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2,4-Dinitroanisole

    • Product Name 2,4-Dinitroanisole
    • Alias DNAN
    • Einecs 221-116-8
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    557026

    chemical_name 2,4-Dinitroanisole
    cas_number 119-27-7
    molecular_formula C7H6N2O5
    molecular_weight 198.13 g/mol
    appearance Yellow crystalline solid
    melting_point 85-86 °C
    boiling_point 338.4 °C
    density 1.53 g/cm³
    solubility_in_water Insoluble
    flash_point 164 °C
    smiles COC1=CC(=C(C=C1[N+](=O)[O-])[N+](=O)[O-])
    pubchem_cid 8178
    iupac_name 1-methoxy-2,4-dinitrobenzene

    As an accredited 2,4-Dinitroanisole factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 2,4-Dinitroanisole is packaged in a 500g amber glass bottle with a tight-sealed lid, featuring a hazard-labeled exterior.
    Shipping 2,4-Dinitroanisole is shipped as a hazardous material due to its combustible nature. It should be packaged in tightly sealed containers, clearly labeled with appropriate hazard warnings, and transported according to UN regulations (UN 1320). Avoid heat, sparks, and open flames. Ship in compliance with local and international chemical transport regulations.
    Storage 2,4-Dinitroanisole should be stored in a cool, dry, and well-ventilated area, away from sources of heat, ignition, and incompatible materials such as strong oxidizing agents. The container must be tightly closed and clearly labeled. Avoid direct sunlight and moisture. Storage areas should be equipped with spill control measures and comply with relevant safety regulations for energetic and hazardous substances.
    Application of 2,4-Dinitroanisole

    Applications of 2,4-Dinitroanisole in Industrial Manufacturing

    As the direct producer of 2,4-Dinitroanisole with proven expertise in precision chemical manufacturing, we supply this nitroaromatic compound to experienced downstream sectors where stringent quality and technical specifications are demanded. Below, we summarize the verified industrial segments, production ratios, compliance demands, and typical processing routes where customers integrate our material into advanced application technologies.

    1. Melt-Cast Explosives Formulation for Defense Ordnance

    2,4-Dinitroanisole serves as a principal melt-cast matrix ingredient in insensitive munitions, replacing traditional compounds to achieve lowered sensitivity and improved safety for military-grade explosives. Manufacturing partners incorporate the material during controlled melt granulation stages, achieving batch consistency and stability critical for ordnance fillings such as IMX-series and PBX charges. Blending ratios and temperature control directly affect the shock resistance and detonation behavior of finalized products.

    Industry compliance standards

    • NATO STANAG 4439 (Insensitivity of Munitions to Impact and Jet Tests)
    • U.S. Mil-Std-2105D (Insensitive Munitions Standards)
    • REACH Regulation (EC) No 1907/2006 – Annex XVII (Handling of precursors)
    • ISO 9001:2015-certified ordnance production QC

    Typical usage ratio

    • 35%–40% w/w of explosive matrix; precise percentage adjusted based on the desired balance between melting point and mechanical sensitivity, particularly when incorporated with ammonium perchlorate or RDX.

    Downstream process integration

    • Integrated during the melt-cast phase following dissolution of energetic fillers, prior to final charge granulation and pour-cooling in explosive component facilities.

    Final product types

    • Insensitive munition warheads (IMX-104, IMX-101)
    • Artillery shell fillings
    • Commercial mining explosives (specialty blast boosters)
    • Explosive device casings designed for reduced accidental detonation risk

    2. Intermediate for High-Performance Energetic Plasticizers

    Downstream manufacturers employ 2,4-Dinitroanisole as a key starting material in synthesizing energetic plasticizers for propellant and binder formulations. The aromatic nitro groups enhance compatibility with nitrocellulose matrices in rocket motors and missile propellants, maintaining flexibility while offering controlled decomposition temperatures. The input ratio must be engineered according to compatibility with co-monomers in plasticizer synthesis reactors.

    Industry compliance standards

    • U.S. Department of Defense ITAR regulations (for propellant ingredients)
    • ISO 17025:2017 (Analytical chemistry accreditation for energy materials)
    • DEF STAN 13-500 (UK MoD - Propellant requirements)
    • European ADR 2025 (Transport of Energetic Substances)

    Typical usage ratio

    • 5%–12% w/w as a precursor in esterification or azeotrope blending steps; proportions adjusted based on desired energetic plasticizer volatility and migration performance.

