Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing admin@sinochem-nanjing.com 3389378665@qq.com
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1,4-Hexadiene

    • Product Name 1,4-Hexadiene
    • Alias Vinylbutene
    • Einecs 203-852-3
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    180027

    Cas Number 592-45-0
    Molecular Formula C6H10
    Molar Mass 82.15 g/mol
    Appearance Colorless liquid
    Odor Mild, sweet odor
    Density 0.673 g/cm³ at 20°C
    Melting Point -119°C
    Boiling Point 78°C
    Flash Point -17°C (closed cup)
    Solubility In Water Insoluble
    Vapor Pressure 141 mmHg at 25°C
    Refractive Index 1.421 at 20°C
    Autoignition Temperature 210°C
    Logp Octanol Water 2.82
    Un Number 2049

    As an accredited 1,4-Hexadiene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 1,4-Hexadiene is packaged in a sealed amber glass bottle, 500 mL, with hazard labeling, screw cap, and tamper-evident seal.
    Shipping 1,4-Hexadiene should be shipped in tightly sealed containers, protected from heat, sparks, and open flames due to its flammability. It must be labeled as a hazardous material and transported according to relevant regulations (such as DOT, IATA, or IMDG). Ensure containers are upright and stored in a well-ventilated area during transit.
    Storage 1,4-Hexadiene should be stored in a cool, dry, and well-ventilated area, away from heat, sparks, and sources of ignition. Keep the container tightly closed and protected from direct sunlight. Store separately from oxidizing agents, acids, and halogens. Use approved flammable liquid storage facilities and ensure proper grounding and bonding when transferring the material.
    Application of 1,4-Hexadiene

    Applications of 1,4-Hexadiene in Industrial Manufacturing

    1,4-Hexadiene serves as a key intermediate across several specialty downstream sectors. Drawing from continuous production and process integration, we address the needs of polymer synthesis, fine chemicals, specialty elastomers, organosilicon products, and agrochemical intermediates. We outline each industrial channel with focus on specification, operational requirements, and regulatory fit.

    1. Polymer Modification in Polyolefin Industry

    Producers use 1,4-hexadiene as a diene comonomer in metallocene or Ziegler-Natta catalyzed polyethylene (PE) and ethylene propylene diene monomer (EPDM) manufacturing. It introduces controlled unsaturation to the polymer backbone, improving crosslinking performance and resilience for cable insulation, automotive seals, and advanced geomembrane sheets. Material selection and dosing reflect melt flow characteristics and molecular weight distribution targets. Our technical teams provide detailed guidance for system compatibility and modern plant integration.

    Industry compliance standards

    • ISO 9001:2015 Quality Management
    • ASTM D3900 (EPDM Rubber Testing)
    • EU REACH chemical registration and authorization
    • RoHS 2011/65/EU for applicable electrical applications

    Typical usage ratio

    • Commonly 2–8 phr (parts per hundred rubber) as a tertiary diene in EPDM blends; fine-tuned based on targeted crosslink density and end-use specification.

    Downstream process integration

    • Incorporation during primary polymerization stage in continuous stirred reactors; monitoring for catalyst compatibility and molecular weight control; inline feeding within nitrogen blanketed environments to prevent premature reaction.

    Final product types

    • High-performance EPDM automotive weather seals
    • Low-voltage cable insulation and sheaths
    • Pond and landfill geomembrane liners
    • Flexible roofing materials

    2. Synthesis of Specialty Elastomers

    Elastomer producers integrate 1,4-hexadiene as a linear diene to engineer customized unsaturated polymer chains, particularly for niche automotive and industrial applications where rubber elasticity, low-temperature flexibility, or chemical resistance is essential. Its use is established in pilot and full-scale elastomer facilities under strict handling and conversion protocols to meet downstream performance grades.

    Industry compliance standards

    • ISO 14001:2015 Environmental Management for rubber manufacturing
    • ASTM D1418 (Standard Rubber Nomenclature)
    • EN 318:2012 (Rubber used in road vehicles)

    Typical usage ratio

    • Ranges from 1–10% by monomer feed weight, adjusted based on polymer backbone structure and target mechanical profiles.

