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Product Name: Fluorazole
Chemical Family: Heterocyclic azole derivative
CAS Number: 1234-56-7
Synonyms: Fluoroazole, Flz, 5-Fluorotriazole
Recommended Use: Industrial synthesis, laboratory reagent
Manufacturer: ChemAdvance Solutions
Emergency Contact: +1-800-555-0110
GHS Classification: Acute Toxicity – Oral (Category 3), Skin Irritation (Category 2), Eye Damage (Category 1), Specific Target Organ Toxicity – Single Exposure (Category 3)
Signal Word: Danger
Hazard Statements: Toxic if swallowed, causes serious eye damage, may cause respiratory irritation, causes skin irritation
Pictograms: Skull and crossbones, exclamation mark, corrosion
Precautionary Statements: Avoid breathing dust or fumes, wear protective gloves and eye/face protection, wash hands thoroughly after handling, do not eat or drink while using the product
Chemical Name: 5-Fluorotriazole
CAS Number: 1234-56-7
Purity: >97%
Impurities: Traces of unreacted fluorinated precursors (<2%)
Additives: None known
Other Identifiers: Molecular formula C2HFN3, molecular weight 87.05 g/mol
Inhalation: Move to fresh air immediately. Seek urgent medical attention if symptoms like dizziness, coughing, or shortness of breath persist.
Skin Contact: Remove contaminated clothing and rinse skin thoroughly with plenty of water for at least 15 minutes. Seek medical help for irritation or burns.
Eye Contact: Rinse cautiously with water for several minutes, lifting eyelids to ensure thorough irrigation. Urgent medical aid required.
Ingestion: Rinse mouth. Do not induce vomiting. Give water if conscious. Contact a poison center or doctor right away.
Important Symptoms: Burning sensation, headache, shortness of breath, abdominal pain
Suitable Extinguishing Media: Use water spray, foam, dry chemical, or carbon dioxide.
Specific Hazards: Emits toxic fumes containing hydrogen fluoride and nitrogen oxides when burning.
Special Protective Equipment: Firefighters require self-contained breathing apparatus and full protective gear.
Firefighting Advice: Avoid water runoff entering drains and watercourses. Cooling exposed containers with water spray helps reduce risk of thermal decomposition.
Combustion Products: Hydrogen fluoride, nitrogen oxides
Personal Precautions: Wear respirator, protective goggles, gloves, and body covering.
Environmental Precautions: Prevent material from entering sewers, waterways, or soil.
Cleanup Procedures: Ventilate area, use inert absorbent material (sand or vermiculite) to contain spill, carefully transfer to labelled waste container for disposal.
Decontamination: Wash spill area with detergent and water.
Emergency Measures: Evacuate unprotected personnel from area
Safe Handling: Employ proper ventilation, avoid breathing dust and fumes, keep away from food and beverages, use only in chemical fume hoods.
Storage Conditions: Keep container tightly closed in a cool, dry, well-ventilated place. Separate from oxidizing agents or acids.
Incompatible Materials: Strong acids, bases, oxidizers
Packaging Materials: Store in tightly-sealed polyethylene or glass containers
Hygiene Requirements: Remove contaminated clothing, wash hands before breaks and at end of work
Engineering Controls: Local exhaust ventilation recommended, safety showers and eyewash stations necessary in proximity.
Exposure Limits: No established occupational exposure limits; minimize exposure as much as possible.
Respiratory Protection: Use NIOSH-approved respirators for nuisance levels, or full-face respirators for higher concentrations.
Skin Protection: Chemical-resistant gloves (nitrile or neoprene), lab coat or coveralls
Eye Protection: Tight-sealing goggles plus face shield
Other PPE: Avoid open-toed shoes, use protective boots if spill risk exists
Appearance: White to off-white crystalline powder
Odor: Slightly pungent
Odor Threshold: Not determined
pH: 6.5 (1% aqueous solution)
Melting Point: 142–145°C (288–293°F)
Boiling Point: Decomposes before boiling
Flash Point: Non-flammable under standard conditions
Evaporation Rate: Not applicable
Flammability: Not inherently flammable
Vapor Pressure: Negligible at room temperature
Vapor Density: Not determined
Solubility: Soluble in water (35 g/L), soluble in ethanol
Partition Coefficient (n-octanol/water): Log Kow: -0.37
Auto-Ignition Temperature: Not established
Decomposition Temperature: >160°C
Viscosity: Not applicable
Chemical Stability: Stable under recommended storage and handling conditions
Incompatible Substances: Strong oxidizers, acids, halogenating agents
Hazardous Decomposition Products: Hydrogen fluoride, nitrogen oxides, possibly toxic fluorinated compounds
Risk of Hazardous Reactions: Risk of exothermic reactions with acids or strong oxidants
Conditions to Avoid: Exposure to heat, moisture, direct sunlight, sources of ignition
Polymerization: Not known to polymerize
Acute Toxicity: Oral LD50 (rat): 37 mg/kg
Skin Corrosion/Irritation: Causes skin irritation on contact (rabbit, OECD 404)
Eye Damage/Irritation: Causes serious eye damage (rabbit, OECD 405)
Respiratory Sensitization: May cause respiratory irritation and cough at elevated exposure
Skin Sensitization: Not classified as skin sensitizer
Chronic Effects: Prolonged exposure can damage liver, kidneys, and respiratory system
Mutagenicity/Carcinogenicity: No definitive data available
Reproductive Effects: Animal studies suggest no reproductive toxicity
Ecotoxicity: Highly toxic to aquatic life (96h LC50 for fish: 3.2 mg/L)
Persistence and Degradability: Moderately persistent, may not rapidly degrade in the environment
Bioaccumulative Potential: Low potential, due to low Kow value
Mobility in Soil: High mobility in water, risk of leaching to groundwater
Other Adverse Effects: Strong caution recommended around waterways, can cause long-term adverse effects in aquatic environments
Waste Disposal Methods: Treat as hazardous; incinerate at high temperature in permitted facility, avoid landfill use.
Container Disposal: Decontaminate container, then puncture and dispose according to local, regional, national regulations.
Special Precautions: Prevent release to environment, never mix with household waste
Regulatory Status: Subject to EPA and local hazardous waste requirements
UN Number: UN 2811
UN Proper Shipping Name: Toxic solid, organic, n.o.s. (contains 5-Fluorotriazole)
Transportation Hazard Class: 6.1 (Toxic substances)
Packing Group: II
Marine Pollutant: Yes
Label: Toxic, environmentally hazardous
Special Transport Notes: Keep shipments well-sealed, segregate from incompatible materials during transport
OSHA Hazard Communication: Classified hazardous under 29 CFR 1910.1200
TSCA Status: Listed
SARA Title III: Section 313: Not listed
California Proposition 65: Not listed
REACH Regulation (EU): Subject to restrictions, seek updated Annexe XVII compliance reports
Canadian DSL/NDSL: Included, restricted for certain uses
Other Regulations: Requires specific risk management procedures at workplace; regular training for handlers is enforced by national and state authorities
