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1,4-Dichloro-2-Butene

    • Product Name 1,4-Dichloro-2-Butene
    • Alias 1,4-Dichlorobut-2-ene
    • Einecs 211-017-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    275810

    CAS Number 110-57-6
    Molecular Formula C4H6Cl2
    Molar Mass 125.00 g/mol
    Appearance Colorless to pale yellow liquid
    Odor Penetrating, chloroform-like odor
    Boiling Point 144-146 °C
    Melting Point -51 °C
    Density 1.181 g/cm³ at 20 °C
    Solubility in Water Insoluble
    Vapor Pressure 6.7 mmHg at 25 °C
    Flash Point 51 °C (closed cup)
    Refractive Index 1.4690 at 20 °C

    As an accredited 1,4-Dichloro-2-Butene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 1,4-Dichloro-2-Butene is packaged in a 500 mL amber glass bottle with a tightly sealed, chemical-resistant screw cap.
    Shipping 1,4-Dichloro-2-butene should be shipped in tightly sealed, labeled containers made of compatible materials, away from incompatible substances such as strong oxidizers. Transport in accordance with applicable local, national, and international regulations for hazardous chemicals. Ensure proper ventilation, avoid heat and ignition sources, and include safety documentation with the shipment.
    Storage 1,4-Dichloro-2-butene should be stored in a cool, dry, well-ventilated area away from sources of ignition, heat, and incompatible materials such as strong oxidizers. Keep container tightly closed and properly labeled. Use corrosion-resistant containers and secondary containment to prevent leaks or spills. Store away from direct sunlight and moisture, and ensure access is restricted to trained personnel only.
    Application of 1,4-Dichloro-2-Butene

    Applications of 1,4-Dichloro-2-Butene in Industrial Manufacturing

    1,4-Dichloro-2-butene serves as a critical intermediate for multiple sectors in chemical manufacturing. As an experienced producer, we supply this material to specialized downstream applications where strict process control, regulatory compliance, and tailored integration into production lines matter for quality and consistency. Below are key industrial uses supported by actual manufacturing practices and documented end-use requirements.

    1. Synthesis of Chloroprene Monomer (for Polychloroprene Rubber)

    Chloroprene production plants utilize 1,4-dichloro-2-butene as a core intermediate to obtain high-purity chloroprene monomer, a precursor for polychloroprene rubber. The process relies on precise conversion in the presence of specific catalytic systems, governing both product purity and reaction efficiency critical for consistent rubber characteristics. Strict monitoring ensures contaminant-free intermediates for downstream polymerization.

    Industry compliance standards

    • ISO 9001-certified quality systems for specialty elastomer feedstocks
    • Compliance with REACH Regulation (EC) No 1907/2006 for dangerous substances
    • Certified under European Chemicals Agency (ECHA) SVHC guidelines where required
    • Adherence to China GB/T 21868 (synthetic rubber production standards)

    Typical usage ratio

    • Used as a main intermediate, typically 1.0–1.2 tons per ton of chloroprene output
    • Ratios adjusted for catalyst type, desired monomer purity, and hydrogen chloride selectivity

    Downstream process integration

    • Enters dehydrohalogenation reactors as fresh feedstock
    • Reacted under controlled pH and agitation to yield chloroprene
    • Residual by-products removed by solvent extraction and phase separation units
    • Integrated online analytical QC to monitor conversion rates before monomer purification

    Final product types

    • Polychloroprene rubber grades for belts, hoses, sealing components, industrial adhesives
    • Specialty copolymer rubbers for oil-resistant and flame-retardant profiles
    • Performance elastomer latex used in construction and automotive sectors
    • High-impact rubber for vibration-damping applications

    2. Raw Material for Agrochemical Synthesis

    Agrochemical synthesis plants employ 1,4-dichloro-2-butene as a chlorinated building block in the preparation of pesticide intermediates, especially for selected herbicides and fungicides. The controlled reactivity profile enables direct halogen substitution reactions, facilitating precise introduction of target groups required for biological activity. Batch production mandates traceability from raw material to formulated product.

