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1,3-Cyclopentadiene

    • Product Name 1,3-Cyclopentadiene
    • Alias Cyclopentadiene
    • Einecs 204-025-1
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    102216

    Cas Number 542-92-7
    Molecular Formula C5H6
    Molar Mass 66.10 g/mol
    Appearance Colorless liquid (often yellowish due to impurities)
    Odor Pungent, strong odor
    Boiling Point 42 °C (108 °F)
    Melting Point -93 °C (-135.4 °F)
    Density 0.802 g/mL at 25 °C
    Solubility In Water Insoluble
    Vapor Pressure 132 mmHg at 20 °C
    Flash Point -17 °C (1.4 °F)
    Refractive Index 1.456 (at 20 °C)

    As an accredited 1,3-Cyclopentadiene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The 1,3-Cyclopentadiene is packaged in a sealed 500 mL amber glass bottle with hazard labels and safety information clearly displayed.
    Shipping 1,3-Cyclopentadiene should be shipped as a hazardous chemical, complying with relevant transport regulations (such as DOT, IATA, or IMDG). It must be packed in sealed, clearly labeled, approved containers to prevent leaks and exposure. Store away from heat, ignition sources, and incompatible materials. Appropriate documentation and hazard labels are required.
    Storage 1,3-Cyclopentadiene should be stored in a cool, dry, and well-ventilated area, away from heat and direct sunlight. Store in tightly sealed containers under an inert atmosphere such as nitrogen, as it polymerizes readily at room temperature. Keep away from acids, oxidizing agents, and sources of ignition. Refrigeration is recommended to minimize dimerization and maintain stability.
    Application of 1,3-Cyclopentadiene

    Applications of 1,3-Cyclopentadiene in Industrial Manufacturing

    1,3-Cyclopentadiene finds core utility in specialty chemical synthesis, advanced polymer production, high-performance resin manufacturing, agrochemical intermediates, and specialty adhesive formulations. As an original manufacturer, we serve process industries that require consistent quality, defined specification control, and compliance with international manufacturing guidelines.

    1. Dicyclopentadiene Resin Synthesis

    1,3-Cyclopentadiene is an essential feedstock for dicyclopentadiene (DCPD) resin production. Many resin plants use the material for high molecular weight intermediates, required in specialty unsaturated polyester resins and high-gloss coatings. The raw material undergoes controlled dimerization and purification to yield resin-quality DCPD in closed systems with continuous monitoring of conversion ratios and side reaction management. Consistency in the input material specification directly impacts final resin clarity, heat resistance, and adhesion performance.

    Industry compliance standards

    • REACH Regulation (EC 1907/2006) for petrochemical intermediates
    • ISO 9001:2015 quality management in chemical synthesis
    • RoHS for electrical/electronic indirect contact restrictions
    • ASTM D4427 for unsaturated polyester raw materials

    Typical usage ratio

    • 90–98% 1,3-cyclopentadiene input based on desired DCPD output
    • Adjusted for molecular purity (typically >95%) and reaction yield efficiency
    • Small fraction of inhibitor (<0.1%) added to manage dimerization rate

    Downstream process integration

    • Feed enters continuous stirred tank reactors for thermal dimerization
    • Inline distillation to separate DCPD and minimize oligomer formation
    • Purge and recycle system for unreacted monomer

    Final product types

    • DCPD-based unsaturated polyester resins
    • High-impact molding compounds
    • Casting and structure adhesives
    • Protective and marine coatings

    2. Synthesis of Norbornene-Based Polymers

    Norbornene-based polymers require controlled cycloaddition between 1,3-cyclopentadiene and ethylene or its analogs. Polymerization units integrate this raw material at the pre-polymerization stage to produce intermediates with improved heat stability and low dielectric constants. Accurate dosing, temperature control, and impurity monitoring ensure reactor efficiency and consistent polymer chain length for electronic, automotive, and packaging applications.

