Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing admin@sinochem-nanjing.com 3389378665@qq.com
Follow us:

4-Methyl-1-Cyclohexene

    • Product Name 4-Methyl-1-Cyclohexene
    • Alias 4-Methylcyclohexene
    • Einecs 226-641-8
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    446011

    CAS_number 591-47-9
    IUPAC_name 4-Methyl-1-cyclohexene
    Molecular_formula C7H12
    Molar_mass 96.17 g/mol
    Appearance Colorless liquid
    Density 0.798 g/mL at 25°C
    Boiling_point 116-117°C
    Melting_point -126°C
    Flash_point 13°C
    Refractive_index 1.444 at 20°C
    Solubility_in_water Insoluble
    Vapor_pressure 26 mmHg at 25°C

    As an accredited 4-Methyl-1-Cyclohexene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A 500 mL amber glass bottle labeled "4-Methyl-1-Cyclohexene," tightly sealed, with hazard warnings and handling instructions clearly visible.
    Shipping 4-Methyl-1-Cyclohexene should be shipped in tightly sealed containers, protected from light and moisture. It must be transported as a flammable liquid (UN 3295), following all relevant regulations. Ensure proper labeling, avoid sources of ignition, and store in a cool, well-ventilated area during transit. Handle with appropriate personal protective equipment.
    Storage 4-Methyl-1-cyclohexene should be stored in a cool, dry, well-ventilated area, away from heat, sparks, open flames, and incompatible substances such as oxidizing agents. Keep the container tightly closed and properly labeled. Store away from direct sunlight and sources of ignition, and use only non-sparking tools. Ensure containers are grounded and bonded to prevent static discharge.
    Application of 4-Methyl-1-Cyclohexene

    Applications of 4-Methyl-1-Cyclohexene in Industrial Manufacturing

    4-Methyl-1-Cyclohexene serves as a crucial intermediate in several specialized industrial sectors. As a chemical manufacturer, we ensure strict quality controls and consistent batch reproducibility for reliable performance across downstream applications. Below, we outline key scenarios where this raw material demonstrates direct, real-world utility, with detailed insight on compliance, formulation, integration, and final products.

    1. Fragrance Ingredient Synthesis

    Major fragrance and aroma chemical manufacturers use 4-Methyl-1-Cyclohexene as a building block for cyclohexyl-derived aromatic intermediates. Its alkene moiety enables Diels–Alder and Friedel–Crafts alkylation reactions to create musky and woody note chemicals that underpin natural-inspired perfume compositions and fine fragrance concentrates. The raw material enters early-stage reaction steps, where precise purity is critical to minimize off-odors or unwanted by-products in premium-grade formulations.

    Industry compliance standards

    • IFRA (International Fragrance Association) Code of Practice and Standards
    • EU Regulation (EC) No 1223/2009 for cosmetic safety (as applicable to aroma ingredients)
    • REACH Registration and Safety Dossier (European market)
    • Product-specific environmental and safety compliance for downstream use

    Typical usage ratio

    • 1–3% by weight in fragrance intermediate synthesis batches; may adjust within 0.5–5% range based on target compound complexity and downstream reaction yields

    Downstream process integration

    • Acts as a primary reactant during the initial cyclization or alkylation steps in aroma chemical manufacturing before purification and concentration of finished fragrance ingredients

    Final product types

    • Aroma chemicals for fine fragrances (e.g., cyclohexyl-based musks, woody notes)
    • Compounded perfume oils
    • Flavor and fragrance intermediates for consumer product blends

    2. Specialty Polymer Monomer Production

    Chemical plants utilize this intermediate as a feedstock to introduce methyl-cyclohexenyl moieties into specialty polymer backbones. The compound supports ring-opening metathesis polymerization (ROMP) and post-polymerization functionalization in controlled environments, enhancing properties such as flexibility, chemical resistance, and controlled vapor permeability. Its strict reactivity window requires on-line monitoring during high-throughput monomer batch processing.

