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1-Naphthylamine

    • Product Name 1-Naphthylamine
    • Alias alpha-Naphthylamine
    • Einecs 202-080-4
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    860348

    Chemicalname 1-Naphthylamine
    Casnumber 134-32-7
    Molecularformula C10H9N
    Molecularweight 143.19 g/mol
    Appearance Colorless to brown solid
    Meltingpoint 50-53°C
    Boilingpoint 302°C
    Solubilityinwater Slightly soluble
    Density 1.145 g/cm³
    Flashpoint 174°C
    Odor Aromatic amine odor
    Synonyms α-Naphthylamine, 1-Aminonaphthalene
    Pubchemcid 7047
    Pka 4.16
    Ecnumber 205-138-7

    As an accredited 1-Naphthylamine factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 1-Naphthylamine is packaged in a 500g amber glass bottle, tightly sealed, with hazard labeling and chemical identification on the outer box.
    Shipping 1-Naphthylamine is shipped as a hazardous chemical. It should be packed in tightly sealed, clearly labeled containers, protected from light and moisture. The shipping package must comply with local and international regulations, such as those set by DOT and IATA. Use appropriate hazard labels, and safety documentation must accompany the shipment.
    Storage 1-Naphthylamine should be stored in a tightly closed container, in a cool, dry, and well-ventilated area away from direct sunlight. Keep it separate from oxidizing agents and acids. Store in a chemical-resistant container and clearly label it as toxic and potentially carcinogenic. Ensure access is limited to trained personnel and follow relevant safety and environmental regulations.
    Application of 1-Naphthylamine

    Applications of 1-Naphthylamine in Industrial Manufacturing

    As a direct producer of 1-Naphthylamine, we support a range of core downstream industries where this aromatic amine plays a critical intermediate role. Below we detail its key integration in dyes, rubber antioxidants, pigment, and specialty chemical sectors, highlighting real compliance frameworks, formulation principles, process points, and the end products our customers create.

    1. Azo Dye Manufacturing (Acid and Direct Dyes)

    1-Naphthylamine acts as a primary coupling component in the synthesis of azo dyes for textile, leather, and paper applications. Its unique naphthylamine backbone allows controlled diazotization and coupling to produce brilliant and colorfast shades such as Acid Orange 7 and Direct Yellow 12. Our industrial customers rely on specific grade raw material consistent with textile-grade dye regulations and batch-integrity validation.

    Industry compliance standards

    • OEKO-TEX® Standard 100 (Textile Dyes)
    • REACH Regulation (EC) No 1907/2006 for SVHC Declaration
    • ZDHC (Zero Discharge of Hazardous Chemicals) Manufacturing Restricted Substances List (MRSL)
    • EN 71-3:2019 (Safety of Toys - Migration of Certain Elements, for dye use in children's textiles)

    Typical usage ratio

    • 3–10% by weight in diazotization reaction relative to total aromatics, adjusted depending on shade depth and dye class required by customer formulation.

    Downstream process integration

    • Charged into the diazotization coupling vessel following pre-dissolution under controlled pH and temperature (0–5°C). Sequence: Dissolution → Diazotization → Coupling → Isolation and Drying of Dye.

    Final product types

    • Textile Acid Dyes (e.g., Acid Orange 7, Acid Blue 113)
    • Direct Dyes for Cellulosics (e.g., Direct Yellow 12)
    • Paper Colorants
    • Leather Dyes (suede, chrome-tanned formulations)

    2. Rubber Antioxidants Production

    The aromatic amine structure of 1-Naphthylamine serves as a crucial precursor for the synthesis of rubber antioxidants, especially antioxidant RD (IPPD) and other substituted para-phenylenediamines. Rubber chemical plants utilize our material for creating stabilizers that protect elastomers from thermal-oxidative degradation under heavy-duty operating conditions, with strict adherence to industrial safety and environmental requirements.

    Industry compliance standards

    • ISO 9001:2015 (Quality Management for Rubber Chemicals)
    • REACH Compliance for downstream intermediate use
    • ASTM D4676-07 (Standard Classification for Rubber Antioxidants)
    • China GB/T 8829-2003 (Rubber Antioxidants Specifications)

    Typical usage ratio

    • 0.5–2.5 molar equivalents in antioxidant synthesis, based on stoichiometry with para-aminodiphenylamine and other intermediates (not in final rubber formulation but in chemical synthesis stage).

    Downstream process integration

    • Introduced in the condensation reactor during synthesis of para-phenylenediamine antioxidants, after pre-melting or in solvent solution, before neutralization and crystallization of the finished antioxidant powder.

