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Citronitrile (Symrise)

    • Product Name Citronitrile (Symrise)
    • Alias Allylnitrile
    • Einecs 265-745-8
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    194729

    product_name Citronitrile
    manufacturer Symrise
    CAS_number 13877-91-3
    EC_number 237-617-9
    molecular_formula C8H9N
    molecular_weight 119.17 g/mol
    odor_description fresh, citrus, green, aldehydic
    appearance colorless to pale yellow liquid
    boiling_point 235-237°C
    flash_point 94°C
    refractive_index 1.4920 - 1.4960
    density 0.983 - 0.988 g/cm³
    solubility insoluble in water; soluble in alcohol and oils
    use fragrance ingredient
    purity ≥ 95%

    As an accredited Citronitrile (Symrise) factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The packaging for Citronitrile (Symrise) is a 1 kg opaque HDPE bottle with a secure screw cap, labeled with product details.
    Shipping Citronitrile (Symrise) should be shipped in tightly sealed, clearly labeled containers, following all relevant chemical safety regulations. Store and transport in a cool, well-ventilated area, away from heat, ignition sources, and incompatible substances. Proper documentation must accompany the shipment to ensure compliance with local, national, and international transport regulations.
    Storage Citronitrile (Symrise) should be stored in a cool, dry, and well-ventilated area, away from heat sources and direct sunlight. Keep the container tightly closed and stored in its original packaging. Avoid contact with strong oxidizing agents. Ensure proper labeling and segregate from incompatible substances to prevent contamination. Follow all applicable safety and storage guidelines for chemicals.
    Application of Citronitrile (Symrise)

    Applications of Citronitrile (Symrise) in Industrial Manufacturing

    We supply high-purity Citronitrile directly to leading industrial sectors as a key chemical raw material enhancing performance in specialized applications. Through controlled manufacturing and strict batch traceability, our Citronitrile supports critical formulations and processing steps from fine fragrance compounding to advanced material synthesis. Below we detail verified end-use scenarios established in industrial production chains.

    1. Fragrance Ingredient for Fine Perfumery

    Citronitrile acts as a sophisticated modifier in premium fine fragrance formulations, imparting a distinctive citrus-green top note while balancing base elements. Fragrance houses employ it to construct modern accords, especially in niche perfumes requiring high-impact, long-lasting freshness. Our grades maintain compliance with global perfumery safety guidelines for use in skin-applied products. Standard blending involves direct integration in perfume compounds before dilution with solvents and alcohols to achieve target olfactory profiles without performance loss under IFRA emission restrictions.

    Industry compliance standards

    • IFRA Standards (International Fragrance Association)
    • EU Cosmetics Regulation (EC) No 1223/2009
    • REACH Registration (EC No. 1907/2006)
    • USA FDA 21 CFR 700 (Cosmetics)

    Typical usage ratio

    • 0.05%–0.3% of concentrate (adjusted for total fragrance load and IFRA limits by category)

    Downstream process integration

    • Added in the compounding stage prior to final dilution, direct blending with essential oils and aroma chemicals

    Final product types

    • Fine perfumes
    • Eau de toilette
    • Luxury body sprays
    • Signature niche fragrances

    2. Aroma Compound for Household and Industrial Cleaners

    Industrial and household cleaning product manufacturers utilize Citronitrile as an aroma component for surface cleaners, liquid detergents, and air fresheners. By incorporating this compound in fragrance blends, formulators achieve a desirable citrus nuance that enhances user perception of cleanliness while masking strong base odors inherent to surfactant systems. Processing must ensure compatibility with alkali, oxidative, and surfactant matrices. Quality control measures require precise dosage to conform to regulatory fragrance exposure and volatile organic compound (VOC) thresholds across target markets.

