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2-Octanethiol

    • Product Name 2-Octanethiol
    • Alias Octyl mercaptan
    • Einecs 221-508-2
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    Specifications

    HS Code

    342493

    Cas Number 111-88-6
    Iupac Name Octane-2-thiol
    Molecular Formula C8H18S
    Molar Mass 146.30 g/mol
    Appearance Colorless to yellowish liquid
    Boiling Point 201-203 °C
    Melting Point -70 °C
    Density 0.836 g/mL at 25 °C
    Refractive Index 1.443 at 20 °C
    Flash Point 65 °C (closed cup)
    Solubility In Water Insoluble
    Odor Strong, unpleasant, thiol-like

    As an accredited 2-Octanethiol factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 2-Octanethiol is packaged in a 100 mL amber glass bottle with a tight-sealing cap and a warning hazard label.
    Shipping **Shipping Description for 2-Octanethiol:** 2-Octanethiol is shipped in tightly sealed containers, away from heat and ignition sources. It is classified as a flammable, corrosive, and toxic liquid. Transport must comply with relevant hazardous materials regulations (e.g., DOT, IATA, IMDG) and include appropriate labeling, documentation, and protective packaging to prevent leaks and exposure.
    Storage 2-Octanethiol should be stored in a cool, dry, and well-ventilated area, away from heat sources, open flames, and direct sunlight. Store in tightly closed containers made of compatible materials, and segregate from strong oxidizing agents, acids, and bases. Clearly label the container and ensure spill containment measures are in place to prevent environmental release or health hazards.
    Application of 2-Octanethiol

    Applications of 2-Octanethiol in Industrial Manufacturing

    2-Octanethiol features as a functional alkyl mercaptan in advanced chemical synthesis. Our manufacturing plant supplies this intermediate for tightly regulated, process-driven sectors where controlled reactivity and low-odor characteristics are critical. Below, we outline key industrial application routes, including sector-specific compliance, technical dosage, operational flow, and downstream product targets.

    1. Polymerization Chain Transfer for Specialty Polymers

    Downstream polymer producers utilize 2-Octanethiol as a chain transfer agent in the radical polymerization of acrylate and methacrylate monomers. Its controlled chain-terminating function allows for accurate adjustment of molecular weight and polydispersity in high-performance coatings and adhesives. Compliance requires careful selection according to residual sulfur threshold, as well as strict adherence to emissions and residual monomer standards during processing. Manufacturers must tune the input percentage based on targeted polymer architecture, with our technical service offering detailed integration guidance from raw material feed to downstream extrusion and finishing.

    Industry compliance standards

    • REACH Regulation (EC) No 1907/2006
    • US EPA TSCA compliance
    • China RoHS for specialty polymer coatings
    • ISO 14001 for environmental management of emissions

    Typical usage ratio

    • 0.05%–0.2% by weight of polymerization feed; adjusted by target chain length and monomer reactivity ratio

    Downstream process integration

    • Charged in early reactor stage together with initiator, prior to monomer addition
    • Polymerization in sealed reactors using continuous temperature monitoring
    • Post-polymerization purification to remove excess mercaptan and volatile residues
    • Inline viscosity and molecular weight QC during extrusion or solution formulating

    Final product types

    • UV-curable acrylate coatings
    • Pressure-sensitive adhesive films and tapes
    • High-gloss automotive clear coats
    • Low-migration printing inks

    2. Additive in Lubricant and Metalworking Fluid Formulation

    Industrial lubricant manufacturers use 2-Octanethiol as a chemical extreme pressure (EP) agent and anti-wear additive in both neat oils and water-based metalworking fluids. It provides controlled sulfur functionality for surface passivation under high load, reducing tool wear and frictional heat in precision operations. Procurement must focus on supply with low halogen and trace metal content, and batch-level traceability to ensure downstream blend compliance. Dosage varies based on total sulfur content required by OEM specifications and desired film strength in different operational environments.

