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HS Code |
439835 |
| CAS Number | 108-45-2 |
| Molecular Formula | C6H8N2 |
| Molecular Weight | 108.14 g/mol |
| Appearance | White to pale yellow solid |
| Melting Point | 63-66°C |
| Boiling Point | 256°C |
| Density | 1.14 g/cm³ |
| Solubility in Water | Soluble |
| Odor | Ammonia-like |
| Flash Point | 113°C |
| Synonyms | Meta-phenylenediamine, m-Phenylenediamine |
| pKa | 4.1 and 7.6 |
| Refractive Index | 1.644 |
| Vapor Pressure | 0.004 hPa at 25°C |
| EC Number | 203-584-7 |
As an accredited 1,3-Phenylenediamine factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Brown glass bottle containing 500 grams of 1,3-Phenylenediamine; labeled with hazard warnings, batch number, and chemical details. |
| Shipping | 1,3-Phenylenediamine should be shipped in tightly sealed containers, clearly labeled, and protected from moisture, heat, and incompatible substances. It is classified as a hazardous material, requiring compliance with relevant transportation regulations (such as DOT, IATA, or IMDG). Use appropriate personal protective equipment when handling containers during shipping. |
| Storage | 1,3-Phenylenediamine should be stored in a tightly sealed container in a cool, dry, well-ventilated area away from sources of ignition, heat, and incompatible substances such as strong oxidizing agents and acids. Protect from moisture and light. Store away from food and drink. Proper labeling and containment are essential to prevent contamination and accidental exposure. |
Applications of 1,3-Phenylenediamine in Industrial ManufacturingWe supply 1,3-Phenylenediamine for use in specialized industrial processes, supporting advanced manufacturing sectors with consistent, specification-driven quality. The following application scenarios illustrate its critical role across select downstream markets with focused regulatory and technical demands. 1. Oxidative Hair Dye Intermediates for Professional ColorantsIn the cosmetic industry, 1,3-Phenylenediamine functions as a primary intermediate for permanent hair coloring, where its chemical structure enables the development of a wide range of tones and shades through oxidative coupling. Major producers of salon and retail hair dyes require precision in precursor quality and process parameters to deliver stable, predictable color development and meet consumer safety regulations worldwide. Industry compliance standards
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2. Epoxy Resin Curing Agents for Industrial Coatings1,3-Phenylenediamine is integrated as a hardener in advanced epoxy systems, where its aromatic diamine functionality allows for controlled cross-linking in protective coatings exposed to chemicals, abrasion, and thermal cycling. Coating formulators rely on this curing agent to achieve target mechanical and endurance properties, especially for industrial-grade flooring, piping, and storage tank protection in regulated sectors. Industry compliance standards
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3. High-Performance Polyamide Engineering PlasticsDownstream polymerization plants use 1,3-Phenylenediamine in the synthesis of specialty polyamides (e.g., para-aramid fibers and copolyamides), where its meta-linked diamine structure imparts a balance of chemical resistance, heat stability, and dimensional integrity. Formulation and polymerization controls are tightly specified to meet application-specific material standards in demanding engineering environments. Industry compliance standards
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4. Rubber Antioxidant Intermediate for Industrial ElastomersThe manufacture of advanced rubber antioxidants employs 1,3-Phenylenediamine as a key precursor for high-activity antidegradants. Its chemical framework, after targeted alkylation or condensation, provides downstream tire and industrial rubber plants with stabilizers able to withstand ozone, heat, and mechanical fatigue, thus helping maintain compliance with international quality and safety requirements. Industry compliance standards
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5. Dye Intermediate for High-Fastness Synthetic FibersTextile dye manufacturers use 1,3-Phenylenediamine as a core building block for azo and anthraquinone dyes, critical for producing colorants with outstanding fastness for nylon, polyester, and blended textile yarns. Process chemists maintain precise control over condensation, coupling, and purification steps to ensure pigment performance and regulatory acceptance in apparel and industrial textile sectors. Industry compliance standards
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Every batch of 1,3-Phenylenediamine, also known as meta-phenylenediamine, reflects years of deliberate fine-tuning. Our plant runs at the intersection of careful chemical control and the demands of high-volume industry. Model PPD-13, running purity at a minimum of 99.5%, has become the anchor of our output. Through our experience, two factors bring the real difference: unwavering consistency and zero short-cuts on purification. Meeting that margin does not come easy, yet for us, quality doesn’t bend for convenience.
1,3-Phenylenediamine enters the line as an off-white to light grey powder. Over time, we’ve developed separation steps that leave behind the nitro aromatics that often dog lower-spec competitors. Impurities introduce noise into end application—one reason we treat purification as more than an afterthought. Year after year, that’s what keeps end-users coming back for the predictable responses this chemical brings to their formulations.
