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Cis-Bigarade Oxide

    • Product Name Cis-Bigarade Oxide
    • Alias cis-2,6-Dimethyloxepan-2-one
    • Einecs 689-631-1
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    407586

    CAS_Number 28622-73-5
    Molecular_Formula C10H16O
    Molecular_Weight 152.23 g/mol
    Appearance Colorless to pale yellow liquid
    Odor Fresh, citrus, floral
    Density 0.915 - 0.925 g/cm³
    Boiling_Point 228-230°C
    Refractive_Index 1.468 - 1.472
    Flash_Point >100°C
    Solubility Insoluble in water, soluble in alcohol and oils

    As an accredited Cis-Bigarade Oxide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Cis-Bigarade Oxide is packaged in a 100g amber glass bottle with a secure screw cap and detailed labeling for safety.
    Shipping Cis-Bigarade Oxide is shipped in tightly sealed, chemical-resistant containers to prevent leakage and contamination. It should be stored away from heat and direct sunlight during transit, with clear labeling according to hazard regulations. Appropriate documentation accompanies each shipment to ensure compliance with safety and transportation standards.
    Storage Cis-Bigarade Oxide should be stored in a cool, dry, and well-ventilated area, away from direct sunlight and sources of ignition. Keep the container tightly closed and use airtight, chemically compatible containers to prevent contamination and degradation. Store separately from strong oxidizers, acids, and bases. Always follow local regulations and safety guidelines for the storage of chemicals and aromatic compounds.
    Application of Cis-Bigarade Oxide

    Applications of Cis-Bigarade Oxide in Industrial Manufacturing

    Cis-Bigarade Oxide serves distinct roles in specialized chemical and industrial sectors, valued for its nuanced citrus aroma profile, oxidation stability, and regulatory acceptance for use in high-value aroma compositions. As direct manufacturers, we support formulation specialists and industrial processors in fragrance, flavor, and aromatic chemical production, ensuring our raw material integrates directly with evolving global quality standards and downstream requirements.

    1. Fine Fragrance Compounds for Luxury Perfume Manufacturing

    In the fine fragrance sector, manufacturers rely on cis-Bigarade Oxide to impart refined citrus top notes and provide oxidative stability in high-end, long-lasting perfumes. The material enters the compounding process during top note blending, where precision in balancing natural and synthetic aromatic profiles is essential. Fragrance houses and contract manufacturers monitor IFRA and EU Cosmetics regulatory frameworks, employing cis-Bigarade Oxide in concentrations that deliver olfactory clarity without exceeding allergen limits, and perform batch testing to verify component integrity and batch-to-batch consistency before bottling.

    Industry compliance standards

    • IFRA Standards for Restriction and Allergen Disclosure
    • EU Cosmetics Regulation (EC) No 1223/2009
    • REACH Registration Compliance for Fragrance Chemicals
    • Good Manufacturing Practice (GMP) - ISO 22716

    Typical usage ratio

    • Applied at 0.01–0.15% in concentrate, adjusted based on brand-specific olfactory targets and cumulative citrus load
    • Dose adjustments depend on regulatory thresholds for terpene oxidation products in the total formula

    Downstream process integration

    • Introduced during initial blending of top and heart note chemicals in ethanol or DPG-based media
    • Stabilization and homogenization under chilled conditions to preserve volatile profile

    Final product types

    • Prestige category Eau de Parfum (EDP)
    • Niche extrait fragrances
    • Cosmetic-grade scented body sprays
    • High-performance room perfumes

    2. Flavor Additive for Citrus Beverage and Confectionery Formulations

    Cis-Bigarade Oxide is adopted as a minor but impactful flavor modifier in citrus-based beverages and sugar confectioneries, particularly where formulators require an authentic bitter-sweet orange character without introducing harsh pithy notes or instability under heat. Ingredient technologists introduce the oxide during post-emulsification or in pre-mix flavor oil stages to guarantee reproducible distribution, ensuring compliance with global food safety and labeling standards, including specific FEMA and Codex Alimentarius recommendations.

