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1,1'-Dimethyl-4,4'-Bipyridinium Cation

    • Product Name 1,1'-Dimethyl-4,4'-Bipyridinium Cation
    • Alias paraquat
    • Einecs 219-086-1
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    432349

    IUPAC_Name 1,1'-Dimethyl-4,4'-bipyridinium
    Other_Names Paraquat
    Molecular_Formula C12H14N2
    Molar_Mass 186.25 g/mol
    Charge +2
    Appearance Colorless crystalline solid (as cation, but often found as salts, e.g., dichloride which are yellow)
    CAS_Number 4685-14-7
    SMILES C[n+]1ccc(cc1)c2cc[n+](cc2)C
    InChI InChI=1S/C12H14N2/c1-13-7-3-9-11(5-7)12-6-8(2)14(12)4-10(13)12/h3-6H,1-2H3/q+2
    PubChem_CID 9783
    Melting_Point 300 °C (decomposes, paraquat dichloride salt)
    Solubility_in_Water Very soluble (as salts, e.g., dichloride)
    Hazard_Statements Highly toxic, especially by ingestion and inhalation (as paraquat)

    As an accredited 1,1'-Dimethyl-4,4'-Bipyridinium Cation factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Amber glass bottle, 25g, sealed with a screw cap, hazard labeling, chemical name and CAS number displayed, desiccant included.
    Shipping 1,1'-Dimethyl-4,4'-Bipyridinium cation (commonly known as paraquat) should be shipped in tightly sealed, chemical-resistant containers, clearly labeled as hazardous. Transport must comply with local and international regulations for toxic substances, ensuring container integrity and minimizing exposure risks. Handle with appropriate protective equipment and provide documentation detailing the chemical’s hazards and handling procedures.
    Storage **1,1'-Dimethyl-4,4'-Bipyridinium cation** (often encountered as its salt, paraquat) should be stored in a tightly sealed container, away from incompatible materials such as strong oxidizers and reducing agents. Store in a cool, dry, well-ventilated area, protected from light and moisture. Ensure access is restricted to authorized personnel and that proper labeling and safety precautions are observed due to its toxicity.
    Application of 1,1'-Dimethyl-4,4'-Bipyridinium Cation

    Applications of 1,1'-Dimethyl-4,4'-Bipyridinium Cation in Industrial Manufacturing

    1,1'-Dimethyl-4,4'-bipyridinium cation supports key production steps across several industrial sectors. As a chemical manufacturer, we supply this raw material to established downstream clients who maintain regulated, specialized, and volume-driven operations.

    1. Herbicide Formulation for Agriculture

    Downstream agrochemical formulators use the cation for synthesis of paraquat-based contact herbicides, primarily for non-selective weed control in high-output crop farming. In process plants, specialized reaction conditions ensure complete cation incorporation into salt forms, supporting efficient delivery and stability in sprayable formulations. Quality teams test each batch for residual impurities and active content according to client-bound and national certifications.

    Industry compliance standards

    • FAO Specification 222/2018 (paraquat dichloride)
    • US EPA 40 CFR Part 180.205 (tolerance for residues)
    • ISO 9001:2015 Quality Management for agrochemical manufacture
    • REACH Regulation (EC) No 1907/2006 for import/distribution in the EU

    Typical usage ratio

    • Active salt generated from 40–48% w/w of 1,1'-Dimethyl-4,4'-bipyridinium cation, adjusted per target formulation and required field application strength.

    Downstream process integration

    • Cation is introduced during the primary salt formation step with dichloride counter-ion, followed by slurry blending, filtration, and formulation into EC, SL, or WG herbicide formats.

    Final product types

    • Paraquat dichloride 20% SL (Soluble Liquid)
    • Paraquat 42% TC (Technical Concentrate)
    • Paraquat 276 g/L EC (Emulsifiable Concentrate)
    • Weed management ready mix packs for field use

    2. Redox Active Materials in Flow Battery Manufacture

    Specialty energy storage producers employ the cation as a core redox agent in aqueous organic flow batteries. Controlled purity, minimized water content, and tailored counter-ions are essential for long-cycle performance, limiting self-discharge and maximizing energy density. In production, batch verification ensures electrochemical performance before unit cell assembly and field deployment.

    Industry compliance standards

    • IEC 62932-2-1:2020 (Flow Battery Safety)
    • UN 38.3 Rechargeable Battery Transport Regulations (for finished battery modules)
    • ISO 14001:2015 Environmental Management for battery material plants
    • RoHS 2011/65/EU for restricted substances

    Typical usage ratio

    • 40–60 g/L in electrolyte solution; precise dosing determined by cell design and total system energy storage requirements.