    Industry compliance standards

    • IFRA Standards – Category 9, 10A/B (Household & Industrial Cleaners)
    • EU Detergents Regulation (EC) No 648/2004
    • USA EPA Fragrance Ingredient Labeling Program
    • A.I.S.E. Guidelines (Association for Soaps, Detergents and Maintenance Products)

    Typical usage ratio

    • 0.03%–0.15% in finished detergent or cleaner formulations; adjusted for product type, application area, and regional VOC directives

    Downstream process integration

    • Introduced during fragrance incorporation, post-neutralization, prior to product filling and packaging

    Final product types

    • Surface cleaners
    • Hard surface disinfectants
    • Fabric detergents
    • Aerosol and gel air fresheners

    3. Scent Intermediate for Industrial Flavor Synthesis

    Citronitrile serves as a precursor or intermediate in the industrial synthesis of flavoring agents, particularly for beverage and food flavor houses aiming to achieve lifelike citrus and herbal flavor notes under strictly monitored production. Its conversion by selective hydrogenation or oxidation can yield valuable derivatives integrated into flavor bases compliant with food additive regulations. Manufacturing procedures necessitate validated traceability, avoidance of allergenic by-products, and adherence to designated purity profiles for safe use in human consumption.

    Industry compliance standards

    • FAO/WHO JECFA Food Additive Status
    • EU Commission Regulation (EU) No 1334/2008
    • USA FEMA GRAS (Generally Recognized as Safe)
    • ISO 22000:2018 Food Safety Management System

    Typical usage ratio

    • Dependent on downstream transformation: typical conversion rates 0.1%–0.5% molar input as synthesis intermediate

    Downstream process integration

    • Employed at precursor synthesis stage, catalyzed transformation prior to formulation into food flavor bases

    Final product types

    • Natural and nature-identical citrus flavors
    • Herbal and green flavor bases for soft drinks
    • Specialty food aromatics
    • Concentrated flavor syrups

    4. Building Block for Agrochemical Synthesis

    Leading agrochemical developers use Citronitrile as a fine chemical intermediate in the synthesis of selected crop protection active ingredients, exploiting the nitrile's reactivity for subsequent functionalization by catalytic or nucleophilic substitution steps. Our production ensures tight control of impurity profiles and batch reproducibility, supporting consistent outcomes in multi-step agrochemical synthesis lines. Final active incorporation follows strict residue and environmental safety guidelines to protect both food safety and ecological systems.

    Industry compliance standards

    • EU Regulation (EC) No 1107/2009 (Plant Protection Products)
    • OECD Good Laboratory Practice (GLP)
    • USA EPA Pesticide Registration (FIFRA)
    • FAO/WHO Codex Pesticide Residue Limits

    Typical usage ratio

    • 1.0%–5.5% as starting material in active ingredient synthesis, adjusted according to desired downstream transformation paths

    Downstream process integration

    • Introduced in primary chemical synthesis, typically in batch or continuous stirred-tank reactors under controlled temperature and pressure

    Final product types

    • Herbicide and fungicide actives
    • Precursor compounds for plant growth regulators
    • Intermediate cores for insecticidal agents
    • Custom crop protection blending ingredients

    5. Synthesis Intermediate for Pharmaceutical Intermediates

    Major API and generic drug manufacturers use Citronitrile as an intermediate in the synthesis of select heterocyclic compounds and bioactive molecules. The nitrile group enables diversified downstream reactions, such as amidation and cyclization, essential in constructing complex pharmaceutical scaffolds. Our pharmaceutical-grade product aligns with GMP traceability and is supplied with comprehensive analytical documentation. Final transformation steps must strictly meet pharmacopoeial purity and impurity limits before further processing in API manufacturing.

