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Acenaphthene

    • Product Name Acenaphthene
    • Alias 1,2-Dihydroacenaphthylene
    • Einecs 201-549-0
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    361393

    ChemicalName Acenaphthene
    CASNumber 83-32-9
    MolecularFormula C12H10
    MolarMass 154.21 g/mol
    Appearance Colorless to pale yellow crystalline solid
    MeltingPoint 93-95 °C
    BoilingPoint 279 °C
    Density 1.24 g/cm³
    SolubilityInWater Insoluble
    FlashPoint 140 °C
    VaporPressure 0.0031 mmHg (25 °C)
    Odor Naphthalene-like
    Synonyms 1,2-Dihydroacenaphthylene
    PubChemCID 9231

    As an accredited Acenaphthene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Acenaphthene (250g) is supplied in an amber glass bottle with a tight-sealing cap, featuring hazard labels and safety instructions.
    Shipping Acenaphthene should be shipped in tightly sealed containers, protected from physical damage and labeled according to hazardous material regulations. It must be transported in compliance with local, national, and international regulations for flammable solids (UN 1325, Class 4.1). Store and ship away from sources of ignition and strong oxidizers. Handle with care.
    Storage Acenaphthene should be stored in a tightly closed container in a cool, dry, and well-ventilated area, away from sources of ignition and incompatible substances such as strong oxidizers. Keep away from direct sunlight and heat. The storage area should be clearly labeled and designed to prevent environmental contamination or unauthorized access. Follow all local, state, and federal regulations for hazardous material storage.
    Application of Acenaphthene

    Applications of Acenaphthene in Industrial Manufacturing

    As a manufacturer specializing in high-purity acenaphthene, we supply downstream industries with precisely formulated materials essential for advanced chemical synthesis, specialized coatings, agricultural actives, and high-performance intermediates. Our production integrates strict quality controls to meet specific sector requirements and deliver reliable solutions to long-established industrial applications.

    1. Advanced Naphthalene-Based Dyes and Pigments

    Acenaphthene serves as a key building block in the synthesis of naphthalimide and perylene dyes, widely used for industrial coloration in plastics, fibers, and specialty coatings. Our clients incorporate the material primarily during the early condensation stage, where its two-ring structure participates in cyclization and functional group transformation, contributing to enhanced solubility and lightfastness of the resulting pigment. The selection and dosage depend on end-use brightness, solvent compatibility, and targeted fastness properties, with consistent batch integration by precise gravimetric control.

    Industry compliance standards

    • OEKO-TEX® Standard 100 for textiles
    • REACH Annex XVII (restriction of certain dyes)
    • EN 71-3 (safety of toys for colored materials)
    • ISO 105 series (color fastness testing)

    Typical usage ratio

    • 0.2%–1.5% of total monomer or precursor batch, adjusted for pigment intensity and substrate compatibility

    Downstream process integration

    • Initial charge in condensation reactors for dye synthesis, supporting subsequent sulfonation or imide formation; controlled addition alongside aminonaphthalene or phthalic anhydride

    Final product types

    • Naphthalimide yellow and red dyes for plastics and fibers
    • Perylene-based high-stability pigments for automotive paints
    • Specialty UV-absorber dyes for engineering polymers
    • Textile colorants for high-fastness applications

    2. High-Purity Intermediates for Agrochemical Active Ingredient Synthesis

    Acenaphthene underpins several synthetic routes for agricultural active ingredients, particularly carboximides and selective fungicide molecules. Downstream manufacturers rely on its aromatic stability and methyl group activation to construct fused-ring scaffolds essential for selective activity. The raw material enters multi-stage Grignard or Friedel-Crafts reactions, with scale-up operations demanding strict impurity control and careful titration against catalyst response. Final formulations achieve regulatory clearance for field use following thorough residual precursor checks.

    Industry compliance standards

    • FAO/WHO Specifications for Plant Protection Products
    • US EPA Pesticide Registration (40 CFR Part 180)
    • ISO 9001:2015 for agrochemical manufacturing
    • OECD Guidelines for the Testing of Chemicals (GLP)

    Typical usage ratio

    • 1.0%–4.5% based on molar input into active ingredient synthetic route; proportion varies with desired yield, impurity threshold, and downstream coupling requirements

    Downstream process integration

    • Stagewise introduction during fused-arene ring formation, typically before oxidation/cyclization steps; precise dosing via automated addition at controlled temperatures to maximize conversion to target carboximide or imide intermediates

