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Product Name: Pramirofen
Chemical Formula: C16H13NO2
Chemical Family: Benzamide derivative
Intended Use: Herbicide for select crop protection applications
Manufacturer Information: Supplied by licensed agrochemical companies, contact available on product packaging
Emergency Contact Number: Provided on accompanying product literature and local regulatory bodies
Hazard Classification: Acute toxicity (oral, dermal, inhalation), skin and eye irritant, possible reproductive hazard
Signal Word: Warning
Hazard Pictograms: Corrosive, exclamation mark, environment
Routes of Exposure: Inhalation, skin contact, ingestion, eye contact
Potential Health Effects: Eye redness or tearing, skin irritation, headache or respiratory discomfort upon inhalation, nausea or upset stomach if ingested
Environmental Effects: Toxic to aquatic life, may cause long-term adverse effects to aquatic environments
Main Component: Pramirofen
CAS Number: 123-45-6
Concentration: Technical concentrate typically ≥95%
Impurities: No hazardous impurities above regulatory disclosure limits
Solvents or Fillers: Formulations may contain nonhazardous carriers or suspending agents
Inhalation: Move to fresh air, keep comfortable for breathing; seek medical attention if symptoms continue
Skin Contact: Remove contaminated clothing, wash skin with mild soap and water, seek medical attention for irritation or discomfort
Eye Contact: Flush with cool water for at least 15 minutes, remove contact lenses if present, obtain medical assistance
Ingestion: Rinse mouth, offer water if person is alert, do not induce vomiting, contact poison control or seek immediate medical help
Immediate Care: Emergency decontamination recommended for large exposures
Suitable Extinguishing Media: Water spray, foam, dry chemical, carbon dioxide
Unsuitable Extinguishing Media: Strong water jets may spread contamination
Specific Hazards: Combustion can release toxic fumes including nitrogen oxides, carbon monoxide, carbon dioxide
Protective Equipment: Firefighters should wear full protective gear, self-contained breathing apparatus
Special Procedures: Contain run-off from fire control to prevent entry into waterways
Personal Precautions: Wear suitable gloves, goggles, protective footwear, avoid direct contact
Environmental Precautions: Prevent entry into drains, sewers, and water bodies
Clean-Up Procedures: Sweep up spills and place waste into labeled containers for proper disposal; wash area with detergent and water; ventilate area
Disposal: Dispose collected material according to local regulations
Safe Handling Practices: Use only in well-ventilated areas, avoid generating dust, keep away from food and drink, wash hands before breaks and after use
Storage Requirements: Store in tightly closed, clearly labeled containers; keep cool, dry, away from sources of ignition, incompatible materials, and direct sunlight
Other Instructions: Keep away from children, pets, and unauthorized personnel
Engineering Controls: Use local exhaust ventilation to control exposure in confined spaces
Personal Protective Equipment: Impervious gloves, long-sleeved protective clothing, safety goggles or face shields, and, if dust develops, appropriate respirators
Hygiene Measures: Do not eat, drink, or smoke while using this product; wash thoroughly after handling
Monitoring: Regular monitoring for airborne concentration may assist in keeping exposure below recommended limits
Appearance: White to off-white crystalline solid
Odor: Faint characteristic or odorless
Melting Point: 128–135°C
Boiling Point: Not easily decomposed before boiling
Density: Approximately 1.2 g/cm³
Solubility: Slightly soluble in water, soluble in organic solvents
Vapor Pressure: Very low at room temperature
pH: Neutral to slightly basic in suspension
Flash Point: Not applicable due to high melting point
Chemical Stability: Stable under recommended storage conditions
Reactivity: Non-reactive under normal use, avoid strong acids and bases
Conditions to Avoid: Excessive heat, open flame, prolonged exposure to light
Incompatible Materials: Strong oxidizing agents, reducing agents
Hazardous Decomposition Products: Carbon oxides, nitrogen oxides upon combustion
Acute Toxicity – Oral: LD50 (rat) between 500–2000 mg/kg
Acute Toxicity – Dermal: LD50 (rabbit) above 2000 mg/kg
Inhalation Toxicity: Limited inhalation risk due to low volatility
Carcinogenicity: Not classified as carcinogenic according to current data
Reproductive Effects: Animal studies suggest possible developmental effects at high exposures
Other Effects: Prolonged or repeated contact may cause skin dryness or cracking
Ecotoxicity: Highly toxic to fish and aquatic invertebrates; risk of bioaccumulation in aquatic systems
Persistence and Degradability: Moderately persistent in soil; slow biodegradation under certain conditions
Mobility in Soil: Moderate; potential to reach groundwater if not managed properly
Other Adverse Effects: Large spills may negatively impact soil and water ecosystems
Waste Disposal Methods: Dispose of in compliance with local, regional, and national regulations; incineration preferred over landfill
Packaging Disposal: Rinse thoroughly, render unusable, and send to licensed reprocessors
Avoidance: Do not allow product, rinse water, or containers to enter drains, surface water, or groundwater
Contaminated Materials: Treat as hazardous waste
UN Number: 3077
UN Proper Shipping Name: Environmentally hazardous substance, solid, n.o.s. (Pramirofen)
Transport Hazard Class: 9
Packing Group: III
Transport Precautions: Protect from physical damage, moisture, and high temperatures during transit
Labeling: Environmentally hazardous substance symbol required
Special Precautions: Transport according to local and international hazardous materials regulations
Classification: Classified as hazardous according to GHS and relevant national legislation
Inventory Status: Listed on relevant chemical regulatory inventories
SARA Title III: Not listed under Section 313
REACH Registration: Manufacturer or supplier fulfills all relevant registration duties
Other Regulations: Follow provisions under local environmental, health, and workplace safety laws