    Industry compliance standards

    • FEMA GRAS Status: FEMA No. 3165
    • US FDA 21 CFR 182.20 for Flavouring Agents
    • Codex Alimentarius GSFA Functional Class: Flavouring Substances
    • EU Regulation (EC) No 1334/2008 for Flavourings

    Typical usage ratio

    • Standard application 1–10 ppm in finished beverage or candy formulas
    • Maximum level set according to regional flavoring regulations and organoleptic threshold studies for bitterness perception

    Downstream process integration

    • Blended into flavor oil concentrate or aqueous pre-mix with carrier solvents
    • Heat-stable inclusion post-pasteurization or during cold-fill bottling to maintain profile integrity

    Final product types

    • Bottled citrus sodas and sparkling drinks
    • Premium soft drink flavor emulsions
    • Candied orange peel formulations
    • Hard and soft sugar confectionery with natural orange flavor

    3. High-Stability Fragrance Ingredients for Detergents and Cleaning Chemicals

    Household and institutional cleaning product formulators value cis-Bigarade Oxide for its remarkable oxidation resistance, making it ideal in liquid and powder detergents requiring long-term storage stability and sharp citrus freshness even post manufacture. Manufacturers dose the oxide in surfactant bases or solid powder blends, meticulously quantifying levels to conform with GHS safety disclosures and regional restriction lists while maintaining performance in high-alkaline or bleach environments.

    Industry compliance standards

    • EU Detergents Regulation (EC) No 648/2004
    • GHS Labeling Requirements for Chemical Mixtures
    • IFRA Guidelines for Household Application Fragrances
    • California Proposition 65 notifications for cleaning products (if shipped to US markets)

    Typical usage ratio

    • Formulators employ at 0.005–0.03% within aromatics content, often below skin sensitization threshold
    • Specific levels set based on total citrus terpene load and product format (liquid/powder)

    Downstream process integration

    • Added into nonionic/anionic surfactant blend tanks post saponification or in powder blending lines after base granulation
    • Mixed prior to final scent reaction and QC batch sampling for shelf stability evaluation

    Final product types

    • Liquid laundry detergents for consumer sector
    • Automatic dishwasher tablets
    • Industrial surface cleaning concentrates
    • Household multi-surface sprays with citrus profiles

    4. Aroma Chemicals for Essential Oil Rectification and Citrus Reconstitution

    Essential oil processors and blenders utilize cis-Bigarade Oxide to standardize bitter orange oil profiles or create rectified compositions for bespoke perfumery and aromatherapy applications, addressing seasonal and regional variation in natural distillate content. Material is introduced upon completion of primary oil distillation or during fractional stripping stages, and technical teams perform GC-MS assessments to verify compliance with international oil purity and labeling guidelines.

    Industry compliance standards

    • ISO 9842:2016 (Oil of Bitter Orange, Citrus aurantium L.)
    • IFRA Standards for Essential Oil Safety
    • US Pharmacopeia/European Pharmacopoeia EO Quality (where applicable)
    • GB/T 22760—Chinese National Standard for Citrus Oils

    Typical usage ratio

    • Blending of 0.1–1% into citrus oil batches, depending on target isomeric oil profile and customer specification sheet
    • Adjustment based on detailed volatile content analysis and batch origin

    Downstream process integration

    • Added post-distillation, prior to filtration and bulk homogenization tank step
    • Full batch quantification via GC-MS to certify standardized isomer composition

    Final product types

    • Rectified bitter orange oils for aromatherapy
    • Custom standardized essential oil blends for fine fragrance
    • Therapeutic essential oils for certified aromatherapeutic use
    • Natural aroma concentrate bases for downstream compounding
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    Certification & Compliance
    More Introduction

    Cis-Bigarade Oxide: Lifting Quality and Reliability in Citrus Fragrances

    Bridging Tradition and Modern Sourcing

    In the world of chemical manufacturing, sourcing genuine aroma molecules remains both a matter of craft and raw responsibility. Our production of Cis-Bigarade Oxide reflects decades of careful refinement and control. Harvesting and processing plant-based precursors for this unique oxide demand close attention—timing of each cut, temperature during extraction, and the sequence of fractionation make all the difference in what ultimately fills the drums. Staff at the distillation benches labor over every batch, checking for the familiar, piercing-green, bittersweet citrus note that distinguishes real bigarade from confusing imitations.

