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3-Chloropropene

    • Product Name 3-Chloropropene
    • Alias Allyl chloride
    • Einecs 203-457-6
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    630018

    Iupac Name 3-Chloroprop-1-ene
    Common Names Allyl chloride
    Cas Number 107-05-1
    Molecular Formula C3H5Cl
    Molecular Weight 76.53 g/mol
    Appearance Colorless to pale yellow liquid
    Odor Pungent, garlic-like
    Boiling Point 45.0 °C
    Melting Point -134 °C
    Density 0.939 g/cm³ (at 20 °C)
    Solubility In Water 0.36 g/100 mL (at 20 °C)
    Flammability Highly flammable
    Vapor Pressure 439 mmHg (at 25 °C)

    As an accredited 3-Chloropropene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A 1-liter amber glass bottle with a secure screw cap, labeled “3-Chloropropene,” hazard symbols, batch number, and handling instructions.
    Shipping 3-Chloropropene is shipped in tightly sealed containers, typically under nitrogen or another inert gas, to prevent leakage and degradation. It is transported as a hazardous material due to its flammability and toxicity, following strict DOT and international regulations. Proper labeling, documentation, and emergency response measures are mandatory during shipping.
    Storage 3-Chloropropene should be stored in a cool, dry, well-ventilated area away from heat sources, open flames, and direct sunlight. Containers must be tightly closed and made from compatible materials, such as stainless steel. Store separately from oxidizers, acids, and bases. Ensure proper labeling and keep away from ignition sources, as it is flammable and volatile. Use appropriate secondary containment.
    Application of 3-Chloropropene

    Applications of 3-Chloropropene in Industrial Manufacturing

    3-Chloropropene, also known as allyl chloride, is a key intermediate used across several industrial production chains. The following sections provide detailed application insights for major downstream industries, each reflecting real manufacturing practice, relevant compliance frameworks, and specific process integration points.

    1. Epichlorohydrin Synthesis for Epoxy Resin Raw Materials

    Large-scale producers use 3-chloropropene as a primary feedstock in the manufacture of epichlorohydrin through reaction with hypochlorous acid, followed by dehydrochlorination. The resulting epichlorohydrin serves as a vital monomer in epoxy and glycidyl resin production. Control of raw material purity and reaction parameters is critical to ensure downstream resin quality and minimize halide residuals. Manufacturers must also address regulatory caps on chlorinated impurities to meet customer and legislative thresholds, especially for applications involving food contact or electronics encapsulation.

    Industry compliance standards

    • OECD Test Guidelines for Industrial Chemicals
    • EU REACH Regulation (EC) No 1907/2006
    • U.S. EPA Toxic Substances Control Act (TSCA)
    • EN 13963 for products in contact applications

    Typical usage ratio

    • 0.95 to 1.05 mol 3-chloropropene per mol hypochlorous acid; fine-tuned based on conversion efficiency and impurity profile

    Downstream process integration

    • Charged into epoxidation reactors as the initial organic halide substrate
    • Reaction stage controls emphasize tandem dehydrochlorination and temperature regulation
    • Continuous distillation downstream to purify epichlorohydrin
    • Final crude product undergoes vacuum stripping before resin synthesis transfer

    Final product types

    • Epoxy resins for adhesives, coatings, and composites
    • Glycidyl ether and ester intermediates
    • Electrical insulation casting compounds
    • Can coatings and protective linings

    2. Allyl Alcohol Production for Polymer and Ester Derivatives

    Industrial manufacturers utilize 3-chloropropene for hydrolysis to allyl alcohol, enabling further conversion to diverse esters and plasticizers. The hydrolysis runs under controlled basic aqueous conditions with high selectivity for secondary alcohol formation. Stringent monitoring of by-products like dichloropropane is required to meet technical grade standards for downstream polymerization or esterification. Trace contaminants are minimized to allow polymer producers to achieve consistent molecular weight and performance parameters in end use.

    Industry compliance standards

    • ISO 9001:2015 for chemical process control
    • EU Directive 2002/72/EC for food contact plastic monomers (if further processed)
    • Japanese Chemical Substances Control Law (CSCL)
    • DIN EN 15343 for traceability in polymer feedstocks

    Typical usage ratio

    • 1.0–1.2 mol 3-chloropropene per mol sodium hydroxide; adjusted for reaction efficiency and downstream hydrolysis yield

    Downstream process integration

    • Feeds directly into a continuous hydrolysis column
    • Allyl alcohol separated through azeotropic distillation and phase decantation
    • Post-purification includes activated carbon filtration for color reduction
    • Transferred for on-site esterification or for bulk shipment to polymerization plants