    Industry compliance standards

    • ISO 9001:2015 for polymer manufacturing quality systems
    • RoHS (Restriction of Hazardous Substances, EU Directive 2011/65/EU) for electrical and electronics applications
    • FDA 21 CFR 177.1520 (where polymers are intended for indirect food contact)
    • REACH compliance for European distribution

    Typical usage ratio

    • 3–8 mol% as a comonomer in advanced specialty polymer synthesis; adjustment based on mechanical or barrier property targets and compatibility with main polymer chain

    Downstream process integration

    • Direct addition in the pre-polymerization monomer feed, where it undergoes ROMP or co-polymerization reactions to generate tailored polymer chains before pelletizing, molding, or extrusion steps

    Final product types

    • Thermoset and thermoplastic resins with cycloaliphatic content
    • High-performance coatings with enhanced flexibility
    • Membrane materials for filtration technologies
    • Polymer modifiers for specialty adhesives

    3. Agrochemical Intermediate Manufacturing

    Producers of crop protection actives incorporate 4-Methyl-1-Cyclohexene into synthetic routes for select herbicidal and pesticidal compounds. Its structure introduces desired ring tension and hydrophobicity in the agrochemical scaffolds, supporting the formulation of actives with targeted field efficacy. Accurate dosing at precise stages is essential to avoid residual unreacted intermediates and comply with regulatory impurity thresholds for agricultural use.

    Industry compliance standards

    • FAO/WHO Codex Alimentarius guidelines for agricultural chemicals
    • ISO 17025 laboratory accreditation for quality control
    • US EPA pesticide registration requirements
    • EU Regulation (EC) No 1107/2009 for plant protection products

    Typical usage ratio

    • 2–6% by mass in intermediate synthesis steps, scaled to downstream batch sizes and reactivity requirements for each active ingredient

    Downstream process integration

    • Feeds directly into cyclization or alkylation stages during active ingredient synthesis; monitored for conversion to limit trace intermediates in the formulated product

    Final product types

    • Herbicide technical concentrates
    • Pesticide active ingredient crystals and granules
    • Basis intermediates for downstream agrochemical formulation (EC, SC, WG)

    4. Industrial Rubber and Elastomer Additive Synthesis

    In high-performance rubber compounding, derivatives of 4-Methyl-1-Cyclohexene function as cross-linker precursors and chain modifiers, particularly in applications stressing dimensional stability and heat resistance. Compounders calculate input ratios according to batch-specific tensile and elongation targets, while maintaining compatibility with sulfur or peroxide curing systems, enabling custom elastomer grade development for critical industrial use.

    Industry compliance standards

    • ASTM D2000 for automotive EDPM and general rubber materials
    • ISO 14001 (environmental compliance in rubber processing)
    • REACH (for elastomer additives in European Union applications)
    • UL 94 flammability rating for elastomers in electrical and industrial assemblies

    Typical usage ratio

    • 0.5–2% by weight as an additive precursor, with final dosage optimized for targeted cross-link density and to prevent blooming or phase separation during curing

    Downstream process integration

    • Introduced in the masterbatch or compounding stage, where it reacts or disperses prior to vulcanization; adjustment follows QC elastomer property testing

    Final product types

    • Engineered rubber articles for automotive and industrial seals
    • Heat-resistant hoses and gaskets
    • Industrial vibration damping and insulation materials
    • Custom elastomer grades for specialty applications

    5. Fine Chemical Intermediate for Pharmaceutical Synthesis

    GMP-compliant fine chemical manufacturers use this molecule as a key intermediate to build chiral cyclohexyl structures in active pharmaceutical ingredient (API) precursors. Its reactivity profile supports regioselective transformations, which in turn facilitate stereospecific modifications during multi-step synthesis routes for advanced pharmaceutical compounds, including certain central nervous system (CNS) and antihypertensive candidates.

    Industry compliance standards

    • ICH Q7 Good Manufacturing Practice for Active Pharmaceutical Ingredients
    • USP/NF Monographs (United States Pharmacopeia/National Formulary)
    • EU GMP EudraLex Volume 4, Part II for APIs
    • FDA Drug Master File (DMF) registration for relevant intermediates

    Typical usage ratio

    • 1–4 molar equivalents as a reaction intermediate, adjusted per API target yield and multi-stage synthetic conversion limits

    Downstream process integration

    • Used in controlled-stage chiral resolution or alkylation/transformation reactions; entered during intermediate step with in-process QC on enantiomeric purity and conversion efficiency

    Final product types

    • Pharmaceutical fine chemical intermediates
    • Building blocks for chiral API synthesis (e.g., CNS drugs, antihypertensives)
    • Precursor compounds for advanced pharmaceutical research
    Free Quote

    Competitive 4-Methyl-1-Cyclohexene prices that fit your budget—flexible terms and customized quotes for every order.

