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1,2-Phenylenediamine

    • Product Name 1,2-Phenylenediamine
    • Alias o-Phenylenediamine
    • Einecs 202-425-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    918943

    Chemical_Name 1,2-Phenylenediamine
    Other_Names o-Phenylenediamine
    Molecular_Formula C6H8N2
    Molar_Mass 108.14 g/mol
    CAS_Number 95-54-5
    Appearance Grayish to purple crystalline solid
    Melting_Point 102-104 °C
    Boiling_Point 256 °C
    Density 1.21 g/cm³
    Solubility_in_Water Moderately soluble
    Odor Aromatic amine-like odor
    Flash_Point 149 °C
    Refractive_Index 1.635
    pKa 0.86, 7.79 (for the two amine groups)
    EC_Number 202-430-6

    As an accredited 1,2-Phenylenediamine factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 250g of 1,2-Phenylenediamine is packaged in an amber glass bottle with a tightly sealed cap and hazard labels.
    Shipping 1,2-Phenylenediamine is typically shipped in tightly sealed containers made of compatible materials, protected from light and moisture. It should be labeled as a hazardous material and transported according to local, national, and international regulations, such as UN 1673. Ensure proper ventilation, handling, and storage to prevent exposure and environmental contamination.
    Storage 1,2-Phenylenediamine should be stored in a tightly closed container, in a cool, dry, well-ventilated area, away from sources of ignition and incompatible substances such as strong oxidizers and acids. Protect it from light and moisture. Storage areas should be clearly labeled and access restricted to trained personnel. Follow all appropriate safety regulations for handling hazardous chemicals.
    Application of 1,2-Phenylenediamine

    Applications of 1,2-Phenylenediamine in Industrial Manufacturing

    1,2-Phenylenediamine serves as a critical intermediate in several highly regulated industrial sectors, supporting complex chemical transformation processes. As the direct manufacturer, we focus on supplying material that matches precise requirements in each application field, ensuring traceability and performance across demanding industrial workflows.

    1. Dye and Pigment Synthesis for Textiles and Leather

    In the colorant manufacturing sector, 1,2-Phenylenediamine is a key precursor for the synthesis of azo and anthraquinone dyes, used in textile and leather coloration. It reliably undergoes diazotization and coupling reactions, allowing dye producers to achieve controlled shade development, color fastness, and reproducibility in bulk-scale batches. Quality management systems require precise control at every stage, as impurities can affect both shade and regulatory compliance.

    Industry compliance standards

    • OEKO-TEX® Standard 100
    • ZDHC Manufacturing Restricted Substances List (MRSL)
    • REACH Annex XVII and SVHC (EU chemical restriction)
    • GB 20406–2006 (Textile dyeing auxiliaries in China)

    Typical usage ratio

    • 3%–10% by weight in diazo component for direct and acid dye formulations, adjusted based on target hue and intensity; lower concentrations for lighter shades or when blending with other amines

    Downstream process integration

    • Add as a primary aromatic amine monomer during the diazotization stage, preceding coupling with naphthol or phenol derivatives; additional purification, sulfonation, and granulation may follow depending on dye type

    Final product types

    • Reactive dyes for cotton and cellulosic fibers
    • Acid and metal-complex dyes for wool, nylon, and leather
    • Direct textile dyes suitable for high-wash-resistance applications
    • Specialty pigments for automotive and industrial leather finishing

    2. Hair Colorant Intermediate Production

    Cosmetic ingredient formulators use 1,2-Phenylenediamine as a core intermediate in permanent (oxidative) hair dye formulations. Its reactivity with hydrogen peroxide and coupling agents is fundamental to controlled color development during the salon or at-home dyeing process. Strict regulatory limits on residual levels and allergenic compounds require robust input quality and validated clean-room blending protocols.