    Industry compliance standards

    • EN ISO 14001:2015 Environmental Management in production plants
    • UL 94 for flame retardancy in electronics
    • GMP for raw material handling as per EU 2023/2006
    • ISO 17334 for polymer intermediates testing

    Typical usage ratio

    • 40–60% 1,3-cyclopentadiene relative to total monomer feed
    • Modified according to target molecular weight and mechanical properties
    • Ethylene or co-monomer balance adjusted to influence glass transition temperature

    Downstream process integration

    • Monomer enters closed autoclave or flow reactor for cycloaddition
    • Pressure, catalyst concentration, and feed rate controlled inline
    • Post-reaction purification and blending with impact modifiers

    Final product types

    • Cycloolefin copolymer (COC) films and sheets
    • Optical-grade molded electronic housings
    • Specialty packaging barriers
    • Medical device polymer components

    3. Agrochemical Intermediate Manufacturing

    Agrochemical formulators utilize 1,3-cyclopentadiene as a highly reactive building block in cyclopentene and norbornene-derivative intermediates. The material enters defined synthetic steps to yield insecticidal and herbicidal active ingredients. Its reactivity suits batch and semi-continuous reactors with multi-step purification, ensuring the absence of persistent impurities. Critical process checks secure low residual monomer content for compliance, product safety, and field performance.

    Industry compliance standards

    • FAO/WHO Specifications and Evaluations for Plant Protection Products
    • Chemical Control Order under US EPA TSCA Section 5
    • OECD Good Laboratory Practice (GLP)
    • ISO 17025 Accredited Analytical Testing

    Typical usage ratio

    • 15–35% 1,3-cyclopentadiene in stepwise batch synthesis
    • Ratio set based on yield, inherent purity, and downstream active loading
    • In-process controls maintain residuals below 0.1%

    Downstream process integration

    • Material feeds into initial cycloaddition and substitution steps
    • Reactors designed for hazardous intermediate containment
    • Final purification aligns with active ingredient isolation protocols

    Final product types

    • Norbornene-based pesticides
    • Herbicidal cyclopentene intermediates
    • Insect suppressant additives
    • Formulated crop protection solutions

    4. Specialty Adhesive Raw Material

    1,3-Cyclopentadiene finds application in high-grade adhesive resin formulation. Downstream converters utilize its controlled dimerization and co-polymerization in tackifier resins for automotive and electrical adhesives. These processes demand precise temperature control and reaction monitoring to tailor adhesion strength, thermal resistance, and clarity. Quality assurance departments depend on feedstock consistency to minimize gel formation and off-color issues in final adhesives.

    Industry compliance standards

    • ISO 12409 for adhesive raw material specification
    • UL QOQZ2 for recognition of adhesive components
    • REACH Annex XVII for restriction of chemical constituents
    • ASTM D1002 for lap shear strength of adhesive bonds

    Typical usage ratio

    • 20–60% by mass in adhesive tackifier resin systems
    • Adjusted for end-use application (automotive, electronics, construction)
    • Post-dimerization adjustment to achieve performance targets

    Downstream process integration

    • Feedstock introduced in co-polymerization reactors or dimerization vessels
    • Timed addition of functional co-monomers to modify rheology
    • In-line product filtration and blending for improved cure profiles

    Final product types

    • Contact adhesives for electronics assembly
    • Pressure sensitive automotive tapes
    • Heat-resistant sealant resins
    • Tackifier components for structural glues

    5. Chemical Synthesis of Fine and Specialty Chemicals

    Fine chemical manufacturers employ 1,3-cyclopentadiene as a starting compound for complex organic syntheses involving Diels-Alder reactions. The material serves in custom intermediates, pharmaceutical starting compounds, and specialty fragrance precursors where reaction specificity and minimal byproduct generation are prioritized. Laboratories and commercial production lines rely on stabilized monomer supply to support multi-step syntheses under tightly controlled temperature, pressure, and catalyst conditions.