    Downstream process integration

    • Charged directly into pilot-scale organic synthesis reactors during the aromatic nitration and subsequent esterification sequences, typically under jacketed agitation with acid-resistant apparatus.

    Final product types

    • Polymeric binder plasticizers for solid rocket propellants
    • High-energy adhesive films for missile components
    • Flexible cast sheets for advanced solid propulsion media
    • Specialized propellant additive masterbatches for aerospace

    3. Phlegmatizing Agent in Primary Explosive Mixtures

    Specialty initiator and detonator manufacturers use 2,4-Dinitroanisole as a phlegmatizing agent in the compounding of primary explosive formulations such as lead styphnate or DDNP. By controlling sensitivity and improving the thermal behavior of micro-granular mixtures, integration at this stage allows for tailored initiation train responses. Formulators adjust ratios based on granular particle morphology and required shelf-stability of the mixed powders.

    Industry compliance standards

    • U.S. ATF - 27 CFR Part 555 (Explosives Manufacturing and Storage)
    • United Nations Orange Book – Class 1 Handling (Explosives)
    • EN 13763-11:2003 (European Detonator Standards)
    • Organization for the Prohibition of Chemical Weapons (OPCW) Handling Protocols

    Typical usage ratio

    • 0.5%–3% by mass, depending on granulation fineness and required stability parameters within the complete initiator matrix.

    Downstream process integration

    • Introduced during wet mixing and granulation stages where the primary explosive is agitated with phlegmatizing agents prior to sieving, drying, and pelletizing.

    Final product types

    • Electrical detonators
    • Blast initiator caps
    • Mining detonator assemblies
    • Safety fuse heads for pyrotechnics and specialty devices

    4. Dye and Pigment Intermediate for Nitroaromatic Colorants

    Certain dye manufacturing plants utilize 2,4-Dinitroanisole in the synthesis pathway for select nitroaromatic colorants, where its methoxylated structure offers a reactive platform for further substitution or reduction, enabling formulation of deeply saturated yellow and orange dyes. The ratio used is calibrated according to the required chroma intensity and fastness in final pigment dispersions for plastics and inks.

    Industry compliance standards

    • EU REACH Annex XVII (Colorant Restrictions for Consumer Goods)
    • ISO 9001:2015 (Pigment and Dye Production QC)
    • EN 71-3:2019 (Migration of Certain Elements in Toys, for pigment use in children’s products)
    • US FDA 21 CFR Part 74 (Color Additive Regulations, where applicable)

    Typical usage ratio

    • 10%–24% by weight, with precise input determined by chromophore extension requirements and batch output volumes in the azo- or anthraquinone dye synthesis stages.

    Downstream process integration

    • Added to the condensation or diazotization reactors following initial substrate preparation; bulk quantities charged under inert atmosphere for reaction management and color development.

    Final product types

    • Nitroaromatic pigments for engineering plastics
    • Industrial printing inks
    • High-performance coatings for textiles and papers
    • Concentrated color masterbatches for polymers

    5. Research Use in Analytical Standards for Explosives Detection

    Regulated laboratories and detection device manufacturers deploy 2,4-Dinitroanisole as an analytical reference standard in calibrating and validating trace explosives detection equipment, such as GC-MS or IMS-based systems. Laboratories require precisely characterized, high-purity lots to support forensic or security screening calibration, ensuring specificity in detecting energetic materials within compliance testing workflows.

    Industry compliance standards

    • ISO/IEC 17025:2017 (Accreditation for Testing and Calibration Laboratories)
    • ASTM E2677-16 (Standard Guide for the Selection of Analytical Methods for Explosives)
    • FBI Quality Assurance Standards for Forensic Explosives Analysis
    • European CEN/TR 16910 (Detection of Explosives in Security-Sensitive Environments)

    Typical usage ratio

    • 1–50 ppm in reference standards or spike solutions; calibrations adjusted for matrix interference and sensitivity thresholds of analytical instruments.

    Downstream process integration

    • Weighing and dissolution into certified analytical solvents, followed by aliquoting into standard ampoules or calibration kits for laboratory quality control or instrument tuning.

    Final product types

    • Reference standards for explosives detection
    • Calibration kits for GC-MS, HPLC, and IMS instruments
    • Analytical proficiency test panels
    • Security screening device validation samples
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    Certification & Compliance
    More Introduction

    2,4-Dinitroanisole: Modern Energetic Ingredient Built on Experience

    What Sets 2,4-Dinitroanisole Apart

    Every day on our production line, the value of practical chemistry meets the rigors of safety and responsible supply. In this space, 2,4-Dinitroanisole (DNAN) carved out a new opportunities, outperforming long-time standards like TNT in specific energetic and munitions applications. Having worked closely with field engineers, handling experts, and researchers, I’ve seen firsthand that the shift toward DNAN didn’t happen by accident or marketing trends. As a manufacturer, our focus is to deliver a material that brings both performance and responsibility to the table.