    Industry compliance standards

    • ASTM D4951 (additive elements in lubricants)
    • DIN 51502 (classification of lubricating greases)
    • ANSI/AGMA 9005 (industrial gear lubricants)
    • REACH SVHC restriction for workplace exposure

    Typical usage ratio

    • 0.1%–0.5% in finished base oil; increase to 1.0% for high-load, low-speed gear oils, dose is cross-checked against total EP additive balance

    Downstream process integration

    • Blended in with base oils and other additives under mild heating (40–60°C)
    • Vacuum degassing to ensure batch homogeneity and remove volatile residues
    • Compatibility screening with detergents and defoamers via lab-scale pilot runs
    • QC for elemental sulfur analysis and functional EP strength (Four-Ball test)

    Final product types

    • Premium industrial gear oils
    • Water-soluble metal cutting and forming fluids
    • High-performance hydraulic oils
    • Greases for mining and steel plant equipment

    3. Odorant Component in Natural Gas and LPG Distribution

    Major gas utilities and LPG bottlers employ 2-Octanethiol as a sulfur-based odorant for safety detection. With a distinct, identifiable odor threshold and low volatility compared to tert-butyl mercaptan, it supports pipeline leak detection and compliance with public safety mandates. Quality oversight covers purity, oxidation stability, and absence of off-odor byproducts, as mandated by national and regional gas supply codes. Metering equipment must deliver exact ppm-level dosing, routinely verified through in-line analyzers to ensure population safety without regulator trigger overshoot.

    Industry compliance standards

    • EN 549 (gas distribution odorization Europe)
    • 49 CFR Part 192.625 (US Pipeline Safety Regulations for odorization)
    • OIML R140 (international gas meter regulation)
    • GB 50494 (China city gas odorization standard)

    Typical usage ratio

    • 8–50 mg per cubic meter of gas, depending on pipeline length, gas composition, and regional detection sensitivity requirements

    Downstream process integration

    • Injected at main depot before grid distribution using precision dosing pumps
    • Regular sampling and headspace GC analysis for odor concentration verification
    • Documentation and reporting in central SCADA system per regulatory mandate
    • Batch separation of odorant blends to avoid cross-compatibility issues with other materials in the network

    Final product types

    • Odorized city and industrial natural gas
    • Household and commercial LPG cylinders
    • Retail CNG filling station gas
    • Emergency backup gas supplies

    4. Intermediate for Sulfur-Containing Agrochemical Synthesis

    Agrochemical formulators incorporate 2-Octanethiol as a key sulfur donor in the synthesis of selective herbicides and regulated pesticides. The material reacts via alkylation and cyclization routes, forming key intermediates with specific biological functions. Strict management of precursor traceability, heavy metal impurities, and batch analytical certification underlies downstream process approval. Typical process usage includes carefully staged dosing to control exothermicity and sulfur conversion efficiency. Final product performance and stewardship are subject to international and local government approval, with full QC documentation retained at batch and formulation level.

    Industry compliance standards

    • OECD Principles of Good Laboratory Practice (GLP)
    • FAO/WHO International Code of Conduct on Pesticide Management
    • China ICAMA pesticide registration protocols
    • EU PPP Regulation (EC) No 1107/2009

    Typical usage ratio

    • 0.3–1.5 molar equivalents relative to main alkylating agent, adjusted for process yield and side reaction minimization; verified at pilot scale

    Downstream process integration

    • Charged in closed reactor systems, maintained under nitrogen to minimize oxidation
    • Sulfur donor role during cyclization/agro-intermediate synthesis steps
    • Multi-step distillation and solvent exchange for crude purification
    • Analytical confirmation of residual sulfur and absence of odorous byproducts

    Final product types

    • Sulfur-containing herbicide key intermediates
    • Active pesticide ingredient precursors
    • Crop protection agent blends
    • Agrochemical technical grade bulk

    5. Vulcanization Modifier in Rubber Compound Manufacturing

    Leading tire and technical rubber goods factories use 2-Octanethiol as a vulcanization modifier to fine-tune crosslink structure and improve dynamic fatigue resistance. Aliphatic mercaptan introduction allows manufacturers to adjust cure rate and final elastomer flexibility, especially for demanding automotive and industrial sealing applications. Stringent sourcing ensures mercaptan content with narrow sulfur spectrum and exclusion of high-boiling odorants. Rubber chemists determine the concentration through pre-trial batch designs, balancing processing time with end-use mechanical requirements, and verifying through standard stress-strain and fatigue tests.

