Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing admin@sinochem-nanjing.com 3389378665@qq.com
Follow us:

1,5-Cyclooctadiene

    • Product Name 1,5-Cyclooctadiene
    • Alias COD
    • Einecs 211-111-1
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    863179

    Chemicalname 1,5-Cyclooctadiene
    Casnumber 111-78-4
    Molecularformula C8H12
    Molarmass 108.18 g/mol
    Appearance Colorless liquid
    Density 0.857 g/mL at 25°C
    Meltingpoint -17 °C
    Boilingpoint 153 °C
    Refractiveindex 1.4869 at 20°C
    Flashpoint 35 °C (closed cup)

    As an accredited 1,5-Cyclooctadiene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 500 mL of 1,5-Cyclooctadiene is supplied in an amber glass bottle with a secure screw cap and clear hazard labeling.
    Shipping 1,5-Cyclooctadiene is shipped in tightly sealed containers, typically made of metal or glass, to prevent leaks and contamination. It should be stored and transported in a cool, dry, well-ventilated area away from heat, sparks, and open flames. Comply with hazardous material regulations due to its flammability.
    Storage 1,5-Cyclooctadiene should be stored in a cool, dry, well-ventilated area away from heat, sparks, and open flame. Keep the container tightly closed and protected from light. Store separately from oxidizing agents, acids, and strong bases. Use proper grounding and bonding since the liquid is flammable. Store in appropriate, labeled chemical containers to avoid leaks or contamination.
    Application of 1,5-Cyclooctadiene

    Applications of 1,5-Cyclooctadiene in Industrial Manufacturing

    As a factory-direct manufacturer, we supply 1,5-Cyclooctadiene primarily to specialty chemical producers and advanced material manufacturers. The following sectors represent the main approved and practiced industrial applications of this raw material, each requiring precise compliance and integration within their specific production lines.

    1. Catalyst Ligand Production for Olefin Polymerization

    In advanced polymer manufacturing, particularly metallocene and post-metallocene catalyst systems, 1,5-Cyclooctadiene serves as a key chelating ligand precursor. Major polyolefin producers utilize this material to synthesize transition metal complexes that enable precise control over polymer microstructure. Our quality standards and purity levels support leading catalyst synthesis protocols adopted globally by polyethylene and polypropylene resin producers.

    Industry compliance standards

    • ISO 9001:2015 Quality Management Systems
    • EU REACH Regulation (EC 1907/2006) Registration
    • OECD Good Laboratory Practice for Material Synthesis

    Typical usage ratio

    • 0.8–1.1 molar equivalents relative to target metal center; customers adjust based on desired catalyst activity and single-site character

    Downstream process integration

    • Introduced during ligand precursor synthesis, typically under inert atmosphere in organic solvent systems before complexation with transition metals

    Final product types

    • Metallocene catalyst precursors
    • Activated catalyst complexes for polyolefin production
    • Functionalized organometallic intermediates for advanced materials

    2. Cyclooctene Monomer Feedstock for Specialty Polymer Synthesis

    Producers of polynorbornene rubber and related specialty elastomers employ 1,5-Cyclooctadiene as a direct monomer or co-monomer. The compound undergoes ring-opening metathesis polymerization (ROMP), yielding base polymers with high flexibility, chemical resistance, and unique molecular architecture widely required in the automotive, electronics, and industrial sealing markets.

    Industry compliance standards

    • IATF 16949:2016 for automotive polymers
    • ISO 14001:2015 for environmental controls in polymer synthesis
    • GADSL (Global Automotive Declarable Substance List) compliance

    Typical usage ratio

    • Up to 100% of olefin feedstock, or as little as 20% when blended with other cyclic olefins depending on desired final polymer properties

    Downstream process integration

    • Fed directly into continuous or batch metathesis polymerization reactors; purity of feedstock crucial for control of molecular weight and structural regularity

    Final product types

    • Polynorbornene elastomers
    • ROMP-derived specialty rubbers
    • Impact-resistant thermoset intermediates

    3. Intermediate for Agrochemical Synthesis

    The agrochemical sector employs 1,5-Cyclooctadiene as a specialized starting material to access bicyclic and polycyclic compounds, which become structural components in certain crop protection agents. Process chemists transform the diene through Diels–Alder reactions and downstream functionalization steps to synthesize intermediates used in patented active agrochemical ingredients.