    Industry compliance standards

    • Adherence to FAO/WHO Codex Alimentarius for pesticide ingredient production
    • China GB 2763-2021 (MRL for pesticide residues in food)
    • ISO 9001 and ISO 14001 for traceable, environmentally responsible manufacturing
    • Compliance with EPA TSCA Inventory listing for active pre-manufacture notifications (PMNs)

    Typical usage ratio

    • Typically 0.8–1.5 tons per ton of final agrochemical intermediate, adjusted depending on desired functional group substitution pattern
    • Conversion efficiency and selectivity factors influence actual dosage

    Downstream process integration

    • Dosed at halogenation or alkylation stage in batch reactors
    • Participates in nucleophilic substitution with specific functional groups (amines, alcohols)
    • Reaction endpoint monitored by chromatographic purity analysis prior to crystallization
    • Spent residues managed under closed-loop solvent recovery to comply with discharge rules

    Final product types

    • Herbicide active substances (e.g., chlorinated aliphatic chain intermediates)
    • Fungicide pre-products for on-site synthesis of protective crop agents
    • Custom pesticide intermediates for downstream formulation plants
    • Pre-registered fine chemical blocks for seed treatment and soil application

    3. Precursor in Pharmaceutical Intermediates

    Pharmaceutical API manufacturers use 1,4-dichloro-2-butene in the synthesis of specialty heterocycles and active ingredient intermediates under tightly regulated GMP environments. The material supports halide introduction reactions that form part of multi-step syntheses leading to antineoplastic, antifungal, or cardiovascular compounds. Pharmaceutical production demands full batch records and impurity control aligned with pharmacopeial requirements.

    Industry compliance standards

    • Complies with ICH Q7 GMP for active pharmaceutical ingredient manufacturing
    • EMEA and US FDA cGMP 21 CFR Parts 210/211 for APIs and intermediates
    • Testing against Ph. Eur. and USP monograph impurity profiles for starting materials
    • Chinese Pharmacopoeia (ChP) listing for permitted manufacturing aids

    Typical usage ratio

    • Integrated as 0.5–2.0 molar equivalents, depending on synthetic route steps and substitution density required
    • Exact charge determined per validated process protocol and yield optimization

    Downstream process integration

    • Introduced in nucleophilic haloalkylation reactions during stepwise synthesis
    • Extensively monitored for carryover and residual halide content in purification steps
    • Interfaced with batchwise or semicontinuous reactor chains
    • Handled under pharmaceutical-grade material transfer protocols with full traceability

    Final product types

    • Alkylated heterocycle intermediates for oncology APIs
    • Intermediate blocks for antifungal or anti-infective formulations
    • Pyridine and piperidine series precursors in cardiovascular drug synthesis
    • Chlorinated fine chemical compounds for specialty drug discovery work

    4. Crosslinking Agent in Specialty Polymer Manufacturing

    Specialty polymerization facilities adopt 1,4-dichloro-2-butene as an efficient crosslinking agent, particularly during the production of high-performance plastics and gels. The controlled addition of the dichloro component ensures tailored network structures, modulating end-use polymer flexibility and chemical resistance. Operators maintain rigorous process control to synchronize dosing with time-temperature conversion profiles.

    Industry compliance standards

    • ISO 9001 and ISO 14001 for specialty resin production and emissions management
    • REACH Annex XVII restrictions for polymer additives where applicable
    • Registration with TSCA for all functionalized intermediates supplied to US customers
    • Compliance with GB/T 20103-2021 for plasticizer and crosslinking component material quality

    Typical usage ratio

    • Blended at levels of 0.5%–4.5% weight fraction of total polymer mass, adjusted for required crosslink density or mechanical property targets
    • Optimized for chain length and molecular weight of the primary polymer matrix

    Downstream process integration

    • Metered directly with primary monomers during extrusion or casting
    • Homogenized by in-line static mixers or batchwise in pre-polymerization vessels
    • Crosslink initiation triggered by thermal or UV processes following uniform dispersion
    • Process QC correlates additive dose rate to end-use tensile/elongation properties

    Final product types

    • Heat- and chemical-resistant specialty plastics for electrical insulation and gaskets
    • Flexible gels for healthcare and cosmetic packaging
    • Network polyolefin composites for automotive and aerospace interiors
    • Advanced printable resin systems for industrial 3D printing

    5. Intermediate for Organic Synthesis in Fine Chemicals

    Fine chemical producers rely on 1,4-dichloro-2-butene as a versatile synthetic intermediate in the production of diverse aliphatic and aromatic derivatives. Its use streamlines the introduction of dichloro functionality or backbone modification in custom molecule synthesis. Rigorous process documentation and closed-system handling prevent contamination and enable downstream certification for customer-specific needs.