    Final product types

    • Plasticizers for polymer resins
    • Allyl esters (e.g., diallyl phthalate) for heat-resistant plastics
    • Crosslinkers for specialty acrylics and elastomers
    • Intermediate alcohols for fragrances and flavors (industrial grade only)

    3. Synthesis of Allyl Amines for Agrochemical Active Ingredients

    Major crop protection producers rely on 3-chloropropene for amination processes, generating allyl amines that serve as critical structures within certain herbicide and fungicide active ingredients. The batch process typically uses aqueous ammonia or primary amines under pressurized conditions. Input quality impacts not only regioselectivity but also the impurity profile, which directly relates to regulatory approvals in agricultural chemicals. Downstream manufacturers submit finished active inputs to stringent pesticide and environmental standards to ensure public safety.

    Industry compliance standards

    • FAO/WHO CIPAC reference methods for technical material purity
    • EU Regulation (EC) No 1107/2009 for plant protection products
    • U.S. EPA FIFRA pesticide registration guidelines
    • China GB 2763 for maximum residue limits

    Typical usage ratio

    • 1.0–1.5 mol 3-chloropropene per mol ammonia or amine; varies by target amine and side reaction control

    Downstream process integration

    • Dosed into pressurized reactors with ammonia with continuous phase separation
    • Product stream passes through solvent extraction and acid/base washes
    • Final distillation to isolate purified allyl amines
    • Direct hand-off to synthesis trains for herbicide AI production

    Final product types

    • Active ingredients for broadleaf herbicides
    • Systemic fungicide building blocks
    • Precursor intermediates for growth regulator formulation
    • Seed treatment actives

    4. Manufacture of Quaternary Ammonium Compounds for Industrial Water Treatment

    Water treatment formulators synthesize quaternary ammonium derivatives using 3-chloropropene as a reactive alkylating agent. The quaternization reaction occurs with various tertiary amines, generating functional surfactant molecules for anti-microbial, anti-scaling, and dispersant applications. Process engineers tightly monitor addition rates and reaction temperature to control molecular weight distribution and active content. All outputs require compliance with wastewater discharge quality and market-specific chemical registration before application in recirculating cooling or boiler water systems.

    Industry compliance standards

    • ANSI/AWWA B453 for water treatment chemicals
    • U.S. EPA National Pollutant Discharge Elimination System (NPDES)
    • EU Biocidal Products Regulation (BPR) 528/2012
    • ISO 14001:2015 for environmental management in manufacturing

    Typical usage ratio

    • 0.8–1.3 mol 3-chloropropene per mol tertiary amine, depending on the desired alkyl chain substitution pattern

    Downstream process integration

    • Metered addition into quaternization reactors with controlled atmosphere
    • Phase split and neutralization to remove residual reagents
    • Final polishing with ion exchange or activated carbon to achieve purity targets
    • Packed for bulk transport in aqueous or solvent carrier matrices

    Final product types

    • Cationic flocculants for water clarification
    • Antiscalant components for power plant cooling
    • Microbial control additives for industrial process water
    • Antistatic solutions for electronics rinsing water

    5. Production of Allyl Sulfonate Intermediates for Textile Auxiliaries

    The textile chemicals sector utilizes 3-chloropropene for sulfonation to yield allyl sulfonates, used as reactive functional intermediates in dye dispersants, wetting agents, and emulsion stabilizers. Controlled addition of sodium sulfite to the feed stream, alongside process refinements to minimize over-sulfonation and halide retention, shapes the physical-chemical profile of the resulting auxiliaries. Quality assurance focuses on molecular uniformity and absence of unreacted halides or sulfoxides, aligning with strict textile eco-labeling and effluent guidelines.

    Industry compliance standards

    • OEKO-TEX® Eco Passport for textile chemicals
    • ZDHC MRSL (Manufacturing Restricted Substances List)
    • ISO 14001:2015 certified production practices
    • REACH Annex XVII for restricted organohalide content

    Typical usage ratio

    • 1.0–1.3 mol 3-chloropropene per mol sodium sulfite; adjusted according to degrees of functionalization required in end-use auxiliaries

    Downstream process integration

    • 3-chloropropene charged into sulfonation reactors with buffered sulfite solutions and temperature control
    • Phase separation to recover organic sulfonate layer
    • Neutralization and vacuum stripping to liquid or solid product form
    • Batch testing of active content before formulation into textile auxiliary blends

    Final product types

    • Dye dispersant chemicals
    • Emulsifiers for dyeing and printing
    • Fiber processing lubricants
    • Antisoiling agents for textile finishing

    6. Manufacture of Allyl Ether Compounds in Silicone and Polyacrylate Industry

    Producers in the silicone and polyacrylate sectors introduce 3-chloropropene for etherification with polyols or phenols, yielding allyl ethers with tailored reactivity and hydrophobicity. Selection of catalyst systems and precise temperature/time profiles influence substitution patterns and volatility profiles. Downstream QC ensures that trace halides and by-products remain below cut-offs for use in high-clarity, weather-resistant sealants and adhesives. Prepared intermediates integrate into polymer backbones with real-time tracking of migration and residuals for end market compliance.