    Downstream process integration

    • Cation is dissolved and conditioned as the catholyte or anolyte component, composed with compatible organic and inorganic salts to form the full electrochemical circuit of the flow battery.

    Final product types

    • Large-scale stationary flow battery modules
    • Grid-level renewable energy storage systems
    • Custom modular energy storage cells
    • Lab-scale redox flow test units

    3. Electron Transfer Mediators in Electrochemical Synthesis

    Fine chemical, pharmaceutical, and material science sectors utilize the cation as a single-electron transfer mediator in controlled-potential electrolysis. Its role drives selective oxidation or reduction steps unobtainable by traditional redox reagents. Production labs manage input purity and solution concentration, optimizing mediator cycling, current efficiency, and minimizing byproduct formation. Output is subject to method validation and international synthesis standards.

    Industry compliance standards

    • cGMP (ICH Q7) for pharmaceutical intermediates
    • ISO 17025 laboratory process validation
    • OECD 407/423 for chemical process hazard assessment
    • REACH Annex VIII Registration (where applicable)

    Typical usage ratio

    • 0.5–5 mol% relative to substrate, adjusted based on substrate reactivity and target scale; concentration further controlled to avoid mediator decomposition during long electrolysis runs.

    Downstream process integration

    • Mediator is charged and introduced to anodic or cathodic cell compartments, supporting in-situ or ex-situ substrate transformations prior to downstream separation and purification steps.

    Final product types

    • Specialty chemical intermediates
    • Active pharmaceutical ingredients (regulated intermediates only)
    • Conductive polymer materials
    • Aromatic oxidation/reduction products

    4. Electron Acceptors in Photocatalysis Research and Development

    Photocatalysis groups use the cation as a selective electron acceptor in experimental photoredox cycles, optimizing yields of fine organics and advanced intermediates for electronics or pharmaceutical research. Purity and photostability remain critical parameters, so our raw material undergoes batch-level verification in line with tightly controlled specification. Its solution is freshly prepared to ensure result reproducibility in both scale-up and laboratory test environments.

    Industry compliance standards

    • GLP (OECD Principles of Good Laboratory Practice)
    • ISO 9001:2015 Quality Management for R&D supply chain
    • Hazard Communication (GHS/CLP-compliant SDS and labelling)
    • Analytical reagent standards (ACS specification if used in US laboratories)

    Typical usage ratio

    • 0.05–0.3 M in irradiation solutions, fine-tuned based on desired photoredox rate and stoichiometry of organic substrates under test.

    Downstream process integration

    • Material charged at the beginning of photoreactor runs, in presence of light source and photocatalyst, providing precise electron pairing during key transformation steps prior to quench and product recovery.

    Final product types

    • Prototype functionalized organic compounds
    • Fluorinated and alkylated intermediates
    • Material science building blocks for small-batch electronics
    • Pharma research molecules (not commercial APIs)
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    Certification & Compliance
    More Introduction

    1,1'-Dimethyl-4,4'-Bipyridinium Cation: Precision Chemistry from a Manufacturer’s Bench

    Introduction

    Making chemicals is more than mixing ingredients. Every day in the plant, each batch, each bottle, means putting years of experience into a product so that scientists and growers, researchers and engineers, can move their own work forward with confidence. 1,1'-Dimethyl-4,4'-Bipyridinium cation sits squarely in this world. Produced with close attention to detail, this compound is more than just a formula, it's the result of exact controls during every step in process.

    Understanding the Compound

    Long before its entry into laboratories and onto fields, this material—best known as the active component of paraquat—starts with our core feedstocks. Its structure, two pyridine rings linked and methyl groups attached, gives it properties that scientists rely on for predictable reactions. The ionic nature and molecular symmetry don’t just satisfy the textbook; they guarantee stability, fast action, and a reactivity profile chemists count on for a broad set of applications.

    From Reaction Vessel to Real Application

    We steer our chemistry so the finished 1,1'-Dimethyl-4,4'-Bipyridinium cation delivers exactly what agronomists and researchers expect. Our process keeps impurities low. Impurities can trigger unwanted reactivity or interfere in formulations; keeping them in check translates to products that behave the same way, batch after batch. Because most end-users work in settings where a molecule’s behavior can make or break results, consistency matters more than anything.

    From an operator’s view, each process step calls for tight monitoring—temperature, pressure, sequence, and timing. These aren’t academic exercises. Heat too fast, and energy builds up in the reactor, which can generate byproducts. Cool too soon, and crystal formation gets off track, leading to a lower yield or harder-to-filter slurries. Knowledge passed down from seasoned plant managers helps train new staff to spot the subtle changes that signal something is off. That’s how we build trust in what comes off our lines.