    Final product types

    • Systemic fungicide actives (e.g., naphthalimide class)
    • Seed treatment formulations
    • Crop protection pre-emergence products
    • Stabilized pesticide dispersions

    3. Precursor for Hydronaphthalene Derivatives in Fine Chemical Synthesis

    Several fine chemical producers select acenaphthene for partial hydrogenation to hydronaphthalene derivatives, which serve as valuable intermediates in fragrance bases, reducing agents, and electronic material synthesis. The raw material’s rigid aromatic structure enables controlled catalytic hydrogenation in fixed-bed or slurry reactors. By tailoring pressure and temperature profiles, processors balance conversion and selectivity, achieving optimal feedstock for subsequent chlorination or esterification steps. These derivatives are integral to specialty polymers and fine aroma compounds.

    Industry compliance standards

    • ISO 14001 (environmental management for fine chemicals)
    • GMP for industrial aromatics (as applicable in major economies)
    • JECFA specifications for precursors in food-flavor manufacture
    • IECQ QC 080000 (Hazardous Substance Process Management)

    Typical usage ratio

    • 5%–12% by weight in hydrogenation input stream; optimized according to desired hydronaphthalene purity and downstream production volume

    Downstream process integration

    • Initial charge for catalytic hydrogenation, followed by fractional distillation to isolate hydronaphthalene isomers for subsequent transformation; dosage controlled to match reactor loading and catalyst turnover number

    Final product types

    • Hydronaphthalene-based perfume intermediates
    • Hindered amine light stabilizers (HALS) for plastics
    • Specialty reducing agents for advanced organic syntheses
    • Precursors for OLED electronic materials

    4. Raw Material for High-Performance Resins and Thermosetting Polymers

    Process engineers in the performance polymer sector utilize acenaphthene as a monomer precursor for high-temperature and corrosion-resistant resins, including certain naphthalene-based phenolic and epoxy systems. The raw material enters condensation polymerization or epoxidation processes, supporting the targeted development of mechanical strength and chemical durability in composite matrices. Strict batch traceability, solvent exclusion, and fine filtration precede blending, and the formulation ratio adapts to the resin functionality and cross-link density required by the application.

    Industry compliance standards

    • UL 94 (flammability for plastic materials)
    • ASTM D1655 (standards for thermosetting resin raw materials)
    • RoHS Directive 2011/65/EU (electronics applications)
    • ISO 9001:2015 (polymers and composites)

    Typical usage ratio

    • 0.8%–3.0% by weight in resin precursor formulation; dosage tailored to curing conditions and target glass transition temperature

    Downstream process integration

    • Blend during prepolymer synthesis, commonly added prior to or concurrent with catalyst and cross-linker to adjust aromatic balance and resin infusibility; strict process validation for each production batch

    Final product types

    • High-temperature insulating resins for electronics
    • Corrosion-resistant phenolic composites for industrial filtration
    • Structural adhesives for aerospace and automotive components
    • Specialty encapsulation formulations

    5. Specialty Products for Lubricant and Oil Additive Manufacturing

    Lubricant and oil additive formulators employ acenaphthene as an intermediate to produce synthetic base stocks and dispersants, especially for high-performance greases. During downstream alkylation and sulfonation, the aromatic character supports thermal stability and sludge-dispersing properties. Careful control over addition temperature and sequence enables precise molecular tailoring, maximizing clean-running and anti-oxidant behavior in finished lubricant systems. Compliance targets depend on transportation and mechanical system requirements.

    Industry compliance standards

    • API SN/CF (engine oil quality)
    • SAE J183 (engine oil standards)
    • ASTM D4485 (diesel engine oil formulations)
    • ISO 21469 (safety in lubricant manufacture)

    Typical usage ratio

    • 0.5%–2.0% of the additive package; ratio flexes depending on target viscosity, ash level, and in-use detergent property

    Downstream process integration

    • Charged during additive package synthesis, particularly before alkylation or sulfonation; integrated with other aromatic building blocks via continuous or batch processing, followed by purification and neutralization

    Final product types

    • Synthetic lubricant base stocks
    • Dispersant and detergent additive concentrates
    • High-temperature, oxidation-stable greases
    • Heavy machinery hydraulic oils
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    Certification & Compliance
    More Introduction

    Acenaphthene: An Experienced Perspective from the Manufacturer

    Understanding Acenaphthene from the Ground Up

    Acenaphthene, a polycyclic aromatic hydrocarbon, holds a unique place in our product portfolio. Decades of refining our processes have taken this crystalline solid, C12H10, from a byproduct in coal tar distillation to a raw material recognized for reliability. Over time, we've observed both changing regulations and evolving market needs, all while ensuring our acenaphthene remains consistent, safe, and tailored for demanding industrial applications.