    Industry compliance standards

    • ISO 9001:2015 for tire/rubber goods manufacturing
    • ASTM D3182 (rubber compounding practices)
    • UNECE R117 (tire performance and rolling resistance)
    • GB/T 2941-2006 (China vulcanized rubber QC)

    Typical usage ratio

    • 0.1–0.7 phr (parts per hundred rubber); determined by curing speed, type of rubber base, and final elastic property requirements

    Downstream process integration

    • Introduced with other curatives into Banbury/closed mixing system
    • Integrated into masterbatch; intensive mixing until dispersion completes
    • Pressed and molded during thermoforming stages
    • Physical properties validated using Mooney viscosity and scorch time QC checks

    Final product types

    • High-performance automobile tires
    • Conveyor and transmission belts
    • Industrial O-rings and automotive gaskets
    • Anti-vibration rubber mounts

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    Certification & Compliance
    More Introduction

    2-Octanethiol – Practical Insights From the Production Floor

    Direct From the Source: What Sets Our 2-Octanethiol Apart

    Daily life in a chemical plant teaches a few essentials about quality and reliability. 2-Octanethiol is no stranger here—its formula, C8H18S, hints at a simple structure, but every batch coming off our line reflects the care we put in at each stage. You won’t find this compound in your local hardware store, but its fingerprint runs through a surprising number of industrial applications, connecting small-scale custom synthesis to large-batch manufacturing in specialty markets.

    We handle 2-Octanethiol in liquid form—clear, sometimes pale yellow, with a pronounced odor characteristic of alkanethiols. Each drum, tank, or vessel that rolls out of our facility carries tight adherence to industry standards for purity. Most commercial users look for purity above 98%, and we aim above that baseline every day. Monitors check for impurities such as octane or disulfides, since even trace carries affect polymerization results or fine chemical production.

    Experience on the Floor: Fine-tuning Purity and Consistency

    2-Octanethiol is not grabbed straight from a reaction pot and thrown into a drum. Drawing from years of on-site troubleshooting, every process step earns attention—starting from selecting the right octanol and ensuring thiolation steps go to completion, to careful distillation and final filtration. Some manufacturers cut corners by using less controlled procedures or skipping purification stages—those shortcuts come back later as customer complaints or process failures. We have found through trial that finishing with precision distillation locks down a tight boiling range, so end users know exactly what’s in the tank.

    For custom or high-spec orders, some users push for 99%+ purity, low moisture, and controlled sulfur content outside the main thiol group. To meet these marks, we examine GC traces for minor byproducts. By running on-site analytics side by side with process teams, feedback is immediate—any deviation goes back for correction, not downstream as a headache. Over the years, this hands-on approach cut our returns and post-sale troubleshooting to near zero.

    Where 2-Octanethiol Leaves Its Mark

    Users come from fields as different as polymer chemistry, fine fragrance, lubricant modification, and electronics. In rubber production, 2-Octanethiol acts as a natural chain transfer agent—balancing out molecular weights in emulsion polymerization systems and keeping the final product predictable. In specialty coatings and adhesives, its reactivity gives chemists a way to tweak surface properties or drive selective reactions not possible with more reactive or branching thiols like tert-dodecanethiol.

    Polymers manufactured using this molecule often show a reliable mix of flexibility and toughness, vital in hoses, seals, and gaskets that see rugged use. Process engineers want a chain transfer agent that doesn’t break down early or react with other additives. We learned early that small shifts in purity or storage make a difference—unfiltered or oxidized material leads to gelation, off-colors, or unpredictable viscosity in finished batches. Years of feedback pushed us to improve both process and packaging—shipped strictly under nitrogen, dry and sealed tight, ready for whatever handling regime is needed further down the supply chain.