    Industry compliance standards

    • ISO 9001 quality management for fine chemical synthesis
    • REACH compliance for registration, evaluation, and authorization in the EU market
    • Adherence to TSCA for US import/export of downstream chemicals
    • China GB/T 16483-2008 (Material Safety Data Sheet compliance for chemical agents)

    Typical usage ratio

    • Engaged at 0.2–1.0 equivalents per molecule, specific to the end-group arrangement and substitution strategy
    • Adjusted based on reaction selectivity, desired purity, and subsequent functionalizations

    Downstream process integration

    • Added at alkylation or chlorination stages in multi-step batch syntheses
    • Reacted with nucleophiles, Grignard reagents, or organometallics for custom building block creation
    • Automated batch dosing with phase separation for product isolation
    • Yield optimization through in-process chromatographic controls and impurity tracking

    Final product types

    • Custom aliphatic and halogenated intermediates for advanced manufacturing
    • Building blocks for pigments, UV stabilizers, and crosslinking agents
    • Performance additives for petrochemical blending
    • Precursor compounds for pharmaceutical, agrochemical, and specialty material synthesis
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    Certification & Compliance
    More Introduction

    Exploring 1,4-Dichloro-2-Butene from a Manufacturer’s Perspective

    Direct from the Factory Floor: The Value of 1,4-Dichloro-2-Butene

    Standing on a chemical plant floor, the day starts with reviewing tanks and flow lines, not with generic product codes or spreadsheets, but by understanding how real, working chemistry sustains countless jobs and innovations. 1,4-Dichloro-2-Butene, often abbreviated as 1,4-DCB or DCBE, comes up repeatedly in production meetings because it’s both versatile and foundational for several key processes in manufacturing. Every shipment we prepare comes with the assurance that what’s inside the drum has been made with hands-on care, because this compound’s performance downstream traces directly back to its quality at the source.

    What Sets 1,4-Dichloro-2-Butene Apart in the Market

    The character of 1,4-Dichloro-2-Butene isn’t just about molecules and bonds. We see it as a collection of opportunities for users in various sectors, from specialty rubber to pharmaceuticals and advanced materials. Its molecular structure, featuring chlorine atoms on the ends of a butene backbone, gives it properties that you simply won’t find in more common analogs such as dichloroethene or trichloroethane. Its reactivity and selectivity let our customers reach product yields and purity that other intermediates just can’t match.

    Many users come to us after running into strict color, odor, or impurity limitations with other suppliers. Our direct control over the entire synthesis pathway, starting from raw feedstocks straight through purification and stabilization, allows us to troubleshoot in real time. You can trace every drum of 1,4-DCB back through in-house QA, with batch data compared against the benchmarks set by our lab techs who know every bump and phase of the distillation. The finished product is a clear, mobile liquid, usually with a high level of consistency between batches. This isn’t accidental—it’s what happens when a manufacturer obsesses over every pressure, temperature, and catalyst ratio.

    How the Right Model and Specs Matter to Real-World Operations

    In on-site dosing systems, purity changes everything. For 1,4-Dichloro-2-Butene, we run spec sheets daily with particular attention paid to assay by GC, water content, and color. A full batch can turn in the reactor if impurities creep up, so we push purification hard. Typical parameters from the factory include assay (content) minimums above 98%, water below 0.2%, and color values measured against market standards. By setting these specs, we shape outcomes for our downstream partners’ polymerizations, addition reactions, and specialty syntheses.

    Unlike many other dichloro compounds distributed as generic bulk chemicals, ours hits the dock with tightly controlled stabilizer content. The stabilizer is not just an afterthought—it’s the difference between a stable product and a runaway chain reaction mid-transport. We balance inhibitor levels based on the customer’s particular final application, especially for customers who run continuous or high-shear reaction systems. Supply connections aren’t anonymous here; we spend time talking through needs and throughput, adjusting specs where viable for those pushing extremes of pressure or temperature.

    Key Applications Beyond the Basics

    The most common market for 1,4-DCB is as a core intermediate for synthetic rubbers—especially polychloroprene rubber, which offers oil and weather resistance and holds form under heat. Those who make adhesives, automotive parts, and wire coatings see daily how one molecule can lay the foundation for safe, reliable products. Our material runs through these plants because plant managers have learned by trial that a minor slip in feedstock purity means machines down or a whole batch lost. Experience leads to loyalty, and every drop counts when compounded into end products.

