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2-Methyl-1-Butene

    • Product Name 2-Methyl-1-Butene
    • Alias isohexene
    • Einecs 204-661-8
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    937029

    ChemicalName 2-Methyl-1-Butene
    CASNumber 563-46-2
    MolecularFormula C5H10
    MolarMass 70.13 g/mol
    Appearance Colorless liquid
    BoilingPoint 36 °C
    MeltingPoint -139 °C
    Density 0.653 g/cm³ (at 20 °C)
    RefractiveIndex 1.39 (at 20 °C)
    FlashPoint -27 °C
    VaporPressure 340 mmHg (at 20 °C)
    SolubilityInWater Insoluble
    Odor Petroleum-like
    Structure CH2=CHCH2CH(CH3)2
    PubChemCID 11221

    As an accredited 2-Methyl-1-Butene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The 2-Methyl-1-Butene is packaged in a 500 mL amber glass bottle with a tight-sealing cap, labeled with hazard information.
    Shipping 2-Methyl-1-Butene is shipped as a flammable liquid, typically in tightly sealed, UN-approved steel drums or cylinders. It must be stored and transported away from heat, sparks, and open flames, with proper labeling according to hazardous materials regulations. Adequate ventilation and grounding are required to prevent the buildup of flammable vapors.
    Storage 2-Methyl-1-butene should be stored in a cool, dry, and well-ventilated area, away from heat sources, open flames, and oxidizing agents. It must be kept in tightly sealed containers made of materials compatible with alkenes. Protect from direct sunlight and static electricity. Storage areas should be equipped with proper fire suppression systems due to its flammability and potential for vapor accumulation.
    Application of 2-Methyl-1-Butene

    Applications of 2-Methyl-1-Butene in Industrial Manufacturing

    As a direct manufacturer of 2-Methyl-1-Butene, we support multiple advanced industrial sectors with consistent supply and tailored technical support. The following sections detail the primary downstream segments where this material forms a critical intermediate or functional additive, including technical, regulatory, and operational details for each field.

    1. Synthesis of Perfume Intermediates in Specialty Chemicals

    2-Methyl-1-Butene serves as a key alkylating agent in the manufacture of aroma chemicals, especially for the preparation of ionones and related intermediates. Manufacturers use it to introduce specific branched chain structures into base aromatic molecules, adjusting scent characteristics and performance in final products. The reactions require controlled addition processes and tight moisture monitoring to prevent undesired side reactions affecting scent purity, with output bound by IFRA and national fragrance regulations.

    Industry compliance standards

    • IFRA Standards for fragrance compound safety
    • EU REACH Regulation (EC) No 1907/2006
    • ISO 9235 (Aromatic Natural Raw Materials)
    • Cosmetic Ingredient Review (CIR) recommendations

    Typical usage ratio

    • Mix rates: 0.5–5% w/w of total aromatic intermediate batch. Final concentration depends on target alkylation degree and reactivity of aromatic core compound.

    Downstream process integration

    • Incorporate during ionone or damascone backbone synthesis in a closed reactor system after dehydration of aromatics.
    • Used as a reactant in Friedel–Crafts alkylation for modifying methyl ketone skeletons.
    • Requires dry solvent and Lewis acid catalyst environment.
    • Followed by vacuum distillation and fine fractionation.

    Final product types

    • Synthetic ionones (alpha-ionone, beta-ionone)
    • Methyl ionone derivatives in perfumes
    • Bases for fine fragrances and consumer goods
    • Aroma chemicals for flavor and fragrance houses

    2. Production of Polyolefin Comonomers

    Major polyolefin manufacturers employ 2-Methyl-1-Butene as a functional comonomer for the copolymerization of ethylene and propylene in next-generation LLDPE, VLDPE, and specialized elastomeric materials. Its branched structure introduces desired flexibility and impact strength to films, injection-molded components, and high-clarity packaging. Operators add the raw material in the monomer feed zone under controlled temperatures, meeting strict purity specifications to avoid poisoning catalyst beds in Ziegler-Natta or metallocene polymerization units.