    Industry compliance standards

    • ISO 9001:2015 and ISO 14001:2015 certification for supply chain and EHS controls
    • EU Regulation (EC) No 1107/2009 for plant protection product active substances
    • EPA FIFRA regulations for US-bound downstream products

    Typical usage ratio

    • Ranges from 0.3 to 0.8 mole per mole of target Diels–Alder precursor, adjusted for desired intermediate yield and purity

    Downstream process integration

    • Charged to reaction vessels during early intermediate synthesis stages for Diels–Alder and subsequent functionalization; requires controlled addition for optimal selectivity

    Final product types

    • Cyclooctane-derived agrochemical building blocks
    • Bicyclic active ingredient intermediates
    • Finished plant protection agent components

    4. Cross-linking Agent in High-Performance Rubber Formulations

    Manufacturers of specialty elastomers for automotive and industrial applications employ 1,5-Cyclooctadiene as a cross-linking agent, taking advantage of its diene structure during peroxide or sulfur vulcanization. This usage enhances mechanical strength, heat resistance, and dynamic mechanical properties in final rubber goods where process consistency and compound longevity are stringent requirements.

    Industry compliance standards

    • ISO 6943:2011 for vulcanized rubber fatigue testing
    • ASTM D2000 for automotive rubber specifications
    • RoHS Directive 2011/65/EU for heavy metal and SVHC control in end-use goods

    Typical usage ratio

    • 1–5 phr (parts per hundred rubber) depending on base polymer type, required cross-link density, and vulcanization system

    Downstream process integration

    • Included during compounding stages using internal mixers prior to vulcanization, ensuring full dispersion and stable reactivity with co-agents and base polymers

    Final product types

    • Automotive weatherstrip seals
    • Industrial vibration isolators
    • Heat-resistant conveyor belts and hoses
    Free Quote

    Competitive 1,5-Cyclooctadiene prices that fit your budget—flexible terms and customized quotes for every order.

    For samples, pricing, or more information, please call us at +8615371019725 or mail to admin@sinochem-nanjing.com.

    We will respond to you as soon as possible.

    Tel: +8615371019725

    Email: admin@sinochem-nanjing.com

    Get Free Quote of Sinochem Nanjing Corporation

    Flexible payment, competitive price, premium service - Inquire now!

    Certification & Compliance
    More Introduction

    Introducing 1,5-Cyclooctadiene: Our Experience Shaping High-Purity Industrial Solutions

    Every Batch Grows From Direct, Hands-On Manufacturing

    At our plant, 1,5-Cyclooctadiene isn’t just another item leaving the reactor—it's a product that we have shaped through years of refining process variables, monitoring reaction kinetics, and listening to feedback from our customers in various industries. We do not stand at arm’s length. We built our cyclooctadiene line from the ground up, shaping purity and consistency by balancing feedstock quality and column design, and improving raw material throughput without compromising the double-bond integrity of the molecule.

    Product Overview Shaped by Practice—not Templates

    We produce 1,5-Cyclooctadiene (commonly referenced as COD) with a molecular formula C8H12, and with over fifty thousand tons passing through our hands, daily operations remind us of the critical details. COD carries two cis-double bonds, sitting at positions 1 and 5 on the eight-membered ring. The molecule’s geometry is more than a chemical curiosity—it drives demand from catalyst producers, polymer researchers, and specialty chemical makers. In our operations, COD isn’t an interchangeable part; the balance between purity and isomer content sets each batch apart. COD produced by direct cyclization of butadiene brings out specific reactivity that downstream customers have repeatedly come back to credit for reduced byproducts or improved catalyst yields.

    Why Purity Matters—Lessons from Our Reactors

    Running COD in metallocene catalysis doesn’t leave room for guesswork. Impurities, even in the ppm range, interrupt ligand formation and sometimes force downstream users to halt an entire synthesis. We’ve seen firsthand what happens if traces of peroxides or isomerized diene sneak through—reaction rates slow, metal-ligand complexes show competitive side reactions, and unwanted polymers develop. Too many customers have called us after struggling with off-site product, chasing problems back to inconsistent quality. Each drum we fill follows a regime of multi-stage distillation and GC analysis because on-specification is not a checkbox, it’s the only way to avoid process interruptions. If your product fails, those problems echo through your lab or plant, so we never ship questionable material.

    Distinguishing Ourselves from Commodity Blenders—Direct Experience with Downstream Sensitivities

    Some suppliers focus purely on volume or serving as logistics hubs for global bulk. We run a closed integration from raw butadiene feedstock through to the final drum. This connection gives us precision in controlling byproduct limits, keeping cyclooctene or unwanted oligomers out of our product line. When research clients or high-throughput polymer plants specify sub-100 ppm moisture or pinpoint isomer ratios, we match it at the source, not by post-additive cosmetic fixes. On top of that, we store, package, and distribute under inert conditions, eliminating the risk of contamination that too often creeps in with domestic transfers or third-party warehousing.