    Specifications Grown from Manufacturing Experience

    Our production line delivers acenaphthene to meet high-purity standards suitable for downstream chemistry. The crystal clarity and distinctive blue fluorescence under UV come from multiple purification cycles. We take pride in our commitment to removing impurities such as acenaphthylene and naphthalene, with routine analysis showing purity consistently above 98%. Moisture content remains low, usually below 0.1%, confirmed through Karl Fischer titration. The melting point averages 91–94°C — a range reflecting both batch consistency and the stability crucial for specialty uses. Particle size and form both matter: we provide material mostly in granule form as this improves handling during weighing and feeds seamlessly into reactors.

    Why Industry Chooses Acenaphthene

    Practical experience in the lab and on the factory floor has reinforced acenaphthene’s value. Organic synthesis firms rely on its reactivity for building complex molecules — especially pharmaceutical intermediates and fine chemicals. It plays a foundational role in dye chemistry, where our customers report improved yields when using our high-purity acenaphthene as a precursor for naphthalic anhydride and other colorants. Some manufacturers in the plastics sector favor our material for its behavior during heat stabilizer production, since it integrates smoothly and leaves fewer byproducts than less purified sources. We've also supported aroma chemical producers, who exploit its unique backbone for synthesizing fragrance intermediates. Over the years, collaboration with technical end-users has led to adjustments in packaging and batch sizes, making storage and transfer easier while reducing physical waste in high-throughput plants.

    What Sets Our Acenaphthene Apart

    Long-term relationships with industrial chemists have shaped our process choices. Unlike standardized commodity batches sourced from non-dedicated lines, we use special extraction and recrystallization protocols. Residual sulfur and nitrogen impurities can disrupt downstream catalytic reactions; we've invested in extra purification steps to address these. Our internal audits regularly confirm that the total polycyclic aromatic hydrocarbon content remains far below the levels that trigger regulatory scrutiny in North America, Europe, and East Asia. Trace analysis by GC-MS and HPLC detects sub-ppm levels of contaminants, ensuring customers no longer need to run additional clean-up steps that used to cost time and budget.

    Comparing to acenaphthylene or naphthalene, there is a clear distinction in both chemical behavior and end-use. Acenaphthylene reacts less reliably in ring-opening reactions due to its higher aromatic stabilization energy. Naphthalene, though structurally similar, cannot serve as a direct surrogate since its reactivity under Friedel–Crafts conditions diverges sharply from acenaphthene. Chemists seeking to introduce functional groups onto the peri positions find acenaphthene a more straightforward building block. As a result of this performance difference, many long-standing customers have built processes around our product, choosing not to substitute even when price pressures fluctuate.

    Meeting Customer Needs through Direct Manufacturing

    As a manufacturer, we control every stage from raw material procurement to finished packaging. Coal tar distillation may seem antiquated, but our experience has shown that using select feedstock grades delivers the most reproducible acenaphthene yield. Over the years, we’ve minimized waste streams and improved energy efficiency by optimizing fractional condensation conditions. Customer requests led us to adopt anti-caking agents in larger packaging formats, preventing bridging in silos and easing automated feed into chemical reactors. In recent years, feedback from transportation partners prompted us to switch to more robust sacks and drums, reducing transit losses and lowering the risk of product degradation during long shipments in hot climates.

    Tight communication between our manufacturing, QA, logistics, and customer support teams means technical issues get solved early. For instance, some specialty pigment makers once faced batch-to-batch variation in their final orange and red hues; a closer look traced color drift to trace oxidants in some acenaphthene supplies. We worked with these partners, introducing extra vacuum stripping at the tail end of our distillation, which brought consistency back and restored customer confidence. These practical collaborations set us apart from bulk resellers, who often lack process flexibility or responsiveness.

    Safety, Compliance, and Handling — Knowledge Born of Practice

    Manufacturing experience in the chemical field confers a deep understanding of how safety and compliance influence material choice. Acenaphthene does not present the acute danger of heavy PAH compounds, yet we treat it with the same respect and vigilance embedded in our broader corporate ethos. Ventilation, closed-loop transfer, and dust suppression practices have evolved over decades in our production areas, protecting both personnel and customers down the supply chain. Risk management extends to packaging innovations: after several high-profile incidents in third-party warehouses connected to mishandling of motor oils and related PAHs, we added clear labeling about incompatibilities with strong oxidizers and recommendations for cool, dry storage. Periodic hazard assessments performed in-house keep our safety data up to date with global regulatory frameworks. Customers appreciate these proactive steps, knowing that industrial continuity and environmental compliance are not left to chance.

