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Limonene Oxide

    • Product Name Limonene Oxide
    • Alias 1,2-Epoxy-p-menthane
    • Einecs 246-391-2
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    871225

    CAS_Number 1195-92-2
    Molecular_Formula C10H16O
    Molar_Mass 152.23 g/mol
    Appearance Colorless to pale yellow liquid
    Odor Citrus-like
    Boiling_Point 208 °C
    Density 0.965 g/cm3
    Refractive_Index 1.452
    Melting_Point -74 °C
    Solubility_in_Water Insoluble
    Flash_Point 87 °C
    Storage_Temperature Store at room temperature

    As an accredited Limonene Oxide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Limonene Oxide is supplied in an amber glass bottle, 100 mL, sealed with a plastic cap and labeled with safety information.
    Shipping Limonene Oxide should be shipped in tightly sealed containers, protected from light and moisture. Transport in accordance with local, national, and international regulations for hazardous chemicals. Ensure upright positioning to prevent leaks. Label clearly as a chemical substance. Avoid exposure to heat, sources of ignition, and incompatible materials during transit.
    Storage Limonene Oxide should be stored in a cool, dry, well-ventilated area, away from sources of ignition and incompatible substances such as oxidizing agents. Keep containers tightly closed and protected from light and moisture. Use containers made of compatible materials like glass or specific plastics. Ensure labeling is clear and handling meets chemical safety standards to prevent accidental exposure or degradation.
    Application of Limonene Oxide

    Applications of Limonene Oxide in Industrial Manufacturing

    Limonene oxide is a specialized monoterpene epoxide derived from citrus sources, applied by downstream manufacturers in several regulated industrial processes. This section outlines specific application scenarios where limonene oxide plays a pivotal role, focusing on real-world use cases, process integration details, compliance needs, and dosage considerations unique to each sector.

    1. Fragrance Intermediate for Fine and Functional Perfumes

    Fragrance compounders incorporate limonene oxide as a high-impact intermediate in producing fresh, citrus-like, and slightly floral notes within signature blends, targeting both luxury fine perfumes and technical fragrances for personal care and home care. Due to its oxidative stability and compatibility with terpene blends, formulation chemists use it in targeted proportions to achieve top-note modifications and improve perfume longevity, especially in citrus-forward formulations.

    Industry compliance standards

    • IFRA (International Fragrance Association) Standards and Restrictions
    • EU Cosmetic Regulation (EC) No 1223/2009
    • US FDA 21 CFR for flavor and fragrance uses
    • Good Manufacturing Practice (GMP) for fragrance compounding

    Typical usage ratio

    • 0.01% – 0.2% by finished formulation weight; adjusted downward in leave-on skin/contact products per IFRA quantitative limits.

    Downstream process integration

    • Added directly to the blending phase post-saponification for soaps or during the heart note composition stage in perfume concentrates; undergoes pre-mixing with solvents or carriers to control volatility during batch production.

    Final product types

    • Fine fragrances (eau de parfum, eau de toilette)
    • Liquid air fresheners
    • Technical perfumery compounds for industrial detergents
    • Solid or gel home air care products

    2. Green Solvent Formulations for Industrial and Institutional Cleaners

    In the industrial cleaning sector, formulation chemists use limonene oxide as a high-performance green solvent substitute to conventional petrochemical-based solvents, benefiting from its low aquatic toxicity profile and biodegradability. When blended into concentrated surface cleaners, degreasers, or graffiti removers, it enhances both solvency power and wetting properties for challenging soils, particularly organic resin and greasy residues on metal and polymer substrates.

    Industry compliance standards

    • REACH (Registration, Evaluation, Authorisation and Restriction of Chemicals) compliance in Europe
    • US EPA Safer Choice Program for safer chemical use
    • OECD 301 biodegradability testing
    • OSHA Hazard Communication Standard (29 CFR 1910.1200)

    Typical usage ratio

    • 2% – 10% by weight in concentrated industrial cleaners, adjusted according to required solvency and surface compatibility tests.