    Among citrus oxides, Cis-Bigarade Oxide holds a reputation in professional perfumery for its distinctive top note—one lifting up any fresh accord with brisk, leafy brightness. This character mostly arises from its geometric molecular shape. Not every extraction technique preserves the delicate arrangement of the cis isomer. We have found over years of practice that gentle vacuum distillation protects the fragile oxide linkage, eliminating thermal side reactions that can breed harshness. This technique sets our material apart from certain commercial samples, which often drift toward muddiness and lack that natural sweet-green flash. Our team never takes shortcuts—our repeat buyers expect clarity and precise strength in the aromatic profile.

    Purity at Every Jar: Sensory and Analytical Assurance

    Manufacturing at scale introduces risk. Tanks can pick up impurities. Plant fibers yield to moisture, and copper reacts if it sits exposed. In many commodity facilities, these factors chew into product grade and trust. Here, dedicated stainless lines and regular maintenance strip variables to a minimum. We employ a three-stage purification, beginning with filtration through food-grade media, then fine distillation, and finally gas-phase scrubbing. Out of each lot, samples land in our sensory panel's hands—and instruments. Trained noses can sense off-notes in parts per million long before any machine can. This tradition of on-site panel sampling, all within the same building as synthesis, keeps the feedback loop immediate.

    Once olfecatory checks pass, we turn to chromatography. Our team quantifies cis isomer content and confirms absence of bigarade oxide’s more pungent trans form. Per industry demand, we hold the major peak for cis at over 92 percent in the finished concentrate. This high isomeric purity means formulators dial in both intensity and authenticity, each time they open a pail. Some mass-market suppliers never guarantee a traceable isomer content, which can leave perfumers with uncertain output. Our own downstream blends, meant for fine fragrance and food use, never stray from this tight bottleneck.

    Why Bigarade Oxide Matters

    (true bigarade oil gives its fruit aroma to everything from classic cologne to orange sodas). There are other molecules in citrus, but none marry such earthy richness to the flash of zesty top note as bigarade’s oxide. Natural orange oil carries many compounds, yet Cis-Bigarade Oxide singles out a signature, sharper brightness—creating that pink-spicy, woody nuance highly valued among perfumers. Without it, the heart of cologne blanks out, seeming empty or plain. Overuse of synthetic limonene or decanal flattens the experience, replacing authenticity with generic, linear sweetness.

    Down on the production floor, our team spends as much time in the lab tuning yields as they do in aging stores—because freshly made oxide undergoes subtle shifts as it stabilizes in storage. Too soon in blending, and harsh edge may dominate; too late, and the aroma softens, threatening loss of potency. Years of batch records let us time the move from reactor to warehouse to customer dock. This knowledge anchors reliability—a core promise in our business.

    Cheaper bigarade substitutes sometimes parade as “citrus oxide blends.” Their origin varies, with rice hulls or even petrochemical byproducts stepping in. Some makers may blend in offcuts from orange terpenes, masking the lack of true oxide with vanillin or methyl heptenone. Our focus stays on verifiable citrus origin, and every tank receives a full spectrum GC-MS fingerprint before approval. Customers know exactly what they’re getting, batch after batch.

    Model and Handling: Consistency by Process

    Each shipment of Cis-Bigarade Oxide leaves in HDPE drums, labeled for trackable origin and age. We configure the viscosity for clean pipetting and easy dissolution. Bulk buyers receive two viscosity grades tailored by downstream demand—one for fast dilution in alcohol, another for technical-grade applications in solvent-free blends. Particle size does not feature, as this is a pure liquid concentrate free from carriers or diluents. Each batch brings a faint tinge in color, ranging from nearly colorless to faint straw, varying mainly from crop cycle rather than process.