    For samples, pricing, or more information, please call us at +8615371019725 or mail to admin@sinochem-nanjing.com.

    We will respond to you as soon as possible.

    Tel: +8615371019725

    Email: admin@sinochem-nanjing.com

    Get Free Quote of Sinochem Nanjing Corporation

    Flexible payment, competitive price, premium service - Inquire now!

    Certification & Compliance
    More Introduction

    Introducing 4-Methyl-1-Cyclohexene: Chemical Building Block with Purpose

    Every manufacturer who works with specialty chemicals knows there are a handful of compounds you reach for again and again to solve tough process challenges, minimize unwanted steps, or deliver cost-savings. 4-Methyl-1-Cyclohexene fits squarely in that category for us. After years on both batch and continuous lines, it’s clear this molecule stands out not just on paper, but in the day-to-day reliability it brings to a range of downstream transformations.

    Model, Purity, and What That Delivers

    Our facility produces 4-Methyl-1-Cyclohexene under close-controlled conditions. Purity runs upwards of 98%. By refining our batch separation steps and monitoring key quality parameters, we keep peroxide formation and water content extremely low. We’ve seen how a stray percent of impurity can throw an entire synthesis into disarray—especially in applications like coupling chemistry or where catalyst deactivation can grind a line to a halt. So we don’t take shortcuts on purity. Our QC team spends time checking every lot against a set of standards we’ve evolved with input from our most demanding pharma and agchem customers.

    What does this mean for a user? Reaction reproducibility, fewer purification headaches, and predictable yields. Customers often share their reaction profiles with us directly. Over time we build a feedback loop, tweaking process controls to avoid runaway exotherms, unnecessary side-product formation, or downstream isolation issues. This collaboration shapes every barrel we send out the door.

    Chemical Attributes and What Makes It Useful

    4-Methyl-1-Cyclohexene brings a unique blend of properties to a chemist’s toolbox. The cyclohexene core grants stability versus open-chain analogs and stands up to a range of reagent conditions without isomerizing easily. The methyl substituent at the 4-position subtly tunes ring strain and increases resistance to oxidation compared to the parent cyclohexene. We’ve seen this structure weather harsh process conditions where competitors like 3-methyl-1-cyclohexene tend to degrade or polymerize. Customers in fragrance and flavor, surface coatings, and especially in custom intermediates highlight the thermal and oxidative stability as a deciding issue for multi-step processes.

    This little twist in the molecule lets process chemists push boundaries—higher temperatures, tougher reductive or oxidative conditions—without product drift. That often means lower cycle costs, less rework, and fewer disposal headaches from side-product formation. We learned early on that theory only goes so far; several pilot partners put our material through multi-week run campaigns before switching their business our way. Hearing that a subtle methyl isomer controls everything from catalyst poisoning to resin shelf life makes a synthesis manager sit up and take notice.

    Practical Handling: Looking Beyond the Datasheet

    From a handling perspective, the clear liquid form of 4-Methyl-1-Cyclohexene means pumping, dosing, and pipetting all proceed without drama. It doesn’t gum up valves or quietly corrode pumps like some allylic analogs do. Customers working on kilo and multi-ton scales have shared their appreciation for a product that doesn’t require aggressive nitrogen blanketing or constant maintenance of seals and couplers. We build our drum and tanker filling on these insights—every minor loss or product hang-up translates to real operational cost.

    The odor profile, while noticeable, doesn’t carry the overpowering punch of lower-ring alkenes. Plants handling flavor and fragrance intermediates appreciate this in their day-to-day. It doesn’t permeate plastic liners or leak through storage totes the way unsaturated hydrocarbons often do. Safety features in our supply chain—like tailored venting and anti-static packaging—have been shaped by user feed-back rather than just safety requirements. Our drivers and warehouse teams know every aspect of its storage profile based on years of practical shipments, not just a regulatory line item.