    Specifications and Characteristics

    Chemists want certainty every time they work. The crystalline salt of 1,1'-Dimethyl-4,4'-Bipyridinium arrives as a fine, often off-white or pale powder. Its solubility in water, plus distinctive charge distribution, creates advantages in formulation and delivery, especially for agricultural uses and redox chemistry experiments.

    Every shipment meets a clear spec for both content and purity. We use proven analytical tools like HPLC, NMR, and titration daily to check both intermediates and end products. Staff in our quality lab sample lots regularly; we don’t skip corners to chase volume. Our in-house blends show a measured balance between the right salt form and water content, fighting off clumping and over-drying that can make dosing unreliable.

    Applications: The Real-World Picture

    One thing stands out: in agriculture, the use of 1,1'-Dimethyl-4,4'-Bipyridinium as the primary agent in non-selective herbicides changed field management. Farmers treat overgrown ground or fire breaks with solutions containing the product. Our clients report the importance of reliable dissolution—no stubborn clumps or variable particle size, which can mess up spray patterns and hit rates.

    Research teams use this cation as a staple in redox studies and as an electron acceptor. In the world of chemistry, few compounds offer the redox potential shifts and robust response under repeated cycling that this salt manages. Its sharp transitions in electrochemical assays make calibration easier and results more reproducible. We’ve talked over the years with customers in battery and energy storage who value this reliability.

    There are fields where this compound finds fewer headlines—water treatment, advanced synthetic routes, or industrial disinfection. Over decades, labs reported to us that switching source material can cause rough patches in scaled reactions or influence reproducibility. Having a steady formulation removes one question mark for those customers.

    Differences from Other Similar Compounds

    Not all bipyridinium products work the same. 1,1'-Dimethyl-4,4'-Bipyridinium cation brings both methylation and a symmetric framework, making it more stable under light and oxidative stress compared to the non-methylated parent. Some suppliers mix grades or don’t separate isomers well; our route avoids this. We see steady demand from research labs hunting for clean spectra and pot growers who cannot risk crop loss due to impurity-driven batch variability.

    Compared with related viologen salts, our product resists breakdown even in tough field environments. For scientists using automated pipetting or robotic handling, lower dust and uniform flow properties cut headaches with sample prep or dosing mistakes. All of this comes from conscious effort, not chance. We redesign our filtration beds and optimize drying just to get closer to the performance chemists ask for.

    Production Choices and Quality Control

    Behind each package is a factory team who watch pH shifts, color changes, gas evolution, and filtration rates, logging every metric. The debates between production and QC over a single-point deviation in purity or color often lead to continuous improvement. Our documentation includes not only batch tests but records of tank cleaning, raw material lots, and even operator notes about unusual readings.

    Our team clocks plenty of hours tinkering with process water grades. Hardness, organic load, and even pipework cleaning influence how the intermediate behaves before isolation. We spend time calibrating equipment for inline monitoring, but trust experienced eyes to catch what instruments occasionally miss. Each product lot travels from reactor to finishing to packaging with traceability right back to those moments on the shift.

    Worker Safety and Community Responsibility

    Working with 1,1'-Dimethyl-4,4'-Bipyridinium means keeping sharp focus on people’s well-being. Its toxic properties require more than posted signs; we drill every staff member on containment and cleanup. Respirator fit checks, spill kit drills, and monthly audits matter every day; managers and operators stay in close communication. We designed our loading bays to catch spills and wash-downs, so product and rinse water go straight to treatment, not the floor or drains.

    We also keep lines open with the fire department and local regulators. Routine open-house events bring community members into the plant, and we regularly answer questions about our waste streams and emissions. Transparency didn’t start as a marketing idea here—many of us grew up nearby, and our kids play ball with local teachers’ children. The choices we make around product, process, and disposal ripple out, and that’s never far from our mind.

    Regulatory and Market Context

    Any chemical manufacturer feels the weight of regulations. Whether it’s the European Union’s tightening on pesticide use or shifting U.S. rules for chemical shipping, we stay sharp on compliance. Each drum out the door matches global safety and transport expectations. Detailed labeling, batch archiving, and hazard records stay part of every transaction, not just the big ones. Our site’s regulatory specialists spend as much time in dialog with buyers as they do sifting law changes, making sure nothing slips through.

    Our customers count on consistent product, but they also watch market volatility. Feedstock price hikes, supply delays, or even geopolitical shocks put pressure on business, yet our plant aims to buffer these shocks by stockpiling raw materials and keeping relationships tight with suppliers. It means sometimes carrying higher inventory than the textbook says you should, but it smooths out swings in delivery or price.