    The Drive for Lower Sensitivity

    Safety dominates every decision around energetic materials—both on our floor and in the hands of customers working downstream. DNAN came to the fore because it offers a lower sensitivity to shock, friction, and impact compared to traditional nitroaromatic explosives. Workers appreciate a powder that reduces accidental ignition risk during processing, blending, or filling. That shift means we can step up safety on production lines and in shipment, while placing a high-energy compound into the hands of operators without raising daily hazards. This isn’t just a box on a datasheet. Operators talk and we listen: less sensitivity translates to fewer stoppages, fewer worries about minor impacts, and a smoother workflow.

    Engineering Real Solutions—Making Consistent DNAN

    Creating DNAN isn’t a plug-and-play routine. We learned quickly that production methods directly shape purity, granularity, free-flowing properties, and the consistency of each lot. Maintaining controlled crystallization and purifying out trace contaminants form the backbone of our batch QA. Through frequent assessment, we check for off-color, caking, or dusting—even if specifications technically permit variance. Field customers don’t want surprises when charging their processes or molds, so reliability in bulk quality protects both the end user and our own reputation. Each batch leaves our plant with a certificate confirming analytical and physical metrics, no shortcuts taken.

    Performance in Formulations—DNAN in Action

    R&D teams have long asked for more than just a safe explosive. They want materials that unlock dependable ballistic performance and coupling in complex formulations—especially melt-cast explosives. DNAN fits as a drop-in replacement for TNT in many recipes for insensitive munitions because it’s designed to support both melting and casting with good thermal stability. The melt point, sitting higher than TNT yet lower than many alternatives, permits easier thermal handling in real-world casting environments. This keeps batch processes smoother, decreases re-melt failures, and leads to chemical compatibility with both nitrate esters and metallic powders. In continuous line production, the right melt-cast energetic delivers cleaner demolding and reliable crystal structure throughout solidification.

    Suitability Across Explosives and Propellants

    DNAN goes into more than just traditional munitions. Formulators turn to it when looking to engineer less sensitive compositions for shaped charges, boosters, mines, and other specialty energetic articles. It mixes readily with nitramines such as RDX or HMX for customized performance envelopes—achieving the desired detonation velocity and brisance while keeping sensitivity within safe working margins. In all these blends, the choice of DNAN frequently reduces volatility during blending and makes handling procedures less strict, even as energy density remains competitive. The result extends the working life of filling lines and reduces the rate of quality downgrades due to mishaps.

    Why Quality and Traceability Matter

    Experience has shown that troubles in this business often start with a break in traceability. One variation in purity or physical form may cause a problem that doesn’t show up until a device is being filled or fielded. So, we run trace-back and lot integrity as standard practice for every shipment—every drum, every container. Customers often audit our facility because regulatory compliance drives both national security and civil protection requirements. We have worked alongside auditors to produce supply chains that not only meet codes but inspire confidence: the batch you tested in the lab is the same batch you’ll receive in production, fully documented from precursor chemicals through finished DNAN. This level of traceability supports critical defense and safety applications, far from being just a paperwork exercise.

    Benchmarks Compared to TNT or Melt-Cast Alternatives

    In the decades before DNAN, TNT ruled as the industry standard for melt-cast energetics. TNT became indispensable mostly because of its ease of melting, handling, and casting in factory conditions. That being said, TNT’s high sensitivity and known toxicology drawbacks kept risk levels above what many modern users find acceptable. Working directly with customers, we heard the same concerns—TNT fumes created exposure issues, environmental persistency raised cleanup costs, and legacy health advisories reduced its appeal for long-term manufacture.

    DNAN answers these issues. Its vapor pressure is significantly lower than TNT, so occupational exposure to fumes drops during casting and post-cure inspections. With moderate toxicity and easier waste treatment, operational safety officers and environmental stewards report fewer headaches and smoother permitting. The lack of free nitroaromatic byproducts in pure DNAN means downstream wastewater is less challenging to treat. These concrete improvements over legacy materials drive demand far more reliably than theoretical performance claims on paper.