    Usage in Synthesis and Industrial Applications

    We’ve supplied 4-Methyl-1-Cyclohexene into applications as wide as pharmaceutical building blocks, UV-curable resins, flavor and fragrance intermediates, and even specialty rubbers. The most consistent value comes in transformations where regioselectivity and stability matter. For example, in Diels-Alder cycloadditions, this compound delivers predictable endo/exo ratios and less side-product versus isomer blends. Alkylation steps downstream of hydrogenation processes benefit from the methyl group’s electronic effects, creating fewer unwanted branched or ring-contracted products than cyclohexene or lower-methyl isomers.

    Some customers have described their investigations switching from generic cyclohexene to 4-Methyl-1-Cyclohexene purely because raw material price fluctuations or supply interruptions forced their hand. They report better batch-to-batch yields and more robust product profiles, especially in the manufacture of custom intermediates for agrochemicals. Each spike or supply hiccup across the industry tests the resilience of a supply chain. Our records show that customers who work closely with us, communicating their downstream demands, achieve not only cost stability but process improvements. They avoid revalidating product lines and keep their operations humming through rocky markets.

    Another interesting use grows from the structure’s capacity as a stable monomer in ring-opening metathesis polymerization (ROMP). It doesn’t decompose or interfere with catalytic cycles the way some open-chain analogs do. This attribute lets polymer chemists craft specialty elastomers or functionalized resin beads that hold up under stress and exposure. The methyl group keeps the polymer backbone less prone to cleavage, granting a key durability advantage. Plant engineers highlighted to us how stopping mid-campaign due to feedstock instability can derail production timelines. With a reliable, repeatable supply of our 4-Methyl-1-Cyclohexene, those stress points go down.

    Comparing Against the Field: What Sets It Apart

    The most common question a new partner asks is how this product stacks up against other cyclohexene isomers or related ring-based alkenes. Regular cyclohexene offers cost advantages when selectivity isn’t critical. But in nearly every case that matters to our customers, 4-Methyl-1-Cyclohexene brings added performance. Whether it’s oxidative robustness for resin manufacturers or sharper reactivity in pharmaceutical coupling chemistries, the methyl group at the 4-position isn’t just a nominal difference. It controls everything from isomer ratios in synthesis to the way the molecule presents to a catalyst surface.

    Compared to 3-methyl or 1,4-dimethyl cyclohexenes, which are also available commercially, we see less byproduct formation and reduced process fouling. Our reactors and those of our contract manufacturers spend less time under maintenance and more time in productive synthesis. For users in fragrance intermediates, targeting a repeatable, clean aroma profile turns into real value when your starting material holds up through aggressive process conditions. The methyl isomer also avoids regulatory headaches found with styrene and open-chain analogs; its vapor pressure and air emissions profile fit more easily into environmental permitting.

    We’ve been approached by coating formulators frustrated by the sensitivity of their base materials to UV and oxidation. Many turn to value-tier aliphatic alkenes and run into shelf-life problems or customer complaints about off-odors. Trials with 4-Methyl-1-Cyclohexene consistently provide the durability and neutral scent they want. Some may weigh raw material costs and be tempted by cheaper ring systems, but the downstream cost savings—in longer product life, fewer customer returns, and less compliance paperwork—tip the balance for many users.

    Production Challenges and Our Solutions

    Reliably producing high-purity unsaturated hydrocarbons often turns out harder than it looks from the outside. Air and moisture control, safe storage, and transportation risks require in-plant protocols refined over experience—sometimes the hard way. In our earliest years, we learned that even minor lapses in atmospheric exclusion show up as oxidative byproducts, detectable by smell or more critically, an HPLC trace. For that reason, we built our plant with customized venting and inline nitrogen blanketing. Our workers carry out regular drum inspections to prevent leaks and maintain product integrity.