    Industry compliance standards

    • EU Regulation No 1223/2009 (Cosmetics Regulation, Annex III/IV/V limits)
    • US Food and Drug Administration (CFR Title 21, Hair Dye Ingredient Monographs)
    • China Hygienic Standard for Cosmetics (GB 7916-87)
    • ISO 22716 Cosmetics — Good Manufacturing Practices (GMP)

    Typical usage ratio

    • Up to 2% w/w in final oxidative colorant cream; typically 0.1%–1%, depending on target hair shade, country-specific restrictions, and desired coverage results

    Downstream process integration

    • Melt or disperse into cream or gel base under vacuum and low oxygen; incorporate before final emulsification and microfiltration; maintain nitrogen blanket to prevent oxidation during blending and filling

    Final product types

    • Permanent (oxidative) hair color creams and gels
    • Professional salon-use hair dye kits
    • Do-it-yourself (DIY) at-home hair color kits
    • Gray coverage hair treatment formulas

    3. Polymer Additives for Rubber Chemicals

    1,2-Phenylenediamine acts as a primary intermediate in the manufacture of antioxidant additives for synthetic and natural rubber. By reacting to form diaryl-p-phenylenediamines (like 6PPD), it increases elastomer resistance to ozone, heat, and oxidation. Tire and industrial rubber compounders rely on consistently pure input to meet durability and safety profiles required by automotive and heavy machinery sectors.

    Industry compliance standards

    • ISO 9001:2015 (Quality Management Systems for chemical manufacturing)
    • SAE J200 (Classification System for Rubber Materials)
    • EU REACH (registration and risk assessment for rubber additives)
    • ASTM D4678-14 (Standard Practice for Rubber—Preparation, Testing, and Analysis)

    Typical usage ratio

    • Used at 0.5%–2% by weight in rubber batch as a precursor for antidegradant additive synthesis; incorporated upstream before compounding and final vulcanization

    Downstream process integration

    • Combine with polymer feed during additive manufacture; perform controlled condensation with substituted aryl ketones under inert atmosphere, followed by purification and granulation before blending with bulk elastomer

    Final product types

    • Radial and bias-ply tire rubber
    • Conveyor belts and V-belts
    • Hoses, seals, and gaskets for automotive and industrial applications
    • Rubber sheets for construction and mining industry

    4. Corrosion Inhibitor Synthesis for Metalworking Fluids

    In lubricant chemistry, 1,2-Phenylenediamine enables the production of organic corrosion inhibitors suited for aggressive water and oil-based metalworking environments. Through Schiff base or Mannich reaction pathways, downstream formulators create compounds that form strong complexes to minimize rust formation and pitting on steel and ferrous alloys. Reliable purity and traceability are vital to downstream product certification for use in critical industrial maintenance fluids.

    Industry compliance standards

    • ASTM D4627 (Standard Test Method for Iron Chip Corrosion in Water-Dilutable Metalworking Fluids)
    • DIN EN ISO 6743-13 (Classification of lubricating fluids for metalworking)
    • REACH registration for specialty corrosion inhibitors
    • RoHS Directive 2011/65/EU (for restricted substances in metalworking chemicals)

    Typical usage ratio

    • 1%–5% as raw material in corrosion inhibitor synthesis; dosage in end-use metalworking fluid concentrates typically 0.05%–0.2% of finished product

    Downstream process integration

    • React with selected aldehydes or ketones under controlled pH and temperature during batch synthesis; resulting inhibitors are formulated into fluid concentrates at blending and packaging stage

    Final product types

    • Water-soluble cutting fluid concentrates
    • Oil-based rust-preventive fluids
    • Temporary protective coatings for steel coils and machine parts
    • Low-foaming metal cleaning syndets for precision component manufacturing

    5. Pharmaceutical Intermediate for Active Pharmaceutical Ingredient (API) Synthesis

    In fine chemical and pharmaceutical manufacturing, 1,2-Phenylenediamine is utilized as a building block in the synthesis of various APIs and diagnostic agents. Its bidentate amine structure supports cyclization, condensation, and derivatization for high-value compounds such as antibacterial and antitubercular agents, and intermediates for imaging diagnostics. Downstream production mandates stringent GMP compliance, validated trace impurity profiles, and full batch documentation.