    Regulatory and Environmental Impact

    Within the regulatory landscape, DNAN features a lower profile for hazardous waste and disposal management. Batch manufacturing always generates residues—cleanup, container rinsing, equipment purges. DNAN’s lower aquatic toxicity and rapid degradation under UV mean our waste streams draw less scrutiny from environmental regulators, especially compared to high-profile persistent explosives. Each year, environmental compliance reviews shape both our product output and plant upgrades. The use of DNAN enables our team to meet stringent discharge and emissions standards while simplifying remediation plans if accidental release occurs. All compliance checks from procurement to disposal use hard evidence, making DNAN a reliable bet for chemical managers juggling the demands of environment, health, and operational cost controls.

    Improving Worker Health and Process Hygiene

    Historically, routine exposure to dusts and vapors from energetic nitroaromatics led to chronic health problems for plant workers—everything from skin contact to inhalation risk. Early on, we realized success hinges on a clean, dust-minimized process. DNAN’s physical characteristics, when our crystallization controls are strict, create coarse, low-dust batches that are easy to handle by scoop or metered feed. In plant trials, workers on DNAN lines show fewer issues with irritation, headaches, or sensitization compared to legacy TNT sites. The practical result shows up in fewer accident reports, lower PPE requirements, and improved worker morale, as people see their day-to-day job evolving toward safer routines.

    Industrial Feedback: Lessons Learned

    End-users and partners have brought hard truths to every progress meeting. One challenge: DNAN’s melting characteristics demand careful process adjustment on lines built for TNT. The melting range is a few degrees higher; operators re-tune thermal control units and casting lines to prevent incomplete melts or hot spots, which could affect casting consistency. Through cooperative troubleshooting with customers, we developed SOPs for ramping temperature in steps and redesigning molds for smoother fills. These field collaborations have honed our support responses and improved outcomes at both legacy sites and greenfield builds.

    Customers using DNAN for multi-stage munitions also noted its compatibility with modern plasticizers and binders. We continually run blend compatibility and aging tests to catch issues with nitrated binders or stabilizer packages. Only by catching these snags early can we recommend the right protective packaging, storage moisture levels, and even container linings. These practical plant-based insights make all the difference when scaling up from the test bench to multiton annual production.

    Market Demand—Supply with Security

    Increased interest in insensitive munitions, led by updated military requirements and global safety standards, meant steady growth in DNAN requests. As demand rose, we invested in dedicated lines, raw material quality upgrades, and semi-automated controls to keep output both traceable and consistent. Tight global supply chains combined with regulatory scrutiny meant customers couldn’t afford delays or off-spec material. By maintaining robust storage, stockpiling key intermediates, and securing several transportation channels, we continue to guarantee shipment timelines that users rely on, especially for critical production cycles. Transparency in our operations reflects lessons learned the hard way: customers don’t tolerate surprises, and manufacturing needs more backup than just low price-point deals.

    Customer Support and Technical Resources

    Supplying DNAN to field sites never ends with delivery. Our technical teams consistently advise clients in process set-up, troubleshooting, and safety drills. Practical guides—based on factory hazards and incident reviews—encourage better handling, spill response, and equipment cleaning protocols. If any downstream process reveals a batch inconsistency, we stay engaged from lab analysis to on-site resolution. Years of collaboration have built a network of client process improvements, which feeds back into our own plant upgrades and even tweaks to final product specs. Each plant’s feedback loop forms the front line of robust supply and mutual improvement.

    The Path to Continued Innovation

    Users rarely settle for “almost as good” alternatives. They want better energetics that serve both safety and performance goals, all at practical cost and without adding regulatory hurdles. Through recurring R&D, we continuously refine batch yield, purity, and dust management for DNAN. We experiment with different crystallization rates, anti-caking agents, and packaging types to further minimize exposure risks in transport and at frontline storage depots. Trials run alongside formulation experts who stress-test the powder in aggressive cast-cure combinations, high-energy compaction, and temperature cycling. These investments aren’t made in a vacuum; they reflect pressing demands from users navigating tight margins and ever-evolving safety codes.

    Conclusion: DNAN in Industry Use—A Product With a Purpose

    No material can be all things to all users. As a manufacturer with thousands of tons processed and delivered, we’ve seen the benefits and the everyday realities up close. DNAN’s place in the energetic sector stems directly from the demands of working chemists, safety engineers, and line operators faced with new challenges every production cycle. It stands out among older powders not because of abstract promise, but because its chemistry and manufacture answer questions of lasting importance: consistency, lower daily hazards, smooth process integration, and regulatory compliance. Each improvement and each feedback cycle ties back to our plant floor, where the practical matters of today form the foundation of reliable, safer energetic materials for the future.