    Trends Shaping the Acenaphthene Market and Our Response

    Shifting global economics and sustainability initiatives have begun to reshape how acenaphthene enters both lab and production-scale applications. Several customer partners, particularly in the EU and Japan, now request information on our sourcing practices and the energy profile of our operations. We’ve launched projects designed to further improve recovery yields and harness residual heat from the purification cycle, lowering both cost and emissions per unit produced. For buyers focused on green chemistry, we supply documentation detailing the absence of persistent organic pollutants and endocrine-disrupting impurities in our acenaphthene. Younger R&D groups also ask about recyclable packaging, leading us to pilot returnable drum systems that maintain product integrity while minimizing single-use plastics.

    Our technical team tracks emerging research — such as photocatalytic degradation routes for PAH contaminants — and shares meaningful updates with partners considering new process routes. Demand from electronics manufacturers has generated novel questions about acenaphthene as a precursor in advanced organic semiconductors. While this lies outside historical uses, collaboration with early-stage device labs has fueled renewed investment in analytical toolkits, pushing detection of trace ions and halides to even lower limits. By updating test protocols and refining batch records, we provide the transparency that high-tech clients require for their material certification.

    Practical Solutions to Persistent Industry Issues

    The acenaphthene market faces cycles of supply instability because only a few producers maintain dedicated capacity. We’ve explored partnerships with upstream coal processing firms to guarantee steady feedstock, negotiating multi-year contracts that shield our downstream customers from price spikes and material rationing. Logistics headaches — especially at international borders prone to delays or inspections — led us to invest in digital traceability systems. These provide real-time batch data and shipment tracking, minimizing paperwork ties and speeding up customs processing. This hands-on approach saved one auto additives maker from a several-week shutdown during a recent global shipping crunch, underscoring the value of a hands-on manufacturer relationship.

    Industrial buyers expect both documentation and human responsiveness. Our sales and technical support people have chemistry backgrounds, enabling fast troubleshooting if an application specialist encounters unexpected solubility or reactivity quirks. During batch scale-up, one customer found polymerization inhibitors interacting poorly with trace organics from their old acenaphthene supplier; working together, we identified and eliminated those impurities, restoring both product yield and safety margins.

    Why Acenaphthene Remains a Core Raw Material

    Within the chemical landscape, acenaphthene occupies a resilient niche. Not every high-value aromatic compound offers this combination of solubility, reactivity, and stability. No other polycyclic hydrocarbon enables such straightforward transformations for functional pigments and specialty chemicals. There are faster, cheaper, or lighter alternatives, but in practice, when precision and reproducibility drive the process, acenaphthene continues to anchor many industrial syntheses. Our customers return batch after batch not simply for a formula on a label, but for a partnership grounded in shared track records, rigorous standards, and mutual understanding of both challenges and breakthroughs in the chemical sector.

    Looking Forward: Next Steps in Acenaphthene Manufacturing

    Manufacturers cannot rest on tradition or legacy expertise alone. The next wave of improvements in acenaphthene production hinges on both technological and social shifts. New environmental benchmarks and regulatory limits constantly push us to revisit what constitutes “pure enough” and “safe enough.” We are piloting analytical methods based on high-resolution chromatography and spectroscopy, extending the scope of batch records and ensuring each drum or bag arrives ready for use in sensitive applications. Our R&D group explores both raw material flexibility — exploring biomass-derived aromatics and cleaner extraction media — and advanced process intensification. Conversations with leading-edge customers in electronics and materials science drive cycles of process adjustment, product feedback, and mutual learning. With each iteration, the gap between laboratory ideal and industrial reality narrows, enabling more reliable use of acenaphthene across established and emerging fields.

    From this vantage point, we see acenaphthene not as a finished product but as an evolving solution to tomorrow’s chemical challenges. Each year, new applications emerge, driven by the hands-on needs of synthesis specialists, pigment experts, and process chemists. The longevity and continued improvement of our acenaphthene reflect a belief shared by everyone on our team: building quality, consistency, and value starts at the source — in the plant, in the lab, and through direct, genuine engagement with those who rely on our chemistry every day.