    Unlike some products, Cis-Bigarade Oxide resists rapid oxidation—and yet, air and light eventually spark changes in its bouquet. Because of this, we seal drums under nitrogen and encourage customers to use up partial drums quickly. Our technical liaisons suggest drawing down into smaller, opaque containers. From long collaboration with global flavor houses, we track shelf lives that vary by storage—less than eight months in open air, up to two years under inert gas conditions at 12°C. Checking for loss of sharpness is a simple matter of diluting a drop per 100mL ethanol and sampling with professional glassware.

    No material survives careless storage or imprecise blending. This holds especially true for delicate aromatics. Our feedback lines remain open, and we routinely adjust production techniques based on end-user reports, especially when top perfumers provide notes on drift or change in their signature bases.

    Usage in Real Formulations

    Master perfumers often reach for our Cis-Bigarade Oxide to start new citrus top notes in colognes and eaux. Classic blends of neroli, petitgrain, and lavender receive extra brilliance, extending the “lift” of the opening without adding harsh alcohol spike. In modern soda flavorings, formulators prize its ability to mimic the burst and retronasal impact of fresh-peeled Seville orange—without having to chase seasonal crop variability. Blenders in premium cleaning products and air fresheners claim a special satisfaction from the material, saying it evokes cleanliness and sunshine in a way that synthetic limonene simply cannot.

    We have seen demand spread well beyond classic perfumery. Some beverage brands use tiny drops to shape citrus notes into something both clean and wild, without resorting to heavy aldehyde content. Chefs working with “aroma cocktails” and culinary mists find the balanced green-bitter note indispensable for certain high-end savory or pastry works. Experience shows that blending at fractions of a percent is usually enough—overdosing quickly overwhelms more subtle notes.

    In all, the difference between real cis oxide and cheaper alternatives emerges most strongly when fragrance or flavor encounters air and skin. Our material holds its complex, leafy-green overtones as the base dries down, rather than falling away in a simple, generic orange burst. The finest noses and seasoned R&D teams notice these details immediately. They drive steady demand for our consistent output year after year.

    How Our Bigarade Differs from the Rest

    Most differences in Cis-Bigarade Oxide outside commodity circles stem from origin and handling. Some traders co-mingle finished material from multiple extraction sources, which can dull the aromatic edge and risk contamination. We keep each batch traceable from field to drum, logging all soil reports, varietal data, and extraction coordinates. This yields a reliability customers come to count on. Furthermore, we avoid stabilizers and carriers—some market samples get padded with propylene glycol or glyceryl caprylate, leading to “stickiness” or opacity that blurs the initial aroma.

    Other suppliers, often geared toward high-output flavor manufacture, run faster distillation rates, seeking volume. Our slower, low-vacuum rectification yields less per day, but preserves the molecular integrity and critical green note. Repeat customers sometimes compare samples side-by-side and report our oxide holding both bitterness and subtlety as a true-to-nature signature.

    Another point of difference comes from our no-blend, single-crop approach. Warehouse sampling tracks batch uniformity, and if irregularity pops up—cloudiness, overly sharp top, loss of heart-green—we’re able to pull and adjust process parameters at source. We never rework with synthetic blends to “mask” off-seasons. Instead, field teams offer early warnings, and chemists tweak timing or conditions, always learning from the relationship between soil, crop, and finished aroma.

    Many end-users, especially in France and Japan, demand full qualitative analysis with each drum. Our policy supplies both full spectrum chromatograms and a sensory scorecard, so customers purchase on clarity, strength, and purity, not claims or labels alone. While regulatory standards continue to evolve, we surpass requirements for trace solvent, heavy metals, and PAH markers, following protocols shared by both IFRA and FSSC 22000.