    Comparing 2-Octanethiol To Other Alkanethiols

    Length of the carbon chain and the side-group architecture distinguish alkanethiols in industrial use. Customers sometimes ask what sets 2-Octanethiol apart from, for instance, 1-hexanethiol, 1-octanethiol, or tert-dodecanethiol. We’ve run enough comparative trials to see that, while all share that characteristic thiol ‘bite’ and reactivity, targeted differences alter their behavior in practical settings.

    Branching in tert-dodecanethiol slows down its reactivity, making it less prone to runaway reactions in high-radical environments. 2-Octanethiol, with its straight, moderate chain, offers a blend of volatility and manageable reactivity. The boiling point sits high enough for controlled addition—close to 194°C, as measured on the line—with vapor pressure low enough to control emissions and odor. Not all thiols behave this way; 1-hexanethiol is more volatile and can slip through leaks or vents, sometimes causing regulatory headaches or air quality complaints on tightly managed sites. Use 2-Octanethiol, and the plant floor smells less aggressive; the ambient air clears faster.

    Compared to 1-octanethiol, 2-Octanethiol introduces slight differences in where the sulfur group anchors—shifting reaction outcomes subtly in end polymer structures or organic syntheses. Having tested both in lab and production runs, we noticed the shift in properties: chain transfer rates, completed polymer chain lengths, and the compatibility of the end products with additives. Technical staff find these insights most useful when developing new product formulations; sticking to 2-Octanethiol gives a tighter window on both reactivity and storage life, translating to better process control and upfront forecasting.

    Challenges and Solutions: Handling, Storage, and Worker Safety

    No tool in the chemical world is without risk, and thiols get a reputation for odor and handling demands. We learned to respect both the molecular bite and the practical challenges from the start. Uncontrolled exposure leads to strong, lingering odors penetrating workspaces and personal protective equipment. Over the years, our team adopted air filtration, nitrogen-sealed storage, and closed-loop sampling. A packaging line built for thiols, kept oxygen-free, makes a world of difference in everyday operations. Even the maintenance staff, who work behind the scenes fixing pumps or valves, now use seals and gaskets picked to resist permeation—not all elastomers hold up against thiols, and early switchouts kept downtime and accidents at bay.

    Workers in the plant control exposure through a mix of ventilation upgrades and continuous monitoring. Local exhaust hoods, personal air monitors, and a clear culture of reporting keep incidents to a minimum. We found over time that regular equipment audits caught sore spots early—gaskets degrading, storage drum welds failing, or transfer lines picking up small leaks. These are less about regulations on paper and more about protecting the crew clocking in day after day. Those changes, along with annual safety refreshers, translate directly into fewer complaints and a more stable workforce.

    Quality Control Beyond the Spec Sheet

    Delivering exactly what’s promised takes more than specs on a sheet; it comes from experience working through what customers actually need. Many buyers arrive frustrated from inconsistent product deliveries elsewhere. Out of spec? Customers call for late-night guidance and quick resolution; having engineers on the floor who blend lab expertise with real-world troubleshooting bridges the gap. Practical approaches to QC—sampling more lots, checking retention samples against shipped material months later—caught batch drift early.

    Sophisticated GC and NMR methods became part of our routine after discovering they revealed subtle batch-to-batch deviations missed by older titration methods. Most inconsistencies come from byproducts formed in the reaction or changes in feedstock quality. Variant odor profiles, color shifts, or slow formation of disulfide impurities tell more about process drift than a page of test results. Operators and lab techs review these details daily, flag issues fast, and feedback goes straight into the next run.

    Documenting process tweaks means new operators get a running start, while R&D teams know what really happened in each campaign. We keep this record open—a living system improves quality faster than locked paperwork. Viewing it all together, quality does not start at the test bench; it starts with worker training, equipment maintenance, and supplier partnerships built over time.