    Downstream process integration

    • Introduced in the secondary solvent blending stage, following water and surfactant addition; dispersion aided by mechanical agitation; stability checks performed prior to pH and viscosity adjustments.

    Final product types

    • Industrial degreasers for metal and equipment surfaces
    • Graffiti removers
    • Institutional kitchen surface cleaners
    • Hard surface hand-cleaning gels and wipes

    3. Polymerization Initiator and Additive in Epoxy Resin Systems

    Limonene oxide is leveraged by composite materials producers as a reactive diluent and co-monomer in bio-based epoxy resin systems. Its function is to adjust curing kinetics and mechanical flexibility while introducing partial renewable content in advanced composites for automotive interiors, electronics encapsulation, and industrial coatings. Process engineers and formulators balance loading ratios to optimize viscosity, pot life, and final crosslink density without compromising system stability or performance.

    Industry compliance standards

    • RoHS (Restriction of Hazardous Substances Directive) for electronic encapsulation
    • REACH Annex XVII restrictions for monomers and additives
    • ISO 9001 Quality Management System for polymer manufacturing
    • UL 746C for polymeric materials safety (electronic applications)

    Typical usage ratio

    • 5% – 20% by weight of total resin system; exact ratio tailored to matrix viscosity and composite mechanical requirement specifications.

    Downstream process integration

    • Mixed into base epoxy resin during pre-polymerization blending under controlled temperature; batch homogenization ensures uniform mono-epoxide dispersion prior to addition of curing agents and fillers.

    Final product types

    • Bio-based epoxy laminates for electronic circuit boards
    • Low-VOC industrial floor coatings
    • Automotive interior composite panels
    • Adhesive systems for structural bonding

    4. Synthesis Intermediate in Agrochemical Active Ingredient Manufacture

    Chemical synthesis facilities use limonene oxide as a selective intermediate for introducing oxygenated terpene motifs in crop protection agents, such as pyrethroid or carbamate precursors. The unique epoxide structure enables precise ring-opening functionalization and downstream transformations, essential during the preparation of advanced molecules aimed at improved environmental profiles and efficacy in the field. Compliance and traceability requirements during synthesis are closely monitored under agrochemical control standards.

    Industry compliance standards

    • ISO 9001:2015 for API/intermediate production
    • FAO/WHO specifications for manufacturing pesticide actives
    • EU Regulation (EC) No 1107/2009 for Plant Protection Products
    • US EPA Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA)

    Typical usage ratio

    • Stoichiometric ratios (typically, 1:1 molar basis with target functional group); exact loading based on desired intermediate conversion during process scale-up.

    Downstream process integration

    • Introduced during the early-stage organic synthesis step, specifically before ring-opening and further derivatization; continuous monitoring assures complete consumption, avoiding residuals in the final technical active.

    Final product types

    • Terpenoid-based herbicide or insecticide technical concentrates
    • Precursor blocks for pyrethroid synthesis
    • Functionalized carbamate pesticide APIs
    • Bio-active adjuvant intermediates

    5. Renewable Flavor Ingredient in Food and Beverage Preparations

    Manufacturers in the food and beverage sector utilize limonene oxide as a legally permitted, nature-identical flavoring agent to impart fresh, citrus aroma in non-alcoholic beverages, confectioneries, chewing gum, and liquid concentrates. The ingredient must meet food-grade benchmarks and be dosed precisely to achieve desirable sensory profiles without exceeding regulatory threshold limits. Processing teams closely manage its addition near the end of flavor blending to retain its integrity and sensory impact after heat pasteurization or dilution.

    Industry compliance standards

    • US FDA 21 CFR § 172.515 – Synthetic flavoring substances
    • EU Regulation (EC) No 1334/2008 on flavorings
    • Food Chemicals Codex (FCC) monograph
    • General Principles of Food Hygiene (Codex Alimentarius)

    Typical usage ratio

    • 1 – 20 ppm in finished food or beverage; maximum use level set by country-specific flavoring legislation and sensory limits.

    Downstream process integration

    • Added after base matrix pasteurization during flavor compounding; temperature-controlled dosing and rapid stirring prevent volatilization and preserve citrus aroma until final product bottling or packaging.