    Industry compliance standards

    • FDA 21 CFR 177.1520 (polyolefin plastics for food contact)
    • EU Regulation (EU) No 10/2011 on plastic materials and articles
    • ASTM D3350 (polyethylene specification)
    • ISO 1872-1 & ISO 1133 (polymers and melt flow standards)

    Typical usage ratio

    • Comonomer: 0.3–2.5 mol% of total monomer charge, depending on desired density and clarity of final polyolefin resin.

    Downstream process integration

    • Feed directly into gas-phase or slurry-phase polymerization reactors with continuous dosing systems.
    • Monitored for hydrocarbon purity to protect existing catalyst selectivity and avoid gel formation.
    • Polymerization proceeds under inert atmosphere and controlled pressure.
    • Copolymer later pelletized, extruded, or compounded.

    Final product types

    • Puncture-resistant LLDPE film grades
    • Low modulus VLDPE resins for food packaging
    • Elastic ethylene-alpha-olefin copolymers
    • Polyolefin elastomer blends for automotive and cable insulation

    3. Synthesis of Lubricant Additives and Viscosity Modifiers

    Chemical formulators rely on 2-Methyl-1-Butene as a reactive intermediate in the controlled oligomerization process to produce polyalphaolefin (PAO) base oils and viscosity index improvers. Its high purity permits efficient cationic or Ziegler-Natta catalysis, yielding base stocks with well-defined molecular weights critical for formulating synthetic lubricants designed for modern automotive and industrial applications. Precise control over oligomer chain length and branching provides target performance properties in finished lubricant packages.

    Industry compliance standards

    • API Group IV/Group V base oil classification
    • ACEA and ILSAC engine oil standards
    • ASTM D445 (kinematic viscosity)
    • OEM lubricant approval schemes (e.g., Mercedes-Benz MB Approval 229.5)

    Typical usage ratio

    • Feeds: 5–25% in oligomerization charge, depending on desired PAO molecular weight and viscosity grade.

    Downstream process integration

    • Enters batch oligomerization with precise co-monomer ratios in reactor vessels (AlCl3 catalysis or metallocene route).
    • Downstream vacuum stripping removes unreacted monomers.
    • Distillation separates PAO fractions by viscosity index.
    • Final blending with functional additives occurs under nitrogen.

    Final product types

    • PAO base fluids (Group IV synthetic lubricants)
    • High VI engine oil packages
    • Hydraulic and gear fluid formulations
    • Performance-enhanced industrial greases

    4. Manufacture of Pharmaceutical Synthesis Intermediates

    2-Methyl-1-Butene contributes as an alkylating building block in the production of specific active pharmaceutical ingredients (APIs) and their intermediates. It provides a methyl-branched structure required for synthesizing certain beta-lactam antibiotics and selective beta-adrenergic agonists. High control during the alkylation or addition steps in GMP-controlled suites assures batch-to-batch consistency and absence of undesired isomers. Each synthetic route is selected and validated based on regulatory filings and impurity profiles.

    Industry compliance standards

    • ICH Q7 Good Manufacturing Practice for APIs
    • USP & EP monographs (relevant to specific intermediates)
    • cGMP FDA 21 CFR Parts 210/211
    • EMEA guidelines for pharmaceutical raw materials

    Typical usage ratio

    • Used at 0.8–3 equivalents relative to key functional groups, adjusted based on intermediate purity and conversion rates.

    Downstream process integration

    • Added at alkylation or chain extension step in multi-stage synthesis.
    • Precise feed dosing is automated, with in-process analytics confirming conversion.
    • Pilot-plant to commercial scale, under validated cleaning and tracing procedures.
    • Residuals thoroughly purged before API isolation and crystallization.