    Industry compliance standards

    • ICH Q7 for GMP of Active Pharmaceutical Ingredients
    • Ph. Eur., USP for raw material traceability (when used for pharma intermediates)
    • ISO 9001:2015 documented process controls
    • Hazardous chemical management according to OSHA 1910.1200

    Typical usage ratio

    • 5–25% in multi-component reaction batches
    • Reaction stoichiometry and scaling based on target compound synthesis
    • Purity selection (≥97%) strongly affects reaction pathway

    Downstream process integration

    • Entry point at initial Diels-Alder condensation or cycloaddition step
    • Process includes sequential purification and chromatography for intermediates
    • Product work-up aligned with downstream synthetic requirements

    Final product types

    • Pharmaceutical active intermediates
    • Fine fragrance aldehyde precursors
    • Specialty flavor and aroma chemicals
    • Laboratory reagent-grade chemicals
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    Competitive 1,3-Cyclopentadiene prices that fit your budget—flexible terms and customized quotes for every order.

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    Certification & Compliance
    More Introduction

    1,3-Cyclopentadiene: An Insider’s Look from the Manufacturer’s Floor

    What It Takes to Deliver Reliable 1,3-Cyclopentadiene

    Every batch of 1,3-cyclopentadiene we produce tells a story about hands-on chemical manufacturing. We prepare it onsite, starting with quality dicyclopentadiene feedstock. Our production team knows exactly how sensitive this dienic hydrocarbon acts during cracking, so the process always stays closely guarded. Volatility, an unmistakable aroma, and a tendency to dimerize on standing: these traits come together to shape how we handle it, how we package it, and how we talk about it to our customers.

    Purity and Consistency—Real Concerns for Real Chemists

    Every customer who buys 1,3-cyclopentadiene wants to avoid byproduct problems. Our colleagues keep purity tight, often running extra distillation passes when any color or residue starts to show up. We’ve learned over time that this material carries more than just chemical reactivity; even a small jump in impurity throws off polymerizations and specialty syntheses. For researchers building novel catalysts or laying the groundwork for new polymer backbones, a slight inconsistency in the diene’s purity can set back whole projects.

    Typical assay ranges for our stabilized monomer hover well above 97 percent, with stabilized formulations offered when we know the product faces extended shipping or longer storage on the shelf. Some chemists ask for higher purities, and we’re frank about tradeoffs: the higher the specification, the more rapid the need for use or the closer you get to dimerization—even in sealed containers. We use glass ampoules for the purest grades, and stainless drums for routine deliveries. Each container is matched to the shelf life and use scenario our technical team expects.

    Why Producers Stay Cautious with 1,3-Cyclopentadiene

    This monomer’s tendency to rapidly transform itself through dimerization means it’s almost always shipped right after cracking. Waiting too long changes the product—reverting it back to dicyclopentadiene, and sometimes even yielding a low-reactivity mixture that frustrates bench chemists working on time-sensitive cycloaddition or polymerization experiments. We see firsthand that delays between cracking and use shrink productivity in more than one lab, which is why our operations line up production runs with courier pickups and custom scheduling.

    The sharp, pungent odor serves as an unmistakable signal in any workspace. Our team uses tailored PPE, and we guide our customers on how to safely open drums and ampoules in ventilated hoods. Leaks don’t go unnoticed. Though all volatile dienes demand care, 1,3-cyclopentadiene occupies a special place: it is both uniquely vigorous and challenging to keep at its monomeric state.

    How Customers Put Our Monomer to Work

    Years of supplying this chemical to customers in academia, electronics, specialty polymers, and pharmaceutical intermediates have shown us what makes 1,3-cyclopentadiene singular. Its double bonds engage quickly in Diels-Alder reactions, producing hydrocarbon skeletons for new catalysts, specialty plastics, and complex intermediates. Many of the top polymer chemistry breakthroughs would look different without access to monomeric cyclopentadiene, sourced at the right purity and freshness.

    We’ve seen this material help build thermosetting resins, particularly those that demand tight thermal and mechanical stability. The electronics industry taps these cyclopentadiene-based resins for high-performance adhesives: speed and reactivity at room temperature allow fabrication with less catalyst and lower energy costs. In the pharmaceutical sector, it lets medicinal chemists construct frameworks that would prove much harder—or even impossible—without this diene’s unique reactivity.

    Our clients often need rapid deliveries timed to large-scale syntheses, especially in pilot plants or custom manufacturing runs for early-stage drug and polymer candidates. Projects succeed or stumble based on marrying the right day of manufacture with the user’s schedule. That’s where the logistics knowledge built up over decades pays off. We coordinate closely with partners so no product loses its edge—either becoming too dimerized or risking purity loss before it’s put to work.