    Industry compliance standards

    • ICH Q7 Good Manufacturing Practice for APIs
    • Ph. Eur. (European Pharmacopoeia) monographs
    • US FDA cGMP (Title 21 CFR Parts 210 & 211)
    • Chinese Pharmacopoeia (ChP) for API intermediate standards

    Typical usage ratio

    • Typically 0.1 mol x target product mol, calculated based on pharmaceutical reaction stoichiometry; adjusted for downstream conversion efficiency and desired batch scale

    Downstream process integration

    • Charge to reactor during heterocycle condensation or as a nucleophile for diazotization/coupling in multi-step API synthesis; requires validated raw material release and in-process testing for each batch

    Final product types

    • Antimicrobial API intermediates
    • Fluorescent diagnostic dye compounds (for in vitro tests)
    • Pyrimidine- or benzimidazole-based pharmaceuticals
    • Contrast agents in imaging reagent preparation
    Free Quote

    Competitive 1,2-Phenylenediamine prices that fit your budget—flexible terms and customized quotes for every order.

    For samples, pricing, or more information, please call us at +8615371019725 or mail to admin@sinochem-nanjing.com.

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    Certification & Compliance
    More Introduction

    1,2-Phenylenediamine: The Value of Experience in Chemical Manufacturing

    Building Reliability Into Every Batch

    Those of us who have spent years working directly with 1,2-Phenylenediamine understand that its value goes beyond formulas and data sheets. In our manufacturing facility, consistency and purity aren’t glamorous catchphrases—each day, they set the rhythm of production and guide every choice we make. Over the years, our focus on process control and hands-on quality assurance fostered deep expertise with this aromatic diamine. Our team relies on analytical instruments and experienced eyes to catch small variations and keep our product within tight specifications.

    Our standard model for 1,2-Phenylenediamine features a crystalline powder, typically ranging from grey to faint purple. It’s the attention to visual details and odor—subtle as they seem—that can hint at issues in a batch long before standardized tests catch them. This vigilance ensures that the end-user can depend on our material to perform identically each time, whether in pigment synthesis, rubber antioxidants, or hair dye formulations.

    How We See Customer Needs

    Manufacturers like us seldom get to pause and discuss the practical challenges clients face—lead time variability, raw material drift, the slump of slow reaction kinetics. After shipping hundreds of tons of 1,2-Phenylenediamine over the years, we learned that the story is always about utility. For those in the dye sector, batch tint and purity shape product reliability. For rubber compounders, the amine’s reactivity impacts stability and shelf-life.

    Working closely with our partners, we document minor impurity profiles often ignored in bulk supply. That sort of attention enables our clients to fine-tune their reactions, optimize processes, and avoid costly troubleshooting.

    Specifications From the Manufacturing Floor Up

    Technical parameters for our 1,2-Phenylenediamine product didn’t fall from a textbook. They came out of long stretches monitoring purification stages, especially amid sweltering summers or the deep cold of winter. We typically achieve a purity above 99%, with controlled water and ash content. Color, bulk density, and melting point targets only look simple in a spreadsheet; they stem from real batch data logged over dozens of campaigns. Too high a water fraction sometimes comes from tight-wrapped packaging or overlooked HVAC adjustments during storage. Instead of chasing numbers for their own sake, we base our controls on what actually matters downstream.

    Both powdered and granular forms have devoted users. Our powder batches suit high-surface-area reaction vessels and allow quick dissolution for immediate processing. Granular variants help reduce airborne dust, making the job easier in facilities where house-keeping and operator health carry weight. Some customers shift between both types depending on seasonal operating conditions; others stick with what their lines have been built to handle. We keep our order system flexible in response.