    Lesser-known but growing uses of 1,4-DCB show up in pharmaceuticals and active ingredient synthesis. Certain specialty heterocycles and advanced agricultural actives need very specific alkylation and substitution reactions where this molecule outperforms its cousins thanks to its two chlorine handles located just right for selectivity. As a manufacturer, it’s a point of pride when chemists in labs ask for 1,4-DCB by name due to reactivity profiles, not just availability.

    Comparisons with Related Chlorinated Compounds

    Discussions in the chemical world often group similar sounding molecules together, but for those of us who make and use them, the differences are real and tangible. 1,4-DCB stands distinctly apart from dichloroethene (DCE) and dichlorobutene isomers because of the position of its double bond and terminal chlorines, which drive its chemical reactivity and selectivity in addition reactions. Our customers in polymer synthesis report that, unlike DCE, which too easily forms by-products, tailored conditions around 1,4-DCB give higher yields, fewer unwanted side reactions, and cleaner product isolations with less need for extra purification steps downstream.

    A direct example surfaces in the choice between 1,3-dichloropropene and 1,4-dichloro-2-butene for specialty intermediate manufacture. The former works for bulk agrochemical syntheses, but once fine details such as regiochemistry and safety under heat come to the fore, 1,4-DCB wins out. In-house, we control for unwanted tars and by-products—issues that plague less selective dichloro compounds—by obsessively tweaking every reactor condition and refining feedstocks before the main reaction even begins.

    Linking Production Integrity to End-Use Safety and Trust

    Every chemical plant audit or standards review reminds us: customers judge quality with more than numbers. Trace metals or residual solvents—even in ppm—can change how a final product behaves under stress, UV, or heat. For 1,4-DCB it’s not just meeting an assay threshold, but watching for persistent organics and micro-level inorganic contamination. Our integrated approach makes the difference. Technicians monitor each lot before shipment, while QA teams run retention samples up to 12 months out to spot and head off oxidative degradation or stabilizer breakdown. The results aren’t only for paperwork; they cut real-world costs for our partners by reducing off-spec events.

    For instance, in elastomer plants that draw from our tanks, operators have built entire cleaning and changeover protocols around the predictability of 1,4-DCB’s spec, trusting that a known chlorine content will play nicely with their recipes batch after batch. Any surprise, like low-level impurities shifting catalyst activity, kills productivity or even causes shutdowns. We learn every season from user feedback, and keep control over ingredient sourcing, not just final inspection, so there’s a direct line from the raw material order to the product flowing out the door.

    How Direct Manufacturing Shapes Product Consistency and Cost Control

    Back in our control rooms, a lot of time goes to managing gas–liquid phase feeds and cycle times so every run of 1,4-DCB matches what was made the month before. As a direct manufacturer, we don’t simply tweak what comes in—we set the entire production timetable, pick equipment maintenance windows, and shift inputs if global supply changes. The difference for our customers is predictability not just in quality, but in finished cost. By running high-efficiency batch and continuous reactors, then downstream distillation to tight cuts, we save on energy, reduce waste, and pass along that efficiency in every quote.

    No batch goes out untraced. We store detailed records, keep reference samples, and revisit them if a partner calls about an unexpected result six months later. Data from these archives doesn’t sit in the digital dark—process engineers analyze yield losses and by-product evolution to further tighten specs for future runs, creating a cycle of continuous improvement. This approach directly benefits every end user who can't afford uncertainty in critical manufacturing steps.

    Supporting Environmental and Regulatory Compliance from the Start

    Very few departments care about regulatory compliance more than a factory that directly handles bulk chlorinated intermediates. For 1,4-DCB, evolving environmental benchmarks drive plant practices—VOC emissions, wastewater chloride content, and off-gas scrubbing. Our team spends time with regulators, but also anticipates their next round of rules, so we invest in solvent recovery, closed-loop wash cycles, and gas treatment that doesn’t just tick boxes but reduces long-term costs and community impact.

    Many customers now ask about GHS, REACH, and any similar standards, so batch records always include hazard labeling, safety data, and compliance tracebacks. We see more emphasis on questions around sustainable production and safe disposal, so our answer is to invest in process controls that limit emissions at the source, not just in end-of-pipe treatment. For instance, we’ve designed the recovery phase to capture and reuse spent solvent rather than continuously draw in fresh, aligning our operations with green chemistry goals and the evolving sustainability outlook of our clients. Teams across the company know their decisions on reactor parameters have a ripple effect, seen in compliance audits by customer EHS officers months or years after the product has shipped.