    Comparisons and Clear Differences: 1,3 vs Other Dienes

    It’s not uncommon for new users to ask about the advantages 1,3-cyclopentadiene offers compared to butadiene, isoprene, or even its dimer, dicyclopentadiene. The answer seems straightforward to us who see cycles of synthesis and product testing weekly. 1,3-cyclopentadiene stands out because it leads to five-membered ring adducts, where butadiene or isoprene create six-carbon systems. That structural outcome gives chemists routes into compounds not easily reached by other dienes.

    We hear from polymer formulators who tried to swap in other dienes, only to find the cyclopentadiene’s product brings better thermal resistance or rigidity. In practice, it behaves differently—not only in what it builds but in the handling tricks it demands. Dicyclopentadiene, often used in bulk for resins and intermediates, isn’t a drop-in replacement. The high purity monomer cracks back out for adduct formation, but as every process operator in our shop knows, it never behaves quite like the original monomer.

    Compared to simple open-chain dienes, cyclopentadiene often prompts higher reaction rates in classic pericyclic transformations. The energy barrier for Diels-Alder reactions drops, which lets process and research chemists cut cycle times and squeeze more throughput or higher selectivity from their reactors. Over years of collaboration, some clients have even fine-tuned new catalysts by running parallel tests—one with cyclopentadiene and another with butadiene or isoprene. The difference shows up quickly in product yields and byproduct profiles, especially for oxygen or sulfur heterocycles.

    Specifying What Works: Our Approach on Grades

    Because no two projects match up perfectly, we offer our 1,3-cyclopentadiene in more than one grade. The routine polymer research operation often buys in 98% stabilized monomer for balance between stability and speed. For short-run syntheses in electronics, our team recommends higher purity and fresher monomer. Academic groups sometimes request ampouled, unstabilized grades for mechanistic studies—and we fill those orders with clear instructions about use within hours. We favor honest discussions about tradeoffs rather than letting excess stability chemicals accumulate, which might interfere with sensitive reactions.

    One notable point: 1,3-cyclopentadiene’s tendency to dimerize means large inventory stockpiles rarely work, even at the plant. Our shipping schedules stay nimble, with just-in-time runs for customers locked into research timelines. We keep the cold chain running for customers who want to stretch storage time without sacrificing reactivity. If partners need custom drums or filling environments, we set up cleanroom transfers or inert headspace packaging.

    Real Manufacturing—Not Trading, Not Reselling

    Operating as a true manufacturer brings both challenges and advantages to supplying this demanding monomer. We control our own dicyclopentadiene cracking lines, which lets us adjust production schedules based on real customer demand, not just market spot prices. Plant operators measure by eye and by instrument, testing for contaminants after every distillation pass. Fielding technical questions ourselves, instead of routing them through layers of resellers, gives our chemists and engineers a close connection to each customer’s process.

    Logistics can present hurdles: making sure a time-sensitive batch of monomer reaches a custom blend facility across continents, or arranging for cool packs and expedited customs clearance to keep the product fresh. Our technical support stays on call for troubleshooting spills, dimerization events, or clarification on storage. This hands-on approach goes deeper than what a distributor’s datasheet provides. We can track barrel numbers and run spectrum analyses to help a customer diagnose a stuck Diels-Alder reaction, because we stood at the same bench—sometimes using the same glassware.

    Reducing Waste, Improving Safety—Day-to-Day Realities

    One lesson stands out after years of work: safe, flexible systems keep operations on track. We design our filling, storage, and shipping protocols around the quirks of monomeric cyclopentadiene. Skipping steps or reusing old containers has never ended well. To protect workers and customers, the site’s air handling and containment setup always stays ahead of production runs. Drum labeling, real-time lot tracking, and routine measurement of oxygen and diene vapor levels create checks we count on every day.

    Waste management is another live issue. Leftover diene, even in trace quantities, needs to be neutralized quickly. Our crews process distillation residues and offcuts in segregated streams—ensuring no accidental dimer escapes into the plant’s waste system. By targeting waste volume reduction and maximizing high-purity yield, we improve both cost-efficiency and sustainability for our own operations and our end users’ value chains.