    Final product types

    • Ready-to-drink citrus beverages
    • Chewing gums
    • Flavored candies and jellies
    • Instant beverage powders and concentrates
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    Certification & Compliance
    More Introduction

    Introducing Limonene Oxide: Insights From a Chemical Manufacturer

    Innovation Born From Citrus: The Story of Limonene Oxide

    In the world of specialty chemicals, few products offer both the versatility and reliability found in Limonene Oxide. Coming straight from our production lines, this chemical bridges the natural world and industrial demand in a way that’s rewarding to witness. Instead of simply pushing out derivatives that fill a niche, we focus on refining every batch for performance across a growing span of applications. Limonene Oxide is a model of quality and adaptability, and its journey from orange peels to specialized fluid speaks volumes about the evolution of our industry.

    Direct from the Source: How Limonene Oxide Is Made

    Reliable upstream access to d-limonene, the core raw material, anchors our manufacturing process. Sourced mainly from citrus peel waste collected from food packing plants, d-limonene stands out as a naturally derived hydrocarbon. Through careful catalytic oxidation, our plant transforms d-limonene into Limonene Oxide using a method that prioritizes both product purity and environmental responsibility. Achieving a higher purity in the final oxide means smoother performance in downstream uses.

    Thanks to our direct control over the manufacturing process, we monitor each key parameter, from reaction temperature to oxygen concentration. Instead of working with ready-made intermediates, we run every batch under in-house analysis, using gas chromatography and spectrometric controls for consistency. That level of oversight shows up in the stability and color of our product, minimizing off-odors and unreacted residues. Many developers in coating, adhesive, and fragrance markets look for these details as a sign of a trustworthy supplier.

    Limonene Oxide Model and Specifications

    Our most in-demand grade is the Limonene Oxide Technical Grade, composed mainly of a 1,2-epoxide structure. Chemists value this epoxide functionality for its high reactivity, especially in polymer synthesis and formulation work. We typically supply material in drum packages to minimize exposure and keep oxygen away. Laboratory analysis typically places the limonene oxide content above 95%, and moisture content below 0.3%. Even though the oxide appears as a colorless to pale yellow liquid, minor changes in color from one batch to the next tell a story about raw material origin and process tweaks.

    We avoid masking cosmetic flaws: If a batch takes on a slightly darker hue, we acknowledge that the starting citrus feedstock might have varied in terpene content or that a reactor cycle ran longer. It’s more honest—and helpful for process engineers using the oxide in polymerization or fragrance applications.

    Applications: Beyond Just a Citrus Scent

    Many first hear about limonene oxide in the context of flavor or fragrance, given its mildly citrus aroma. Yet, our daily work with customers demonstrates that this molecule does much more. In the lab, chemists use limonene oxide as a building block for specialized resins and crosslinked polymers. The unique ring epoxide structure reacts readily with a wide variety of nucleophiles, an attribute that opens doors to synthesizing new specialty monomers.

    Our close collaborations with customers from the coatings, adhesives, and elastomers sectors taught us that limonene oxide can serve as both a co-monomer and a crosslinker. Using our technical grade, developers report improved hardness or chemical resistance in resins compared to when they use similar cyclic epoxides derived from petrochemical streams. End users in the field of biomedical research have also turned to Limonene Oxide as a biorenewable feedstock for advanced hydrogel systems and drug delivery platforms.

    This diversification in end uses comes from control over stereochemistry and purity. We routinely analyze batches for unwanted side-products, especially diol and polymerization by-products, because even subtle impurities can throw off hard-earned structure–property relationships in synthetic work.

    What Sets Our Limonene Oxide Apart?

    Talking about quality means more than just quoting numbers from a data sheet. Decades as a chemical manufacturer have taught us that every user approaches limonene oxide with slightly different expectations. Some might need a perfectly neutral odor profile because their application is in a flavor or fragrance matrix. Others, particularly those in specialty polymer development, value transparency about possible trace residues.