    Innovation: Responding to Changing Industry Demands

    Across nearly two decades, customer needs evolved alongside regulatory shifts and advances in automation. More sectors demand detailed traceability, cleaner footprints, and greener process inputs. We responded with subtle shifts in solvent recovery and waste treatment—solvent reuse, closed-system loading and unloading, and focused attention on limiting residual sulfur or peroxide formation. Moving to low-odor process improvements let us keep production up in neighborhoods increasingly sensitive to air quality. Small producers sometimes struggle to adapt to these demands, cycling product through outdated systems; our ongoing plant investments in vapor recovery and airtight logistics cut fugitive emissions through a measured, practical approach.

    For the research sector, we field requests for specialty grades—ultra-low metals, narrow-range fractions, or custom-packed quantities. Each variation brings challenges from laboratory setup to pilot-scale synthesis. Experience running kilo lab lines, then scaling to tonnage, makes transitions smooth. Synthetic chemists and formulators get feedback from us in real time—we address shelf life, packaging compatibilities, or cross-contamination issues before they disrupt a production project. In this business, most learning comes hands-on; we draw from failures as much as successes, redesigning systems, changing suppliers, or swapping pumps if the data calls for it. Responsiveness—not a perfect plan in theory—keeps projects moving and customers coming back.

    Environmental Considerations and Process Waste Management

    Manufacturing thiols can generate byproducts prone to strong odors and environmental impact. Over the years, our facility adapted by integrating vapor recovery units at both production and filling lines. That step reduced on-site emissions and cut down the number of odor complaints from surrounding areas. Regulatory pressure spurs improvement, but plant morale benefits even more. Facilities that ignore environmental controls see more turnover and lost production days from upset neighbors or compliance officers.

    Most waste streams carry a mix of unreacted alcohols, sulfides, and minor couplings. We feed these through distillation and scrubbing systems, recycling solvents for other in-plant uses and neutralizing sulfur compounds before offsite shipment. Early in our journey, we learned that sulfur-laden waste in open tanks or unvented spaces creates challenges not only for the plant, but for local air and water utilities. Working with outside waste handlers made sense, but designing in-house pre-treatment gave us a direct view on bottlenecks and the confidence to guarantee cleaner outputs. By continuously upgrading these systems, we turned what was once a burden into a source of process solvents and even modest revenue from reclaimed material.

    The route to cleaner operations isn’t always smooth—each new process tweak can trigger new issues, and audits from internal teams or outside regulators keep us focused. Our operators often suggest modifications, like repositioning vents or adjusting scrubber timing, because their daily experience offers practical fixes that management might overlook. This involvement, plus transparent reporting and open lines for complaint resolution, keeps everyone invested in better outcomes.

    Reliability, Reputation, and Customer Feedback

    Reputation in the chemical business is rarely built on marketing—repeat customers define how well things work on the ground. In our story, every improvement in handling, spec, or documentation came from conversations with plant managers, line chemists, and logistics coordinators. Customers know which suppliers solve problems head-on. Others quietly switch to competitors after the first missed delivery or poor response to a spill or off-spec tank.

    Over hundreds of shipments, we’ve faced challenges from customs delays, temperature swings en route, to last-minute order changes. By maintaining dedicated staff for customer-facing logistics and embedding technical support with the supply chain team, issues get resolved quickly. One memorable incident involved a shipment stuck in port; an old packaging standard failed, leaking odor into a storage yard. Instead of dodging responsibility, we replaced the entire shipment at our own cost, traced the root issue to a missed gasket check during assembly, and rebuilt our QA steps. That event strengthened partnerships with both the customer and the carrier, reminding everyone that ownership of results doesn’t stop at the factory gate.

    In batch-to-batch performance, small inconsistencies stand out even more now that industries rely on digital batch records and validation. Feedback loops run across continents—an out-of-spec sample at a customer’s Asian site often prompts a midnight call to our US plant. Processes evolved so that anyone on our team, from senior chemists to shift supervisors, understands the customer process enough to field real-world questions. Most buyers don’t want another brochure—they want to know someone’s listening on the other end, with the authority and experience to solve the issue now, not at some later quarterly review.

