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Mesitylene: What You Need to Know About Its Safety Sheet

Identification

Chemical Name: Mesitylene
Chemical Formula: C9H12
Synonyms: 1,3,5-Trimethylbenzene
Common Use: Solvent, intermediate in chemical synthesis
Appearance: Colorless liquid with aromatic odor
CAS Number: 108-67-8

Hazard Identification

GHS Classification: Flammable liquid, Eye irritant, Harmful to aquatic life
Signal Word: Warning
Hazard Statements: Highly flammable liquid and vapor, Causes mild eye irritation, May cause drowsiness or dizziness, Toxic to aquatic life with long lasting effects
Routes of Exposure: Inhalation, skin contact, eye contact, ingestion
Label Pictograms: Flame, Exclamation mark, Environment

Composition / Information on Ingredients

Component: 1,3,5-Trimethylbenzene (Mesitylene)
Concentration: Typically 99% or higher in commercial products

First Aid Measures

Inhalation: Move person to fresh air, keep at rest, seek medical help if breathing becomes difficult
Skin Contact: Remove contaminated clothing, wash skin thoroughly with soap and water
Eye Contact: Rinse carefully with water for several minutes, remove contact lenses if present, continue rinsing, seek medical advice if irritation persists
Ingestion: Rinse mouth, do not induce vomiting, seek medical attention

Fire-Fighting Measures

Fire Hazards: Forms explosive mixtures with air, vapors spread along ground and ignite at distance
Suitable Extinguishing Media: Foam, dry chemical powder, carbon dioxide, water spray
Unusual Fire Hazards: Container can rupture or explode under intense heat
Protective Equipment: Firefighters use self-contained breathing apparatus and protective gear

Accidental Release Measures

Personal Precautions: Evacuate area, keep away from sources of ignition, ventilate area
Environmental Precautions: Prevent spillage from entering drains or waterways
Cleanup Methods: Contain spill with inert absorbent material like sand, collect in sealed container for disposal, use non-sparking tools

Handling and Storage

Safe Handling: Use only outdoors or in a well-ventilated space, keep away from flames or anything that creates sparks, avoid breathing vapor, prevent static discharge
Storage Requirements: Store in tightly closed containers, out of sunlight, in cool dry areas, keep away from oxidizers and acids, ground storage containers to prevent static

Exposure Controls and Personal Protection

Permissible Limits: Avoid exceeding recommended workplace exposure limits based on local regulations
Engineering Controls: Use local exhaust or explosion-proof ventilation to keep vapor below limits
Personal Protection: Wear chemical safety goggles, chemical-resistant gloves, flame-resistant clothing, and approved respirator for vapor
Hygiene Measures: Wash hands thoroughly post-use, do not eat, drink, or smoke while handling

Physical and Chemical Properties

Physical State: Liquid
Color: Colorless
Odor: Distinct aromatic scent
Boiling Point: About 164°C
Melting Point: -44°C
Flash Point: Around 48°C (closed cup)
Vapor Pressure: Roughly 1.3 kPa at 20°C
Solubility: Insoluble in water, mixes with organic solvents
Density: About 0.864 g/cm³ at 20°C

Stability and Reactivity

Stability: Stable under normal conditions, sensitive to strong oxidizing agents
Incompatible Materials: Strong acids, peroxides, oxidizers
Hazardous Reactions: May form peroxides on extended exposure to air
Decomposition Products: Carbon monoxide, carbon dioxide, other aromatic compounds during burning

Toxicological Information

Acute Toxicity: Minimal toxicity on short-term exposure; high vapor levels may irritate respiratory tract and cause drowsiness
Skin and Eye Irritation: Repeated or prolonged skin exposure may cause dryness, redness, mild eye irritation
Chronic Exposure: Long-term inhalation could affect liver and kidneys
Sensitization: No clear evidence
Other Risks: No proven human carcinogenicity with mesitylene, though long-term health data remain limited

Ecological Information

Aquatic Toxicity: Harmful to aquatic organisms with potential for long-lasting effects
Persistence: Does not easily degrade in water or soil
Bioaccumulation: May accumulate in aquatic life
Mobility: Low mobility in soil, but floats on water surface

Disposal Considerations

Waste Disposal: Consult local, regional, and national regulations for incineration or chemical waste treatment
Packaging: Empty containers can hold residue fumes, handle with care, recycle if possible, avoid direct disposal in environment

Transport Information

UN Number: 3295
Proper Shipping Name: Hydrocarbons, liquid, n.o.s. (Mesitylene)
Hazard Class: 3 (Flammable Liquids)
Packing Group: III
Transport Precautions: Keep containers upright and secured, transport in covered vehicles, shield from sources of heat

Regulatory Information

Labeling Requirements: Follow flammable liquid and harmful substance symbols
Workplace Restrictions: Subject to national chemical safety and workplace hazard regulations
Environmental Protection: Includes restrictions on discharge to water and requirements for air emissions control
Community Right-to-Know: Listed in many national chemical inventories, reported as part of community hazard communication programs