    Direct control over every step—starting with citrus feedstock selection and extending all the way to drumming and dispatch—forms the foundation for reliability. Instead of shaving off quality to push volumes, we stay true to process parameters, recognizing that an extra distillation, while time-consuming, preserves the integrity of the final product. It is not just about avoiding regulatory surprises, but about helping formulators avoid headaches during scale-up.

    Compared to generic third-party-sourced limonene oxides, our product traces its origin right back to a known citrus crop, followed by a fully documented conversion. That kind of traceability minimizes the possibility of contamination by petrochemical residues or non-food aromatics; it’s a detail often overlooked, until a project hits a snag from an unstable ingredient.

    Comparing Limonene Oxide to Other Epoxides and Monomers

    Plenty of customers ask how limonene oxide compares to classic epoxides like epichlorohydrin or cyclohexene oxide. From a chemist’s perspective, limonene oxide brings a larger, chiral framework—a feature that translates into selectivity in downstream reactions. Its biogenic origin and renewable sourcing often earns preference among developers seeking alternatives to fossil-based substrates, especially in green polymer chemistry and natural product synthesis.

    In terms of physical handling, limonene oxide stands as a lower toxicity choice versus halogenated epoxides—no need for special ventilation or disposal systems that drive up costs for small or medium-sized operations. Additionally, its volatility and flammability profile lines up with standard hydrocarbon solvents, so it slots easily into many existing workflow setups. One interesting distinction is the molecular weight and boiling range: limonene oxide sits in the midrange, lending itself to both solvent applications and reactive uses, in contrast with smaller, more volatile epoxides that might evaporate before full conversion can be achieved.

    Transparency and Safety: Straight Talk from the Production Floor

    Decades in manufacturing build an appreciation for the real-world challenges companies face when they introduce a new raw material. With Limonene Oxide, every batch comes with a full suite of analytical documentation—chromatograms, spectra, and moisture content data included. By keeping a line of communication open with downstream users, we get feedback about how our process changes might ripple downstream.

    On the safety side, compared to many synthetic epoxides, limonene oxide offers a lower toxicity profile. Teams working with the material appreciate not having to overhaul their plant safety setups. Of course, standard precautions—gloves, goggles, and good ventilation—still apply, since limonene oxide remains a reactive epoxide.

    Supply Reliability: No Guesswork, Just Supply Chain Collaboration

    Fluctuations in the supply of bio-based chemicals happen—any manufacturer who says otherwise hasn’t navigated a poor harvest season. By working directly with citrus peel processors, we lock in a steady flow of d-limonene ahead of the main production cycles. This foresight translates into shorter lead times and fewer stockouts. When hurricanes or blights hit certain citrus regions, we tap partnerships in different countries, spreading the risk across multiple suppliers.

    This isn’t just theory—our team has weathered swings in citrus oil prices by keeping a buffer stock of d-limonene feed and through downtime planning. That stable supply means customers can plan their own production runs without sudden surprises, which strengthens mutual trust in the long run.

    Quality Commitment in Every Drum

    Formulators and R&D professionals know that the smallest impurities or batches outside their specified range mean wasted hours and sinking budgets. We keep that front of mind. Every production campaign starts with fresh maintenance on the reactor systems and a review of analyticals. By the time Limonene Oxide leaves our warehouse, it’s been checked for peroxide number, acidity, color, and key contaminant ions.

    Some clients appreciate these details more than others, depending on whether their application puts a premium on optical clarity or odor. We find that transparency about small deviations in the batch pays off: Formulation chemists can make adjustments before a minor variance snowballs into a product failure.

    Fragrance and Flavor Industry: Meeting High Expectations

    Fragrance houses and flavor manufacturers pay attention to every whiff of an ingredient before committing it to their blends. Limonene oxide, while subtle and citrusy, shows delicate hints that can shift with changes in feedstock or reaction conditions. We’ve taken pains over the years to minimize foreign notes by adopting a two-stage vacuum distillation system. Those extra steps trim out trace aldehydes and oxidized terpene by-products, leading to a purer, rounder aromatic profile.