    Final product types

    • Antioxidant IPPD (N-isopropyl-N'-phenyl-p-phenylenediamine)
    • Antioxidant DPPD (diphenyl-p-phenylenediamine)
    • Rubber protective agents for tires, hoses, seals, conveyor belts
    • Automotive and industrial rubber goods

    3. Pigment Intermediate Synthesis

    1-Naphthylamine functions as a strategic intermediate in the production of organic pigments, particularly naphthol and azoic pigments. Its naphthalene ring structure allows targeted derivatization for pigmentary amines, where purity, free amine index, and trace impurity control are monitored to meet new-generation pigment compound migration and heavy metal release regulatory limits.

    Industry compliance standards

    • EN 71-7:2014 (Safety of Toys – Finger Paints; Pigment Migration)
    • AP(89)1 Resolution (Council of Europe - Heavy Metals in Pigments)
    • REACH Authorization List (Pigments for Plastics and Coatings)
    • China GB 9685-2016 (Hygienic Standards for Uses of Additives in Food Containers and Packaging Materials, for pigment in indirect food contact packaging)

    Typical usage ratio

    • 3–12% on the total charge in the synthesis batch for pigmentary amines, modulated based on the shade strength and intended application (plasticizers, coatings, inks).

    Downstream process integration

    • Charged to the pigment synthesis line after alkaline hydrolysis and filtration, then reacted with diazonium salts or acetoacetarylamide compounds during pigment coupling stage before milling, washing, and pigment finishing.

    Final product types

    • Azoic Pigments (e.g., Pigment Orange 5, Pigment Red 1)
    • Naphthol-based Pigment Dispersions
    • Color concentrates for plastics and packaging inks
    • Decorative paints and industrial coatings

    4. Pharmaceutical Intermediate for Sulfonamide Synthesis

    Our customers in the pharmaceutical sector employ 1-Naphthylamine as an advanced intermediate in the synthesis of several sulfonamide drugs and related intermediates. The manufacturing workflow relies on medical-grade impurity control with trace metal analysis and extensive documentation for traceability under drug master file requirements, especially for generics manufacturing and API suppliers.

    Industry compliance standards

    • ICH Q7 GMP for Active Pharmaceutical Ingredients
    • Ph. Eur. (European Pharmacopoeia) monographs referencing sulfonamide intermediates
    • US FDA 21 CFR Part 211 (Finished Pharmaceuticals cGMP)
    • China NMPA Drug Master File (DMF) submission for starting intermediates

    Typical usage ratio

    • 0.8–1.2 molar equivalents in sulfonation and diazotization routes, adjusted according to impurity threshold setpoints for target sulfa compound synthesis.

    Downstream process integration

    • Added to sulfonation or amination tanks following initial charge of either acid chloride or amidosulfonic acid; monitored for endpoint by HPLC during batch processing, before purification and crystallization of pharmaceutical-grade intermediates.

    Final product types

    • Sulfanilic acid derivatives for further synthesis
    • API intermediates for oral and topical sulfonamide drugs (e.g., Sulfanilamide, Sulfadiazine)
    • Bulk intermediates for veterinary drug manufacture
    • Specialty fine chemicals for pharmaceutical R&D

    5. Laboratory Diagnostic Reagent Production

    Specialty diagnostic reagent manufacturers use high-purity grades of 1-Naphthylamine for colorimetric analysis, including Griess and related reactions for nitrate and nitrite detection. Product integration in this sector requires low-amine background, stringent packaging protocols, and documented traceability to ensure accuracy and reproducibility in clinical and industrial analytics.

    Industry compliance standards

    • ISO 13485:2016 (Medical Devices – Quality Management)
    • CLSI (Clinical and Laboratory Standards Institute) GP01 ED4:2015
    • FDA 21 CFR 820 (Quality System Regulation for Medical Device Reagents)
    • European IVD Regulation (2017/746/EU) for reagent production

    Typical usage ratio

    • 1–4 mg/mL in aqueous diagnostic reagent formulation; tailored adjustments based on analytical calibration curves per test kit specification.

    Downstream process integration

    • Introduced to blending vessels during final reagent formulation stage, dissolved in buffer with stabilizers, then aliquoted into test kit vials under nitrogen atmosphere to prevent oxidative degradation.