    Final product types

    • API intermediates for beta-lactam antibiotics
    • Synthetic blocks for beta-adrenergic medications
    • Chiral intermediates for cardiovascular drugs
    • Fine chemicals pre-cursors under GMP

    5. Preparation of Tertiary Alcohols for Resins and Plasticizers

    2-Methyl-1-Butene reacts with water in the presence of acid catalysts to provide tertiary alcohols, which downstream resin and plasticizer manufacturers use for further esterification and polymer applications. This pathway produces high boiling, branched alcohols crucial for enhancing flexibility and processability in thermoplastic and thermoset resin systems. Process conditions optimize selectivity and desired chain-length distribution, with attention to minimizing cracking or color body formation.

    Industry compliance standards

    • ISO 9001:2015 Quality Management for chemical intermediates
    • REACH chemical safety documentation for plasticizer raw materials
    • ASTM D1612 for plasticizer evaluation
    • OSHA CFR 29 1910 for handling process chemicals

    Typical usage ratio

    • Applied at 1:1–1.5:1 molar ratio vs. water input; actual ratios adjusted based on alcohol chain length sought.

    Downstream process integration

    • Injected in aqueous acid-catalyzed hydration reactors at 80–120°C.
    • Unreacted feedstock captured for recycling after phase separation.
    • Alcohol output undergoes neutralization and distillation.
    • Flows directly to downstream esterification or resinification plants.

    Final product types

    • Tertiary amyl alcohols for alkyd and vinyl ester resins
    • High performance plasticizer esters
    • Solvent additives for coating and ink industries
    • Speciality monomers for impact-modified plastics
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    Certification & Compliance
    More Introduction

    2-Methyl-1-Butene: In the Eyes of the Producer

    An Introduction Shaped by Experience

    Most people driving down the highway never spare a moment for the molecules that shape their world. Here, though, in the heart of our plant, 2-Methyl-1-Butene stands as more than a chemical name stamped on a drum. We have watched the demand for olefins surge, more so for those with branch points, as specialty polymers, lubricants, and flavors stretch for specific performance or unique chemical footprints. Our story with this molecule spans decades, traced along the stainless steel pipes, measured in the hum of reactors, and checked in the curled ends of chromatograph printouts. Every batch tells us how small changes—tighter fractionation, a tweak in the distillation regime, a shift in feedstock—can alter outcomes that impact hundreds of downstream industries.

    Understanding the Material and Its Makeup

    2-Methyl-1-Butene—traditionally known by chemists for its five-carbon backbone and double bond—offers more than meets the technical eye. Our material, labeled here as Model 2MB-195, emerges from a process based on high-purity isobutylene and ethylene, refined through multiple distillation columns. We take pride in driving impurities down to levels well below one percent. We see every day how even a fraction of water or oxygenate feeds can complicate a polymerization feedstock or throw off an odorant blend. 2-Methyl-1-Butene, with a methyl branch at position two, brings a combination of volatility and chemical reactivity that linear pentenes can’t deliver.

    Colorless in appearance and light in scent, this molecule boils at roughly 31 degrees Celsius. Our typical manufacturing lot weights range from a few kilograms for labs to tens of metric tons for industrial synthesis. Storage and transport on our side require strict controls—steel cylinders, nitrogen padding, triple-checked seals. Leaks or off-spec batches translate directly into production delays for our partners. So, attention to equipment reliability and regular maintenance on compressors, chillers, and storage tanks proves as necessary as batch analysis.

    How We’ve Seen It Used: Stories from the Supply Floor

    Most customers reaching out for 2-Methyl-1-Butene develop advanced performance materials. We supply this product most often to manufacturers of specialty chemicals. They rely on its alkene functionality for alkylation. The molecule’s structure—different from unbranched 1-pentene—gives branch points in end polymers, which can change softening points and flexibility in the final product. Researchers in pharmaceutical synthesis often need a non-aromatic, branched pentene for catalytic reactions. Our crew has supported teams as they move from milligram-scale bench top studies to hundreds of kilograms for kilo labs.