Nothing about this compound feels theoretical. The drive to create high-value polymers drives our largest year-on-year production spikes. When users in the aramid polymer or epoxy curing industries put in their requirements, they calculate based on lived experience. In aramid fiber synthesis, the presence of unwanted by-products, even at small concentrations, means mechanical properties take a clear hit. Those fibers start to lose their edge in strength, abrasion resistance, and thermal stability. Our production team tracks historical performance data not to fill a report, but to flag shifts long before they bloom into problems.
We keep a sharp eye on the dye and pigment sector as well. 1,3-Phenylenediamine brings sharp shades and permanence, important for everything from textile colorants to hair dyes. Consistent melting point—measured batch by batch just before lines open—and controlled moisture content mean no clumping, no color shifts, and no unexplained sediment. Any hint of instability shows fastest in this sector, so our chemists run advanced chromatography, verifying purity across every production run.
In corrosion inhibitor manufacture, another layer of 1,3-Phenylenediamine properties comes into play. Here, it’s not about color or physical performance. Instead, predictable reactivity and consistent purity shape product shelf life and downstream handling. Over time, we’ve learned which impurities cause batch failures and which sneak through less rigorous approaches. Our controls reflect hard-won lessons in both.
There’s a reason we press hard for better handling standards than what get published in generic guidelines. Dust control at the charging hoppers comes from bitter experience—a dust collector might look like optional expense, right up until the day a batch sees contamination or a worker takes a risk. We add extra filtration and precisely measure water content as the compound heads into final drying. Among the dozens of specialty aromatic amines we manufacture, 1,3-Phenylenediamine presents the tightest controls for airborne particulates and moisture migration.
A plant making 1,3-Phenylenediamine can’t afford breakdowns. Our lines run closed-loop, constantly cycling small samples to analytical suites. Teams rotate in six-hour shifts to keep nothing left behind with assumption, not measurement. Sulfate ions, which can sneak in from incomplete washing, receive extra attention since they can poison catalysts in downstream synthesis.
Most of our shifts have seen older batches from less controlled environments: the dust caking, the residual nitro smell, the higher iron content from corroded equipment. We back-traced those issues to weak process steps—something you fix only by investing in upgraded reactors, new filter media, and robust operator training.
Among phenylenediamines, each isomer paves a unique road for performance and handling. The 1,2- (ortho-) isomer grabs attention in rubber antioxidants, but the spacing of amine groups leaves it less useful where crosslinking or high-temperature strength matters. 1,4- (para-)phenylenediamine goes for the starring role in para-aramids, but in applications asking for tailored flex and crosslink density, 1,3- is the right choice. That m- bridge gives it different reactivity and allows polymers to gain a balance of rigidity and flexibility—a sweet spot for certain aramid fibers, resins, and epoxy systems.
Side-by-side, end-users looking for consistent, moderate basicity and manageable reactivity find their answer here. The ortho- variant often brings unwanted color or stability questions, especially in dye manufacture, where the 1,3- isomer’s chemical footprint reduces the risk of by-product coloration. Our analytical line-up spends most of its time ensuring the isomer profile on each shipment leaves no doubt about what’s inside every drum.
Each kilo carries dual stories: performance at scale and responsibility in handling. The amine groups in 1,3-phenylenediamine remain reactive and present risks different from less reactive aromatics. Many workers recall the old approach—loosely capped drums and open transfer. The cost of cleanup and exposure—plus downstream failure—taught us to insist on sealed charging systems, closed transfer, and clear labeling that prioritizes safety for everyone in the chain.
Exposure to airborne dust or skin contact draws real consequences. We see gloves and sealed eyewear as part of standard gear every shift. Our environmental controls have grown stricter: reaction waste routing through neutralization, rigorous air scrubbers, and regular filter change-outs to protect both operators and surrounding communities. These costs may not appear in specification sheets, but they drive customer trust and regulatory compliance.
A side discussion always revolves around responsible sourcing. The aromatic raw materials we use stick to chains with clear traceability, avoiding supply blips and ethical concerns down the line. Years of working with regulators taught us: shortcuts always resurface, whether as lost business or heavier fines. Responsible waste stream management, leak detection, and periodic audits close the loop, making sure our obligations last well beyond product delivery.
Over recent years, we’ve seen raw material jumps, tightening environmental restrictions, and up-and-down demand curves. Older methods of synthesis once hinged on less controlled nitration and reduction, but newer regulatory scrutiny forced every manufacturer to tighten process controls. We welcomed the shift, anticipating that lower effluent volumes, tighter impurity removal, and safer work environments would mean better margins in the long haul. Early adopters—ourselves included—learn that every tweak pays back in reputation when users see their products outperform.