    Industry compliance standards

    • ICH Q7 GMP for Active Pharmaceutical Ingredients
    • USP/NF (United States Pharmacopeia)
    • EP (European Pharmacopoeia)
    • Japanese Pharmacopoeia (JP)

    Typical usage ratio

    • 1.5%–8.0% as an intermediate (mole ratio relative to target product), optimized per specific process yield and scaling requirements

    Downstream process integration

    • Added at early or intermediate synthesis stages for construction of active pharmaceutical ingredient (API) frameworks under validated process control

    Final product types

    • API intermediates for cardiovascular drugs
    • Building blocks for CNS-active agents
    • Precursors for anti-infective compounds
    • Advanced heterocyclic chemical synthons

    6. Component for High-Performance Polymer Additives

    Polymer producers employ Citronitrile-derived compounds in the formulation of specialty plasticizers and performance additives, improving the flexibility, processability, and stability of engineering plastics and coatings. Integration requires precision blending and monitoring to ensure final polymer characteristics meet application-specific requirements, especially in automotive and electronics components. Material selection adheres to global chemical regulation to guarantee finished product quality and end-user safety—especially for items subject to mechanical and temperature exposure.

    Industry compliance standards

    • EU REACH Regulation (EC) No 1907/2006
    • RoHS Directive 2011/65/EU (Restriction of Hazardous Substances)
    • UL 94 Flammability Standards
    • ISO 9001:2015 Quality Management for Polymers

    Typical usage ratio

    • 0.1%–0.6% in masterbatch or compound, adjusted for polymer matrix compatibility and targeted enhancement effect

    Downstream process integration

    • Directly dosed into extruders or compounding lines before pelletization and downstream molding operations

    Final product types

    • Engineering plastic components
    • Polymer films for electronics
    • Automotive trim parts
    • Protective functional coatings
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    Certification & Compliance
    More Introduction

    Citronitrile (Symrise): The Practical Choice for Aroma and Synthesis

    Taking a Closer Look at Citronitrile

    At our facility, real manufacturing happens — with hands-on experience and continuous evaluation of every batch that leaves our site. For decades, our lines have produced Citronitrile with consistent quality, targeting industries that demand reliable results. Workers here take pride in the process, and this commitment shows in the finished product. Citronitrile, under the Symrise brand, has made its mark among fragrance and intermediate material makers for its distinct performance traits and clarity of profile.

    Key Characteristics and Handling

    Each drum and tote that leaves our dock contains a clear, colorless to faintly yellow liquid with a fresh, green-citrus character recognizable even in low concentrations. With a molecular formula of C8H13N and a structure that brings together an aliphatic nitrile group bonded to a citronellene backbone, Citronitrile stands out in both performance consistency and chemical stability.

    Industries find value in its flashpoint near 71°C and boiling range between 210°C and 215°C. From a handling perspective, this product holds together even under the stresses of large-scale mixing and transport, showing resilience during formulation and compounding, especially in environments requiring elevated temperatures. In our experience, purity levels consistently test above 97%, and impurity profiles stay low, providing confidence with every shipment—our teams track these metrics batch by batch.

    Why Manufacturers Depend on Citronitrile

    Perfumers trust Citronitrile for its ability to push top-note brightness in compositions—from fine fragrances to personal care products. The structure lends a sharp, fresh accent that survives into the heart notes, unlike many other synthetic citruses that fade fast or turn sour. In technical uses, our Citronitrile serves as a robust intermediate. Chemical companies draw on its accessible nitrile group for further transformation, especially where downstream amines, acids, or cyclizations depend on substrate integrity. Attempts to substitute it with generic citronellal derivatives turn up performance gaps, particularly in yield and aroma retention during synthesis.

    Manufacturing plants working with Citronitrile benefit from its predictable solubility profile. We’ve resolved many challenges for partners scaling up—Citronitrile holds in both polar and nonpolar phases, and our internal reports show consistent results whether working on pilot plants or full-scale reactors.

    Comparing Citronitrile (Symrise) to Other Citrus Nitriles

    We often encounter buyers asking why they shouldn’t settle for less expensive substitutes or generic alternatives sourced without nameplate identification. Here the real-world difference shows. Citronitrile (Symrise) comes with a guaranteed isomeric profile—minimal unwanted side components, low levels of byproducts like citronellal or citronellol, and much less variability in odour and purity.

