleshooting. During polymerization, even slight moisture intrusion can bring down molecular weights or cause premature gelling. One regional partner struggled with filter blockages in their continuous nylon 66 line until we helped them trace back source moisture content and switch to custom-packaged lots with added moisture scavenger.

    Another client manufacturing heat-resistant polyamides reported difficulties with residual color and inconsistent mechanical strength. Through joint testing, we discovered the upstream reaction needed a tighter hold on reaction time and temperature control, prompting us to rework part of our distillation sequence. This added transparency and higher purity kept their product specs inside a much narrower window.

    Since many research teams seek novel copolymer structures, a consistent and traceable adipoyl dichloride supply supports broader innovation. Our application engineers exchange knowledge across industries, helping textile makers, 3D printing ventures, and electronics developers navigate side reactions, byproduct profiles, and optimum storage conditions.

    Comparing Adipoyl Dichloride with Other Acid Chlorides

    Among aliphatic diacid chlorides, adipoyl dichloride strikes a valuable balance between reactivity, ease of handling, and the downstream properties it imparts to polymers. Sebacoyl dichloride extends carbon chain length and imparts slightly different flexibility to polyamides, but supply costs and process volatility increase with each carbon atom added.

    Terephthaloyl dichloride, used for aromatic polyamides such as Kevlar, brings in higher rigidity but also requires harsher reaction conditions and stricter solvent management. Acetyl chloride or succinyl chloride, though useful in some acylations, lack the double terminal chloride functionality and sufficient chain length to match adipoyl dichloride’s output in engineering plastics.

    We see many end users blend grades from different suppliers for cost reasons, only to encounter yield drops or erratic physical properties due to hidden contaminants. Unlike commodity acid chlorides, our production emphasizes reproducible chlorination and rigorous moisture suppression, which repeated customer audits have confirmed.

    Sustainability, Safety, and Responsible Handling

    Attention to safety spans far beyond regulatory checklists. Adipoyl dichloride reacts vigorously with water to produce HCl, so our plant integrates closed system unloading, dual-contained transfer piping, and hands-on training for every batch release. Within our operation, spill response and emissions controls are not just box-ticking exercises; they’re part of daily accountability to the team and environment.

    Since many customers request guidance on safe handling, we provide detail on local exhaust needs, appropriate storage atmosphere, and personal protective equipment. Shippers and warehouse managers receive clear communication on what happens if drums sustain impact, or if a leak is detected at a customer site.

    Material traceability is a growing industry trend. Record-keeping for each batch extends all the way through raw material logs, processing parameters, and confirmation of shipment seal integrity. This attention to detail helps avoid inadvertent mixing with food-grade or other sensitive cargos in shared warehouses, a risk flagged by several customers in international ports.

    Pursuing Greater Value for Advanced Materials

    As more manufacturers pivot toward lightweight, durable materials for mobility and energy storage, we see steady growth in demand for high-integrity adipoyl dichloride. This increase goes hand in hand with stricter expectations for purity, packaging, and specialized application support. Sustainability efforts have also led several of our partners to look for greener chlorination agents, closed-loop purification strategies, and lower emissions footprints.

    Our R&D group collaborates on synthesis routes using less hazardous chlorinating agents where feasible. We also work on process intensification—cutting down solvent waste and improving energy efficiency—due to feedback from key nylon and amide polymer clients under increasing regulatory and consumer pressure.

    Refining batch sizes and containerization for global delivery brings its own set of process challenges. In the past five years, multiple international customers have sought custom packaging compliant with transport norms in North America, Europe, and Asia. By working with supply chain partners, we offer container types ranging from mild steel drums for high-volume users to glass ampoules for analytical and synthetic labs, while updating documentation to include all relevant safety and customs requirements.

    Direct Feedback Loop with Global Polymer Producers

    Maintaining open communication with every type of user—industrial, research, or specialty—has taught us the value of acting on technical feedback. One recurring issue is the influence of minor batch impurities on the mechanical and dyeing properties of engineered plastics. Our analytical group now routinely screens for ketones, aldehydes, and unsaturated species in addition to standard acid and chloride purities.

    Another area ripe for continuous improvement comes from customer automation. More lines now run automated feed and mass balance controls, so any deviation in feedstock purity or moisture can cause extensive process upsets. Our team continues to invest in online sensors and remote reporting tools so operators can quantify the results of real-world performance, not just what the data sheet promises.

    For customers exploring next-generation materials, such as nanocomposites or high-temperature-capable copolymers, access to detailed process history and batch analytical data from our plant offers a solid foundation for scaling up experiments.

    The Path Forward for High-Purity Adipoyl Dichloride

    The impact of adipoyl dichloride extends far beyond its use as a building block for polyamide 66. We see increased adoption in the custom synthesis of polyesters, amide-imide copolymers, and specialty acrylates. Our production team stays in regular contact with R&D centers shaping the future of lightweight vehicles, energy transmission, and high-performance adhesives.

    For custom applications, such as biomedical devices or electronic encapsulants, performance benchmarks keep rising. We answer these demands with improved analytical control and packaging suited for each delivery profile.

    Through decades of continuous innovation, we reinforce what our customers value most: transparency, reliability, and real-world expertise. Each batch reflects the lessons learned in manufacturing, regulatory navigation, technical troubleshooting, and a commitment to sustainable, forward-thinking chemical production.

    As the chemical landscape shifts and new markets emerge, our investment in technology, personnel, and process discipline ensures that our adipoyl dichloride delivers exceptional value. The journey does not end at the loading dock; it continues in partnership with those driving the next wave of polymer innovation.