    Problem-Solving: Supply, Handling, and Waste

    Every manufacturer faces tough tradeoffs. Shipping 1,1'-Dimethyl-4,4'-Bipyridinium cation across long distances can risk moisture uptake or caking; our packaging shop uses sealed liners and tamper-proof containers designed with input from customers who see rough handling in field depots. We work with carriers who understand the material, not just generic shippers. They know how minor temperature spikes or jostling crate can affect downstream use.

    Leftover product and spent solutions cannot get tossed out as ordinary trash. We built and maintain our own effluent treatment plant to break down traces and catch residues before anything leaves the site. In the early days, we sent some waste off-site, but root-cause analysis on minor tank leaks and loadout spills convinced us the better answer lies in investing in at-source control and cleanout. People inside our operation challenge management to prove our disposal won’t hit river quality. Regular water sampling outside the fence gives us confidence—or a red flag.

    Our customers also puzzle over disposal at their sites, especially in research applications or in places where paraquat bans have tightened. We provide technical support for degradation protocols, explaining what works and what doesn’t, based not only on published chemistry but our own lab trials. That exchange of practical solutions, not just cut-and-paste sheets, helps users stay in compliance and avoid safety lapses.

    Innovation and Product Evolution

    Processes are never set in stone, and our engineering group keeps looking for small changes that limit solvent use, cut emissions, and boost yield. Each time we recover more intermediate or streamline a wash stage, downstream users gain a purer, more predictable material. Our in-plant R&D shares lessons with outside partners—manufacturers, not marketers—who field test new grades or applications. This roundtrip, from plant to user and back, has us refining drying times, looking at post-synthetic treatments, and listening to what fails in a customer’s workflow.

    As research into alternative bipyridinium salts rises, we see new directions for this backbone molecule—potentially in battery systems or as models for photochemical studies. Even with old-school uses like weed control, there’s room for tweaks. The feedback from grower surveys and university outreach points out where solubility, dustiness, or tank-mix compatibility needs work. We log those points, lab-test new blends, and run small-batch pilot lots long before shifting mainline production.

    Challenges in Modern Manufacturing

    Modern buyers want more than just a product that meets stated specs—they demand deeper proof of sustainable sourcing, ethical labor, and reduced environmental footprint. Our response comes from open audits, staff training, and direct implementation projects. Solar on plant roofs, zero liquid discharge trials, and solvent recovery all play their part. These steps take investment, but as manufacturers, we shoulder the cost not just for customer satisfaction, but for the long-term health of our operation and neighborhood.

    Trade wars, tighter border checks, and pandemic impacts have put strain on logistics and cash flow across the sector. Small or remote buyers used to order directly from us, but changing rules around hazardous materials shipping forced many to rethink access. We keep our technical and export support teams close to production, so each lot can hit the route needed with the right declarations and packing, no matter how small. This approach avoids resellers getting too far from the maker’s intent.

    Ties Between Manufacturer and User

    We build relationships through direct feedback. If a batch came in dusty, if a solution showed behavior not seen before, users reach our line staff, not just a generic help desk. Engineers and chemists from our operation have walked fields, spent time in university labs, and joined startup pilots to see how 1,1'-Dimethyl-4,4'-Bipyridinium works in reality. This keeps us honest about our strengths and areas that need more focus.

    Losing face-to-face contact during the pandemic showed us the limits of remote troubleshooting. Some challenges—unusual color, strange settling, hard crusts in tanks—can only be solved through site visits. The manufacturer-to-consumer link really means accountability and a promise to fix issues even at our own cost if we misstepped in production.

    Meeting Shifting Demands

    As more regions talk about restricting use or find new health data on related compounds, we adapt. Changes in demand force us to plan further ahead, whether ramping up batches for sudden orders or scaling down to hold less finished stock in the face of uncertain regulatory changes. Process flexibility and constant retraining keep staff alert to both production tweaks and risk management.

    Buyers look to us not just for molecules, but also for process know-how—how to blend, what to avoid, and how to track residues. These conversations sharpen our own protocols and often turn up new ways to improve both product and support. Regulation helps create a level playing field, but it’s the practical relationships—manufacturers talking to users, not third parties—that foster trust and keep progress moving.

    The Manufacturer’s Perspective on the Path Ahead

    Producing 1,1'-Dimethyl-4,4'-Bipyridinium cation means carrying on a tradition of precision and practical chemistry. Each kilo that leaves our plant reflects long shifts, regular improvement, and the back-and-forth between user and maker. As markets, applications, and regulations keep changing, we’re ready to balance our technical roots and commitment to whoever needs the product—whether it’s for plants, power, or pure research. From the manufacturing floor, every batch is personal, and each customer’s satisfaction runs back through our own chain of supply and pride.