    Final product types

    • Colorimetric nitrite/nitrate test kits for clinical laboratories
    • Environmental water quality field kits
    • Industrial food safety screening kits
    • Educational laboratory reagents for research and teaching
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    Certification & Compliance
    More Introduction

    1-Naphthylamine: A Direct Output from Our Plant

    Introduction to 1-Naphthylamine

    Everyday operations in our chemical plant revolve around straightforward production and rigorous quality monitoring. 1-Naphthylamine takes up a significant portion of our output. As a raw material with over a century of history in industrial chemistry, its presence in our production lines is continuous, not just as an order but as a mainstay. During synthesis, small adjustments in temperature and reactant purity influence the yield and final purity. Models and labels exist — ours matches global standards for technical and analytical applications, but the process behind the specification actually matters to deliver repeatable, genuine outcomes batch after batch.

    In our production, the integrity of base naphthalene and the amination process influences how well downstream users can depend on each shipment. On our side, controlling for trace contaminants means we minimize risks for dyestuff producers, rubber additive manufacturing, and specialized research labs who expect not just a product that fits a line in a catalogue, but one that does not compromise reaction efficiency or introduce unexpected side reactions. Not everyone sees the daily challenge of keeping oxygen out to preserve color and minimize by-products. For us, keeping that extra vigilance makes a difference when years-old clients report cleaner splits and fewer filter issues.

    Why Experience with 1-Naphthylamine Production Matters

    Some compounds invite casual handling — 1-Naphthylamine is not one of them. Even modest exposure to light or moisture can start to degrade the solid, which leads to darker color and performance deviations in end-use formulas. Our factory’s workflow fixes this at source by adopting sealed transfers, quick-drying protocols, and fast packaging. No two runs are the same, especially as market demands shift and different users request alternate grades — technical for synthetics, higher purity for research, or made-to-order derivatives.

    Our lines run batches at scales that answer both regular bulk contracts and smaller, bespoke requests. In this process, the main purity specification locates at 99% minimum for technical grade. For analytical quality, more intensive purification steps deliver an improved purity spectrum and narrowed impurity profiles. Each grade finds meaningful placement: textile pigment makers use technical grade; analytical users opt for the higher purity. Running purification columns or optimizing extraction solvent ratios is part of the behind-the-scenes troubleshooting, ensuring neither off-color nor residue-heavy material gets past final inspection.

    Downstream Uses Rooted in Reliable Chemistry

    Dyestuff manufacturing depends on the consistency of starting products. Our 1-Naphthylamine feeds directly into production lines for azo dyes. Minute changes in structure or impurity load translate directly down the chain into color reliability, batch yield, and regulatory compliance. Textile producers rarely tolerate fluctuating input, especially as global standardization tightens. Removing even trace levels of secondary amines or naphthalene derivatives means dyebaths produce the expected color every time. The same is true for rubber antioxidant production processes — inconsistent inputs force formula adjustments and downtime.

    Research uses involve analytical methods, detector calibration, and reaction setup in chemical synthesis. For many users, how precisely the product matches specification sets the tone for how the entire experiment unfolds. Some research labs ask for detailed impurity breakdowns, and we pull out extra runs of high-performance liquid chromatography or GC-MS to supply real numbers. Sometimes conversation extends to direct visits, so third-party teams inspect our protocols and confirm we avoid cross-contamination with aromatic amines of different character.

    Difference Between Our 1-Naphthylamine and Alternative Aromatic Amines

    The market contains several naphthylamines and even more from the broader family of aromatic amines. Some end-users mistakenly view 1-Naphthylamine as interchangeable with 2-Naphthylamine. This assumption can introduce problems further down the value chain, as they differ in toxicity, reactivity, and regulatory treatment. Our in-plant separation and QC protocols guarantee that 1-Naphthylamine remains distinct, drawing a hard line between positional isomers during both manufacture and packaging.

    1-Naphthylamine, produced as a white to light tan crystalline powder, offers a different reactivity profile compared to its isomer, 2-Naphthylamine. Industrial uses tend to diverge: 1-Naphthylamine persists in legal, large-volume production for dye intermediates, while 2-Naphthylamine largely disappeared from global commerce given its high carcinogenic risk. Plant workers are fully briefed, and equipment is segregated, to prevent any confusion or mishandling, especially where customer requirements and shipment records demand clear traceability.

    Adding Value through Transparent Manufacturing

    Operational reliability draws customers back. Our approach has not relied on basic batch output alone; rather, clients expect substance and consistency. True specification fulfillment comes from meticulous monitoring, with operator logs capturing flow rate, temperature profiles, and checkpoint purities throughout each shift. Deviations prompt immediate dialogue between technicians, rather than passing problems onward or waiting for post-shipment complaints. We’ve seen cases where a half-percent deviation in purity made material unusable for highly regulated pigment work — the lesson learned, more detailed batch tracking, frequent early testing, and non-negotiable discard policies when parameters do not match.