    Our emphasis on full chain control isn’t about marketing—it saves years in R&D scaleups. Once, a metallocene catalyst group flagged unexplained reactivity drops; we found the culprit to be micro-oxidized diene content that only direct-supply oversight could catch. These details do not show up in a spec sheet, but for those of us who have spent months troubleshooting reactor problems, the practicalities of upstream control spell the difference between a productive campaign and a series of wasted runs.

    Meeting Industry Standards from a Foundation of Trust and Verification

    Our COD production process follows a strict consistency protocol, but we do not rely solely on in-house assurances. Our facility maintains ISO 9001 certification because third-party audits uncover details that complacency misses. Each lot’s COA isn’t an afterthought—when we triple-check for total unsaturation, trace sulfur, and halogen content, it’s because our most demanding customers operate in pharmaceutical and electronics fields where trace contamination damages both product and reputation.

    The most experienced customers—catalyst houses, research labs, fine chemical producers—do not settle for generic drums. Over the years, requests for special packing, from corrosion-resistant drums to lined totes for moisture-sensitive shipments, have become routine. We adopted nitrogen blanketing and real-time temperature monitoring after seeing one batch suffer transit degradation due to an unnoticed valve leak. Each challenge faced and solved in our own operation shapes the reliability that our customers now expect without question.

    Real-World Applications Backed by Reliable Performance

    Every chemical dealer will claim broad applicability for COD, but only a manufacturer sees firsthand how diverse customers extract value from a consistent product. Olefin metathesis catalysts build on painstaking control of diene backbone reactivity. Seasoned catalyst manufacturers explained how COD’s chelating properties allow for more robust ligand fields, tightening process windows and creating more selective Ziegler-Natta polymerizations. Cod’s rigidity and reactivity find a home in specialty polymerizations, not available from simple cycloalkenes.

    Workers at specialty resin facilities explain how reliable COD supply underpins scale-up success, not just initial small-batch experiments. Chromatography resin startups report that yields scale cleanly from gram to metric ton only if minor isomer and unsaturation variances stay within tight bands—something our hands-on production line delivers time after time.

    Specification Details Reflecting Actual Manufacturing Experience

    Much of the market focuses on GC area purity, but those numbers only tell one part of the story. In our experience, downstream performance also tracks with residual peroxides, water content, and subtle oxygenate levels. By working with synthesis chemists and processing engineers, we learned to keep peroxide levels below 10 ppm, and to ship at moisture levels close to detection limits. That attention matters in batch-to-batch reproducibility. We tightly control isomer content—COD is not a uniform entity; its profile changes with minor temperature swings or residence time variations in the reactor. These operational details spring from daily problem-solving on our own line, not standard operating procedure handbooks.

    What Differentiates Us From Off-the-Shelf Alternatives

    Our facility does not depend on blending partial batches to pump up output. Every drum of COD is the direct result of closed-loop synthesis and finishing at source. We learned early that relying on repackaged product or multiple trans-shipment steps opens the door for trace contamination—sometimes metal ions, sometimes atmospheric oxygen—which can scramble a planned synthesis or introduce new failure points downstream. Hazardous shipments that pass through outside hands can build up static, moisture, and quality issues that only full-scope manufacturing surveillance can catch.

    Customers have described situations where COD from trading sources came in with hidden stabilizers or disguised tars formed in poorly purged columns. This doesn’t just hurt the bottom line—it costs weeks in troubleshooting and redesign. By keeping every stage under our own roof, we pass on not just a higher purity number but peace of mind when you commit plant-scale runs to a product you can’t risk failing on trace impurity grounds.

    Continuous Process Improvement—Lessons On The Job

    Every batch we run carries lessons from process upsets, yield shortfalls, and raw material variability. We have upgraded our raw butadiene feed screening to reduce trace inhibitors, and we re-engineered our distillation columns for greater selectivity following a single off-spec incident years ago. Every lab anomaly has pushed us to audit our plant, rebuild valves, or implement stricter traceability protocols. Many times, new customer requirements spark upgrades—epoxy resin producers asked for lower iron content, leading us to overhaul transfer lines and sampling practices. Each improvement becomes part of the baseline for every new batch.