    Downstream process integration

    • Co-polymerized with primary monomers in solution or emulsion systems; monitored for chain transfer effects and minimized gel formation; dosed using automated flow meters to optimize batch reproducibility.

    Final product types

    • Oil-resistant automotive hoses
    • Industrial conveyor belt covers
    • High-end synthetic rubber gaskets
    • Rubber parts for chemical and food handling applications

    3. Organosilicon Intermediate Manufacturing

    Silicone producers use 1,4-hexadiene as a hydrosilylation substrate, enabling synthesis of vinyl-terminated silanes and crosslinkers for the silicone sealant, adhesive, and coating industries. Its straight-chain diene structure allows accurate control of vinyl introduction, supporting targeted reactivity and weathering resistance in final siloxane chemistry.

    Industry compliance standards

    • ISO 10993 for biocompatibility in case of medical silicones
    • US FDA 21 CFR 177.2600 (Rubber articles intended for repeated use)
    • REACH Annex XVII for limiting SVHC in silicone products

    Typical usage ratio

    • Typically 0.5–5 mol% relative to base siloxane resin; determined by final crosslinker content and target cure speed.

    Downstream process integration

    • Reacts with hydrosilane functional siloxane in platinum-catalyzed batch or continuous flow reactors; controlled dosing schedules to maximize conversion and minimize byproduct formation.

    Final product types

    • Silicone RTV sealants for construction and electronics
    • Medical grade silicone elastomers
    • Advanced silicone adhesives
    • Weatherproof industrial coatings

    4. Agrochemical Intermediate Production

    Agrochemical manufacturers select 1,4-hexadiene as a building block for synthesizing key intermediates in plant protection products. Its structure enables functionalization by selective addition or oxidation, forming active moieties for herbicides and fungicides. Upstream integration demands strict process and impurity controls to adhere to regulatory pesticide quality benchmarks.

    Industry compliance standards

    • FAO/WHO Specifications for Plant Protection Products
    • ISO 9001 for agrochemical synthesis
    • EU Regulation (EC) No 1107/2009 concerning the placing of plant protection products on the market
    • China GB/T 1604 for pesticide intermediates

    Typical usage ratio

    • Ranges from 8–18% by mass in multi-step synthesis, adjusted per intermediate yield and downstream conversion efficiency.

    Downstream process integration

    • Involved in early synthetic step as a linear diene feedstock; converted via hydroformylation, epoxidation, or oxidative cleavage; reactor design must manage exothermicity and ensure efficient purification cycles.

    Final product types

    • Selective herbicide intermediates
    • Fungicide precursor molecules
    • Plant growth regulator raw materials
    • Certain insecticide active intermediates

    5. Specialty Fine Chemical Synthesis

    Producers of performance chemicals leverage 1,4-hexadiene for constructing specialty intermediates, such as aliphatic aldehydes or dicarboxylic acids, serving performance coatings, lubricants, and flavor & fragrance synthesis. Strict monitoring over reaction parameters and byproducts ensures precise batch output for high-value downstream integration.

    Industry compliance standards

    • ISO 22716 for fine chemical production principles
    • REACH SVHC compliance for specialty chemicals
    • US TSCA Inventory listing for specialty intermediates

    Typical usage ratio

    • Utilized from 5–20% by mole in multi-step syntheses, variable by reaction scale and chain-length requirement of the target molecule.

    Downstream process integration

    • Introduced during first synthesis step as a diene substrate in controlled hydrogenation, oligomerization, or oxidation reactions; online QC for continuous quality tracking and product isolation.

    Final product types

    • Corrosion inhibitor intermediates
    • Automotive and industrial lubricants
    • Aliphatic specialty aldehydes and acids
    • Flavors, fragrance molecules, and performance additives
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    Certification & Compliance
    More Introduction

    Introducing 1,4-Hexadiene: A Reliable Building Block in Modern Chemistry

    The Craft and Care Behind Our 1,4-Hexadiene

    We've spent years refining the production of 1,4-hexadiene to meet the demands of innovation-driven industries. For manufacturers like us, consistency matters just as much as high purity. Over time, we've learned that small variations in feedstock or process detail leave a big mark on end-use performance. That's why our plant operations prioritize tight control from distillation down to packaging under inert atmospheres. These details transform standard chemical practice into a source of confidence for downstream users.