    Supply is not just numbers on containers; it calls for clear QC documentation, visible chain of custody, and accessible batch samples stored for years. Regular inspections by certifying authorities, as well as internal audits, keep every run transparent. Our workforce rotates cross-training on new analysis equipment, so fresh perspectives recalibrate standard operating procedures, raising internal standards with each passing year. Clients often ask for historical batch data, impurity traces, and full sample packages — our database and storage system, accessible within hours, often clinches repeat contracts.

    Navigating Regulatory and Environmental Responsibility

    Chemical production, especially with aromatic amines, brings unavoidable health and safety obligations. Our safety measures do not stop at the shop floor. Plant design features containment sections and localized fume extraction, minimizing exposure risk. Regular monitoring of air and wastewater ensures nothing leaves untreated. All by-products, primarily small fractions of naphthalene or other amines, are sent through closed-loop recovery or high-efficiency scrubbers. Our staff conduct frequent safety drills for storage, transfer, and emergency response. Beyond compliance, these practices provide peace of mind, internally and for clients whose own brands depend on secure, hazard-free sourcing chains.

    Increasing scrutiny by occupational health bodies shapes our improvements. One audit prompted us to double-walled packaging and invest in volatile emission reduction, a move reflected both in reports and in our workers’ confidence handling material daily. Our documents cover the sourcing of raw material, complete records of each intermediates’ batch, and final product traceability, forming a robust paper and digital trail responding readily to regulatory requests or downstream consumer inquiries.

    Practical Lessons from Decades in Production

    Every batch and technical upgrade has fed into a long-term knowledge bank. In the past, downtime from equipment failures reminded us how directly production lines tie into customer promises. A single shipment delivered out of specification translates to weeks of rework and lost trust. Addressing these lessons, we stepped up investments in real-time analytical technology, refining temperature feedback loops, and cross-checking every internal sample, long before loading day.

    Suppliers sometimes pitch cheaper or more convenient synthesis routes. Through practical trials, we have seen that shortcutting critical intermediate purification sacrifices downstream quality and increases environmental load, offsetting cost savings in the long run. The industry’s history repeated itself: competitors relying on such tactics lost reputation or faced regulatory hurdles. Our persistence with incremental improvements — purer solvents, sealed process installations, staff cross-training — keeps us competitive.

    How We Help Solve Industry Challenges

    Our most valuable input often comes not just from what goes into the reactor, but from conversations with those who use 1-Naphthylamine daily. Multi-national dye manufacturers, research chemists, and small custom pigment makers share specific bottlenecks and product performance requirements. After hearing repeated complaints about “greying” or “off-tint” batches, our lab team ran months of impurity profiling, identifying the root cause in trace oxidized by-products. Adjustments in inert gas coverage and improved filtering brought batch consistency back to required standards.

    Moisture and airborne contaminants have appeared as recurring challenges in storage and shipping. To address customer reports of caking, we modified our packaging processes, adding stronger desiccant management and more frequent moisture checks before shipping. These seemingly minor changes stopped mid-transit clumping and led to noticeable feedback from overseas clients. Practical, direct solutions build more loyalty than fixes attempted after product is already in production lines.

    Ongoing Collaboration with End-Users

    Direct feedback loops mean our technical support does not dwell only in theory. Over time, clients brought application issues to our attention: requests for compatibility testing in certain dye formulations or concerns about shelf life in warm, humid climates. Each request informed upgrades in batch stability testing and packaging design. Routine joint site visits with end-users allow us to audit in-field storage conditions, tweak delivery volumes, and sometimes even adjust our finishing processes to meet unique handling needs.

    In a world shifting toward digital integration, we’ve opened up more granular supply data sharing, including live order tracking, real-time certificate uploads, and accessibility for technical documentation. End-users with recurring or mission-critical needs receive priority lines for urgent support, drawing on long-standing relationships with our technical leadership. Proactive support for final use means fewer surprises, greater trust, and less downtime across entire client operations.

    Conclusion: Value Built on Reliable Practice

    Our plant staff and engineers invest both technical rigor and daily common sense into every shipment of 1-Naphthylamine. Markets do not reward shortcuts or theoretical promises; real business stems from evidence built across years — in batch control, transparency, user feedback, and readiness to respond to challenges as they arise. This reliability keeps our product in daily demand across regions, applications, and regulatory environments.

    By producing and delivering 1-Naphthylamine built on robust protocols and open communication, we support both traditional dye industries and modern research users. We keep learning from every interaction, tightening internal controls, and raising standards. These practices, proven and transparent, form the foundation for continued confidence in each batch shipped — not as abstract metrics, but in direct, experience-backed outcomes for clients on five continents. Our commitment remains to substance over show: chemistry that works, because effort and attention were built into every step.