    Years in the field teach what tight specification control means for advanced catalysts, elastomer intermediates, or pharmaceutical precursors using COD. Those hours spent fine-tuning column cut points, monitoring additive-free drums, and fielding late-night troubleshooting calls give us a direct connection to your challenges—a level of insight that template chemical sellers simply cannot match.

    Supporting Sustainable and Responsible Chemistry

    With growing demand for lower-carbon intermediates, our plant invested in energy-efficient heat-exchange systems to recycle energy throughout COD production. By minimizing flaring and controlling emissions at every stage, we can assure end-users that their supply not only meets technical demands but also aligns with stricter environmental standards emerging worldwide. Surplus hydrogen and lighter fractions now go into supporting local fuel streams or other chemical syntheses, minimizing waste by turning every part of the process into a useful product.

    Clients ask more questions these days about lifecycle analysis, not just final product specs. We provide full-chain traceability and routinely host on-site audits, because face-to-face engagement remains the clearest way to build trust. Every synthesis is traceable—you can track the origin, processing, and final shipping date for each shipment, not a spreadsheet abstraction.

    Open Communication With Our Users: Every Spec Tells a Story

    Our relationships with users run deeper than a once-off purchase. Polymer R&D teams have stayed in touch over several product generations, walking us through how even minor changes in COD handling influenced project success. In one case, a research consortium working on next-generation ethylene oligomerization catalysts shared raw kinetic data with us, leading to an entire pilot program to test alternative COD isomer distribution. These partnerships grow from a culture of shared problem-solving—a spirit bred from day-to-day plant operations and trust built through transparent performance.

    On-the-ground input doesn’t just inform product tweaks; it shapes how we prepare and package every lot. Feedback from downstream users—often with process-specific requirements unknown to a general seller—allows us to adapt. For some, it means smaller kegs with special lining; for others, tamper-evident seals and tracked temperature locks in every shipment. Only through regular, direct conversations with plant engineers and chemists do we keep pace with the changing demands of industries that never stop innovating.

    COD Across the Sectors: Unique Demands and Our Response

    Specialty elastomer producers buy COD for crosslinking-intensive processes. If we let residual metals creep in, unwanted scission reactions ruin batch consistency and bump failure rates. Metathesis catalyst fabricators look for reproducibility and minimal side-product formation, with special attention to stabilizer-free supply. Electronics and photopolymer groups require absolute dryness and traceability, since even ppm-level contaminants can interfere with ultra-high-purity downstream reactions.

    Demand from medical polymer and precision coating sectors has driven us to push boundaries for analytical detection and removal of stabilizers, ensuring COD reaches new levels of reactivity control. Each sector brings its own challenges—from new alloys in shipping valves to upgraded gas scrubbers that never make it onto a website data sheet. Our plant evolves under real conditions, not by chasing marketing trends but by solving the daily needs of chemists, engineers, and formulary teams.

    Direct Manufacturing vs. Third-Party Supply Chains—The Real Advantages

    Stories circulate about off-quality COD that cost pilot plants thousands in downtime and lost batches. By holding each stage within our own operation, we prevent common failures: unnoticed tanker contamination, moisture ingress during cross-docking, or gradual isomerization from improper bulk handling. Fielding urgent calls from customers scrambling for compliant product after being let down by third-parties reminds us that our approach—direct, integrated manufacturing—directly protects your projects.

    Every experienced operator knows problems almost never start in the catalog or on the order sheet—they creep in during overlooked transfer steps, unnoticed thermal cycling, or lack of root-cause review. Our hands-on, full-line approach means every part of the chain stays visible, documented, and in our control. Downstream users see it less in words and more in fewer headaches: smoother syntheses, on-time deliveries, transparent quality documentation, and the confidence to undertake challenging scale-up runs.

    The Bottom Line: Proactive Experience Over Transactional Supply

    Building a reputation for consistent COD does not come from abstract guarantees, but from tangible results and practical lessons. Over decades, troubleshooting dozens of types of reactors and responding directly to line workers facing urgent production issues, we have developed not just an understanding of the product but an active partnership with those who use it at the sharpest edge of industry demand. The lessons learned reshape every drum we send out.

    We invite every partner—not just procurement teams but working chemists and engineers—to engage with our technical group, visit our facility, and walk through our process controls. The invitation stands, not as a marketing line but from firsthand belief that open engagement and technical transparency build industries up. In our view, every specification should trace back to a problem solved, a failure avoided, or a success in a customer facility. That’s the real value behind our 1,5-Cyclooctadiene.