    Industry compliance standards

    • ASTM D6287 for silicone crosslinkers
    • EN 14022 for adhesives and sealants safety
    • ISO 10993 for medical adhesive compatibility (if targeted at medical devices)
    • EU REACH Regulation—substance evaluation process

    Typical usage ratio

    • 1.0–1.15 mol 3-chloropropene per functional group on polyol/phenol, according to target functionality index in final polymer system

    Downstream process integration

    • Continuous etherification with catalyst beds for precision in oligomer formation
    • Excess reagent recovery through stripping columns and solvent recycling
    • Analytical GC/HPLC control to limit unreacted halides
    • On-site transfer to compounding or bulk polymerization

    Final product types

    • Silicone-based sealants for glazing, construction, and auto industries
    • High-performance polyacrylate adhesives
    • Flexible polymer films and sheets
    • Electronic encapsulation materials
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    Certification & Compliance
    More Introduction

    Unlocking Value and Application from 3-Chloropropene: A Manufacturer’s Perspective

    What Sets 3-Chloropropene Apart in Chemical Manufacturing

    Over the span of decades working at the forefront of chemical synthesis, a handful of chlorinated hydrocarbons have shaped downstream manufacturing in ways that ripple through entire industries. Among these, 3-Chloropropene, often called allyl chloride, continues to draw steady demand from partners in polymer, pharmaceutical, and agrochemical fields. From my own production floor, I have seen its unique reactivity frequently open doors that other chemicals simply won’t budge.

    The structure of 3-Chloropropene—a three-carbon chain with a chlorine atom on one side and a reactive double bond between carbons one and two—might look simple on paper. Experience tells a different story. That double bond turns it into a workhorse for further modifications. It’s not just about “functional groups” as seen in textbooks. The way this molecule behaves in reactors gives chemists a rare balance between stability during storage and energetic reactivity at the right moment. This dual quality matters when daily production relies on repeatable, reliable performance.

    Understanding Our Standards and Models

    We manufacture 3-Chloropropene to a strict technical standard honed by direct feedback from the folks actually running polymerization and alkylation processes. Throughout the years, we’ve focused on keeping residual moisture, high-boiling impurities, and unsaturated byproducts well below typical tolerance levels. That’s not just for show. Even low concentrations of these contaminants can foul up catalysts or trigger off-spec side reactions, adding cost at every subsequent step. We test for purity above 99.5% by gas chromatography and regularly monitor for color, acidity, and density to avoid drift across batches.

    Depending on the site and customer, some request a higher-purity model for pharmaceutical precursors, chasing a narrower impurity profile. In those batches, we dedicate extra distillation time and conduct a more detailed review of chlorinated side products. Questions often crop up about why this matters. From our side, it isn’t about overengineering—it’s survival in a supply chain where quality slips show up fast at small scale and compound with every subsequent batch.

    Everyday Applications: Where the Real Value Is Found

    Hands-on work in the plant shows that 3-Chloropropene’s main job across our partners involves two tasks: acting as a starting block in the manufacture of epichlorohydrin, and serving as an alkylating agent to introduce allyl groups into bigger molecules. The move from 3-Chloropropene to epichlorohydrin uses an extra step, but the purity and reliable reactivity at this phase end up protecting yields all the way up the processing chain. Bottlenecks drop, energy costs go down, and plant utilization improves—less time spent chasing off-spec material, fewer wasted man-hours flushing lines.

    On the plastics end, cured resins built from 3-Chloropropene-derived epoxies serve everything from printed circuit boards to coatings on industrial tanks. It might sound far removed from upstream chemistry, but I can’t count the times I’ve fielded feedback about corrosion resistance on offshore equipment traced directly to a chemical tweak in our facility. Out on the production floor, the crew can adjust profiles to give resin makers exactly what they need to prevent delamination, warping, or yellowing years down the line.

    Comparisons to Other Chemical Feedstocks

    Having spent years lining up supply for both 3-Chloropropene and competing alkyl chlorides, I’ve watched how certain projects favor one input or another. Direct substitutes for 3-Chloropropene include 1-chloropropane and 2-chloropropane, each lacking the allylic double bond. The moment you remove that double bond, reactivity changes entirely. Only 3-Chloropropene offers an easy entry point for nucleophilic substitutions leading to a wide family of derivatives. The difference plays out in reactor uptime and the range of downstream modifications available.