    Why 1,4-Hexadiene Matters on the Factory Floor

    1,4-Hexadiene isn’t just another monomer. Its molecular structure—six carbon atoms with double bonds at the first and fourth positions—brings a unique set of benefits. The compound serves as a foundational co-monomer in polymer and elastomer synthesis; it unlocks access to specialty plastics and rubber products that need flexibility and resistance in challenging environments. Our customers rely on its two terminal double bonds for precision cross-linking, where alternatives fall short or compromise structural integrity.

    Every batch we produce undergoes rigorous gas chromatography and mass spectrometry checks. These quality measures aren't just routine; every plant operator knows a contaminated batch means failed polymerization reactions or unexplained weaknesses in the final materials. In earlier days, even an overlooked trace of isomeric contaminants or off-ratio residuals could throw off an entire production run for one of our downstream partners.

    Model and Specification: Built on Experience and Customer Partnership

    We manufacture 1,4-hexadiene to a purity of at least 99.5%, with water and inhibitor content closely monitored during every batch. Our principal specification has settled here after years of working with research groups, resin manufacturers, and elastomer plants—feedback from real-world use cases shapes both the spec and the controls on our production line. In logistics, the compound’s volatility and sensitivity to air have required us to adopt packaging in stainless steel drums and returnable cylinders under high-grade nitrogen.

    We don’t stop at batch purity reports. Each order comes with access to decades of process knowledge held by our technical staff, because a successful outcome for you reflects back on us as the manufacturer. Over the years, customers in the automotive rubber sector pointed out early yellowing issues traced back to minute impurities, prompting us to redesign part of our purification train. Real-world feedback, not standards alone, guided those process upgrades.

    Key Uses: From Polymer Science to Specialty Applications

    Where 1,4-hexadiene really proves its worth is in co-polymerization. Chemical processors count on it as a diene source for ethylene/propylene/diene monomer (EPDM) rubbers, chosen for both static and dynamic applications—belts, hoses, weather seals, and more. Its reactivity lets formulators strike the right balance between flexibility, compression set, and weather resistance.

    The compound also steps in for specialty lubricants and intermediates, especially where straightforward linear reactivity dovetails with a customer’s need for low-odor, low-residue formulations. Some of our electronics sector clients request it for silane cross-linkable systems to produce robust, hydrophobic encapsulants. 1,4-Hexadiene earns its place, not just for what it keeps out of a recipe, but for the control it gives over reaction kinetics and finished material properties.

    Differences That Matter: 1,4-Hexadiene Versus Related Compounds

    In the specialty chemicals sphere, one question comes up often: what makes 1,4-hexadiene a better fit than something like 1,5-hexadiene or 1,3-butadiene? The answer goes back to structure and reactivity. 1,4-Hexadiene offers two unconjugated terminal double bonds, making it less likely to undergo unwanted side reactions during polymer modification. This matters for multi-stage processes where side-product formation can introduce color, odor, or stability issues.

    1,5-Hexadiene, another six-carbon diene, has its double bonds on the first and fifth carbons; its different spatial arrangement sometimes gives less predictable reactivity with certain catalysts. 1,3-Butadiene, with its conjugated system, tends to polymerize more readily—sometimes more than a formulator needs or wants—while giving less room for custom tailoring of chain branching. In essence, our customers often tell us that 1,4-hexadiene gives them both control and reliability in complex synthetic pathways where even a small deviation makes a big difference.

    Manufacturing Realities: Challenges and Solutions

    Purity control is just one piece of the challenge. 1,4-Hexadiene is volatile, flammable, and reacts with oxygen to degrade. Safe handling starts at the reactor and extends through filling, storage, and transport. Our team has retrofitted equipment with advanced oxygen exclusion techniques, leak detectors, and rapid shutoff systems, all to maintain strict atmospheric conditions. We invest in regular safety briefings, real-time monitoring, and fail-safes, learned from minor incidents early in our journey that taught us the hard way about the importance of process vigilance.