    Understanding Application Contexts

    Experience tells us markets have their cycles. There are years when the pigment manufacturers drive most orders, and cycles when polymer research pushes us for higher-order amines and specialty derivatives. In the dye industry, 1,2-Phenylenediamine acts as a key ingredient for azo and anthraquinone dyes thanks to its strong amine reactivity and ortho-positioned amine groups. Its structure—both amines on adjacent carbons—unlocks access to color shades and durability unattainable with other aromatic diamines.

    In the area of rubber production, the material steps in as an antioxidant and anti-degradant. While certain substitutes can offer basic stabilization, none match the balance of reactivity and cost offered by this compound. Our prolonged collaboration with tire and belt manufacturers sharpened our understanding of which impurity levels actually influence long-term rubber stability. By monitoring trace oxidizing agents and ensuring fast delivery in moisture-controlled packaging, we support high-performing rubber blends resistant to heat and weathering.

    A niche—but growing—market uses our 1,2-Phenylenediamine in hair coloring formulations. Formulators value it for providing deep, lasting color, and its compatibility with modifiers. We follow these regulatory developments closely, as requirements around purity and contaminant residues get stricter every year. That feedback cycle—formulation lab to factory—helped us fine-tune our purification setups to deliver what’s needed for sensitive cosmetic applications.

    What Sets It Apart

    Among common diamines—orthogonal, meta, and para—structural differences drive profound changes in reactivity and application. 1,2-Phenylenediamine, with its ortho relationship, gives higher cyclization reactivity and efficient coupling possibilities compared to its 1,3- or 1,4-counterparts. Years of hands-on experience in making and using this product show that the ortho isomer provides better throughput for dye synthesis steps that hinge on rapid condensation; its byproducts are easier to separate thanks to predictable solubility in common solvents.

    1,3-Phenylenediamine and 1,4-Phenylenediamine compete on paper for similar applications, but we observe most of our customers return to the ortho variant when they need reliable downstream performance. Subtle distinctions—such as a slightly higher melting point and a distinct color formation in finished products—give the ortho isomer the advantage. From a process point of view, this translates to higher conversion rates and fewer reaction failures.

    Manufacturing Know-How and Process Experience

    From the vantage point of the production floor, nothing replaces hands-on management of the synthesis and purification chain. Our crews have logged countless hours checking intermediate stages for unwanted side-reactions that might sneak in if the temperature profile drifts or solvents aren’t spotlessly dry. Detailed batch records—tied to specific reactor runs—help us spot patterns, learn from anomalies, and steadily improve workflows.

    On some occasions, we collaborated directly with forward-thinking customers to troubleshoot reaction bottlenecks. For instance, one pigment manufacturer struggled with color drift due to trace amounts of iron, picked up during early filtration. Working together, we adapted our system to minimize metallic contact, allowing their end product to stabilize in shade and intensity. Such feedback loops teach us more than any theoretical modeling ever could.

    Our technical team relies not just on modern analytical instruments but also on routine sensory checks—odor, color, and even the feel of the powder. Each trait, whether visual or measured, ties back to performance at our customer sites. By putting in the time to understand real-world setbacks—reactor clogs, filter fouling, inconsistent reaction endpoints—we refine both product and service.

    Environmental Responsibility and Worker Safety

    Producing 1,2-Phenylenediamine safely poses genuine challenges—vapor capture, waste treatment, protection of operators, and environmental safeguards weave through every shift. We invest in active ventilation systems, closed transfer lines, and operator training. Waste streams receive exhaustive treatment, including thermal oxidation and chemical neutralization, shaped by hard-learned lessons from years of inspection feedback and regulation changes.

    By maintaining this focus, we not only protect our crews but also guarantee no cross-contamination of adjacent product lines—a crucial point for customers with low-tolerance applications. This continuous improvement attitude means clients relying on pharmaceutical, cosmetic, or high-purity technical grades know they’re sourcing material made with health and environmental impacts in mind.