    The beverage and flavor industry recognizes 2-Methyl-1-Butene as a precursor for some proprietary aroma compounds. We work with tight release schedules to ensure their product launches stay on track. Lubricant additive manufacturers choose this molecule for its reactivity and volatility profile during the synthesis of friction modifiers. In each case, the underlying requirements differ—some prize ultra-low sulfur, others want an ironclad carbon chain distribution.

    Some colleagues in the plastics industry prefer 2-Methyl-2-Butene, which shifts the double bond. Over the years, buyers have come to us with both requests; on our side, we see the trade-offs. 2-Methyl-1-Butene reacts more cleanly in Ziegler-Natta and metallocene-catalyzed reactions. In contrast, the 2-Butene isomer works for different alkylation patterns needed in fuels or plasticizers. By controlling the ratio and refining methods, we give our partners the choice, though not every plant invests in the specialized catalysts needed for each case.

    Manufacturing Challenges Only the Plant Can See

    From our perch inside production, every molecule of 2-Methyl-1-Butene embodies hours of hands-on oversight. We manage high-throughput distillation units, control trace impurities, and adjust feedstocks in response to market swings. Safety standards shape everything, from loading railcars to stepping into a refrigerated tank farm. We remember specific incidents—one year, a chilling line developed a micro-crack, and product purity dropped by parts per million, enough to stall a partner’s pilot production. Months were spent reworking the process, rewriting procedures, upgrading sensors to prevent a recurrence.

    These stories are rarely told outside plant walls. Customers ask about assay and water content, but we live with the reality that trace unsaturates and unseen metal ions can ruin a batch down the line. Process control boils down to troubleshooting—sometimes with nothing more than a slide rule, sometimes through days of gas chromatography. Our emphasis on real-time monitoring grew from lessons written in overtime logs rather than in product brochures. These investments pay back in reliability, a factor never spelled out in specifications but always felt by anyone running a continuous process.

    Product Comparison Drawn from the Shop Floor

    Discussions that only consultants indulge often focus on the interchangeability of C5 olefins. From experience, we know the details differ. Linear pentenes—like 1-pentene—bring entirely different reactivity to copolymer synthesis. The methyl group at the two position in our main product tweaks sterics and electron density enough to tip the balance in coordination catalysts. That difference can determine melt flow or impact resistance in a finished polyolefin.

    We run side-by-side production of both 2-Methyl-1-Butene and closely related isomers. These side-by-side runs drive home the need for precise plant scheduling and tank cleaning. Customers often ask for comparative data. What works for a flavor intermediate does not suit an elastomer feed. Plant engineers choose different gaskets, seating materials, and inerting protocols for each. Downstream, blenders see shifts in azeotrope formation and separation. These wrinkles come from long nights of maintenance logs and “off hours” troubleshooting, not just published tables.

    Regulatory and Safety Realities

    2-Methyl-1-Butene asks for care in every step, from bulk transfer to sealing vessels. Our HSE department spends time anticipating risks—flammable vapors, the potential for peroxides if exposed to air over long periods. We’ve invested in double-valve systems on all tanker connections and switch out storage hardware cyclically to reduce long-term wear. Collaborations with fire brigades evolved out of practical incidents, not paperwork alone.

    On the compliance side, we answer regularly to requests for purity data, export documentation, and batch tracebacks. Each request becomes a mini-audit. The market for high-purity alkenes draws attention from food safety authorities, REACH regulations, and local environmental groups. Both instrument uptime and documentation have earned as much attention in our workflow as drum loading or reactor design. We value transparency—customers facing audits or seeking compliance support get detailed answers, shaped by years of successful inspections and occasional late-night phone calls with inspectors.