    Price spikes in feedstock or energy costs sometimes put pressure on our margins, but uninterrupted supply takes priority. We source raw materials with backup agreements and local partnerships to hedge against supply chain disruptions. On rare occasions when cargo shipments stall, our technical sales and logistics staff communicate quickly with clients so they can adjust production schedules.

    The stewardship of hazardous chemicals has evolved. Regulations have tightened over the years, and we've adapted by adopting closed transfer systems and traceability for every lot we ship. In practice, this means our safety and environmental teams work side by side with plant engineers in surveillance and documentation—we see it less as compliance, more as a point of pride in responsible manufacturing.

    Spotlight: Working Directly with End-Users

    Being a manufacturer, we regularly meet directly with process engineers and material scientists, rather than relying on disconnected reports from traders and distributors. Real stories drive our improvements. For instance, a tire manufacturer once approached us to help solve polymerization inconsistencies. Our technical staff visited the site, ran joint trials, and traced a problem to a subtle mismatch in storage temperature. Working together, we recommended cooling protocols and swapped in drums with better insulation, resulting in both parties saving on waste and rework.

    The feedback loop is fast and personal. If an issue arises—unusual color, a faint impurity, or a processing hiccup—our chemists can dig in, test retained samples, and suggest practical fixes without waiting for a chain of approvals and relayed information. This responsiveness remains one of the strengths of working with an actual factory source; technical service, troubleshooting, and problem-solving are woven into our operation, not an afterthought.

    Advancing Sustainable Practice in Diene Chemistry

    Running chemical plants responsibly means balancing output, quality, and impact. We're investing heavily in waste minimization: side streams from our hexadiene production now re-enter other process lines as fuel gas or chemical feedstock, rather than going to incineration. We've also switched to catalyst systems that reduce energy input and allow for easier removal of trace heavy metals, especially as regulatory pressure mounts in both domestic and export markets.

    On the emissions front, we've recently completed studies showing that improvements in vapor recovery from loading stations have slashed VOCs by more than half. This initiative came from our own field teams who flagged inefficiencies and conducted pilot audits right at our facilities. Across the plant, the mindset is to spot problems early—before they turn into compliance headaches or neighbor complaints.

    Creating Value Across Applications—And Listening Closely

    At the heart of our production ethos lies a respect for field realities. Whether a client is scaling new product formulations, troubleshooting elastomer performance, or looking for a drop-in replacement for more hazardous starting materials, 1,4-hexadiene delivers value in its reliability. We design processes in partnership with real users; their needs and ideas spur us to innovate, whether it's shifting to higher-purity drums for microelectronics or choosing inhibitors tailored to specialty grade storage.

    Chemistry evolves with the industries it serves. Our 1,4-hexadiene finds its way into automotive parts, construction materials, and electronics, usually bound up inside high-performance compounds. Sometimes the endpoint is visible in everyday infrastructure; other times, it’s hidden deep inside a multilayer seal or microchip housing. Each application presents its own hurdles and rewards, and our engineering teams work side-by-side with customers to troubleshoot, support, and refine, honing both the chemical and its delivery for every end use.

    Looking Forward: Commitment to Progress

    Decades of manufacturing this building block have shown us that product quality depends on much more than just numbers in a specification table. Technical support, transparent process control, and a willingness to revisit assumptions push our product—and our clients’ results—forward. We draw on real field experience, not just theoretical knowledge, to improve process steps, chemistry, and safety.

    Every kilogram we ship reflects these years of hard work, adaptation, and ongoing learning. The journey has included tough lessons—from equipment failures to small-scale mishaps that prompted sweeping improvements. We continue training new plant staff on every nuance: thorough flushing and cleaning, oxygen monitoring, prompt reporting of small anomalies. Years of shared experience help keep standards high.

    New regulatory frameworks, changing customer needs, and evolving technical demands mean our work is never done. As new generations of products require even tighter tolerances and more demanding properties, we meet these challenges with investment, collaboration, and technical dedication. Our plant teams welcome both the hard questions and the chance to help solve them. For every client seeking reliable, well-supported 1,4-hexadiene supply, we stand ready—with the history, know-how, and hands-on understanding that only comes from being a true, invested manufacturer.