    Feedback from the Front Lines

    Customers regularly share their field notes. A multinational drinks brand buying twenty drums a year discovered their signature “spray” effect diminished when running out of our supply, turning to a generic European sample. The difference grew clear after taste-panel sessions: the substitute lacked the characteristic bitterness and green floral “pop.” Similarly, European candle makers seek our oxide for its burn stability—the aroma persists, blending with hot wax rather than disappearing as so often happens with lighter oil-derived materials.

    Fulfilling these performance promises takes more than high-purity extraction—it depends on stable climate storage, batch documentation, and direct shipping. Our logistics compound stays climate-controlled year-round, holding both raw and finished goods to promise the end-user the material they remember and request by name. Any incident—a leaky seal, over-aged sample, frost-damaged lot—gets logged, traced, addressed, and adjusted for the future.

    No chemical is perfect. Disaster can strike: hail can devastate orange groves, a fire might stall production, shipping delays can threaten supply chains. We mitigate with both on-site reserves and close relations with farming partners, guaranteeing that barring force majeure, consistency holds.

    Environmental Commitment and Sourcing

    Sustainable practice is no longer a buzzword—it’s the baseline of trust. Every year, our procurement teams review grower lists, working only with partners that pass third-party certification for water management, biodiversity, and chemical inputs. Unlike some commodity factories, we avoid outsourcing to brokers, instead building long-term supply chains where fieldwork supports both crop and community resilience. This also helps keep stories and experience as part of our products, rather than reducing everything to anonymous extracts.

    Waste byproduct from orange pressing undergoes composting or bioenergy generation, depending on which cycle maximizes reuse. We avoid hypochlorite cleaning steps, using food-grade steam where possible. Laboratory solvents circulate in closed loops to avoid accidental release, and waste effluent meets both local and transshipment port standards. All packaging material undergoes vendor verification for food-grade purity and recyclability.

    Industry demands transparency. Each year, our team submits for voluntary third-party audit of both chemical and social operations. Full data on solvent use, emission, and waste ends up reported in our public sustainability disclosures. Visiting customers have the run of our facility, from extraction benches to aroma panels, ensuring open dialogue and direct evidence supports our performance claims.

    Meeting Future Needs: Challenges and Development

    Rising demand in the global citrus market has tested every part of our supply chain. Local climate shifts alter oil composition season to season, compelling technical staff to adapt extraction protocols every harvest. Regulatory bodies tighten purity definitions, calling for continual upgrade in analytics and traceability. Responding to calls for greater transparency, our company adopted full blockchain traceability for all bigarade shipments—so brand purchasers in Singapore or Mexico can chart every movement, from picking to bottling.

    Customer education never stops. Too many formulators get lured by low prices and end up wrestling with off-smells or instability. We regularly host workshops in major industry capitals, sharing sidestream analyses and best-practice paperwork. These direct interactions sharpen our own learning curve, feeding improvements back into process and product—making both the professional’s job easier and the end result more honest.

    We also invest steadily in research, testing new cultivars and extraction methods to expand yield and quality. Several years ago, refining a slow-steam distillation run delivered an unexpected jump in cis oxide content. Now, technicians experiment with enzyme treatments during pressing, tuning for precursor release. Change comes slow, but enhancement repeats: new ideas feed our tradition.

    Delivering on Our Promises

    In chemical manufacturing, trust is hard-earned. Nothing substitutes for batch logs, test panels, and the lived experience that comes from facing crop failure, market flux, or technical surprise. Over years in the field and at the bench, we have learned that real value grows out of that intersection of chemistry and care. Cis-Bigarade Oxide, handled right, helps perfumers, flavorists, and formulators build aroma profiles that carry both memory and promise—clean, bitter, sweet, authentic.

    We stand committed to this tradition, growing from feedback, learning from each season, and delivering a product whose consistent quality reflects every hand along the chain. Among aromatic chemicals, few bear such expectation as bigarade oxide. Fewer still reward the work. We keep at it, one batch at a time.