    Working with Partners: A Producer’s View

    We have learned to engage with partners as more than a source of price quotes. The most effective collaboration grows from shared problem solving. A customer scaling up a new copolymer asks about trace chlorides; another formulator needs lower water content for pilot batches. Our response isn’t a templated answer. Whether by adjusting drying columns or shifting production schedules to avoid crossover contamination, we troubleshoot together.

    There’s always a tension—production schedules are tight, raw material supply shifts, end-user needs push us to adapt. One recent partner needed custom shipment packaging due to space limits in a pilot facility. We arranged specialized tank sizes and transport routes, proof of a willingness to go beyond the drum. These experiences underline why communication, not just a data sheet, matters for high-purity specialty chemicals.

    Innovation Runs Both Ways

    Research teams ask us about the scalability and long-term stability of 2-Methyl-1-Butene. Many try to cross the bridge from academic curiosity to industrial process, and we have chosen to offer both technical support and historical context. Copying a process from the literature rarely accounts for heat load in summer months, fouling in real-world condensers, or what downtime does to a pilot plant. Years spent in operation have taught our engineers which sealants last, which distillation trays stand up to repeated cleaning, and how to reprocess off-spec streams to cut waste.

    The flow between lab and plant works two ways. We have worked with researchers developing new analytical techniques—gas chromatography columns with better resolution, moisture analyzers sensitive enough to pick up seasonal shifts. When they succeed, the impact is tangible: higher yields, less downtime, fewer frustrated phone calls from end users juggling production targets.

    Reliability, Built from the Ground Up

    Over time, our view on what ‘quality’ means has evolved beyond numbers on a spec sheet. We have seen how small deviations in 2-Methyl-1-Butene purity echo down an entire value chain: lost hours in a blending hall, a spoiled run of elastomers, delays in pharmaceutical validation. These misses scar the production calendar in ways outsiders never notice. That is why plant staff walk every pipe run, listen to pump noises, and read the vibration charts that can warn of imminent trouble.

    Building in redundancy costs more up front, but we have learned from mistakes and breakdowns. Our investment in monitoring—infrared detectors, real-time feedback loops, and more robust sampling—grows out of red-ink notes in shift logs and lessons from accident reviews. Reliable delivery and consistently high purity mean fewer emergencies for all involved, from the tanker driver to the research scientist.

    Looking Forward: Challenges and Solutions

    Pressure builds every year: greener raw materials, tighter emission limits, customers demanding both lower environmental impact and greater traceability. We see that the future for 2-Methyl-1-Butene production must include more efficient catalysts, energy recycling loops, and smart process controls that fine-tune reactions in real time.

    Some solutions demand patience—development of separation technologies to shave energy use, new drying media to cut water in outgoing product, digital twins that mirror the plant for predicting trouble before a valve leaks. These changes often come out of suggestions from operators on the floor, not just the engineering office. We foster a culture that rewards speaking up, examining failures openly, and building improvements from the people closest to the process.

    Customers bring their own insights. Sometimes a problem in packaging or logistics leads us to rethink what “standard” means. We’ve rolled out returnable packaging, expanded digital tracking for shipments, and run joint HAZOP reviews with users. These efforts pay off not just in safety or reliability, but also in deeper partnerships that weather supply shocks and price swings.

    Final Thoughts: Why We Keep Improving

    Dedicated manufacturing teams understand 2-Methyl-1-Butene as more than a commodity. Every drum that leaves our site carries with it unseen effort: hours spent in planning meetings, late-night equipment repairs, detailed analysis reports, and a fierce pride in being more than a silent supplier. Innovations in process safety, logistics, analytical science, and customer service come from lessons learned—often the hard way—inside the fence line.

    Our confidence in every shipment stems from this real-world, hard-earned experience. The product label only hints at what’s inside. For those building with 2-Methyl-1-Butene—be they chemists, engineers, or entrepreneurs—they carry forward the result of our determination, expertise, and commitment to continuous improvement. Whether a partner seeks a specialty polymer or a fragrance intermediate, our track record stands behind the product, in every sense of the word.