    Opportunities for Technical Collaboration

    We field more questions about cyclopentadiene than almost any other small-molecule monomer. Whether it’s a new reaction route, an upgrade for resin stability, or an alternate packaging method, our technical team prefers answering directly. Developing new stabilization methods or finding logistics channels that cut down on transit time helps everyone in the chain: from the process engineer making a new resin to the research assistant writing up a new catalyst pathway.

    No two days look exactly alike at the facility, because no project requires 1,3-cyclopentadiene in quite the same way. We follow up with pilot plant buyers who need special handling instructions and speak with university researchers requiring flexibility in lot size, delivery day, or purity checks before large grant milestones. By staying close to the ground floor, we pick up technical pain points early—sometimes before the customer even formulates a question.

    Handling Difficulties—Transparency and Shared Solutions

    Everyone working with this material knows about the “clock” that starts after cracking. We encourage clear communication between our floor teams and our customers. Letting us know about a delay in a polymerization run lets us hold back a batch or recommend an alternate stabilization protocol. If a client reports dimerized product, we check both process and logistics, diving back into refractometry data and batch histories.

    One challenge involves balancing stabilization agents with maximum reactivity. Using too much can suppress the very pathways customers hope to explore. Too little, and expensive monomer dimerizes in transit. Our technical development team runs routine studies to optimize inhibitor loads and to understand degradation in real-world shipping. We share that data with buyers, letting them plan storage and use windows with better confidence.

    Understanding the Material—Not Just Selling It

    Our years as producers of 1,3-cyclopentadiene mean we see these issues play out firsthand. We track the fluctuations in raw dicyclopentadiene markets, evaluate the effect of regional temperature swings on storage and shipment, and watch how customers’ success with the monomer shapes what they ask for in future orders. Keeping close to what matters on the floor—rapid, reliable cracking, strong containment, and responsive logistics—sets the baseline for our operations.

    Beyond technical supply, we see every order as an extension of problem-solving. Sometimes that means offering fast-turn small lots to researchers, and other times providing drum quantities shippable on short notice. We have found that building strong relationships based on clarity, transparency, and technical know-how leads to fewer disrupted syntheses and lower risk of purity disputes.

    Improving for the Future—Listening, Adapting, Leading

    Feedback from both large industrial partners and small research labs shapes our approach. Shorter supply chains, faster lead times, better packaging, and stronger documentation—these aren’t catchphrases for us, but standing business practices born out of real-world lessons. If a customer’s resin polymerizes more cleanly with lower stabilizer loads, we tweak production. When a university group needs near-zero oxygen headspace to pursue sensitive mechanistic work, we build out those capabilities at the plant.

    We continue to invest in refining reactors and distillation columns for safer, more energy-efficient monomer production. Promoting ongoing training for operators and raising our safety standards every season means fewer errors and better outcomes for everyone from plant floor to end user. We treat every change as an experiment—with incremental improvements giving us, and every buyer downstream, an edge.

    Direct Access Means Real Expertise

    Many competing suppliers act only as intermediaries, buying finished goods from outside producers. That approach distances users from the hands-on team that really knows the monomer’s quirks. By controlling our own production, we pull real analytical data straight from the floor and communicate it quickly, closing the gap between what’s happening in manufacturing and what users need to know today.

    Our staff fields questions directly—from safe handling, through reaction troubleshooting, and all the way to logistics planning for time-critical experiments. We support these exchanges with transparent data, not generic answers, because every ton and every liter produced comes with its own process history.

    Final Thoughts from the Manufacturing Floor

    Supplying 1,3-cyclopentadiene remains more than a distribution exercise; it means controlling the touchpoints that matter: fast and effective cracking, attentive purification, reliable analysis, and rapid, safe delivery. Meeting the unique needs of researchers, engineers, and production chemists keeps us always refining, always improving. The reality of manufacturing this demanding monomer holds both complexity and challenge, but the rewards echo in every breakthrough and every smooth synthesis our partners achieve.