    Peroxide control stands as another challenge, especially for customers running downstream free-radical chemistry. We incorporate continuous monitoring and removal steps well beyond general guidance, not just for compliance but out of respect for operator safety and end-product consistency. A strong partnership with our raw material suppliers allows us to audit their process conditions regularly. Over time, this reduces batch-to-batch variability and narrows the window for contamination.

    On the logistics side, education remains critical. Warehouse operators and shipping teams get on-site training not just on paperwork but the feel, odor, and sheen of properly handled 4-Methyl-1-Cyclohexene. If a drum comes in off-spec or something feels wrong, action happens quickly. This culture of accountability grew from years of customer feedback and learning from hands-on experience. Newer team members benefit from that hard-earned legacy month after month.

    Industry Trends Shaping Demand

    Markets for 4-Methyl-1-Cyclohexene continue to evolve. Regions moving toward higher-value specialty chemicals, like East Asia and South America, now source directly from our facility. These customers tend to bring us narrower specs, less tolerance for byproduct, and more detailed supply-chain documentation. As coatings, flavors, and pharmaceutical industries raise their internal standards, we’ve established dedicated technical support teams to close the communication loop. It isn’t just about ticking a box on a certification—it’s about walking customers through process improvement and sharing best practices learned on the ground.

    Sustainability also factors into new demand. Traditional cyclohexene processes rely on feedstocks with higher energy footprints, while the synthetic pathway for our 4-Methyl-1-Cyclohexene makes use of plant-based precursors whenever possible. We source raw materials from partners who provide us with life-cycle data, reducing environmental impact at every stage. Certifications on renewable content, solvent recovery, and emissions compliance back up every shipment. The investment in analytics, waste minimization, and process integration goes beyond market image—customers want assurance that product reliability and supply won’t give way under pressure from regulators or activists.

    We also see technical communities and research labs using our compound as a benchmarking material, especially in catalysis and polymer science. Academic labs rely on consistent, well-documented chemical stocks to publish reproducible research. We publish lot-to-lot analytical data and collaborate with university partners when contaminants or unexpected behavior crops up. This open-industry interface supports not just our direct users, but wider industry standards.

    Working Hand-in-Hand with Customers

    No manufacturer of specialty chemicals thrives behind closed doors. Our largest leaps forward in quality and consistency have come through direct feedback from end-users. Whether in-person at a safety audit or through after-action reports sent weeks after delivery, we listen and iterate. For years, we fielded questions on long-term storage, blending compatibility, safe handling practices, and the best ways to minimize peroxide formation at user sites. Out of this dialogue grew new product containers, updated anti-static liners, and a support hotline staffed by chemists with hands-on plant experience.

    Our technical teams routinely support on-site audits, troubleshooting unexpected reactivity, or helping interpret analytical data from a customer’s own labs. More and more buyers want assurance that batches match or exceed previous lots—not only on nominal purity but on trace contaminants, residual solvents, and long-term stability. Transparency and proactivity keep us ahead of shifting customer needs. We regularly run controlled aging studies and share those data with partners, especially those developing new applications or scaling bench chemistry to production scale. This process takes time, but in our experience, it pays off in fewer surprises and longer, more productive relationships on both sides.

    Looking Toward the Future of 4-Methyl-1-Cyclohexene

    The world never holds still. With each regulation added, market trend shifted, or customer spec rewritten, demand for reliable, high-purity, and robustly documented 4-Methyl-1-Cyclohexene grows. Manufacturers who address these demands with practical experience, not only data sheets, stay relevant. Our continued investment in process controls, logistics, and direct user support keeps us at the front of the market, not just chasing the latest price point—or worse, quality shortcuts.

    We are always looking for new partners ready to share their biggest synthesis headaches, so we can dig in and solve them together. Whether producing fragrance intermediates, developing new adhesive polymers, or engineering next-generation agchem actives, 4-Methyl-1-Cyclohexene remains a trusted and flexible tool for the world’s chemists. This perspective, shaped by decades at the bench and on the plant floor, guides every batch shipped out of our facility.

    Experience shows that a small structural change in a molecule can mean the difference between success and failure in a manufacturing campaign. Having seen, again and again, the practical impact of product reliability and careful process management, we remain focused on the kind of quality and partnership that makes a real difference for industry, research, and innovation alike.