Resulting waste streams from 1,3-phenylenediamine synthesis used to bring headaches. The effort put into on-site neutralization and residue minimization came from both regulatory necessity and practical savings. Current systems sink more capital in automated waste handling and closed monitoring, still the cost recoups when compliance equals uninterrupted production and lower cleanup. We measure exactly where waste reduction strategies directly impact the plant’s bottom line: fewer production stops, fewer unexpected maintenance cycles, and stronger resource efficiency.
Storage presents its own challenge. Even minor fluctuations in temperature or humidity play havoc in maintaining a free-flowing powder. Forklift drivers and warehouse teams know hardened lumps and caking translate to wasted material and extra work. We take storage climate control seriously—not just as an afterthought, but always logged, monitored, and inspected.
Some batches move to customers in fiber drums, others in high-integrity bags, always with double sealing and tamper-evident features. We devote attention to every handoff, using real data from internal audits to flag repeated causes of loss. The lessons here add up over years: even a small rise in water content, picked up in poorly managed shipping or storage, can show up as a risk to downstream product performance. Our investment in predictive analytics paid off by highlighting high-risk nodes before they cause measurable loss.
We field as many requests for product data as for technical support, but the real key to strong supply relationships comes from listening during complaint investigations. Years ago, a major coatings manufacturer suffered recurrence of patchy coverage and blamed their process. Review of our supply isolated a rare uptick in iron content; root cause analysis pushed us to overhaul filtration media ahead of schedule. That event set a cultural norm in-house: every customer claim turns into a deep-dive, always ending in process refinement and tighter data tracking.
We resist the temptation to cut corners on documentation or leave customers in the dark. Material movement logs, purity certifications, and a history of deviation investigations serve as real tools for dialogue. Custom grades do not come from guesswork, but from documented change control and risk review, honed with years spent learning exactly what each end-user process demands from our raw materials.
The cycle repeats—feedback from end-users reveals where batch-to-batch consistency matters, or where a specific impurity profile collides with a new product launch. Our approach gives their teams a say in product development. New test protocols grow out of problems faced in application, not a theoretical spec. By running pilot lots and field-testing alongside customer R&D groups, we deliver more than just chemical: we deliver reliability and a track record of shared success.
Continuous improvement meetings aren’t just management buzzwords. Shopfloor feedback loops and open-door policies create the fastest access to issues before they swell into production losses. Operators report clumping, odor shifts, or color inconsistencies instantly; data logs and trend analysis pull answers as soon as small changes surface. Each quarter, a cross-section of production, warehouse, and technical support reviews live cases and sources long-term fixes. Repeat issues get tackled with operator retraining, mechanical upgrades, or, if required, complete overhaul of upstream purification.
Workforce culture means more than compliance paperwork. Continued technical training, safety refreshers, and daily stand-up briefings set the tone for responsible stewardship of both plant and product. Any slip in standards leaves trailing impacts: we’ve learned the cost of ignoring small leaks, skipped calibrations, and outdated supplier certificates. Plant teams take ownership at every level, placing pride in every outgoing batch.
Laboratory teams work next to production and logistical experts, feeding back what new polymer chemistries and performance trends will drive technical change. With growing interest in lightweight composites and green chemistry, we invest in finding routes to lower-emission production and more robust recycling of off-spec materials. The research does not stand alone from actual production: process engineers, shift leaders, and technical liaisons feed insights to R&D daily.
We see shifts in global demand, with Asia-Pacific regions growing their need for aramid fibers and specialized epoxy systems. Our forward planning means integrating market signals into plant scheduling, capital planning, and resource allocation. While competitive price points matter, history and demonstrated reliability stand as greater markers of success in volatile markets.
Emerging downstream uses—specialty elastomers, battery technology, performance coatings—challenge us to adapt production and analysis beyond traditional boundaries. Close partnerships with universities and commercial labs give us early warning of regulatory or technical shifts, so we tweak formulations, test alternate purification cascades, and trial advanced monitoring hardware. Incremental gains in energy efficiency and resource circularity benefit both our operations and customer reputations.
Through years behind the control panel and countless loading dock conversations, we’ve embraced the reality: consistent, reliable, and conscientious 1,3-Phenylenediamine supply rests on thousands of small, deliberate choices. Every step from raw material intake through shipment inspection becomes a checkpoint, managed by operators who know the cost of missed detail.
For every ton that ships from our facility, an unbroken thread links it to design meetings, customer feedback, operator initiative, and the simple daily habits that guard quality. We build trust not through claims, but through stability our customers measure for themselves, in application, experiment, and performance. That confidence, earned across decades, shapes every bag, drum, and unit of 1,3-phenylenediamine that leaves our floor.