    Another common point of comparison is allyl alcohol. Chemists sometimes weigh whether to start from the alcohol or the chloride. Each path has its own logic, shaped by cost pressures, emissions, and process constraints. From a manufacturing view, our experience shows that the chloride route often wins for plant operators chasing higher yields in chlorinated intermediates or requiring a more shelf-stable intermediate. The boiling point and storage behavior of 3-Chloropropene create fewer headaches for logistics teams than more oxygenated intermediates—especially important for partners working in harsher climates or less controlled storage conditions.

    Safety, Handling, and Reliability From a Plant Perspective

    Decades of handling 3-Chloropropene have highlighted that it isn’t just the label “flammable and toxic” that matters—it’s having an ingrained safety culture reinforced by hands-on routines. We store this product under an inert atmosphere to cut fire risk. Every operator on my floor wears personal gas detection, and we never shortcut ventilation. Leak checks run as part of each batch transfer, not as a quarterly afterthought. Open communication lines between production, maintenance, and environmental teams keep minor incidents from turning into major disruptions.

    Having our own tank farm and dedicated filling infrastructure shortens exposure time during loading and unloading, which minimizes risk. We learned long ago not to rely wholly on specification sheets. When a valve sticks or a coupler fails during the winter run, the margin of error vanishes. The plant’s investment in real-time monitoring and emergency drills earned trust from both operators and downstream users who know the pedigree of every shipment.

    Traceability, Documentation, and Building Trust

    Our responsibility doesn’t end at the tank valve. Regulatory audits taught us that documenting every step, from raw material input through finished product dispatch, equals insurance for our customers. It’s more than ticking a compliance box. Our documentation process tracks precise batch data, operational conditions (pressure, temperature), and even storage durations to quickly trace anomalies if they develop at a partner’s plant. When a customer calls with a yield drop or process hiccup, a quick lookup through the system can isolate root causes tied back to our own batches or confirm if issues arose during shipping or storage elsewhere.

    Many downstream users share those records up their own chains, especially those exporting finished goods into Europe or North America. The network of trust built by transparency remains more valuable than any generic certificate. The fact that we stand behind every drum and tote, with immediate traceable documentation, reduces downtime for our clients and preserves relationships over the long haul.

    Caring for the Environment While Serving Progress

    Our history with 3-Chloropropene traces back well before the surge in environmental awareness. Plant teams saw first-hand how even minor emissions or spills drew scrutiny—or worse, caused health scares in neighboring areas. Early on, we invested in vapor recovery and closed-loop systems for transfer lines. Not due to outside pressure, but because runoff or vented vapors directly threatened the safety and future of the plant community.

    More recently, process improvements reduced fugitive emissions through better distillation sealing and recovery. Waste quenching and destruction proceed under tightly controlled conditions, and regular monitoring ensures that air and water discharges meet or beat local regulatory benchmarks. From hands-on experience, these continuous adjustments create operational savings and unlock new business with partners subject to tighter environmental scrutiny. In the age of environmental certifications and “green” procurement teams, our continued progress keeps us in the game with major buyers requiring data-backed environmental practices.

    Innovation and the Road Ahead

    The real-world utility of 3-Chloropropene isn’t just a story of bulk shipments and on-spec product. Research teams at our site, working hand-in-hand with field engineers and customers’ own R&D groups, keep digging for new uses. High-performance polymers, novel pharmaceutical intermediates, and cleaner catalyst technologies all stem directly from iterative feedback loops and deliberate experimentation. We launch small batches with specialty modifications when a new downstream project justifies fine-tuning the impurity profile or enhancing storage stability. The result often unlocks new markets and partnerships pushing into adjacent industries.

    Practical tweaks in production, like advancing sensor automation or optimizing heat integration, aim to keep our manufacturing footprint efficient. These upgrades, hard-won through trial and error, lower both energy use and off-grade material rates. They aren’t just visible in spreadsheets, but in the predictable flow of material that our best customers come to expect. That stability unlocks efficiency up and down the chain, squeezing out costly shut-downs and last-minute reorders.

    Supply Chain Security and Global Market Dynamics

    No manufacturer operates in isolation, and 3-Chloropropene supply provides a good example. It’s not simply a matter of producing on schedule; it’s about anticipating supply shocks and aligning with customer production cycles. When storms, regulatory swings, or energy market shifts tighten feedstock availability, close customer relationships let us prioritize critical orders without the need for round-the-clock crisis meetings. Real experience through past market disruptions taught us which partners truly depend on consistent supply—and which are willing to chase the cheapest price regardless of risk.