    Some alternatives, even with similar paperwork specs, deliver an off-color tint, leave behind residues in distillation, or create difficulties during downstream hydrogenation or reductive amination. In our experience, off-brand citronitrile can introduce a soapy or fatty overtone after storage, especially if batches see uncontrolled temperature during transit. Producers running demanding processes notice an uptick in these issues, which leads to higher rejection rates and time spent resolving complaints. Long-time users know to ask for our lot numbers because it saves trouble over the long haul.

    Everyday Uses: More Than Just Fragrances

    Personal care brands making soaps, shampoos, and household cleaners know Citronitrile’s value. Just a fraction of a percent shifts the perception of a product; it brings an uplifting effect when combined with grassy or floral bases. Over the years, formulators working in our pilot labs have developed techniques for incorporating Citronitrile into everything from sports sprays to advanced aromatherapy sets. One of our earliest milestones involved helping a regional brand stabilize their entire detergent line’s scent profile against temperature-driven fading — Citronitrile provided the answer, standing firm while cheaper substitutes failed in real-world shelf tests.

    Chemical processors use Citronitrile as a starting point for building more complex ingredients: imines, carbinols, acids, and even more diverse nitrile derivatives. Our teams have optimized process parameters so thermal decomposition remains negligible. The lab bench feedback loops directly with the plant floor, so there’s no disconnect between theory and actual efficiency.

    Solving Problems Other Manufacturers Overlook

    Years ago, a client in agricultural chemicals brought us a puzzle: a longtime alternative source delivered citronitrile that crystalized under basic storage conditions, resulting in plugged lines and repeated downtime. Others complained about volatility losses during summer shipments or persistent background odours in final products. Our Citronitrile maintained a liquid state across routine warehouse temperatures and showed a stable loss rate even in warm climates. Tracing the issue to micro-impurities in other sources, we refined our distillation and purification protocols, resulting in batches that performed better not just on paper but in actual use.

    Batch reliability stays front and center in our plant. We don’t push material out the door until in-house teams agree every lot meets a risk threshold by more than just a narrow margin. We document this work meticulously, from spectroscopic confirmation of purity to GC-MS checks for trace aldehydes. People using Citronitrile downstream in reactors, compounding rooms, and perfumery labs send fewer complaints—and many share results, contributing insights we reinvest in future production.

    Environmental Responsibility in the Production Process

    We recognize how vital it is to monitor environmental impact through every stage. Over the last decade, our plant updated both process controls and solvent recovery loops, lowering overall emissions and residual byproduct load. These changes have cut atmospheric losses, and our waste water readings improved, confirming less carryover of volatile organics. Each regulatory audit brings new challenges, but we approach them as an opportunity to make another step forward. We do not take shortcuts in raw material selection or finished goods documentation, because efficiency is only worth the effort if it lasts.

    Our customers working to secure organic or ecologically sound certifications appreciate that our Citronitrile production avoids persistent contaminants or heavy metal catalysts. What goes into our process sets the standard for what ends up in final goods. That’s not just a compliance box—it’s an everyday plant mindset.

    Performance in Real Production Scenarios

    In personal care labs, Citronitrile brings not just a “freshness” quality, but a resilient backbone that interacts predictably with surfactants, solubilizers, and other aroma chemicals. Whether a client needs a lift in hand soaps or fabric conditioners, our history with the compound provides the know-how to guide dosing and blending, especially in high-throughput systems. Our staff have built application data covering shelf-life performance, batch compatibility, and even fragrance migration over time. With feedback from major clients, the technical team occasionally shares adjustments to standard use levels or established synergy with other volatile top-notes.

    Industrial chemical buyers benefit from batch-to-batch consistency in capacity-controlled reactions—Citronitrile’s reactivity enables efficient conversion, supporting processes where both throughput and minimized impurity formation are key goals. We’ve seen big differences in waste treatment costs and product quality between our Citronitrile and bulk technical grades. Our feedback loops with downstream users drive further improvement: if a customer reports unexpected results, technical support reviews both analytical and operational data. This reduces time spent troubleshooting, which trickles down as lower costs and better margins for those who stick with our supply.