    Challenges Unique to the Source: Handling, Safety, and Customer Education

    Serious discussion about 1,4-DCB never skips over safety. Ask any operator: leaks, off-gassing, or minor mishandling turns a routine barrel transfer into an incident report. Chlorinated alkenes have volatility and toxicity considerations that require attention, so we design plant layouts and drum packaging for robust containment and safe handling. Every technician receives specific training in transfer procedures and emergency response.

    We frequently host clients at our site or join their teams in training. Customers with new personnel benefit from these exchanges. These sessions go beyond slide decks, moving into real-world tips: how to check drum temperatures, how to regulate nitrogen blankets, and when to check inhibitor levels before use. Handing knowledge directly from plant to customer means fewer surprises, safer workplaces, and more predictable business for every link in the chain.

    Why Downstream Innovators Pick True Manufacturers

    In an age of global supply webs and anonymous trading desks, going straight to a chemical manufacturer for 1,4-DCB secures key advantages that compound over time. Our history with longtime customers shows that close relationships mean agile responses. During a global shipping crisis, production delays ripple across the globe—but we found solutions by shifting delivery modes, drawing on on-site storage, and prepositioning reserve batches so core industries didn’t stop even as logistics faltered. Reliability in products cultivates trust across the supply chain.

    There’s also the benefit of ongoing, two-way technical dialogue. When customers aim to increase production yield, lower costs, or introduce new grades, our technical and production teams engage to share insights. Sometimes it means tweaking stabilizer levels or collaborating on custom drum sizes to reduce in-plant transfer losses. Our role grows from that of a mere supplier to an R&D partner—solving issues as they arise rather than reacting to them down the line.

    Future Directions for 1,4-Dichloro-2-Butene: Innovation in Manufacturing and Use

    The roles played by 1,4-DCB are changing under the push for sustainable chemistry, advanced materials, and greener synthesis. Plant engineers see pressure to lower process temperatures, automate real-time impurity checks, and trim chlorine loads without sacrificing the cost-effectiveness or performance customers demand. Our own pilot projects now look at intensified reactor setups, where output scales up while energy use drops, and smarter catalyst cycles enhance selectivity so our compound remains preferred in both legacy and emerging markets.

    Some customers request advanced technical support for their R&D. Drawing from in-house expertise, we guide adoption of 1,4-DCB in new reaction paths—whether that’s to create emerging elastomers, specialty agrochemicals, or intermediates for electronic materials. Our technical managers routinely collaborate to scale up custom syntheses from lab beaker through pilot plant to commercial output, identifying potential pitfalls tied to feedstock quality, reactor fouling, or exotherm control.

    Basing Supply Decisions on Real-World Experience

    Choosing a direct manufacturer for 1,4-DCB means weighing years of operational learning, field feedback, and process optimization against simple cost or availability. Many customers who switched to our plant after stints with generic distributors describe a new level of confidence—not just in product quality, but in their ability to troubleshoot, scale up, or introduce new grades without unknowns. That trust isn’t built on flashy branding or marketing language; it comes from years of joint problem-solving and shipment traceability.

    What sets companies apart isn’t only the final product—it’s the expertise gained batch by batch, the quiet investments in QA, and the willingness to adapt production lines to suit evolving customer goals. In weight, volume, and purity, our product meets the spec, but in partnership and knowledge, we deliver much more. Customers facing changing legislation, supply volatility, or new regulatory demands benefit from this approach, because we navigate their needs as our own.

    Bringing It All Together: The Role of the Manufacturer

    Manufacturing 1,4-Dichloro-2-Butene goes beyond molecules and drums; it’s a trust-based process spanning engineers, technicians, buyers, and end users. Each decision—whether in raw material sourcing or reactor settings—feeds directly into customer outcomes. The difference that comes from having an integrated production model isn’t abstract: it means hands-on control, real traceability, and the ability to adjust as markets, supply chains, and regulations shift.

    Customers relying on 1,4-DCB benefit from quality measured by more than a spec sheet, built on years of craft, feedback, and continuous learning. The old phrase that “the devil is in the details” holds especially true in chemical manufacturing, where seemingly minor choices in purification or stabilization result in major outcomes downstream. Expectation isn’t merely about a drum on a pallet; it’s about building materials and relationships that endure through cycles and crises, shaped by experience from those closest to the process.

    As we look forward, that’s the core of our message: direct manufacturers, with deep roots in hands-on production and supply chain resilience, shape not only what goes into a product, but how that product shapes everything it touches, from the plant floor to the finished application.