    Our close ties with transporters and storage depots streamline delivery, but more importantly, our teams have backup plans in place. Whenever geopolitical risks or local regulation threaten to disrupt logistics, our operations staff can reroute or reschedule deliveries in hours—not days. This flexibility doesn’t show up in glossy sales decks. It’s felt by the plant crews and supply managers on the other end, who know that a delayed shipment can mean hundreds of thousands lost in just one day’s missed production.

    Ongoing Challenges—And Solutions That Come from Experience

    The chemistry looks straightforward in textbooks, but in real production, keeping 3-Chloropropene quality high and costs manageable remains a continual struggle. Feedstock prices shift, energy markets fluctuate, regulations tighten, and transportation bottlenecks appear where least expected.

    Our company works around these hurdles by deepening collaboration both upstream and downstream. Early dialogue with suppliers allows secure feedstock bookings, often locking in price and volume for entire quarters, reducing spot market exposure. Downstream, our technical staff provides direct support—sometimes even on-site assistance—to help partner plants adapt quickly if upstream tweaks affect their own yields or processing limits.

    One persistent challenge is the need for low-waste, cost-effective recycling of byproducts. Over the years, we’ve shifted from simple incineration to chemical recovery, extracting value from what earlier generations saw as nothing but hazardous waste. These efforts fuel secondary revenue streams and reduce our total environmental load, which in turn provides a buffer against future regulatory changes.

    Supporting Advanced Markets and Regulatory Demands

    Our experience carrying 3-Chloropropene to markets across multiple continents brings close contact with regulatory complexity. International production sites and customers working under the EU’s REACH framework or America’s TSCA requirements expect precise supporting data. The paperwork may seem daunting, but direct knowledge of our process and history—no third-party handoffs—lets us provide documentation with both speed and completeness. We regularly host audits and walk-throughs for customers’ own compliance teams, opening our methods to scrutiny to build credibility piece by piece.

    Transparency in operational data, both historical and current, gives our partners confidence when cross-border standards shift. Improved harmonization of our quality and environmental practices, driven by internal commitment as much as outside pressure, has kept our material welcome into higher-value markets where paperwork alone won’t suffice.

    Why the Manufacturer’s Role Matters Most

    From where we stand inside the fence line, the story of 3-Chloropropene isn’t just about bulk chemical supply. Direct manufacturing brings a level of control and accountability that third-party traders and brokers can’t always match. We see every step, from raw material sourcing to on-site blending, storage, and final packaging. The result: predictable quality, full traceability, and the ability to modify processes on short notice to meet unique customer requests.

    This hands-on, responsive approach creates flexibility for our partners. Whether a customer’s specification changes mid-year or a new regulatory concern prompts tighter testing, we can move resources and adjust operations to deliver. Relationships forged through years of shared problem-solving define the trajectory of our products as much as any molecular structure. The chemical itself serves as an engine for broader technological progress—one we help build and refine with each new batch.

    Building Confidence Into Every Shipment

    No marketing claim can substitute for the peace of mind that comes from receiving the material you expect, on schedule, with proven repeatability. Our focus on 3-Chloropropene arises from experience: in industries where downtime costs multiply fast, or where margin for error shrinks amid compliance demands, our role as the direct manufacturer stands out. At the end of the day, the quiet consistency of our deliveries, reinforced by rigorous internal discipline and open dialogue with customers, props up complex global value chains.

    Each drum and shipment of 3-Chloropropene that leaves our plant carries not just a chemical, but a track record of reliability, safety, and continuous refinement. We take pride in walking the floor, monitoring output, and solving challenges in real time—because the actual measure of quality lives in the lived experiences of every user along the chain, from research bench to finished product.

    Connecting Chemistry with Daily Operations

    As the industry continues to evolve, our manufacturing processes for 3-Chloropropene remain rooted in both precision and flexibility. The knowledge gained from every batch, every line stoppage, and every customer’s troubleshooting request shapes how we adapt to new challenges. These ongoing improvements allow us to deliver not just high-purity material, but also partnership and problem-solving at scale.

    We continue to invest in upgrades, develop products side-by-side with our customers, and reinforce the safety and integrity of our operations. Our responsibility expands beyond basic supply—it reaches into the steady, sometimes unglamorous, day-to-day work of keeping complex industries running cleanly and efficiently. That’s how we see our place in the world of 3-Chloropropene: not just as makers of a chemical, but as partners enabling progress on the panels, fibers, and coatings that shape modern life.