    Direct Monitoring and Continuous Improvement

    Our manufacturing culture holds a strong expectation for transparency, and it pays off during both internal review and third-party audit. The plant has put in measurement points along all batches — not only at final packaging but throughout the process. Plant supervisors and hands-on technicians catch issues before they escape containment. No ambiguity about who owns a batch or where a deviation originated. This allows for true traceability, which some global buyers now ask for as a prerequisite.

    Experience tells us process improvement can only happen with a real link between what happens in the reactor and the results downstream. By using real-time process analytics, we achieve sharper control and faster interventions. Minor tweaks honed over time—like revised heating ramp schedules or phased addition of reagents—show measurable return in both finished product and operator safety.

    Clients appreciate open lines of communication. Many share their end-use results, and this feedback pushes us to upgrade both technical protocols and customer support materials. Sometimes the most impactful improvements stem from a simple production-floor observation passed along to R&D.

    Frequently Asked Questions and Cautions

    Potential buyers who work with flavor or fragrance allergens often want confirmation that our Citronitrile avoids problematic side components—yes, we check for regulated impurities every run. Production lots carry clear documentation, and our worker safety team regularly updates instructions to reflect evolving regulations. While Citronitrile blends smoothly into most formulations, direct handling calls for basic safeguards: chemical splash goggles, nitrile gloves, and ventilation for drum opening and transfer.

    Some users new to the chemical worry about storage. We advise containers be kept tightly closed and away from heat sources. The native chemical stability holds up in most common storage environments, but years of shipping teach us to avoid mixing leftovers from varying suppliers. Even at our own site, each drum remains fully tracked from receipt through depletion. Small steps like these prevent off-spec reactions and complaints later.

    From Production Floor to Final Product: Trust in Process

    Our operations team knows every metric behind each drum of Citronitrile, from process yield and energy use to impurity trends. Plant reports highlight both problem batches and success stories, leading to practical improvements in filtering, distillation, and final QC checks. The gap between design and reality shrinks with each year of manufacturing.

    End users recognize the benefits. Tighter control at the manufacturing level translates to better end results—fragrance compositions with depth and staying power, intermediates that convert cleanly, and fewer hauls returned for QA investigation.

    We focus on delivering a straightforward product—one that reflects actual effort by real people, not just broad claims. Feedback from industry users and everyday plant experience keeps us honest. By controlling every step from sourcing to shipment, we minimize surprises and support partners in delivering their own consistent end products.

    Looking Ahead: Meeting Market and Regulatory Demands

    The regulatory landscape never stays still. Our compliance specialists track both current and coming rules related to nitrile chemicals, including global limits on residual solvents and labeling demands. Sourcing and documentation practices evolve to match or exceed these benchmarks. It’s not just about passing an audit once; it’s about creating production habits that endure.

    We remain mindful that every drum plays a part beyond our factory—ending up in products that touch the lives of millions. Rigid quality targets and open-door policies between production, technical support, and end user labs make a difference. Even with rising energy prices or shifting supply chain bottlenecks, the underlying commitment to reliable Citronitrile supply does not change.

    How We Stand Apart

    Our approach to Citronitrile distills years of actual experience into each shipment. We understand what downstream processors reallly face — raw material shortages, unpredictable costs, and market-driven reformulations. The plant culture leaves no room for the “good enough” mentality that leads to hassle or downtime months later. Instead, every batch is a direct result of hands-on attention, data review, and lessons from both successes and setbacks.

    We invite our partners to bring their toughest questions or feedback. From fixing formulation headaches to sharing long-term supply concerns, we keep the dialogue active. Real manufacturing means being answerable for every drum’s history—owners, operators, and technical staff all play a role in keeping standards high.

    Citronitrile (Symrise) reflects that culture: not a commodity, not an afterthought, but a measurable result of work ethic, continuous review, and attention to every stage from synthesis to shipment.