    We’ve learned from perfumers and flavorists that even faint resinous or metallic overtones prove unacceptable in premium fragrance builds. For those blending high-end or natural-certified fragrances, our documentation package also tracks the non-synthetic origin and compliance with IFRA and allergen standards. If clients want to blend with alcohol bases, the solubility profile and chemical stability data are already included in our standard technical data set, so there’s no guesswork.

    Sustainability and Environmental Responsibility

    It’s not just talk—the sustainability angle truly matters when we scale up production of limonene oxide. Our entire process is anchored to the re-use of food-grade citrus byproducts, a practice that diverts thousands of tons of organic material from landfill or low-value animal feed streams. By running solvent recovery systems and scrubbing exhaust at every stage, we limit the energy and emissions footprint from batch production.

    Environmental auditors sometimes visit our plant to check if all our claims line up with on-the-ground reality. Having worked to close loops on solvent usage and to minimize water consumption, we welcome these visits. Almost every adjustment we’ve made—whether changing from heated jackets to vacuum insulation, or tweaking airflow in the oxidation step—is traced back to client feedback about carbon accounting or life cycle assessment needs.

    In lower-waste administrative operations, we’ve begun working towards digital batch records, which allow us to track provenance of both d-limonene and additives used in the process. This transparency means our Limonene Oxide holds up to scrutiny by corporate sustainability teams looking for third-party verification, whether in green chemistry building blocks or as part of up-cycled natural ingredient stories for food and personal care applications.

    Challenges and Solutions: Lessons Learned as a Manufacturer

    Scaling up limonene oxide production from pilot to commercial scale came with no shortage of surprises. We battled catalyst fouling, occasional over-oxidation, and batch-to-batch variability in early years. By staying in close touch with both equipment suppliers and academic partners, we dialed in a process window that lands squarely on high-purity output while keeping byproduct formation minimal.

    There are no shortcuts—training operators to recognize early signs of side reactions kept product losses in check, and integrating real-time analytics helped us course-correct before full batch commitment. Frequent recalibration of GC equipment and weekly purity checks go a long way toward preventing customer returns or missed specs.

    Another lesson: the importance of customer education. By sharing detailed process notes and batch data with R&D teams, many clients were able to adapt formulations more quickly. This pay-it-forward mindset means our partners now rarely see delays or compatibility issues, even when shifting between different natural or synthetic monomer blends.

    Looking Ahead: Supporting Innovation With Trusted Raw Materials

    Limonene Oxide is more than a line item in a chemical catalog. Having supplied it for over a decade, we’ve seen firsthand how it empowers smaller, nimble innovators as well as established enterprises. From launching new resin chemistries to enabling functional fragrances, the molecule’s versatility often exceeds designers’ initial expectations.

    Each year, new applications open up—emulsion polymerization, lubricant additives, microcapsulation actives, and even green corrosion inhibitors. We stay in touch with university research labs and trade groups globally, exchanging use cases, technical hurdles, and performance results. Sometimes, those conversations come back around to process tweaks on our own lines—cycle time improvements, alternate catalysts, or better purification techniques. This culture of continuous improvement keeps the product relevant and responsive to an ever-evolving market.

    Real-world feedback from those who transform our limonene oxide into finished products helps us refine our approach—from batch scheduling to analytical support. Instead of sticking to a rigid product list year after year, we adapt, guided by the changing needs of the chemical, polymer, and flavors industries alike.

    Why Source Limonene Oxide Direct? Views from Our Experience

    Cutting out unnecessary supply chain steps brings measurable results: faster response times, better price stability, and technical support that draws on firsthand troubleshooting. Working as manufacturers, we aim for consistency—not only in the product, but in every shipment and every conversation with a customer’s formulators and R&D leaders.

    While it’s tempting in today’s market to chase every new trend with a barrage of product lines, we’ve chosen a different path: focus on delivering the best possible Limonene Oxide to support the real work being done in chemical development, sustainability, and manufacturing innovation. We look forward to seeing how new generations of chemists and engineers take this molecule in bold new directions, always with a foundation of quality, performance, and trust built on firsthand manufacturing experience.