    Training and Upgrading Skills on the Shop Floor

    Worker skills turn new hires into reliable operators—processing a volatile, high-odor compound like 2-Octanethiol is not a textbook exercise. We invest in tight training cycles; new staff shadow veterans, learning not just which valves to turn but what each sound or smell means during a run. Recognizing the subtleties—how a slight sweet note in odor might mean an upstream equipment leak, or how a temperature spike flags imminent polymerization—comes only from months on task. By signing off on each training phase, operators take direct ownership of plant safety and quality.

    Software upgrades and automation systems make life easier, but old-school senses still matter most in our world. The best operators routinely outperform sensors by catching drifts or anomalies early. Management supports further education, sending techs and engineers to outside courses on process safety, analytical chemistry, and regulatory compliance. Cross-training builds flexibility; if a regular operator misses a shift, the next up keeps the process stable without disruption. Years without a lost-time incident or batch recall aren’t luck—they’re earned by hands-on investment in the next generation of plant crew.

    Beyond Batches: Relationships with Raw Material Suppliers

    Experience taught us that every finished drum of 2-Octanethiol starts years before in the selection of alcohol and sulfur donors. Raw material quality, pricing stability, and supply reliability decide margins and process windows. We maintain direct relationships with both small specialty feedstock suppliers and major chemical producers, staying ahead of market swings or disruptions. Unannounced spot checks on incoming feedstocks caught more than one instance of contamination or incorrect blends, helping us head off processing failures and warranty claims.

    These supplier partnerships run deeper than price. During industry shortages or logistic bottlenecks, longstanding relationships meant first-in-line access on critical inputs. New feedstocks go through qualification trials—sometimes we see subtle differences in odor carryover, water content, or minor constituents, which only show up after several production runs. This learning, shared back with suppliers, shapes their tightening of upstream specs and transparency. Our approach: treat suppliers like process partners, not just vendors, so their buy-in grows alongside our own process control targets.

    Sustainability: Addressing a Greener Tomorrow

    Sustainability isn’t a slogan here; every choice from solvent use to energy inputs matters when local agencies and downstream customers demand real results. This includes switching over to low-emission boiler systems, using less harsh cleaning protocols, and closing the loop on water waste from our thiol production lines. On-site renewable projects contribute to offsetting power usage. Batch documentation now records water, energy, and emissions metrics alongside traditional production data, letting us forecast improvements realistically with each process adjustment.

    The shift toward sustainable manufacturing benefited more than the bottom line. Workshops and open forums give process engineers and front-line operators a chance to suggest process improvements. Ideas like heat recovery loop installation, adjusting cleaning schedules to match demand, or switching to eco-friendlier secondary packaging have all come from staff input. By involving the team and tying bonuses to actual savings (not papered-over projections), every operator becomes part of the sustainability drive.

    Summary of Real-World Applications: What 2-Octanethiol Means For End Users

    Users from adhesives, plastics, and fine chemicals expect smooth integration and predictable performance. 2-Octanethiol delivers in fields where chain transfer agents or sulfur nucleophiles must perform reliably across changing input feeds and environmental controls. In plastics—think seals, tubes, flexible goods—fine-tuning molecular weight and elasticity delivers measurable advantages. Makers of specialty resins and coatings look for a consistent signature in product lots; 2-Octanethiol’s profile, honed by feedback and internal QC, reduces variability and rejects.

    For emerging applications, such as functionalized nanomaterials or surface coatings in electronics, practical know-how allows custom batch sizing, tight purity windows, and open conversation about new process requirements. Chemists developing pilot plant projects often expect more direct answers about how storage, handling, or subtle ingredient drift might influence their results. Our experience feeds into advisory support—direct plant advice, not generic FAQ responses—closing the loop from molecule-making to end product integration.

    Ultimately, 2-Octanethiol brings together decades of hard-won experience, continuous process improvement, and customer-driven innovation. As a manufacturer, we know the real measure of quality is what end users achieve with every delivered drum—from the first drop poured into a polymerization reactor to the final performance on the project line. That’s the ground-level story of 2-Octanethiol’s place in industry, carried forward by knowledge on both sides of the production line.