    Price, Availability, and Supply Chain Realities

    The raw material chain behind 1,2-Phenylenediamine stretches across continents. Onsite synthesis of precursors and strict supplier audits let us adapt quickly to shifts in market availability or regulatory conditions. During global shortages, decisions made years ago to broaden our supplier network and build onsite feedstock synthesis paid off—not just for us but for every customer whose process depends on stable deliveries.

    Our pricing and delivery schedules reflect more than market trends—they respond to energy costs, regulatory costs, and evolving client needs. We never view order fulfilment as transactional; every batch requires hands-on preparation, double-checked for quality and traceability. Lean years taught us to stock beyond just-in-time needs, ensuring partners avoid costly process shutdowns.

    Ongoing Research and Customization

    Rarely does a week pass without a new customer asking for a tweak—an extra filtration, a tighter impurity range, a freshly developed end-use. We keep our doors open for custom requests, applying the hands-on creativity and flexibility that only direct manufacturers can offer. This journey led us to develop several derivative amines and custom blends, always rooted in real feedback and years of joint trials.

    Onsite labs supplement large-scale synthesis, letting us run pilot batches that mimic full production but with rapid turnaround. We built these extra steps into our model because industrial reality moves quickly, and customers can ill afford months of lead time for a new variant.

    Regulatory Shifts: Meeting New Demands

    Global standards for amine-based chemicals shift fast—sometimes faster than communication up the chain. We monitor national and international guidelines, applying lessons from every audit to both documentation and equipment upgrades. From the modernization of our reporting systems to the introduction of batch tracking, our operation adjusted alongside evolving rules, not after the fact.

    With pharmaceutical and food sectors increasingly probing material origins and impurity levels, we trace the lifecycle of our batches from raw chemical feedstock to final delivery. This traceability, rooted in practical experience, instills confidence for audit-laden clients and lets us address concerns directly, not in delayed, chain-of-custody paperwork.

    Lessons From the Field

    Years serving both specialists and large industrial clients showed us that priorities can shift overnight. One quarter might see a rush on high-reactivity batches for dye synthesis pilots; another might demand ultra-low moisture content for a specialty elastomer run. Flexibility at the physical plant level—adjusting heating curves, timing delivery, keeping trained staff ready for overtime—sets a direct manufacturer apart.

    Problems get solved on the shop floor, not in abstract strategy planning. Once, a customer flagged a recurring trace impurity that escaped standard analyses but caused equipment fouling in their downstream process. Collaborating closely and examining batch-by-batch histories, we isolated the source in a rarely checked storage tank valve—an answer missed by any detached viewpoint. The lesson lives on in our maintenance checklist.

    The Direct Manufacturer Difference

    Buying direct from us means more than skipping trading margins. It’s an open door to decades of hands-on learning—failures, breakthroughs, and small victories alike. Customers see transparent batch records, get updates in response to real regulatory changes, and draw on a team that’s solved not just familiar but also unusual process puzzles.

    Our experience with 1,2-Phenylenediamine grew from the ground up. Each improvement—whether in packaging, impurity control, or flexible delivery schedules—tells a story of responding to actual problems, not theoretical possibilities. In a world of distributed, patchy supply chains, the value of working with the manufacturing originator shows up in less downtime, more predictable results, and the freedom to push the edges of application and performance.

    Shaping the Future of 1,2-Phenylenediamine Sourcing

    New uses for 1,2-Phenylenediamine arise each season, drawn from insights in research labs and pilot plants. We keep our systems adaptable, knowing today’s standard can quickly become tomorrow’s starting point. Our job is to match those shifts with steady quality, trusted supply, and technical guidance that only comes from rolling up one’s sleeves and doing the work. Each advancement on the manufacturing side makes it easier for our clients to focus on what comes next—new dyes, tougher rubber, safer and more stable finished products.

    That’s the journey we share: one batch at a time, always ready to tackle the next challenge.